• Title/Summary/Keyword: Fe-Cr

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Properties of nanocomposite coatings by Hybrid coating (Hybrid 코팅에 의한 나노컴포지트 코팅의 특성)

  • Lee, Gyeong-Myeong;Lee, Jae-Hwan;Jeong, Bong-Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.76-76
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    • 2015
  • PVD에 의한 증착 대상 물질인 Ti, AlSi, Cr 및 각각의 타겟 전류, 바이어스, 압력 조건 들을 설계하여 적용시켰으며 PECVD와 CBC 코팅을 조합하여 발생되는 새로운 나노 멀티박막의 특성을 본 연구에서는 시험분석 및 평가하였다. 코팅층 깊이에 따른 조성 변화는 XPS를 이용하였으며 미세조직 및 표면 상태는 FE-SEM을 이용한 정밀 분석을 실시하였다. 또한, 박막의 경도는 나노인덴터를 이용하여 박막 자체의 경도만을 분석하였다. 한편, Pin-on-disk 방식의 마모시험기를 이용하여 표면조도와 상대재의 처리 상태에 따른 마찰계수를 시험 평가하였다.

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Fuel Cell Performance by the Impedance Method (임피던스법을 이용한 연료전지의 특성 연구)

  • 서장수;김귀열;명기환;이성일;김용주
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.927-933
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    • 2000
  • The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650$^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)CO3 melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way , Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a results, the performance of Ni-YSZ anode(40vo1%) was better excellent than the others.

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Impact Behavior of Large SF590A Forged Product (SF 590A 대형 단조품의 충격특성에 관한 연구)

  • Jin, Sang-Uk;Kim, Sang-Shik;Lee, Young-Seon;Lee, Seung-Uk;Kim, Nam-Soo
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.61-66
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    • 2008
  • Impact behavior of large SF590A (Fe-0.65C-1.5Mn-0.035P-0.035S-0.3Cr-0.15Mo-0.4Ni-0.3Cu) forged propeller shaft was studied in this study. Charpy impact specimens were prepared from the forged product with different heat number. The impact value of each specimen with different heat number tends to vary greatly depending on the prior austenite grain size and, less significantly, on the amount of sulfur. The dominant metallurgical factors affecting impact behavior of SF590A forged product are discussed based on fractographic and metallographic observations.

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Dyeing Properties of Protein and Polyamide Fabrics with Arrowroot Extract (칡뿌리를 이용한 단백질 및 폴리아미드 섬유의 염색성)

  • 이정은;이문철;최석철
    • Textile Coloration and Finishing
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    • v.12 no.6
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    • pp.353-360
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    • 2000
  • In this article, arrowroot is extracted in distilled water, and its dyeing properties on wool, nylon, and silk were investigated. Also the effect of mordanting (Al, Cu, Sn, Fe and Cr compounds) on the wash fastness are measured. The wavelength of maximum absorption of the arrowroot extract appears at 250 and 300nm below pH 7, but they shifted to longer wavelength at higher pH values. It appears that the optimum condition of the dyeing of wool, nylon, and silk fabric with arrowroot extract is $60^\circ{C}$, 60 min, and pH 4.0. Mordant treatments are effective in improving wash fastness of polyamide fabrics.

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Dyeability and Antibacterial Activity of the Fabrics with Elm-Bark Extracts (느릅나무 껍질 추출액에 의한 섬유의 염색성 및 항균성)

  • 최영희;권오경;문제기
    • Textile Coloration and Finishing
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    • v.15 no.3
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    • pp.140-145
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    • 2003
  • The purpose of this study is searching the Elm-Bark dyes' dyeability and antibacterial activities according to the dyeing time, pH, a mordant and the method of mordancy. We used two kinds of Elm-Bark dyes which's extracted by the Electrolytic reduction water and Distilled water. Silk fabric and Cotton/nylon union fabric was used for this study. The results are as follow. K/S value is increased according to the dyeing time and the suitable pH level is pH 3. Dyeability is good with Iron(II) sulfate$(FeSO_4\cdot{7H}_2O)$ on the pre-mordancy and Potassium dichromate$(K_2Cr_2O_7)$ on the post-mordancy. The Elm-Bark dyes by the Electrolytic reduction water has good colorfastness more than by the Distilled water. Antibacterial activities is excellent and the ratio is over than 99.5%.

Devised New Amorphous Alloys for Magneetoelastic Resonators (Magneetoelastic Resonators에 사용되는 새로운 비정질 함금)

  • C. K. Kim; C. K. Yoo; R.C. O'Handley
    • Journal of the Korean institute of surface engineering
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    • v.31 no.5
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    • pp.245-250
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    • 1998
  • There is clear pressing need to reduce bias field(Ha,) used on linear magenetomechanical resonator tag by at least a factor of two to allow low-bias operation near the frequency minimum since reducing Ha causes a dramatic increase in well depth, which implies increased stability. However, this makes it more difficult to maintain tight frequncy specs. It can be solved by a reduction of magnetomechanical coupling(k). We determined from an equivalent circuit model that optimal reduced, k, is near 0.3 Also, We determiend the material properties($lambda_s$, :saturated magenetostriction, $M_s$, and,$H_a$) that give k=0.3. From these evaluations, we suggested that on optimal comosition with adequate mathrial properties is $Fe_{55}Co_{15}Cr_6Nb_2B_{18}Si_4$.

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High Temperature Oxidation Behavior of Ni-W Coatings Electrodeposited on Steel (강기판 위에 코팅된 Ni-W의 고온산화거동)

  • 고재황;권식철;장도연;이동복
    • Journal of the Korean institute of surface engineering
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    • v.36 no.6
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    • pp.430-436
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    • 2003
  • The nanoocrystalline Ni-l5W(at.%) coating electrodeposited on the high carbon steel was oxidized at 700 and $800^{\circ}C$ in air, and the resultant oxidation properties were investigated using XRD, EPMA, TGA and TEM. The oxidation resistance of the coating was not so good that most of the coating was oxidized after oxidation at $800^{\circ}C$ for 5 hrs. The oxidation led to the formation of the outer, thin NiO oxide scale and the inner, porous, rather thick ($NiWO_4$+NiO) mixed layer containing a bit of $WO_2$. During oxidation, substrate elements such as Fe and Cr diffused outwardly toward the coating, according to the concentration gradient.

The Study of Structre-Peoperty-Process in Alumina Coating of Steel by Chemical Vapour Deposition Process (화학증착법에 의한 강에의 알루미나 피복에서 구조-성질-과정에 관한 연구)

  • 최진일
    • Journal of the Korean institute of surface engineering
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    • v.22 no.3
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    • pp.135-144
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    • 1989
  • Aluminium Oxide was deposited with a C.V.D.-technique on various substrates. The effects of various treating condition such as temperature, time, heat resistance and composition of substrates were investigated in order to understand the relationship of structure, property and process. Grain size depends upon the activity of adsorption siite and coarsened with increasing temperature and time. Deposition rate decreases in order of electrolytic iron, carbon steel STS430 and STS304, since the active site for adsorption of reactant was more decreased for Cr and Ni than Fe. Oxidation resistance of alumina coated specimens improved markedely and that of stainless steel was prominent.

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The Effect of Hybridized Atomic Orbitals of Ligands on the Calculated Dipole Moments for Octahedral [M(Ⅲ)O$_3S_3$] Type Complexes

  • Ahn, Sang-Woon;Park, Eui-Suh;Choi, Chang-Jin
    • Bulletin of the Korean Chemical Society
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    • v.3 no.3
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    • pp.98-103
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    • 1982
  • Extended Huckel calculations have been performed to obtain molecular orbital energies and the corresponding eigenvectors for $[M(III)O_3S_3]$ type complexes [M(111) = V(111), Cr(III), Mn(III), Fe(III) and Co(III)] adopting the valence basis set orbital $(nP_z)$ and the hybridized atomic orbital of ligands. The effects of the hybridized atomic orbital of ligands on the calculated dipole moments and 10 $D_q$ values are investigated. The calculated 10 $D_q$ values and dipole moments are close to the experimental values when the hybridized atomic orbital of ligands is used to obtain the eigenvector for $[M(III)O_3S_3]$ type complexes.

Characterization of Korean Clays and Pottery by Neutron Activation Analysis (I). Characterization of Korean Porcelainsherds

  • Lee, Chul;Kwun, Oh-Cheun;Kang, Hyung-Tae
    • Bulletin of the Korean Chemical Society
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    • v.7 no.1
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    • pp.73-77
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    • 1986
  • Data on the concentration of Na, K, Sc, Cr, Fe, Co, Cu, Ga, Rb, Cs, Ba, La, Ce, Sm, Eu, Tb, Lu, Hf, Ta, and Th obtained by neutron activation analysis have been used to characterize Korean porcelainsherds by multivariate analysis. The mathematical approach employed is principal component analysis (PCA). PCA was found to be helpful for dimensionality reduction and for obtaining information regarding (a) the number of independent causal variables required to account for the variability in the overall data set, (b) the extent to which a given variable contributes to a component and (c) the number of causal variables required to explain the total variability of each measured variable.