• Title/Summary/Keyword: Fe-Cr

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Study of the Effects of Fe94Si5Cr1-Rubber Absorbers with Sheet-Thickness (Fe94Si5Cr1을 이용한 Sheet 두께에 따른 전파흡수특성 연구)

  • Kim, Moon-Suk;Min, Eui-Hong;Koh, Jae-Gui
    • Journal of the Korean Magnetics Society
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    • v.19 no.2
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    • pp.62-66
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    • 2009
  • The soft magnetic FeSiCr were processed the ball-mill for 30 hours and the shape of FeSiCr particles was changed from sphere to flake type, which was observed using scanning electron microscope. The complex permittivity and permeability spectra and reflection loss of FeSiCr-rubber composite was measured using Network Analyzer in order to investigate the relationship between the microwave absorption and the material constants. The matching frequency shifted toward lower frequency range with microwave absorber thickness, and microwave absorber with FeSiCr-rubber composite showed a maxium reflection loss of -8.3 dB at 1.86 GHz for a 1.3 mm thickness.

A Study of Thermodynamical Reaction Path in Fe-Cr-X Alloys at High Temperature Corrosion Environments (고온 부식환경에 대한 Fe-Cr-X 합금의 열역학적 반응경로에 관한 연구)

  • Lee, Byung-Woo;Kim, Woo-Yeol
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.32 no.4
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    • pp.411-420
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    • 1996
  • The structure of the scale formed on the surface of Fe - Cr - X alloys exposed to 1143K high sulfidation($Ps_2$ = 1.11$\times$$10^-7$ atm, $Po_2$ = 3.11$\times$$10^-20$ atm) or sulfidation/oxidation(($Ps_2$= 1.06$\times$$10^-7$ atm, ($Po_2$ = 3.11$\times$$10^-18$ atm) environment has been observed and analysed using XRD, SEM/EDS. To investigate the possibility of protective film formed on the surface of the alloys, Aluminium, Nickel were selected as alloying elements. Thermodynamic phase stability diagram was used to predict the reaction path of scale formed on Fe - Cr - X alloys. Parabolic rate constant($K_p$) value with 6wt% Al in Fe - 25Cr alloy decreased significantly compared with the Fe - 25Cr alloy without 6wt% Al. Since thin layer of defect free sulfide film, (Al, Cr)Sx, was formed at the alloy/scale interface. Fe - rich sulfide scale at outer layer and Cr - rich sulfide scale containing porosity at inner layer of Fe - 25Cr alloy have been observed. The reaction path for these scales could be predicted by the thermodynamic stability diagram.

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Thermal Stability of Al-Fe-X Alloy System Prepared by Mechanical Alloying and Spark Plasma Sintering: II. Al-Fe-Cr and Al-Fe-Mo (기계적 합금화 및 스파크 플라즈마 소결에 의해 제조된 Al-Fe-X계 합금의 열적 안정성: II. Al-Fe-Cr and Al-Fe-Mo)

  • Lee, Hyun-Kwuon;Lee, Sang-Woo;Cho, Kyeong-Sik
    • Journal of Powder Materials
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    • v.12 no.1
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    • pp.43-50
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    • 2005
  • Mechanical alloying using high-energy ball mill and subsequent spark plasma sintering (SPS) process was applied to Al-Fe-Cr and Al-Fe-Mo powder mixture to investigate effects of Cr and Mo addition on thermal stability of Al-Fe, and thereby to enhance its thermal stability up to $500^{\circC}$. Various analytical techniques including micro-Vickers hardness test, SEM, TEM, X-ray diffractometry and corrosion test were carried out. It was found that addition of Cr and Mo to Al-Fe system played a role of grain growth inhibitor of matrix Al and some precipitates such as $Al_3Fe$ during SPS and subsequent heat treatment. The inhibition of grain growth resulted in increased Vickers hardness and thermal stability up to $500^{\circC}$ comparing to those of Al-Fe alloy system.

Oxidation of $Cr_3C_2$ Composites with Fe-Scale (Fe-Scale과의 반응에 의한 $Cr_3C_2$계 복합체의 산화손상)

  • 한동빈;홍기곤;박병학
    • Journal of the Korean Ceramic Society
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    • v.31 no.7
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    • pp.767-771
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    • 1994
  • In a salb-preheating furnace of steel-making industry, the oxidation/degradation behavior of Cr3C2 ceramic composited dkid button reaction with scale in Fe-oxide system occurs and was thermodynamically examined. The reaction of scale with Cr3C2 skid button produces Cr3C2(s) and C(s), and Co gas is then evolved from the reaction of C(s) with Fe-scale. Cr3C2(s) from oxidation of Cr3C2(s) reacted with Fe-oxide(s) becomes high-melting chromite. The chromite acts as protection layer against further oxidation and improves resistance of the reaction of Cr3C2 skid button with Fe-scale.

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Electronic Behaviors of Passive Films Formed on Fe-Cr and Fe-Cr-Mo Ferritic Stainless Steels Studied by Mott-Schottky and Cyclic Voltammetry Techniques

  • Kim, Suk-Won;Yoon, Sang-In;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.2 no.1
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    • pp.12-17
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    • 2003
  • The effects of Cr content and film formation potential on electronic behaviors of the passive film on Fe-Cr alloys were investigated in borate buffer solution. Influence of pH on passive films of both Fe-Cr and Fe-Cr-Mo alloys was also investigated. Mott-Schottky and cyclic voltammetry techniques were used to elucidate electronic behaviors of passive films and their electrochemical characteristics. AES analysis of passive films was carried out. Results showed that doping density decreased as Cr content and film formation potentials increased. The addition of Mo to Fe-Cr alloy had little influence on donor densities in pH 9.2 solution but some effects on the decrease in donor densities in pH 1.6 acidic solution.

Effects of doping on the electrical conductivity and particle size in olivine type $LiFePO_4$ powders (올리빈형 $LiFePO_4$ 분말의 전기전도도와 입도 크기에 미치는 도핑의 영향)

  • Bai, Jin-Tao;Ha, Jung-Soo;Kim, Chang-Sam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.6
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    • pp.248-252
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    • 2008
  • To get a fine $LiFePO_4$ powder with high electrical conductivity, the influences of doping of aliovalent elements(Cr+B and Cr+Al) on electrical conductivity and of heat treatment conditions on particle size of the doped powders were studied. Two kinds of the doped powders $LiFe_{0.965}Cr_{0.03}B_{0.005}PO_4$ and $LiFe_{0.065}Cr_{0.03}Al_{0.005}PO_4$ were synthesized using mechanochemical milling and subsequent heat treatment at $675{\sim}750^{\circ}C$ for $5{\sim}10\;h$. The doping enhanced grain growth and electrical conductivity. The electrical conductivity at $30^{\circ}C$ was $1{\times}10^{-8}S/cm$ in the doped with Cr and Al, and $5{\times}10^{-10}S/cm$ in the undoped one.

Giant Magnetoresistance of Antiferromagnetic Cr-Al based Multilayer Spin-Valve with Anti-Corrosion and Thermal Stability (내열 내식용 Cr-Al반강자성계 스핀밸브막의 거대자기저항 효과)

  • 김병수;이성훈;이찬규
    • Journal of the Korean Magnetics Society
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    • v.8 no.6
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    • pp.362-368
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    • 1998
  • The magnetic properties, thermal stability and anti-corrosion properties of $Cr_86Al_14$ spin valves multilayers were studied. It was found that the magnetic properties of $Cr_86Al_14$ spin valves depend on the thickness of antiferromagnetic, ferromagnetic and non-ferromagnetic layers. Exchange coupled field ($H_{ex}$) and magnetoresistance ratio (%) showed the largest value of 20 Oe, 2 % in $glass/Cr_{86}Al_{14}(600 $\AA$)/Ni_{81}Fe_{19}(50$\AA$)/Cu(40 $\AA$)/Ni_{81}Fe_{19}(40 $\AA$)$ spin valves. The $H_{ex}$ MR ratios (%) of CrAl and FeMn spin valves were decreased with increasing annealing temperatures and were lost at 150 $^{\circ}C$, 250 $^{\circ}C$ respectively. Based on these result, it was elucidated that CrAl is more thermally stable than FeMn. It was also shown that there was no change of $H_{ex}$ MR ratios in CrAl, while FeMn was changed and lost 15 days later in corrosion resistance test under 35 $^{\circ}C$, 90 % humidity condition. FeMn was found to be pitted and peeled off 15 days later by SEM micrographic analysis.

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Synthesis of Pt/alloy Nanoparticles by Electrical Wire Explosion in Liquid Media and its Characteristics (액중 전기선 폭발 공정을 이용한 Pt/alloy 하이브리드 나노입자의 제조 및 그 특성)

  • Koo, Hye Young;Yun, Jung-Yeul;Yang, Sangsun;Lee, Hye-Moon
    • Particle and aerosol research
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    • v.8 no.2
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    • pp.83-88
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    • 2012
  • The electrical wire explosion process in liquid media is promising for nano-sized metal and/or alloy particles. The hybrid Pt/Fe-Cr-Al and Pt/Ni-Cr-Fe nanoparticles for exhaust emission control system are synthesized by electrical wire explosion process in liquid media. The alloy powders have spherical shape and nanometer size. According to the wire component, while Pt/Fe-Cr-Al nanoparticles are shown the well dispersed Pt on the Fe-Cr-Al core particle, Pt/Ni-Cr-Fe nanoparticles are shown the partially separated Pt on the Ni-Cr-Fe core particle. Morphologies and component of two kinds of hybrid nano catalyst particles were characterized by transmission electron microscope and energy dispersive X-ray spectroscopy analysis.

The Effect of Alloy Elements on the Damping Capacity and Plasma Ion Nitriding Characteristic of Fe-Cr-Mn-X Alloys [I Damping Capacity] (Fe-Cr-Mn-X계 합금의 감쇠능 및 플라즈마이온질화 특성에 미치는 합금원소의 영향 [I 감쇠능])

  • Son, D.U.;Jeong, S.H.;Kim, J.H.;Lee, J.M.;Kim, I.S.;Kang, C.Y.
    • Journal of Power System Engineering
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    • v.9 no.1
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    • pp.70-75
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    • 2005
  • The damping property of Fe-12Cr-22Mn-X alloys has been investigated to develop high damping and high strength alloy. Particularly, the effect of the phase of austenite, alpha and epsilon martensite, which constitute the structure of the alloys Fe-12Cr-22Mn-X alloys, on the damping capacity at room temperature has been investigated. Various fraction of these phases were formed depending on the alloy element and cold work degree. The damping capacity is strongly affected by ${\varepsilon}$ martensite while the other phase, such as ${\alpha}'$ martensite, actually exhibit little effect on damping capacity. In case of Fe-12Cr-22Mn-3Co alloy, the large volume fraction of ${\varepsilon}$ martensite formed at about 30% cold rolling, and in case of Fe-12Cr-22Mn-1Ti alloy, formed at about 20% cold rolling and showed the highest damping capacity. Damping capacity showed higher value in Fe-12Cr-22Mn-1Ti alloy than one in Fe-12Cr-22Mn-3Co alloy.

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