• Title/Summary/Keyword: Fe-Cr

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Magnetoresistance and Hall coefficient in $V_xGe_{l-x}$ single crystal (VGe 단결정의 자기저항과 홀 계수)

  • Park, Jiyoun;Park, Sungyoul;Park, Jeongyong;Hong, Soon-Cheol;Sunglae Cho;Park, Yongsup;Lee, Gu-Won;Park, Hyun-Min;Kim, Y. C.
    • Proceedings of the Korean Magnestics Society Conference
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    • 2003.06a
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    • pp.154-155
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    • 2003
  • Substituting transition metals such as V, Cr, Mn, Fe, Co and Ni into semiconductors have been of interest because of its unique electrical and magnetic properties. It was reported that the magnetoresistance(MR) ratio of CrGe was 1.7% and 1 4% at 120 K in fields of 0.5 and 5 T, respectively. The MR ratio of FeGe was 19% at 180K. The electrical resistivity of CrGe changed according to Cr concentration. In this talk, we report transport properties of V-doped Ge single crystals with several different V concentrations. The carrier densities and mobilities will be determined from Hall measurement.

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Fracture Behavior of Oxide Scales and Influence of Oxide Scales on the Strength of Materials (산화피막의 파괴거동 및 산화피막이 소지금속의 기계적 강도에 미치는 영향)

  • ;;Narita Toshio
    • Transactions of Materials Processing
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    • v.13 no.1
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    • pp.72-77
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    • 2004
  • An Fe-25Cr steel was oxidized in Ar atmosphere at 973K with and without applying external stress of 30∼35 MPa. A 0.1$\mu\textrm{m}$ thick $Cr_2O_3$ scales formed during pre-treatment in Ar atmosphere. Initiation of cracking on the oxide scales took place at grain boundaries during the end of second creep stage, in which cracks were found nearly perpendicular to the tensile directions. On the contrary, a scale developed in $N_2$-0.1%$SO_2$ displaced a poor adherence on the metal substrate. In this sample, a fast grown of scales was observed during creep deformation, and the strength of materials was much lower than in Ar. The creep strain rate of $1.5{\times}10^{-7}/s$ and $5.8{\times}10^{-7}/s$ was determined in Ar and in $N_2$-0.1%$SO_2$ under 30MPa, respectively.

Development of a (16~19)Cr Ferritic Cast Stainless Steel for a Flange Material of Automotive Exhaust Parts (자동차 배기계 플랜지용 16~19 wt.% 페라이트 주조용 스테인리스강 개발)

  • Jang, Hee-Jin;Beom, Won-Jin;Park, Chan-Jin
    • Journal of the Korean institute of surface engineering
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    • v.42 no.2
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    • pp.79-85
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    • 2009
  • We aimed to develop a Fe-($16{\sim}19$)Cr-($0.1{\sim}0.6$)Ti-($0.1{\sim}0.6$)Nb stainless steel for automotive exhaust parts with high corrosion resistance. The alloys with high Cr content showed high resistance to general corrosion and also localized corrosion. The increase of Ti and Nb contents resulted in a linear increase in the general corrosion resistance, while the pitting potential was improved by addition of these elements up to about 0.4 wt.%. The low-carbon Fe-17Cr-0.4Ti-0.4Nb alloy annealed at $850^{\circ}C$ and air-cooled was considered to be the optimum alloy for our purpose with the critical anodic current density of $247{\mu}A/cm^2$ in 0.05 M $H_2SO_4$ solution and the pitting potential of 310 mVSCE in 0.2 M NaCl solution.

The Effect of Cooling Rate on the Structure and Mechanical Properties of Fe-3%Mn-(Cr)-(Mo)-C PM Steels

  • Sulowski, Maciej;Cias, Andrzej;Frydrych, Hanna;Frydrych, Jerzy;Olszewska, Irena;Golen, Ryszard;Sowa, Marek
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.563-564
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    • 2006
  • The effect of different cooling rate on the structure and mechanical properties of Fe-3%Mn-(Cr)-(Mo)-0.3%C steels is described. Pre-alloyed Astaloy CrM and CrL, ferromanganese and graphite were used as the starting powders. Following pressing in a rigid die, compacts were sintered at $1120^{\circ}C$ and $1250^{\circ}C$ in $H_2/N_2$ atmospheres and cooled with cooling rates $1.4^{\circ}C/min$ and $6.5^{\circ}C/min$. Convective cooled specimens were subsequently tempered at $200^{\circ}C$ for 60 and 240 minutes.

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Determination of the Magnetic Moment of $Cr_2O_3$ by a Proportional Relation

  • Kim, Yong-Jin;Kim , Jung Gi
    • Journal of Magnetics
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    • v.1 no.2
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    • pp.55-56
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    • 1996
  • The effective magnetic moment of Cr$_2$O$_3$is determined by assuming that a proportional relation holds between its moment and the effective magnetic moment of hematite determined by the previous derived relaxation expression and the moments of Fe3+ ion and Cr3+ ion. The result obtained from the relation is found to be given by 0.10 in Bohr magneton which is in good agreement with the value obtained by use of the expression.

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Laser를 이용한 Alloy 600 재료표면 합금성분 조절

  • 신진국;서정훈;국일현;강석중;김정수
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05a
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    • pp.723-728
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    • 1995
  • Alloy 600 표면에 레이저 빔을 이용하여 Ni, Cr 흔합분말 및 순수 Cr 분말로 표면합금층을 만들었다. 표면 합금층은 모재와 정합계면를 이루고 있으며 레이저 표면용용 시편에서와 같이 크게 면선단 응고부와 셀룰라 응고부로 나눌 수 있고, 모재에는 레이저 처리과정에서 생긴 수십 $\mu\textrm{m}$ 두께의 열영향 부위가 존재하였다. 그리고 합금층 내부에는 레이저 표면 용용된 시편과 달리 구형의 커다란 기공(pores)이 존재하였다. 레이저 표면 합금층에서 합금원소의 조성 분포를 조사하기 위해 레이저 처리된 시편에 대해 WDX 분석을 하였고, 합금층 내부에 Ni, Cr, Fe 원소의 조성 분포는 매우 균일하였다.

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Stabilization Behavior of Heavy Metals in the EAF Dust-clay Body Mixtures at Various Sintering Conditions (점토계소지내에서 전기로 더스트 중금속의 소성 온도별 안정화거동)

  • Kwon, Yong-Joon;Kim, Yoo-Taek;Lee, Gi-Gang;Kim, Young-Jin;Kang, Seung-Gu;Kim, Jung-Hwan
    • Journal of the Korean Ceramic Society
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    • v.39 no.8
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    • pp.728-734
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    • 2002
  • Stabilization behavior of Cr, Cd, Cu, Pb, Fe and Zn heavy metals in the EAF dust was investigated by adding EAF dust to clay or white clay, respectively, up to 50 wt% with 10 wt% intervals and sintering at temperatures between 200 and $1200^{\circ}C$ with $200^{\circ}C$ intervals with an aid of ICP-AES followed by TCLP test to evaluate heavy metal cation exchange capacity of the clay or the white clay. The clay or the white clay had a better Cr ion exchange capacity than that of zeolite. The TCLP leaching test for the sintered specimens showed that Cr and Fe were rarely detected for all the specimens and the concentration of Cd and Zn decreased with increasing sintering temperature and decreasing EAF dust contents respectively. When the clay or the white clay were mixed with EAF dust, cation exchange may occur between the clay and the EAF dust so that the first stabilization of the mixtures containing semistabilized heavy metals may happen. Stabilization of heavy metals in the ceramic bodies was further completed probably due to the eutectic reaction caused by the sintering of semi-stabilized mixtures. It was conceivable that the white clay rather than the clay may be a better stabilizer for the EAF dust containing heavy metals.

Effects of Heat-Treatments on Transformation Behavior of Matrix Structures in High Alloyed White Cast Iron (고합급백주철에 있어서 열처리가 기지조직의 변태에 미치는 영향)

  • Shin, Sang-Woo;Ryu, Seong-Gon
    • Korean Journal of Materials Research
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    • v.10 no.6
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    • pp.409-414
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    • 2000
  • Three different white cast irons alloyed with Cr, V, Mo and W were prepared in order to study their transformation behavior of matrix structures in heat-treated conditions. The specimens were produced using a 15kg-capacity high frequency induction furnace. Melts were super-heated to $1600^{\circ}C$, and poured at $1550^{\circ}C$ into Y-block pepset molds. Three combinations of the alloying elements were selected so as to obtain the different types of carbides and matrix structures : 3%C-10%Cr-5%Mo-5%W(alloy No. 1), 3%C-10%V-5%Mo-5%W(alloy No. 2) and 3%C-17%Cr-3%V(alloy No. 3). The heat-treatments were conducted as follows: frist of all, as-cast specimens were homogenized at $950^{\circ}C$ for 5h under the vacuum atmosphere. Then, they were austenitized at $1050^{\circ}C$ for 2h and followed by air-hardening in air. The air-hardened specimens were tempered at $300^{\circ}C$ for 3h. The observation of morphology of the matrix structures was carried out in the states of as-cast(AS), air-hardened(AHF) and tempered(AHFT). The matrix structures of each alloy were almost fully pearlitic in the as-cast state but it was transformed to martensite, tempered martensite and retained austenite by the heat-treatments such as air-hardening and tempering.

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A Study on the Formation Mechanism of Microconstituents in Brazed Joint of Duplex Stainless Steel and Cr-Cu Alloy (2상 스테인리스강과 크롬동합금의 브레이징부 생성상의 생성기구에 관한 연구)

  • 김대업
    • Journal of Welding and Joining
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    • v.19 no.5
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    • pp.534-539
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    • 2001
  • The formation mechanism of microconstituents in brazed joints of duplex stainless steel and Cr-Cu alloy which is an essential process of rocket engine manufacturing was investigated using Cu base insert metal. $SUS329J_3L$ and C18200 were used for base metal and AMS 4764 was used for insert metal. The brazing was carried out under various conditions. There were various phases in the joints, because of reaction between liquid insert metal and base metals. Since liquid insert metal reacts with duplex stainless steel, liquid Cu from insert metal infiltrated into the $\alpha/\beta$ interface of duplex stainless steel. Through the process of Cu infiltration, isolated stainless steel pieces come into the liquid insert metal. Since liquid insert metal reacts with Cr-Cu alloy. Cr precipitates from C18200 come into the liquid insert metal. With increment of bonding temperature and holding time, amounts and sizes of phases increased. but Cr-Mn compounds decreased at 1303k for 1.2ks and Mn-rich phases disappeared Fe-Cr compounds formed.

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Self-Healing Investigation of Bisphenol F-Type Epoxy-Modified Mortars with Expansive Admixtures Under Outdoor Exposure Conditions (환경조건에 따른 팽창성 혼화재 및 비스페놀 F형 에폭시수지 병용 모르타르의 자기치유 검토)

  • Park, Seung-Min;Kim, Wan-Ki
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.22-23
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    • 2017
  • The purpose of this study is to ascertain self-healing function on microcracks in bisphenol F-type epoxy-modified mortars using expansive admixtures. The specimens are prepared with various polymer-binder ratios of 0, 5, 10, 20%, expansive admixture contents of 0% and 10%, a sodium carbonate content of 0.25%, and subjected to exposure conditions of CR1, CR2, CR3 and CR4. The specimens are tested for self-healing effect, porosity and FE-SEM analysis. As a result, self-healing effects of bisphenol F-type EPMMs with expansive admixtures are visible in all of the outdoor exposure conditions. In particular, exposure conditions of CR3 and CR4 are most noticeable. And the porosity of EPMMs is reduced with an increase in the polymer-binder ratio, and is considerably smaller than that of unmodified mortar.

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