• Title/Summary/Keyword: Fe-N/C

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Effects of catalyst pretreatment on structural and field emissive properties of carbon nanotubes synthesized by ICP-CVD method (ICP-CVD 방법으로 합성된 탄소 나노튜브의 구조적 물성 및 전계방출 특성에 촉매의 전처리 공정이 미치는 영향)

  • Hong, Seong-Tae;Park, Chang-Kyun;Park, Jin-Seok
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.1862-1864
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    • 2005
  • Carbon nanotubes [CNTs] are grown on TiN-coated Si substrates at $700^{\circ}C$ by inductively coupled plasma-chemical vapor deposition (ICP-CVD). Pre-treatment of Ni catalysts has been performed using an RF magnetron sputtering system. Structural properties and field-emission characteristics of the CNTs grown are analyzed in terms of the RF power applied and the treatment time used in the pre-treatment process. The characterization using various techniques, such as FE-SEM, AFM, and Raman spectroscopy, show that the physical dimension as well as the crystal quality of CNTs are changed by pre-treatment of Ni catalysts. It is also seen that Ni catalysts with proper grain size and uniform surface roughness may produce much better electron emission. The physical reason for all the measured data obtained are discussed to establish the relationship between the structural property and the electron emission characteristic of CNTs.

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Studies on the forming limits for optimization of the tool path in Dieless incremental sheet metal forming (무금형 점진 판재 성형에서 공구경로 최적화를 위한 성형한계에 관한 연구)

  • Lee S. J.;Kim M. C.;Lee Y. S.;Kwon Y. N.;Lee J. H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.249-252
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    • 2005
  • Recently, as the industrial demand for small quantity batch production of sheet metal components, the application of dieless forming technology to production of these component rise with the advantages of the reduction in manufacturing cost and time. In dieless forming processes, the determination of moving path of tool plays an important role in producing successfully formed parts. In order to obtain the optimized moving path of tool avoiding forming failure, it is necessary to examine the forming limit of sheet material. Therefore, in this study, as the new criterion to evaluate the formability of sheet material in dieless forming processes FDD(feeding depth diagram) with respect to feeding depth and punch diameter is proposed. Thus, the FDD for the sheet materials of STS304 and Ti-grade2 were obtained from a series of FDT(feeding depth test). In addition the possibility of the application of FLD in judging forming severity in dieless forming processes was investigated by comparing the results of FE analyses based on FLD and experimental FDT.

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High Temperature Wear of STD 61 Tool Steels Sliding Against Al-9%Si Coated Steels Used for Hot Press Forming (STD 61 공구강과 상대재인 핫 프레스 가공용 Al-9%Si 코팅강의 고온 미끄럼 마모)

  • Choi, Byung-Young;Kim, Hong-Ki
    • Korean Journal of Metals and Materials
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    • v.47 no.10
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    • pp.667-674
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    • 2009
  • High temperature wear of STD 61 tool steels sliding against the Al-9%Si coated steels used for hot press forming has been studied in comparison with that of the tool steels sliding against the uncoated steels. Wear tests have been performed using a pin-on-disc configuration under an applied normal load of 50N for 20 min with heating the coated and uncoated steels up to 800$^{\circ}C$. It was found on the worn surface of the STD 61 tool steels sliding against the Al-9%Si coated steels that the formation of the glazed layers containing Al transferred from the coated tribopair may contribute to a reduction of the coefficient of friction, and detachment in part occur due to delamination wear, resulting in higher specific wear rate. On the other hand the Fe-oxide wear debris entrapped on the softer surface of the uncoated steels can act as a tribosurface, leading to decreased adhesive wear of the STD 61 tool steels, resulting in a lower specific wear rate.

Analysis of Microstructure Evolution using Different Powder Metallurgy Process in Ti-X Alloy System (Ti-X계 합금의 분말야금 공정 차이에 따른 미세조직변화 분석)

  • Kwon, Hyeok-Gon;Kim, Doo-Hyeon;Gang, Min;Park, Ji-Hwan;Oh, Myung-Hoon
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.1
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    • pp.17-24
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    • 2021
  • In this study, Ti-X (X=Mn, Fe, Mo) powder alloys were designed and manufactured by both powder metallurgy (PM) and metal powder injection molding (MIM) process to improve strength and formability compared to CP-Ti powder materials. It was found that the lamellar microstructure consisted of α and β phases was formed in PM-processed alloys. However, MIM-processed alloys showed not the lamellar microstucture but the equiaxed α + β microstructure. It was also revealed that the contents of X component and feedstock were not affected to microstructure evolution. The reason why different microstructure was appeared between PM-processed and MIM-processed alloys is not clear yet, but supposed to be the effect of intersticial elements such as C, H and N derived from feedstock during debinding process of MIM.

Parametric study on the structural behaviour of composite slim floors with hollow-core slabs

  • Spavier, Patricia T.S.;Kataoka, Marcela N.;El Debs, Ana Lucia H.C.
    • Computers and Concrete
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    • v.28 no.5
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    • pp.497-506
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    • 2021
  • Steel-concrete composite structures and precast concrete elements have a common prefabrication process and allow fast construction. The use of hollow-core slabs associated with composite floors can be advantageous. However, there are few studies on the subject, impeding the application of such systems. In this paper, a numerical model representing the considered system using the FE (finite element)-based software DIANA is developed. The results of an experimental test were also presented in Souza (2016) and were used to validate the model. Comparisons between the numerical and test results were performed in terms of the load versus displacement, load versus slip, and load versus strain curves, showing satisfactory agreement. In addition, a wide parametric study was performed, evaluating the influence of several parameters on the behaviour of the composite system: The strength of the steel beam, thickness of the web, thickness and width of the bottom flange of the steel beam and concrete cover thickness on top of the beam. The results indicated a great influence of the steel strength and the thickness of the bottom flange of the steel beam on the capacity of the composite floor. The remaining parameters had limited influences on the results.

Structural and Electrical Properties of Nickel Hydroxide Electrode Prepared by Hydrothermal Synthesis on Nickel Foam (니켈 폼(Ni foam)에 수열 합성법으로 제조한 수산화니켈(Ni(OH)2) 전극의 구조적 및 전기적 특성)

  • Hyunjin Cha;Seokhee Lee;Jeonghwan Park;Young-Guk Son;Donghyun Hwang
    • Journal of the Korean institute of surface engineering
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    • v.56 no.5
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    • pp.320-327
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    • 2023
  • In this study, the nickel hydroxide (Ni(OH)2) electrode for supercapacitor was prepared via hydrothermal method. Based on the nickel (Ni) foam, the electrode does not require any additional binder material or post-processing. Nickel nitrate (Ni(NO3)2) and hexamethylenetetramine (C6H12N4) were used for synthesis, and the synthesis condition was 12 hours at 80 ℃. X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) were used to analyze the structural characteristics of the electrode, and it shown that the nickel hydroxide was successfully prepared after only the one-step hydrothermal synthesis. The electrochemical properties were analyzed through the half-cell test. The prepared electrode shown a pair of oxidation/reduction peaks, indicating that the driving method included the redox reaction on the electrode surface. After the charge/discharge test, the specific capacitance was calculated as the value of 438 F/g at 3 A/g.

Verification of CE-QUAL-W2 Eutrophication Model in Daecheong Reservoir (대청호에서 CE-QUAL-W2 부영양화 모델의 검증)

  • Cha, Yoon-Cheol;Chung, Se-Woong;Lee, Heung-Soo;Oh, Dong-Geun;Ko, Ick-Hwan
    • Proceedings of the Korea Water Resources Association Conference
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    • 2009.05a
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    • pp.1698-1702
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    • 2009
  • 효과적인 저수지 수질관리를 위해서는 신뢰도 높은 수리 및 수질모델이 필요하며, 이러한 모델의 성능은 다양한 수문사상에 대하여 적용함으로써 검증할 수 있다. CE-QUAL-W2 모델(이후 W2)은 횡방향 평균 2차원 수리 수질 해석 모델로써 수체의 길이에 비해 폭이 상대적으로 좁고 수심이 깊은 우리나라 대부분의 저수지 지형에 적합한 모델이다. 본 연구의 목적은 기존 연구에서 가뭄년인 2001년과 평수년인 2004년 수문사상에 대하여 보정한 대청호 W2 부영양화모델을 최근 평수년인 2006년과 가뭄년인 2008년을 대상으로 검증하는데 있다. 모델의 검증은 물수지, 수온성층 구조 변화, 부영양화 해석에 중점을 두었으며, 실측자료와 모의결과의 적합성 비교 평가는 결정계수값$(R^2)$, AME(absolute mean error)와 RMSE(root mean square error)를 이용하였다. 저수지 물수지의 적합성을 검증하기 위하여 모의수위와 실측수위를 비교한 결과, $R^2$값이 2006년과 2008년에 각각 0.9945, 0.9972로 나타나 신뢰도가 높은 것으로 확인되었다. 계절별 성층구조 변화 모의 성능을 검증하기 위해 회남수역과 댐 앞 지점에서 수심별 수온의 모의값과 실측값을 비교하였다. 2006년의 경우 모델은 홍수기 동안 안정적으로 수온 성층현상을 모의하였으나, 댐 앞 지점에서 수온 약층이 형성된 구간에서 실측값과 다소 편차를 보였으며, 오차크기는 AME가 $0.561\sim2.088^{\circ}C$, RMSE는 $0.797\sim2.762^{\circ}C$범위였다. 반면, 가뭄년인 2008년에는 전 기간에 걸쳐 모두 안정적으로 저수지 수온 성층현상을 모의하였으며, 오차크기는 AME $0.413\sim1.162^{\circ}C$, RMSE $0.546\sim1.415^{\circ}C$ 범위였다. 조류의 생산성이 높은 표층에서 T-N, T-P 및 Chl-a 농도 모의결과를 장계교, 대정리, 회남대교, 댐 앞, 추동취수탑 및 문의취수탑에서 시계열로 실측값과 비교 검증한 결과, T-N과 T-P는 2006년과 2008년 모두 모든 비교 지점에서 모의값과 실측값의 시계열 변동이 매우 잘 일치하였으며, 홍수기 이외 기간에는 큰 변동 폭을 보이지 않았다. 그러나 기존 연구에서 확인된 바와 같이 7월 이후부터 T-P 모의값이 실측값을 과대 산정하는 경향을 보였는데, 그 원인은 산소 결핍상태에서 저니층에서 용출되는 철(Fe) 또는 망간(Mn)과 같은 이온 성분이 인과 흡착하여 침전되는 기작이 모의과정에 적절히 반영되지 않은 것이 원인으로 판단된다. 조류(Chl-a)농도의 경우, 2006년과 2008년에 모든 지점에서 모델은 조류의 발생과 시계열 변화를 적절히 모의하였으나, 2008년 1월부터 8월까지 댐 앞과 추동 및 문의취수탑에서는 모의값이 실측값을 과대 산정하는 경향을 보였다. 이는 해마다 그리고 계절별로 우점하는 조류 종이 상이한 반면, 모델에서는 이에 대한 매개변수를 적절히 고려하지 못한 것이 원인으로 판단된다.

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Meat Quality and Nutritional Properties of Hanwoo and Imported New Zealand Beef (한우고기와 뉴질랜드산 냉장수입육의 육질 및 영양성분 비교)

  • Cho, Soo-Hyun;Kang, Geun-Ho;Seong, Pil-Nam;Park, Beom-Young;Jung, Seok-Geun;Kang, Sun-Moon;Kim, Young-Chun;Kim, Ji-Hee;Kim, Dong-Hun
    • Food Science of Animal Resources
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    • v.31 no.6
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    • pp.935-943
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    • 2011
  • This study was conducted to investigate the proximate composition, meat color, Warner-Bratzler shear force (WBS), cooking loss (CL), fatty acids composition, amino acid composition and mineral contents of Hanwoo beef (QG $1^+$, 1) and imported New Zealand black Angus beef with loin, strip loin, eye of round and chuck tender. The intramuscular fat contents were higher in the strip loin, loin and chuck tender of Hanwoo beef than New Zealand beef (p<0.05). Hanwoo QG 1 beef had higher Fe contents in the strip loin (30.52 mg/100g) and chuck tender (40.70 mg/100g) (p<0.05). Hanwoo beef had lower cooking loss and than those of New Zealand beef, whereas New Zealand beef had higher protein and amino acids contents (%) than their counterpart. There was no significant difference in the WBS between two origin samples except the chuck Hanwoo beef had significantly lower saturated fatty acids (SFA) and higher monounsaturated fatty acids contents than New Zealand beef (p<0.05). WBS values indicated that Hanwoo and New Zealand beef had similar tenderness in the loin, striploin and eye of round due to the longer aging periods of the New Zealand beef than Hanwoo beef during the distribution.

The Study on the Additives and Magnetic Property of YIG Ferrites for Circulator/Isolator (서큘레이터/아이솔레이터용 YIG 페라이트의 첨가제와 자기적 특성 연구)

  • 윤휘영;유승규;이수형;윤종남;김정식
    • Journal of the Korean Ceramic Society
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    • v.38 no.12
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    • pp.1155-1161
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    • 2001
  • Yittrium Iron Garnet(YIG) has been used as an important material in the circulator/isolator which is used in RF communication system, mobile phone, adn satellite broadcasting, etc. In this study, we investigated the microstructural and magnetic properties of YIG ferrites with the sintering temperature and additives. We fabricated the YIG ferrites substituted with Ca, In, V by the traditional ceramic sintering method at 1250$\^{C}$, 1275$\^{C}$, 1300$\^{C}$ and 1325$\^{C}$. Powders were granulated by using a spray dryer. Crystallographic and microstructural properties were measured by using XRD and SEM. Magnetic properties were measured by using a VSM for saturation magnetization (4$\pi$M$\_$s/) and FMR (Ferromagnetic Resonance) experiment for ferromagnetic resonance line width (△H). The YIG ferrite, Y$\_$1.6/Ca$\_$1.4/Fe$_4$V$\_$0.7/In$\_$0.3/O$\_$12/, sintered at 1300$\^{C}$, showed higher saturation magnetization and lower ferromagnetic resonance line width than any other sintering temperatures.

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Pollutant Contents with Particle Size Distribution in Bridge Road Drainage Sediment (교량도로 배수받이 퇴적물질의 입경별 오염물질 함량)

  • Lee, Jun-Ho;Cho, Yong-Jin;Bang, Ki-Woong
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.12
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    • pp.1360-1365
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    • 2007
  • The purpose of this study is to present the basic data for nonpoint pollutant loads from bridge road drainage sediments using the results to analyze organic matter and heavy metals from the four bridge drainage sampling sites with sediments of different particle size ranges. The sediment sample was collected from the bridge road drainage and the masses of nine sediments fractions were obtained after drying the separated sediment in an over at $85^{\circ}C:>2,000{\mu}m$, $1,000\sim2,000{\mu}m$, $850\sim1,000{\mu}m$, $425\sim850{\mu}m$, $212\sim425{\mu}m$, $125\sim212{\mu}m$, $90\sim125{\mu}m$, $75\sim90{\mu}m$, $<75{\mu}m$. The sediment extract was analyzed water quality constituents, including chemical oxygen demand(COD), total nitrogen(T-N), total phosphorus(T-P), heavy metals and particle size distribution. The results indicate that most of particle size ranges of the bridge road sediments was $125\sim425{\mu}m$, and portion of $<75{\mu}m$ was low. But most of the pollutants are associated with the finer fractions of the load sediments. As the results of analysis, the range and average values of COD, T-N, T-P, Fe, Cu, Cr, and Pb were $177\sim198.8$ mg/kg(77.6 mg/kg), $23\sim200$ mg/kg(83 mg/kg), T-P $18\sim215$ mg/kg(129 mg/kg), and $1,508\sim5,612$ mg/kg(3,835 mg/kg), $9.2\sim69.3$ mg/kg(49 mg/kg), $19.1\sim662.2$ mg/kg(214 mg/kg), and $28.4\sim251.4$ mg/kg(114 mg/kg), respectively. The relationship between sediment size and pollutants concentration have an inverse proportion. The removal of road sediments with frequently could be reduced the significant nonpoint pollutant load, because of the bridge road sediment contains considerable micro-particles and heavy metals.