• 제목/요약/키워드: Fe analysis

검색결과 4,883건 처리시간 0.032초

X-ray Photoelectron Spectroscopy를 이용한 냉연 강판의 표면 분석 연구 (Surface Analysis of Cold Rolled Steel Sheets by X-ray Photoelectron Spectroscopy)

  • 이도형;소재춘
    • 분석과학
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    • 제7권1호
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    • pp.115-124
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    • 1994
  • 탈지과정을 거친 냉연 강판을 순수로 세정하는 과정에서 발생하는 rust와 이러한 rust 발생을 방지하기 위하여 0.05%(wt) $Na_5P_3O_{10}$ 용액으로 표면처리한 냉연 강판의 표면은 X-ray Photoelectron Spectroscopy(XPS) 방법으로 비교 분석하였다. Rust가 발생한 냉연 강판의 표면은 $Fe_2O_3$ 및 FeO, 그리고 $Fe(OH)_3$등으로 구성되는 산화층이 $1500{\AA}$정도의 두께로 존재함을 알 수 있었고, 한편 $Na_5P_3O_{10}$ 용액으로 표면처리한 냉연 강판의 표면은 $60{\AA}$정도의 인산염 피막이 얇은 Fe 산화층 위에 존재함으로써 보호 피막의 역할을 한다는 것을 알 수 있었다.

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고온 자전 연소합성법과 기계적 미분에 의한 준나노 크기의 Ba-Zn Ferrite 분말의 제조 (Preparation of Quasi-nano-sized of Ba-Zn Ferrites Powders by Self-Propagating High Temperature Synthesis and Mechanical Milling)

  • 최경숙;이종재;김혁돈;최용;이상헌
    • 전기학회논문지
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    • 제57권4호
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    • pp.625-628
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    • 2008
  • Ba-Zn ferrite powders for electromagnetic insulator were synthesized by self-propagating high-temperature synthesis(SHS) with a reaction of $xBaO_2+(1-x)ZnO+0.5Fe_2O_3+Fe{\rightarrow}Ba_xZn_{1-x}Fe_2O_4$. In this study, phase indentification of SHS products was carried out by using x-ray diffractometry and quasi-nano sized Ba-Zn powders were prepared by a pulverizing process. SHS mechanism was studied by thermodynamical analysis about oxidation reaction among $BaO_2,\;ZnO,\;Fe_2O_3$, and Fe. As oxygen pressure increases from 0.25 MPa to 1.0 MPa, the SHS reactions occur well and make clearly the SHS products. X-ray analysis shows that final SHS products formed with the ratio of $BaO_2/ZnO$ of 0.25, 1.0 and 4.0, are mainly $Ba_xZn_{1-x}Fe_2O_4$. Based on thermodynamical evaluation, the heat of formation increases in the order of $ZnFe_2O_4,\;BaFe_2O_4$, and $Ba_xZn_{1-x}Fe_2O_4$. This supports that $Ba_xZn_{1-x}Fe_2O_4$ phase is predominately formed during SHS reaction. The SHS reactions to form $Ba_xZn_{1-x}Fe_2O_4$ depends on oxygen partial pressure, and the heat of formation during the SHS reaction. The SHS reactions tends to occur well with increasing the oxygen partial pressure and BaO2/ZnO ratio in the reactants This means that the SHS reaction for the formation of Ba-Zn ferrite includes the reduction of BaO2/ZnO and the oxidation of Fe. $Ba_xZn_{1-x}Fe_2O_4$ powders after pulverizing is agglomeratedwith a size of about $50{\mu}m$, in which quasi-nano sized particles with about 300nm are present.

파단방지를 위한 튜브인발공정 최적 금형형상 설계에 관한 연구 (Optimal Die Profile Design in Tube Drawing Process for Prevention of Material Fracture)

  • 이상곤;김상우;이영선;이정환;김병민
    • 한국정밀공학회지
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    • 제23권11호
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    • pp.78-84
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    • 2006
  • The objective of this study is to design the optimal die profile that can prevent material fracture in the tube drawing process for automobile steering input shaft. First, the CDV(Critical Damage Value) of material is obtained by the compression test and FE-analysis. The occurrence of fracture is estimated by the FE-analysis considering the CDV. In order to achieve the objective of this study, optimization technique and FE-analysis are applied. FPS(Flexible Polyhedron Search) method, which is one of the non-gradient optimization techniques often used in engineering, is used to search optimal die profile. The drawing die profile is represented by Bezier-curve to generate all the possible die profile. Using FPS method and FE-analysis the optimal drawing die profile is determined. To verify tile effectiveness of the redesigned optimal die, the tube drawing experiment is performed. In the experimental result, it is possible to produce sound product without material fracture using the redesigned optimal die.

유한요소-전달강성계수법을 이용한 축대칭 원추형 셸의 구조해석 (Structural Analysis of Axisymmetric Conical Shells Using Finite Element-Transfer Stiffness Coefficient Method)

  • 최명수;변정환;여동준
    • 동력기계공학회지
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    • 제19권1호
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    • pp.38-44
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    • 2015
  • Various finite elements have been studied and developed to analyze a variety of structures in the finite element method(FEM). The transfer stiffness coefficient method(TSCM) is an effective algorithm for structural analysis but the structures which can be applied were limited. In this paper, a computational algorithm for the structural analysis of axisymmetric conical shells under axisymmetric loading is formulated using the finite element-transfer stiffness coefficient method(FE-TSCM). The basic concept of FE-TSCM is the combination of the modeling technique of FEM and the transfer technique of TSCM. The FE-TSCM has all the advantages of both FEM and TSCM. After carrying out the structural analysis of axisymmetric conical shells using FEM, FE-TSCM, and analytical method we compare the computational results of FE-TSCM with those of the other methods in terms of computational accuracy.

유한요소법을 이용한 쿨링팬의 진동 및 간섭에 관한 연구 (A Study on Resonance and Interference of a Cooling Fan Assembly by Using FEM)

  • 정일호;송하종;박태원;김주용
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2004년도 춘계학술대회논문집
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    • pp.919-924
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    • 2004
  • A CFA(Cooling Fan Assembly) is composed of a fan, motor and shroud, which is at the back of the automotive radiator. By forcing the wind to pass, the CFA controls the cooling performance of the radiator. The noise and vibration of the CFA may be primarily due to the resonance between the CFA and engine. The Interference among the fan, shroud and radiator by deformation is considered when the CFA is designed. In this paper, in order to analyze the structural vibration of the CFA for automobiles, a finite element model of the CFA is established by using a commercial FEM code. After the finite element modeling, the natural frequencies and the mode shapes are obtained from the FE analysis. The natural frequencies are obtained from the vibration test as well. Then, the results of the vibration test are compared with those of the FE analysis. The natural frequencies obtained by experiment have a great similarity to the results from FE model. We have confirmed the validity of the FE model and verify the structural safety for the resonance. The stress and displacements are obtained from FE analysis. We have confirmed the safety for the interference and failure.

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사출성형 유한요소해석과 연계한 비구면렌즈의 광학적 특성평가 (Evaluation of Optical Performance for an Aspheric Lens Connecting with FE Analysis of Injection Molding)

  • 박근;엄혜주;김종필;주원종
    • 소성∙가공
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    • 제16권1호
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    • pp.25-30
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    • 2007
  • The present study covers an integrated simulation method to evaluate optical performance of an aspheric plastic lens by connecting a finite element (FE) analysis of injection molding with a ray tracing simulation. Traditional ray tracing methods have based on the assumption that the optical properties of a lens are homogeneous throughout the entire volume. This assumption is to a certain extent unrealistic for injection-molded plastic lenses because material properties vary at every point due to the injection molding effects. To take into account the effects of the inhomogeneous optical properties of the molded lens, a new.ay tracing scheme is proposed in conjunction with a FE analysis of the injection molding. A numerical scheme is developed to calculate ray paths on every element layer with more realistic information of the refractive indices which can be obtained through the FE analysis. This information is then used to calculate the ray paths based on the FE mesh of which nodal points have unique index values. The proposed tracing scheme is implemented on the tracing of an aspheric lens, and its validity is ascertained through experimental verification.

풍력터빈 지지구조물의 볼트 체결된 L형 플랜지에 대한 인장 실험 및 FE해석 (Tensile Experiment and FE Analysis of L-type Flange Bolt Connection in Wind Turbine Support Structures)

  • 정대진;최익창
    • 풍력에너지저널
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    • 제15권2호
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    • pp.37-44
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    • 2024
  • In this study, a tensile test and FE analysis were conducted on a bolt-connected L-shaped flange to evaluate its behavior and load resistance. A total of five specimens were manufactured using the inner and outer distances and bolt diameters of the L-type flange as experimental variables. As a result of the tensile test of the L-shaped flange, as the internal and external length ratio (b/a) increased, the maximum load decreased and the maximum displacement increased. As the diameter (d) of the bolt increased, the maximum load and the deformation of the wall increased. The shapes of the destruction specimens showed two forms of destruction: one due to the fall of the nut and the surrender of the bolt as the thread of the bolt and nut was worn out, followed by the surrender of the wall. As a result of FE analysis, it was found that elasto-plastic model (EPM) analysis similarly tracks the behavior of the tensile test results.

혼합원자가 Sr$_{1+x}Er _{1-x} FeO _{4-y}$ 훼라이트계의 비화학양론과 물성연구 (A Study on Nonstoichiometry and Physical Properties of the Mixed Valency Sr$_{1+x}Er _{1-x} FeO _{4-y}$ Ferrite System)

  • 여철현;유광선;편무실;이성주;최중길
    • 대한화학회지
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    • 제35권2호
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    • pp.99-104
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    • 1991
  • $K_2NiF_4$형 층상 구조를 갖는 Sr$_{1+x}Er _{1-x} FeO _{4-y}$계에서 x = 0.00, 0.25, 0.50, 0.75 및 1.00인 비화학양론적 화합물 고용체를 1350$^{\circ}$C 대기압에서 제조하였다. X-선 회절 분석결과로 모든 조성에서 고용체의 결정 구조는 준정방정계(pseudo-tetragonal system)였다. 비화학양론적 조성식은 Mohr염 분석으로 결정하였다. Fe$^{4+}$ 이온의 양은 x값이 0.50까지 증가함에 따라 증가하다가 다시 감소하였고 산소 비화학량은 증가하였다. 도한 시료의 Fe$^{3+}$와 Fe$^{4+}$의 혼합원자가 상태를 298K에서 Mossbauer 분광분석으로 확인할 수 있었다. 전기전도도 측정 결과에 따르면 전기전도도는 반도체 영역인 10-2 ∼ 10-7(${\Omega}$-1cm-1)범위에서 변하였고, 활성화에너지는 Fe$^{4+}$의 몰비인 ${\tau}$값이 증가함에 따라 감소하였다. 전기전도성 메카니즘은 Fe$^{3+}$와 Fe$^{4+}$의 혼합원자가 상태간의 전도성전자 건너뜀 모델로 설명할 수 있다.

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KAERI 채널형 전단벽체의 동적해석; 시스템판별, FE 모델향상 및 시간이력 응답 (Dynamic Analysis of a KAERI Channel Type Shear Wall: System Identification, FE Model Updating and Time-History Responses)

  • 조순호
    • 한국지진공학회논문집
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    • 제25권3호
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    • pp.145-152
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    • 2021
  • KAERI has planned to carry out a series of dynamic tests using a shaking table and time-history analyses for a channel-type concrete shear wall to investigate its seismic performance because of the recently frequent occurrence of earthquakes in the south-eastern parts of Korea. The overall size of a test specimen is b×l×h =2500 mm×3500 mm×4500 mm, and it consists of three stories having slabs and walls with thicknesses of 140 mm and 150 mm, respectively. The system identification, FE model updating, and time-history analysis results for a test shear wall are presented herein. By applying the advanced system identification, so-called pLSCF, the improved modal parameters are extracted in the lower modes. Using three FE in-house packages, such as FEMtools, Ruaumoko, and VecTor4, the eigenanalyses are made for an initial FE model, resulting in consistency in eigenvalues. However, they exhibit relatively stiffer behavior, as much as 30 to 50% compared with those extracted from the test in the 1st and 2nd modes. The FE model updating is carried out to consider the 6-dofs spring stiffnesses at the wall base as major parameters by adopting a Bayesian type automatic updating algorithm to minimize the residuals in modal parameters. The updating results indicate that the highest sensitivity is apparent in the vertical translational springs at few locations ranging from 300 to 500% in variation. However, their changes seem to have no physical meaning because of the numerical values. Finally, using the updated FE model, the time-history responses are predicted by Ruaumoko at each floor where accelerometers are located. The accelerograms between test and analysis show an acceptable match in terms of maximum and minimum values. However, the magnitudes and patterns of floor response spectra seem somewhat different because of the slightly different input accelerograms and damping ratios involved.

관통구를 갖는 판구조물의 강도평가 방법에 관한 연구 (A Study on the Strength Evaluation Method of Plate Structures with Penetration-holes)

  • 김을년;장준태
    • 대한조선학회논문집
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    • 제54권6호
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    • pp.476-484
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    • 2017
  • The purpose of this paper is to verify the structural integrity of a region with numerous penetration-holes in offshore structures such as semi-submersible rig and FPSO. In order to effectively check the yielding and buckling strength of plate members with penetration-holes, a screening analysis program was developed with the FE analysis tool to generate fine meshed model using the theoretical and analysis methods. When a hole is appeared in the plate structure members, the flow of stress is altered such that concentrations of stress form near the hole. Stress concentrations are of concern during both preliminary and detail design and need to be addressed from the perspectives of strength. To configure the geometrical shape, very fine meshed FE analysis is needed as the most accurate method. However, this method is practically impossible to apply for the strength verifications for all perforated plates. In this paper, screening analysis method was introduced to reduce analysis tasks prior to detailed FE analysis. This method is applied to not only the peak stress calculation combined stress concentration factor with nominal stress but also nominal equivalent stress calculation considering cutout effects. The areas investigated by very fine meshed analysis were to be chosen through screening analysis without any reinforcements for penetration-holes. If screening analysis results did not satisfy the acceptance criteria, direct FE analysis method as the 2nd step approach were applied with one of the coarse meshed model considering hole or with the very fine meshed model considering the hole shape and size. In order to effectively perform the local fine meshed analysis, automatic model generating program was developed based on the MSC/PATRAN which is pre-post FE analysis program. Buckling strength was also evaluated by Common Structure Rule (CSR) adopted by IACS as the stress obtained from very fine meshed FE analysis. Due to development of the screening analysis program and automatic FE modeling program, it was able to reduce the design periods and structural analysis costs.