• Title/Summary/Keyword: Fe based intermetallic compounds

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Intermetallic Compounds Behavior at Laser Overlay Interface of Aluminum and Fe-based Powder (Al-Fe 레이저 오버레이층 경계면에서의 금속간화합물 거동)

  • Kang, Nam-Hyun;Yoo, Yeon-Gon;Lee, Chang-Woo;Kim, Jeong-Han
    • Journal of Welding and Joining
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    • v.25 no.3
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    • pp.51-56
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    • 2007
  • A $CO_2$ laser overlay was conducted by using a Fe-based powder on the AC2B aluminum substrate. Cracks and intermetallic compounds (IMC) were observed inconsistently along the interface between the overlay and post-molten layer. A scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS) detected some Fe-rich IMC ($Fe_3Al$, FeAl) as well as the brittle Al-rich IMC ($Fe_2Al_5,\;FeAl_3$). Micro vickers hardness proved the formation of Al-rich IMC ($FeAl_3$) along the interface by showing HV0.1 $800{\sim}900$. Furthermore, nano indentation was successfully applied to investigate the behavior of IMC more precisely than the micro vickers hardness.

Electronic Structure and Magnetism of Alloying Elements Substituted B2 FeAl Intermetallic Compounds: A Density Functional Study

  • Yun, Won Seok;Lee, Jee Yong;Kim, In Gee
    • Proceedings of the Korean Magnestics Society Conference
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    • 2012.11a
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    • pp.130-131
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    • 2012
  • In this study, the thermodynamic and magnetic properties of alloying element substituted B2 FeAl systems have been investigated using the all-electron FLAPW method based on the GGA. It was shown that the important changes take place in the structural properties as well as in the magnetism when alloying element is substituted by Fe or Al site in B2 FeAl. Detailed discussion on the thermodynamic and magnetic properties and electronic structure of these intermetallic compounds will be given.

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Effects of Induction Heating Conditions on Ni-Al Based Intermetallic Compound Coating (Ni-Al계 금속간화합물 코팅에 미치는 고주파유도 가열 조건의 영향)

  • Lee, Han-Young;Kim, Tae-Jun;Cho, Yong-Jae
    • Korean Journal of Metals and Materials
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    • v.48 no.2
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    • pp.141-147
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    • 2010
  • An Ni-Al intermetallic coating has been produced by induction heating on mild steel. The effect of the induction heating conditions on the microstructure of the coating has been investigated. The reaction synthesis of the intermetallic compounds was promoted while increasing the heating rate and the holding time at reaction temperature. Especially, an NiAl phase corresponding to the initial composition of mixed powder was predominantly formed. However, the synthesis at low reaction temperatures occurred by solid state diffusion during the holding time and an Fe-Al reaction layer was formed at the interface with the substrate, regardless of the heating rate. The combustion synthesis of the intermetallic compound occurred at a temperature higher than 1023 K and resulted in an almost single phase NiAl structure.

Microstructure and Fracture Property of 1A Grade Duplex Stainless Steel with the Addition of Gadolinium (가돌리늄(Gd) 첨가에 따른 1A 등급 듀플렉스 스테인레스 강의 미세조직 및 파괴 특성 변화)

  • Lim, Jae-han;Jung, Hyun-Do;Ahn, Ji-Ho;Moon, Byung-Moon
    • Journal of Korea Foundry Society
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    • v.36 no.1
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    • pp.24-31
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    • 2016
  • CD4MCU duplex stainless steel with gadolinium was fabricated as a neutron absorbing material by the air induction melting method. The gadolinium formed intermetallic compounds of Cu-Gd-Fe. There were no significant differences in hardness or ultimate tensile strength between experimental alloys. With the addition of gadolinium the yield strength of the cast alloy significantly increased, from $478.8{\pm}11.6$ to $514.2{\pm}29.9MPa$, whereas elongation of the cast alloy decreased with the addition of gadolinium, from $26.0{\pm}7.1$ to $7.0{\pm}2.5%$ due to the formation of gadolinium based intermetallic compounds.

Effect of Process Parameters on Laser Overlay Behavior of Fe-based Alloy Powder on Aluminum Substrate (공정 변수에 따른 Al 모재와 Fe계 합금 분말의 레이저 오버레이층 거동)

  • Yoo, Yeon-Gon;Kang, Nam-Hyun;Kim, Cheol-Hee;Kim, Jeong-Han;Kim, Mok-Soon
    • Journal of Welding and Joining
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    • v.25 no.1
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    • pp.30-36
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    • 2007
  • A joining of dissimilar metal combination faces significant problems such as poor strength and cracking associated with brittle intermetallic compounds(IMC) formed. An application of laser allows low heat input; leading to less dilution and smaller heat affected zone. The $CO_2$ laser overlay was conducted on an AC2B alloy with feeding Fe-based powders. The overlay area was significantly influenced from the travel velocity rather than the powder feeding rate. The interface between the overlay and substrate consisted of the hard and brittle IMC($FeAl_3,\;Fe_3Al,\;Fe_2Al_5$), which initiating and propagating the crack. The reciprocating test for the slide wear was conducted on a multi-pass overlay experiment. Comparing with the multi-pass overlay with no overlap, the overlay with 50% overlap showed better wear resistance.

A Study on Growth of Intermetallic Compounds Layer of Photovoltaic Module Interconnected by Multi-wires under Damp-heat Conditions (고온고습시험에 의한 멀티 와이어 PV 모듈의 금속 간 화합물 층의 성장에 관한 연구)

  • Moon, Ji Yeon;Cho, Seong Hyeon;Son, Hyoung Jin;Jun, Da Yeong;Kim, Sung Hyun
    • Current Photovoltaic Research
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    • v.8 no.4
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    • pp.124-128
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    • 2020
  • Output power of photovoltaic (PV) modules installed outdoors decreases every year due to environmental conditions such as temperature, humidity, and ultraviolet irradiations. In order to promote the installation of PV modules, the reliability must be guaranteed. One of the important factors affecting reliability is intermetallic compounds (IMC) layer formed in ribbon solder joint. For this reason, various studies on soldering properties between the ribbon and cell have been performed to solve the reliability deterioration caused by excessive growth of the IMC layer. However, the IMC layer of the PV module interconnected by multi-wires has been studied less than using the ribbon. It is necessary to study soldering characteristics of the multi-wire module for improvement of its reliability. In this study, we analyzed the growth of IMC layer of the PV module with multi-wire and the degradation of output power through damp-heat test. The fabricated modules were exposed to damp-heat conditions (85 ºC and 85 % relative humidity) for 1000 hours and the output powers of the modules before and after the damp-heat test were measured. Then, the process of dissolving ethylene vinyl acetate (EVA) as an encapsulant of the modules was performed to observe the IMC layer. The growth of IMC layer was evaluated using OM and FE-SEM for cross-sectional analysis and EDS for elemental mapping. Based on these results, we investigated the correlation between the IMC layer and output power of modules.

A Study on the Characteristics of Cast Bonding Aluminium Alloy and Fe-17wt%Cr Steel with Vacuum Die Casting (진공다이캐스트법에 의한 Al합금과 Fe-17wt%Cr 강의 주조접합 특성연구)

  • Kim, Yong-Hyun;Kim, Eok-Soo;Kim, Heung-Sik;Lee, Kwang-Hak
    • Journal of Korea Foundry Society
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    • v.19 no.5
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    • pp.410-418
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    • 1999
  • To overcome the undesirable deformation, peeling off and geometrical restrictions which were mainly caused by differences in thermal expansion coefficients during the cladding of aluminum strip and stainless strip, new processing method based on vacuum die casting is designed and implemented in fabricating Fe-17wt%Cr steel (stainless steel). To increase cast-bonding ability, the surface of Fe-17wt%Cr steel is electrochemical etched to have optimum pit size (above 0.2 mm) and pit density (above 30%). The implementation of vacuum die casting by using surface treated stainless steel (Fe-17wt%Cr Steel) produces good trial products having acceptable cast-bonding ability. The enabling conditions for cast-bonding are pouring temperature $690^{\circ}C$, filling speed 30 m/sec and casting pressure $800\;kg/cm^2$. The microscopic observation of cast-bonded Al/Fe-17wt%Cr steel does not show any evidence of intermetallic compounds. The bonding strength of trial products is $150-400\;kg/cm^2$ and this is stronger than conventionally cladded metal having $30-70\;kg/cm^2$.

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Density Functional Study on Correlation between Magnetism and Crystal Structure of Fe-Al Transition Metal Compounds (Fe-Al 전이금속 화합물의 자성과 결정구조의 상관관계에 대한 밀도범함수연구)

  • Yun, Won-Seok;Kim, In-Gee
    • Journal of the Korean Magnetics Society
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    • v.21 no.2
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    • pp.43-47
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    • 2011
  • It is known that the Fe-Al transition metal compounds have a lot of disagreement about structural stability and magnetism. In this study, the correlation between magnetism and atomic structure of ordered $B_2$, $L1_2$, and $D0_3$ structured Fe-Al compounds has been investigated using the all-electron full-potential linearized augmented plane wave (FLAPW) method based on the generalized gradient approximation (GGA). We found that considered all the structures were calculated to be stabilized in a ferromagnetic state. The calculated spin magnetic moments of the Fe atoms for B2 and $L1_2$ structures were 0.771 and 2.373 ${\mu}_B$, respectively, and that of Fe(I) and Fe(II) in $D0_3$ structure calculated to be 2.409 ${\mu}_B$, 1.911 ${\mu}_B$, respectively. In order to investigate structural stability between $L1_2$ and $D0_3$ structures, we performed the formation enthalpy calculations. As a result, the $D0_3$ structure is found to be more favorable than $L1_2 one by energy difference 16 meV/atom, which is well consistent with the experimental observation. We understood about structural stability and magnetism for Fe-Al compounds in terms of analysis of their atomic and electronic structures.

Effects of Galvannealing Temperatures on Iron-Zn Intermetallic Compounds and Friction Characteristic of Galvannealed Coatings (갈바어닐링온도변화가 합금화용융아연코팅의 합금상과 마찰특성에 미치는 영향)

  • Lee, Jung-Min;Kim, Dong-Hwan;Lee, Seon-Bong;Kim, Dong-Jin;Kim, Byung-Min
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.12
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    • pp.1107-1114
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    • 2008
  • This paper is aimed to understand the effect of different galvannealing temperatures on the frictional properties and Fe-Zn intermetallic phases of the galvannealed (GA) coatings on steel sheets. Their galvannealing treatments were conducted at 465, 505, 515 and $540^{\circ}C$ for about 10s in the additional heating furnace of an industrial continuous hot-dip galvanizing line. The mechanical and the frictional properties of the coatings were estimated using nanoindentation, nanoscratch, micro vickers hardness tests and flat friction tests, which were performed at contact pressures of 4, 20 and 80MPa. Also, the correlation between the microstructure and the frictional properties of the GA coatings were investigated by SEM observation for the cross-section of the GA coating after and before flat friction tests. The results showed that the mechanical and the frictional properties of the coatings are strongly dependent on their phase distributions and microstructure. Especially, in low contact pressure of 4MPa the frictional properties of the coatings were dependent on the surface phases and morphology, while in high contact pressure of 80MPa it was influenced by their mechanical properties based on the dominant phase distributions.