• 한국수소및신에너지학회논문집
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• 제35권2호
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• pp.185-194
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• 2024

Fe-Ni nanocatalysts loaded on carbon black were prepared via spontaneous reduction reaction of iron (II) acetylacetonate and nickel (II) acetylacetonate in dry process. Their morphology and elemental analysis were characterized by scanning electron microscopy, transmission electron microscopy (TEM), and energy dispersive X-ray analyzer. The loading weight of the nanocatalysts was measured by thermogravimetric analyze and the surface area was measured by BET analysis. TEM observation showed that Fe and Ni nanoparticles was well dispersed on the carbon black and their average particle size was 4.82 nm. The loading weight of Fe-Ni nanocatalysts on the carbon black was 6.83-7.32 wt%, and the value increased with increasing iron (II) acetylacetonate content. As the Fe-Ni loading weight increased, the specific surface area decreased significantly by more than 50%, because Fe-Ni nanoparticles block the micropores of carbon black. I-V characteristics showed that water electrolysis performance increased with increasing Ni nanocatalyst content.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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• pp.674-677
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• 2002

Vertically aligned CNTs were grown on Fe-deposited $SiO_2$ substrates using thermal CVD of acetylene gas. The size of Fe particle is controlled by the flow rate of $NH_3$ and pretreatment time, which leads to control the diameter of CNTs. As the diameter of CNTs decreases, the growth rate is enhanced with an inverse dependence of the CNT diameter. The growth rate of CNTs increases linearly as the growth time increases until 30 min but is rapidly decreased over 40 min. We found an inverse relation between the diameter and growth rate of carbon nanotubes. As the diameter of CNTs increases, the compartment layers of bamboo-shaped CNTs appear more frequently. A base-growth model is suitable to explain the dependence of growth rate and structure of CNTs on the diameter size of catalytic particles.

• Bulletin of the Korean Chemical Society
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• 제35권1호
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• pp.69-75
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• 2014

Accurate analysis of fly ash particles is not trivial because of complex nature in physical and chemical properties. SPLITT fractionation (SF) was employed to fractionate the fly ash particles into subpopulations in large quantities. Then the SF-fractions were analyzed by the steric mode of sedimentation field-flow fractionation (Sd/StFFF) for size analysis. The SF-fractions were also analyzed by ICP-OES. The results showed that the fly ash is mainly composed of Fe, Ca, Mg and Mn. No particular trends were observed between the particle size and the concentrations of Fe, Ca, Mg, while Mn, Cu and Zn were in higher concentrations in smaller particles. Sample preparation procedures were established, where the fly ash particles were sieved to remove large contaminants, and then washed with acetone to remove organics on the surface of particles. The sample preparation and analysis methods developed in this study could be applied to other environmental particles.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1191-1192
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• 2006

Eventhough Fe-6.5 wt.% Si alloy shows excellent magnetic properties, magnetic components made of the alloy are not totally because of its extremely low ductility. In order to overcome this demerit of alloy, 6.7 wt.% Si alloy powders were produced by gas atomization and then post-processed to form magnetic cores. By doing so, the total core loss could be minimized by reducing both hysteresis and eddy current loss. From our experiments, we were able to achive a core loss of $390mW/cm^3$ at 0.1 T and 50 kHz through proper processes and a permeability $\mu_{eff}$ of 68 at low frequency.

• Bulletin of the Korean Chemical Society
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• 제30권5호
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• pp.1009-1011
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• 2009

Nano-structured conducting polypyrroles were synthesized in the ionic liquids (ILs) based on 1-alkyl-3-methylimidazolium family with tetrachloroferrate as an anion ($C_n\;mim\;[FeCl_4]\;with\;n\;=\;4,\;8,\;and\;12$). The polypyrrole nanostructures synthesized in ILs were formed as spherical shapes. For ionic liquids with alkyl side chain length $C_4,\;C_4\;mim\;[FeCl_4]$, the size of particles was ranged around 60-nm with a relatively narrow size distribution. As the length of alkyl chain increases, the particle sizes become larger and their distributions become wider. The self-assembled local structures in the solvent ionic liquids are likely to serve as templates of highly organized nano-structured polymers. The length of the alkyl chain in ionic liquids seems to affect these local structures.

• 한국결정성장학회지
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• 제6권3호
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• pp.463-470
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• 1996

알파 알루미나와 철이 첨가된 티타니아 최종층으로 구성된 세라믹 여과막을 졸-겔방법으로 제조하였다. 철이 첨가된 지지 티타니아 복합여과막은 지지체를 혼합졸에 침지하여 제조하였다. 복합여과막을 $550^{\circ}C$에서 $850^{\circ}C$까지 열처리온도에 따르는 미세구조 변화를 주사전자현미경으로 조사하였다. $650^{\circ}C$에서 1시간 소결한 경우, 철이 첨기된 티타니아 복합여과막의 평균입자 크기는 약 40 nm이었다. 철이 첨가된 티나니아 복합여과막은 티타니아 복합여과막보다 열적 저항성이 우수하였다. 철이 첨가된 티타니아 복합여과막은 $650^{\circ}C$까지 균열이 없는 미세구조와 좁은 입도분포를 유지하였다.

• Environmental Engineering Research
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• 제25권3호
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• pp.335-344
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• 2020

This work describes highly efficient recovery and selective leaching of Zn from electric arc furnace dust (EAFD) with different physicochemical properties, induced by acid leaching at ambient conditions. The chemical compositions, mineralogical phases, and particle sizes of the EAFDs were analyzed and compared. The effects of leaching time, liquid/solid ratio, acid type, and acid concentration on the selective leaching of Zn were also studied. The EAFD with high Fe/Zn ratio (> 1, EAFD₃) was richer in ZnFe₂O₄ and exhibited larger particle size than samples with low Fe/Zn ratio (< 1, EAFD_1,2). ANOVA analysis revealed that the Fe/Zn ratios of the EAFDs also have a significant effect on Zn extraction (p < 0.005). Selective leaching of Zn with minimum Fe dissolution was obtained at pH > 4.5, regardless of other parameters or sample properties. The maximum Zn extraction rate obtained by the pH control was over 97% for EAFD₁ and EAFD₂, 76% for EAFD₃, and 80% for EAFD₄. The present results confirm that the Fe/Zn ratio can be used to identify EAFDs that permits facile and high-yield Zn recovery, and pH can be used as a process control factor for selective leaching of Zn regardless of any differences in the properties of the EAFD sample.

• Asian Journal of Atmospheric Environment
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• 제6권2호
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• pp.73-82
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• 2012

This study was aimed to thoroughly estimate the characteristics of indoor particulate matter (PM) collected on subway platforms by the cooperative approach of semi-bulk and single particle analyses. The size-resolved PM and its number concentration were measured on the platform in a heavily traveled subway station in Fukuoka, Japan. Particle Induced X-ray Emission (PIXE) and micro-PIXE techniques were applied to the chemical analyses of semi-bulk and single particle, respectively. There was the close resemblance of timely fluctuation between PM number concentration and train service on the third basement floor (B3F) platform compared to the second basement floor (B2F) and its maximum level was marked in rush hour. Higher number counts in large particles ($>1{\mu}m$) and lower number counts in fine particles ($<1{\mu}m$) were shown on the platform compared to an above ground. PM2.5 accounted for 58.2% and 38.2 % of TSP on B3F and on B2F, respectively. The elements that were ranked at high concentration in size-resolved semi-bulk PM were Fe, Si, Ca, S, and Na. The major elements tending to have more elevated levels on B3F than B2F were Fe (4.4 times), Ca (17.3 times), and Si (46.4 times). Although concentrations were very low, Cr ($11.9ng\;m^{-3}$ on B3F, $2.4ng\;m^{-3}$ on B2F), Mn ($3.4ng\;m^{-3}$ on B3F, $0.9ng\;m^{-3}$ on B2F), and Pb ($0.6ng\;m^{-3}$ on B3F, $1.6ng\;m^{-3}$ on B2F) were detected from PM2.5. Individual PM was nearly all enriched in Fe with Si and Ca. Classifying and source profiling of the individual particles by elemental maps and particle morphology were tried and particles were presumably divided into four groups (i.e., train/rail friction, train-rail sparking, ballast/abrasive, and cement).

• 한국자기학회지
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• 제9권2호
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• pp.78-84
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• 1999

고온연소합성법(self-propagating high temperature synthesis)을 이용하여(Ni, Zn)Fe2O4 분말을 제조하고 초기 분말의 크기와 산소압에 따른 생성물의 미세조직과 자기적 특성을 조사하였다. (Ni, Zn) 페라이트 분체는 다양한 입도의 Fe, Fe2O3, NiO, ZnO의 원료 분말을 n-hexane 용액에서 습식으로 spex mill을 사용하여 5분 혼합하고 12$0^{\circ}C$ 진공로에서 24시간 건조한 후 0.5~10기압의 산소압에서 고온연소합성 반응으로 제조하였다. 성형 압력이 없는 경우 평균 연소온도와 연소속도는 최대 약 125$0^{\circ}C$와 9.8mm/sec였으며 산소압과 ZnO입도가 감소하면 감소하였다. 고온연소합성된 시료는 다공질 구조를 갖고 있으며 X-선 회절 시험으로 시편들의 spinel구조를 관찰하였다. ZnO입도와 산소압이 증가하면 보자력, 최대자화, 잔류자화, 각형비 및 큐리 온도는 각각 13.24Oe, 43.88emu/g, 1.27emu/g, 0.0034emu/gOe, 37.8$^{\circ}C$에서 11.83Oe, 68.87emu/g, 1.23emu/g, 0.00280emu/gOe, 439.$^{\circ}C$와 7.99Oe, 75.84emu/g, 0.791emu/g, 0.001937emu/gOe, 53.8$^{\circ}C$로 변화하였다. 산소압에 따른 겉보기 활성화에너지를 고려하면 페라이트의 연소합성 반응은 ZnO입도와 산소압에 크게 의존한다.

• 한국산업융합학회 논문집
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• 제24권6_2호
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• pp.909-917
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• 2021

This study was carried out experimentally on the production and properties of silicon nanopowders characteristics using a transferred type arc plasma apparatus. To investigate the properties of silicon nanopowder, the purity of argon gas(99.999%, 99.9%) and the partial pressure ratio of nitrogen gas(0~90%) were varied. The total pressure in chamber is 400Torr and the silicon chunk amount used as raw material is 300g. The power supplied to the cathode to generate arc plasma was 9~12kW/h, and the electrode was made of tungsten and graphite with a diameter of 13mm. The particle size, impurity elements and powder evaporation rate of the silicon powder were analyzed using the XRD, FE-SEM, TEM and electronic scale. According to the purity of argon gas, the silicon evaporation rate and the particle size were similar, and impurities were generated more in the case of 99.9% purity than 99.999%. When argon gas and nitrogen gas were mixed in the chamber, the silicon evaporation rate and particle size increased as the partial pressure ratio of nitrogen gas increased. In particular, when the partial pressure ratio of nitrogen gas was 80%, the silicon evaporation rate 80g/h, and the particle size was about 80~100nm.