• Title/Summary/Keyword: Fe-Cr

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Study on Mold-Metal Reaction in Castings of Mn-Steel and Cr-Steel (Mn 및 Cr 주강의 주형반응에 관한 연구)

  • Lee, J.H.;Jeong, J.Y.;Lee, J.N.
    • Journal of Korea Foundry Society
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    • v.5 no.4
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    • pp.271-282
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    • 1985
  • In order to investigate the mold reaction characteristics of Mn steel and Cr steel castings individually, the mold reaction products were examined by scanning electron microscopy, electron prove microanalyzer and X-ray diffractometer. From this experiment, the results were summarized as follows: 1) The mold reaction depth increased with increase of Mn content, while it decreased with increase of Cr content. 2) Mold reaction depth decreased with Mn content at $1200^{\circ}C$. 3) Mn, among the reaction products, forms a low fusion silicate, Mn $O.SiO_2$ while Cr forms a stable oxide, $CrO_3$ which hindering the reaction between FeO and $SiO_2$ thus the formation of $FeO.SiO_2$ was depressed.

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Dietary Intakes, Serum Concentrations, and Urinary Excretions of Fe, Zn, Cu, Mn, Se, Mo, and Cr of Korean Young Adult Women (일부 젊은 성인여자의 Fe, Zn, Cu, Mn, Se, Mo 및 Cr의 식사섭취, 혈청농도 및 소변배설)

  • Kim, Kyune-Hee;Lim, Hyeon-Sook
    • Journal of Nutrition and Health
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    • v.39 no.8
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    • pp.762-772
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    • 2006
  • This study was conducted to investigate dietary intakes, serum concentrations, and urinary excretions of iron (Fe), zinc (Zn), copper (Cu), manganese (Mn), selenium (Se), molybdenum (Mo), and chromium (Cr) of Korean young adult women. A total of 19 apparently healthy young adult women aged in their twenties or thirties participated voluntarily. One-tenth of all foods they consumed for 3 consecutive days were collected, all urine excreted for the same 3 days was gathered, and fasting venous blood was withdrawn for the trace mineral analyses. Of the food, blood, and urine samples, the contents of Zn, Cu, Mn, Se, Mo, and Cr were analyzed by inductively coupled plasma-mass spectroscopy (ICP-MS) and that of Fe by inductively coupled plasma-atomic emission spectroscopy (ICP-AES) after wet digestion. The intake of Fe, $6.94{\pm}2.18mg$, did not meet the estimated average requirement (EAR) for Korean women aged 20-29 years old. On the contrary, the intakes of Zn ($9.35{\pm}4.95mg$), Cu ($1.18{\pm}0.26mg$), and Mn ($3.69{\pm}0.69mg$) were sufficient for each respective EAR. However, some of the subjects did not take the EAR for Zn. The Se intake, $41.93{\pm}9.28{\mu}g$, however, was almost similar to the EAR for Se. Although there are no references for Mo and Cr, the intakes of these minerals ($134.0{\pm}49.1\;and\;136.5{\pm}147.9{\mu}g$, respectively) seemed to be excessively sufficient. Serum Fe concentration, $88.7{\pm}36.8{\mu}g/dL$, seemed to be a little bit lower than its reference median but within its normal range. Approximately one-fourth of the subjects were in anemic determined by Hb and Hct and below the deficiency serum level of Fe, $60{\mu}g/dL$. In addition, serum Se concentration, $3.73{\pm}0.60{\mu}g/dL$, was also below its reference median and normal range. However, serum concentrations of Zn ($99.6{\pm}30.6{\mu}g/dL$) and Mo ($0.25{\pm}0.10{\mu}g/dL$) were fairly good compared to each reference median. The status of Cu could be determined as good although its serum concentration ($91.6{\pm}14.6{\mu}g/dL$) was slightly below its reference median. Since there are no decisive reference values, it was not easy to evaluate serum concentrations of Mn ($0.93{\pm}0.85{\mu}g/dL$) and Cr ($8.60{\pm}7.25{\mu}g/dL$). But Mn and Cr status seemed to be adequate. Urinary Fe excretion, $4.48{\pm}1.98{\mu}g/dL$, was pretty much lower than its reference and that of Se, $2.45{\pm}1.17{\mu}g/dL$, was also lower than its average. On the other hand, those of Zn ($42.95{\pm}20.47{\mu}g/dL$) and Cu ($5.68{\pm}1.50{\mu}g/dL$) were flirty good. In case of Mn, urinary excretion, $0.31{\pm}0.09{\mu}g/dL$, was much greater than its reference. Urinary excretions of Mo ($7.48{\pm}2.95{\mu}g/dL$) and Cr ($1.37{\pm}0.41{\mu}g/dL$) were very higher compared to each reference. The results of this study revealed that Korean young adult women were considerably poor in Fe status, a bit inadequate in Se status, partly inadequate in Zn status, and flirty good in Cu, Mn, Mo and Cr status. However, there was a problem of excessive intakes of Mo and Cr. It, therefore, should be concerned to increase the intakes of Fe, Se and Zn but to decrease Mo and Cr consumption for young adult women.

NaBH4 Hydrolysis Reaction Using Co-P-B Catalyst Supported on FeCrAlloy (Co-P-B/FeCrAlloy 촉매를 이용한 NaBH4 가수분해 반응)

  • Hwang, Byungchan;Jo, Ara;Sin, Sukjae;Choi, Daeki;Nam, Sukwoo;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.35-41
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    • 2013
  • Properties of $NaBH_4$ hydrolysis reaction using Co-P-B/FeCrAlloy catalyst and the catalyst durability were studied. Co-P-B/FeCrAlloy catalyst showed low activation energy such as 25.2 kJ/mol in 5 wt% $NaBH_4$ solution, which was similar that of noble metal catalyst. The activation energy increased as the $NaBH_4$ concentration increased. Formation of gel at high concentration of $NaBH_4$ seriously affected hydrogen evolution rate and the catalyst durability. The catalyst loss decreased as reaction temperature increased due to lower gel formation when the concentration of $NaBH_4$ was over 20 wt%. Considering hydrogen generation rate and durability of catalyst, the catalyst supported with FeCrAlloy heat-treated at $1,000^{\circ}C$ without ultra vibration during dipping and calcination after catalyst dipping was best catalyst. To use catalyst more than three times in 25 wt% $NaBH_4$ solution, it should be reacted at higher temperature than $60^{\circ}C$.

Ductile-to-Brittle Transition Behavior of Two Austenitic Fe-18Cr-10Mn Alloys with the Combined Addition of Nitrogen and Carbon (질소와 탄소가 복합 첨가된 두 오스테나이트계 Fe-18Cr-10Mn 합금의 연성-취성 천이 거동)

  • Lee, S.Y.;Kim, B.Y.;Hwang, B.
    • Journal of the Korean Society for Heat Treatment
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    • v.28 no.1
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    • pp.1-6
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    • 2015
  • The ductile-to-brittle transition behavior of two austenitic Fe-18Cr-10Mn alloys with the combined addition of nitrogen and carbon was investigated in this study. The alloys exhibited a ductile-to-brittle transition behavior because of unusual brittle fracture at low temperatures unlike conventional austenitic alloys. The alloy with higher carbon content had higher yield and tensile strengths than that with lower carbon content due to the solid solution strengthening effect resulting from carbon addition. However, the increase in carbon content promoted the occurrence of intergranular fracture, and thus deteriorated the impact toughness. In order to develop successfully the austenitic Fe-18Cr-10Mn alloys with the excellent combination of strength and toughness in the future, therefore, more systematic studies are required to find the appropriate amount and ratio of nitrogen and carbon.

A Study on the Cracking Behavior in the Welds of Ni-Cr-Fe and Ni-Fe-Cr-Mo Alloys Part I : Solidification Cracking in the Fusion Zone (Ni-Cr-Fe 및 Ni-Fe-Cr-Mo계 합금의 용접부 균열특성에 관한 연구 Part I : 용착금속의 응고균열)

  • 김희봉;이창희
    • Journal of Welding and Joining
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    • v.15 no.4
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    • pp.78-89
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    • 1997
  • This study has evaluated the weld metal solidification cracking behavior of several Ni base superalloys (Incoloy 825, Inconel 718 and Inconel 600). Austenitic stainless steels(304, 310S) were also included for comparison. In addition, a possible mechanism of solidification cracking in the fusion zone was suggested based on the extensive microstructural examinations with SEM, EDAX, TEM, SADP and AEM. The solidification cracking resistance of Ni base superalloys was found to be far inferior to that of austenitic stainless steels. The solidification cracking of Incoloy 825 and Inconel 718 was believel to be closely related with the Laves-austenite (Ti rich in 825 and Nb rich in 718) and MC-austenite eutectic phases formed along the grain boundaries during solidification. Cracking in Inconel 600 was always found along the grain boundaries which were enriched with Ti and P. Further, solidifidcation cracking resistance was dependent not only upon the type of love melting phases but also on the amount of the phases along the solidification grain boundaries.

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Effect of Cold Working on Tensile and Charpy Impact Properties of a High-Nitrogen Fe-18Mn-18Cr-0.61N Austenitic Steel (오스테나이트계 Fe-18Mn-18Cr-0.61N 고질소강의 인장 및 충격 특성에 미치는 냉간 가공의 영향)

  • Lee, S.Y.;Lee, S.I.;Hwang, B.
    • Journal of the Korean Society for Heat Treatment
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    • v.27 no.3
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    • pp.121-126
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    • 2014
  • High-nitrogen Fe-18Mn-18Cr-N austenitic steels with higher yield strength have been recently developed and used for generator retaining rings because they have non-magnetic, high strength, high ductility, and good corrosion resistance. In the present study, a high-nitrogen Fe-18Mn-18Cr-0.61N austenitic steel was fabricated and then tensile and Charpy impact tests were conducted on them in order to investigate the effect of cold working on the mechanical properties. Although the yield and tensile strengths usually increased with cold working, the ductility and impact toughness significantly decreased after cold working. On the other hand, the high-nitrogen austenitic steel exhibited a ductile-brittle transition due to unusual brittle fracture at low temperatures despite having a face-centered cubic structure. The ductile-brittle transition temperature obtained from Charpy impact tests could be remarkably increased by $60^{\circ}C$ after 20% cold working because of the enhanced cleavage-like brittle fracture.

Factors Controlling the Deposition of Airborne Metals on Plant Leaves in a Subtropical Industrial Environment

  • Gajbhiye, Triratnesh;Pandey, Sudhir Kumar;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • v.10 no.3
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    • pp.162-167
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    • 2016
  • This study was conducted in an industrial city (Bilaspur) representative of subtropical area in central India. In order to assess the metal deposition on plant, concentrations of six target metals (i.e., Fe, Mn, Pb, Cu, Cd, and Cr) in both plant leaf and dust (deposited on its surface) samples were measured from six different sites. Metal concentrations in dust samples were found on the order of Fe>Mn> Cr>Pb>Cu>Cd. In contrast, the concentration of metals in plant leaves were seen on the order of Fe>Mn>Cr>Cd>Cu>Pb. As such, Cd showed significantly high concentration in leaves relative to their corresponding dust samples. A high accumulation potential for Fe and Cd was seen from Butea monosperma, while Mn and Pb were accumulated noticeably in Pongamia pinnata and Butea monosperma. Likewise, Cr and Cu were enriched in Calotropis procera, Alstonia scholaris, and Butea monosperma. The overall results of our study suggest that the foliar uptake pattern should vary considerably by an interactive role between plant and metal types.

Heavy Metal Concentrations of Rocks Soils and Plants from the Serpentine Area in Andong Kyungsngbuk-do (경상북도 안동 사문암지역의 모암, 토양 및 식물체 내 중금속 함량)

  • 민일식;송석환;김명희
    • Korean Journal of Environment and Ecology
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    • v.13 no.3
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    • pp.288-294
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    • 1999
  • 경상북도 안동 사문암지역 및 부근의 화강암지역에 분포하는 암석, 토양 및 식물체에 함유되어 있는 원소의 농도를 조사한 결과는 다음과 같다. 본 조사지역에분포하는 사문암에 함유되어 있는 주요 전이원소 함량(Ni 1.164ppm. Cr 366ppm. Co 109ppm. Fe 7.48%) 및 다른 대부분의 전이원소(Sc, Mn, Cu)도 화강암보다 높았으며 우리나라 efms 지역의 사문암에 함유되어 있는 농도와 비교하여 볼 때 매우 유사한 경향을 보이고 있다. 사문아토양의 경우 암석풍화토양 및 산림토양 모두 화강암토양에 비해 Ni, Co, Cr, Fe, Sc, Mn, Cu, Mg, Zn 농도가 높았으며 Pb는 반대의 경향을 나타내었다. 토양내 원소 함량은 이들의 모암에 함유되어 있는 원소 함량의 변화와 일치하고 있으며 같은 모암인 경우 산림식생의 영향에 따라 면 원소들의 차이가 다소 나타났다. 식물체 내 원소의 농도는 토양의 농도에 비해 모두 낮았다. 참억새, 쑥, 소나무에 함유되어 있는 원소별 평균 농도는 모두 동일종간 대부분의 전이원소(Ni, Co, Cr, Fe) 및 As 농도가 화강암토양에 비해 사문암토양에서 더높았다 사문암토양에서 생육하는 식물체 3종 모두 대부분의 원소(Ni, Co, Cr. As, Sc, Fe) 함랴이 지하부에서 더 높았으며 Zn과 Mo는 지상부와 지하부의 농도 차이가 크게 나타나지 않았다 화강암토양에서 생육하는 식물체의 경우 원소별 지상부 및 지하부의 농도차이는 사문암토양에 비해 크지 않았다.

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Long-Term Change of Heavy Metal Concentration in the Kumho River Water (금호강 수 중의 중금속류의 장기변도)

  • 배준웅;이상학;이성호
    • Journal of Environmental Science International
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    • v.10 no.1
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    • pp.27-33
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    • 2001
  • In order to study the long-term change of heavy metal concentrations in the Kumho river water, water analysis was conducted at 13sites surrounding the Kumho river system for 18times from September 1993 to August 1999. Analytical items for the study of water quality are Cu, Zn, Cd, Cr, Fe, Mn and Pb. The six year term studied in this work was divided into Part I and Part II, which covers the period from September 1993 to August 1996 and the period from September 1996 to August 1999, respectively. The mean concentrations of Cu, Zn, Cd, Cr, Fe, Mn and Pb in the unit of ppm for the Part I period showed 0.032, 0.025, 0.006, 0.050, 0.053 and 0.019, respectively. The mean concentrations of Cu, Zn, Cd, Cr, Fe, Mn and Pb in the unit of ppm for the Part II period showed 0.001, 0.001, 0.001, 0.004, 0.020, 0.002 and 0.002, respectively. The heavy metal concentrations in the Kumho river water for te second period were found to be decreased by 1/32, 1/25, 1/6, 1/1.5, 1/2.5, 1/26.5 and 1/9.5 for Cu, Zn, Cd, Cr, Fe, Mn and Pb, respectively. The present results clearly indicate that the water quality in the Kumho river is improving in terms of heavy metal contaminations.

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