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Comparison of Pollutant Removal Efficiency in Road Sediment with Media Using Filter Separator (필터 분리기를 이용한 여재별 도로퇴적물의 오염물질 제거효율 비교)

  • Bang, Ki-Woong;Lee, Jun-Ho;Choi, Chang-Su;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.3
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    • pp.332-340
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    • 2007
  • Storm runoff from road contains significant loads of particulate and dissolved solids, organic constituents and metal elements. Micro particle is important when considering pollution mitigation because pollutant metal and organics have similar behavior with particles. The objective of this research is to evaluate the hydrodynamic filter separator performance for road storm runoff treatment. A various types of media such as perlite, granular activated carbon, zeolite were used for column test packing media and filter separator, and to determine the removal efficiency with various surface loading rate. As the results of column test, the highest SS removal efficiency was using mixed media(granular activated carbon, zeolite and perlite), and granular activated carbon mixed with zeolite has higher heavy metal removal efficiency than perlite. In laboratory scale hydrodynamic filter separator study, the operation ranges of surface loading rates were from 192 to 1,469 $m^3/m^2/day$. The estimated overall removal efficiencies of hydrodynamic filter separator for typical storm runoff were SS 48.1%, BOD 31.9%, COD 32.6%, TN 15.5%, and TP 17.3%, respectively. For the case of heavy metals, overall removal efficiencies were Fe 26.0%, Cu 19.4%, Cr 25.7, Zn 16.6%, and Pb 15.0%, respectively. The most appropriate medium for hydrodynamic filter separator was perlite mixed with granular activated carbon to treatment of road storm runoff.

Contents of Paeonol and Inorganic Components in Herbaceous Root-Bark of Paeonia moutan SIMS (목란근피(牧丹根皮)의 Paeonol 및 무기성분(無機成分) 함량(含量))

  • Chung, Sang-Hwan;Suh, Dong-Hwan;Park, No-Kwuan;Kim, Ki-Jae;Choi, Boo-Sull
    • Korean Journal of Medicinal Crop Science
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    • v.2 no.3
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    • pp.227-233
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    • 1994
  • To get a fundamental data fur management of security, validity, Quality, of Paeonia suffruficosa roots as medicinal herb, the content of paeonol, ash, and inorganic components in Moutan Radicis Cortex produced in 8 regions of Korea was investigated from Oct. 1990 to May 1991. The results are summarized as follows: The average content of paeonol was 0.65%. The content of ash was 3.53%, acid-insoluble ash 0.77% in average, both of them were suitable to the standard value as Korean medical herbs. Total nitrogen content was 1.03%, phosphate 0.55%, potassium 0.82%, and calcium 1.50% in average. The content of MgO was 0.21ppm, 325.83ppm in Fe, 1.82ppm in Cr, 3.73ppm in Cu, 18.93ppm in Zn and Mn 21.27ppm, respectively. Especially Hg was not detected in the products of all regions. The average content of Cd was 0.25ppm, Pb 3.09ppm in Moutan Radicis Cortex, so they were estimated suitably to use as medicinal herb.

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Petrology of the Basalts in the Seongsan-Ilchulbong area, Jeju Island (제주도 성산일출봉 일대 현무암에 대한 암석학적 연구)

  • Koh, Jeong-Seon;Yun, Sung-Hyo;Jeong, Eun-Ju
    • Journal of the Korean earth science society
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    • v.28 no.3
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    • pp.324-342
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    • 2007
  • This study reports petrography and geochemical characteristics of the basalt lava flows in Seongsan-Ilchulbong area, the easternpart of Jeju island, Korea, to understand the evolutionary processes of magma. Basalt lavas are classified into the Pyoseon-ri basalt and the Seongsan-ri basalt. The Pyoseon-ri basalt is dark-gray colored with many vescicles, and mainly consists of olivine, feldspar and rarely of clinopyroxene as phenocrysts. The Seongsan-ri basalt is largely aphanitic basalt and bright-gray colored, divided into two lava-flow units: lower lava flow (B1) and upper lava flow (B2) by the intercalated yellowish lapillistone and paleosol. The lavas plotted into sub-alkaline tholeiitic basalt and alkaline basalt series. The tholeiitic basalts have characteristically higher $SiO_2,\;FeO^T$, and CaO contents, but lower $TiO_2,\;K_2O,\;P_2O_5$ and other incompatible elements compared to the alkali basalts. The tholeiitic basalts have higher $SiO_2$ to the same MgO contents than the alkalic basalts. The contents of Ni, Cr, and MgO show a strong positive correlation, which indicates that low-MgO phases like plagioclase and titanomagnetite were important during the differentiation of magma. The contents of incompatible elements against that of Th show a strong positive correlation. The chondrite-nomalized REE patterns of tholeiitic and alkalic basalts are subparallel each other. LREEs contents of the former are lower than, but HREEs contents are similar to the latter. They both are similar to their K/Ba ratios. The primitive-mantle normalized spider diagram demonstrates that the contents of Ba and Th of all basaltic magma are enriched, and yet Cr, Ni are depleted. The tholeiitic and alkalic basalts may be originated from a different degree of the partial melting of the same mantle material source, and one shows a higher degree of the partial melting than the other.

Geochemical characteristics on the petrological groups of stream sediments and water in primary channels of the Jangheung area, Korea (장흥지역 1차수계 하상퇴적물의 지질집단별 지구화학적 특성과 하천수에 대한 연구)

  • 박영석;김종균;한민수;김용준;장우석;신성천
    • Economic and Environmental Geology
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    • v.35 no.6
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    • pp.509-521
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    • 2002
  • The purpose of this study is to find out geochemical characteristics of stream sediments which are good indicator of geochemical hazard valuation and water in primary channels of the Jangheung area. We separated three groups which were granitoid area, granite gneiss area and tuffeous area by petrological properties. Physical and chemical characteristics of stream water such as temperature, pH, and EC were measured in the field between 1999 and 2001 and stream sediments samples were collected from April to May in 1999. For the chemical analysis of stream sediments samples, XRF, ICP-AES and NAA were used. The contents of the major elements had a similar contents in three groups and those of rare earth elements in granite gneiss area were lower value than those of other two groups. Zn and Cu were higher value than the other toxic elements. Through the enrichment factor and enrichment index features of the elements, we knew that $Fe_2O_3$, MgO, $TiO_2$, MnO and Eu, Yb of the tuffeous area samples and Co, Cr, Zn were enriched.

Effect of pH and Temperature on the Adsorption of Heavy Metals in Acid Mine Drainage (AMD) Onto Coal Mine Drainage Sludge (CMDS) (탄광슬러지를 이용한 금속광산 산성배수 처리 시 pH및 온도의 영향)

  • Cui, Ming-Can;Lim, Jung-Hyun;Kweon, Bo-Youn;Jang, Min;Shim, Yon-Sik;Khim, Jee-Hyeong
    • Journal of Soil and Groundwater Environment
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    • v.14 no.1
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    • pp.29-35
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    • 2009
  • In this study, the effect of pH and temperature on the adsorption behavior of acid mine drainage (AMD) on coal mine drainage sludge (CMDS) has been investigated during the treatment of coal mine drainage (CMD) by electrical purification method. The pH$_{zero\;point\;charge}$ (pH$_{zpc}$) of CMDS was 5. The removal ratio of copper, zinc, cadmium, iron were increased according to the increase of pH value. The adsorption amount of copper showed 0.64 mg g$^{-1}$ sludge. It was independent of pH value. The adsorption amount of the other metals showed l.l times when pH was 3. The adsorption amount of chromium was a little bit increased at the pH value higher than 7 due to a small amount of the chromium was eluted as $Cr(OH)_6^{3-}$. The amount of metals' absorption were decreased according to temperature was increase at pH value was 3. The selectivity order was Cd>Fe > Zn > Cu. The amount of absorption showed q$_{max}$ Cu 2.747 mg g$^{-1}$ andZn 2.525 mg g$^{-1}$ when pH value higher than 5. It was independent of temperature.

Changes in Chemical Composition of Traditional Ewhaju druing Brewing (전통 이화주 양조 중의 화학성분 변화)

  • 김정옥;남상명;김종군
    • Korean journal of food and cookery science
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    • v.9 no.4
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    • pp.272-277
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    • 1993
  • Chemical composition was determined to evaluate the quality of traditional Ewhaju during brewing. The content of moisture, total sugar, reducing sugar, crude protein and crude ash of Ewhaju after the lapse of 20 days from brewing were 47.01%, 47.57%, 29.45%, 4.81% and 0.09%, respectively and free sugar composed with 28.07% of glucose and 1.30% of maltose compared with 17.43% of glucose in one year aged Ewhaju. Contents of minerals were Ca 4.8mg%, Mg 9.2mg%, K 33.0mg%, Na 16.0mg%, Mn 0.76 ppm, Fe 35.0 ppm, Zn 1.1 ppm, Cu 0.12 ppm, Cr 0.20 ppm and Pb 0.22 ppm and rarely changed during fermentation. Total amino acids were 4.23% immediately after brewing 4.54% after the lapse of 100 days. In change of amino acids, methionine and tyrosine slightly increased during fermentation. Total acid contents of Ewhaju at immediately after brewing, in the lapse of 100 days and aged one year were 0.25%, 2.16%, 3.70%, respectively and 0.05%, 0.72% and 1.04%, in volatile acid. The pH in Swhaju remarkably decreased during fermentation; 6.1 at immediatly after brewing, about 3.9 at 100 days and 365 days fermentation.

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Occurrence and Genesis of Amphiboles in Hornblende Gabbro in Guwoonri, Hwacheon and in Otanri, Chuncheon (화천 구운리와 춘천 오탄리 일대에 분포하는 각섬석 반려암체내에 존재하는 각섬석류의 산출양상 및 생성작용)

  • Kim, Guan-Young;Park, Young-Rok
    • The Journal of the Petrological Society of Korea
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    • v.18 no.2
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    • pp.79-91
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    • 2009
  • Jurassic hornblende gabbo intrusives are distributed in Otanri, Chuncheon, and in Guwoonri, Hwacheon located in the northern part of Gyeonggi Massif. The intrusives composed mainly of amphiboles and plagioclase can be divided into two distinct rocks depending on the shape of amphiboles: (i) subspherical amphibole gabbro which has subspherical amphibole phenocryst as a major mafic phase(Sag); (ii) prismatic amphibole gabbro which has prismatic amphiboles as a principal mafic mineral(Pag). Subspherical amphiboles in Sag have higher Cr content and higher Mg($Mg+Fe^{2+}$) ratio relative to the prismatic amphiboles in Pag. This is indicative of conversion of pyroxene into amphibole with pyroxene pseudomorph. Oxygen isotopic results of plagioclase and amphibole separated from the hornblende gabbro suggest that theses minerals have experienced oxygen isotopic exchange with relatively heavy-$^{18}O$fluid for a long period, and magmatic fluid has been involved in the formation of subspherical amphiboles. Amphiboles in hornblende gabbro are composed of distinct species of pargasite, magnesiohornblende, actinolite, which formed at different stages.

A Study on Improvement of Durability for Run-out Table Roller with Hot Rolling by Porous Self-fluxing Alloy Coating (다공질 자용성 합금 피복에 의한 열간 압연용 런-아웃 테이블 롤러의 내구성 향상에 관한 연구)

  • Bae, Myung-Whan;Park, Byoung-Ho;Jung, Hwa
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.2
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    • pp.276-285
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    • 2012
  • The objective of this research is to develop the coating technique by a porous self-fluxing alloy for improving the mechanical properties of run-out table roller surface with the hot rolling. To enhance the durability of run-out table roller with the hot rolling, the high hardness of roller surface should be maintained at high temperatures, and the improvement of wear resistance, corrosion resistance, heat resistance, burn resistance and adhesion resistance should be maintained. In order to be able to transport reliably a hot rolled steel sheet, also, the appropriate friction coefficient on the roller surface should be maintained and the slip between roller and steel should not occur. In this study, the wear resistance of roller increases after the self-fluxing alloy is changed to a cermet by adding the tungsten carbide(WC), and the coefficient of friction increases and the ability of grip is improved because the porosities are made by coating with fine iron powder on the roller surface. As a result, it is found that the ability of grip between the steel and the roller coated by a porous self-fluxing alloy contained to 5 ~ 10 wt% of Fe in the coating layer is improved compared to the roller coated by Ni-Cr. This is because the porosities are made after Fe contained in the roller is partially alloyed by heating with a furnace in the fusing process and the rest is eliminated by oxidation and dissolution.

Trace Elements and Source Assessment of Street Dust in Daegu, Korea (대구지역 도로먼지에 함유된 미량원소성분과 오염원 평가)

  • Song, Hee-Bong;Lee, Eun-Young;Do, Hwa-Seok;Jung, Cheol-Su;Shin, Dong-Chan;Lee, Myoung-Sook;Paek, Yoon-Kyoung;Jeon, Seong-Suk;Shin, Won-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.7
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    • pp.793-800
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    • 2007
  • A total of 48 samples of street dust were collected in Daegu area during April and May 2006, were sieved below 100 ${\mu}m$, and analysed by ICP for the analysis of 14 elements after an acid extraction. Results obtained from the source assessment of trace elements using enrichment factor showed that Ca, Fe, K, Mg, Mn, Na and V were influenced by natural sources such as soil and dust, while Cd, Cr, Cu, Ni, Pb and Zn were influenced by urban anthropogenic sources such as fuel combustion and waste incineration. The measured values were remarkably higher in components from natural sources than in components from urban anthropogenic sources. The concentrations of trace elements in Daegu area were generally higher than in other foreign cities. Samples originated from industrial and commercial areas had higher concentrations of trace elements and pollution indices of heavy metals than those from residential and green areas. The correlation analysis among trace elements indicated that the correlations among components from urban anthropogenic sources were much significant, while those among components from natural sources were less correlated. In addition there were significant correlations between traffic density and components from urban anthropogenic sources.

The Characterization of Spherical Perticles in Steam Generator Sludge (증기발생기 슬러지 중 구형입자의 특성 조사)

  • Pyo, Hyung-Yeal;Park, Yang-Soon;Park, Sun-Dal;Park, Kyoung-Kyun;Song, Byung-Chul;Park, Yong-Joon;Jee, Kwang-Yong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.1
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    • pp.59-64
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    • 2006
  • Ion exchange resin particles should not be found in steam generator(S/G) sludge. The suspicious spherical resin particles observed in S/G sludge sample were characterized for particle size distribution under optical microscope using the micro-technique, for element analysis by the electron probe micro analysis (EPMA), and for molecular identification by the IR spectroscopy. The particle sizes are distributed from 1 to $200{\mu}m$ for the sludge, while 40 to $500{\mu}m$ for the spherical resin particles. The results of the elemental analysis showed different major impurities: Si, Al, Mn, Cr, Ni, Zn and Ti for the sludge particles, while Si, Cu, Zn for the spherical resin particles. However, both particles contain Fe as a matrix of magnetite $(Fe_3O_4)$. IR spectrum of the spherical particles was not quite similar to the IR spectrum of ion exchange resins used in S/G system. These results indicate that the spherical particles are not related to ion exchange resin particles and may be formed by the process of the sludge formation.

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