• Title/Summary/Keyword: Fe addition

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Enhanced salt coating on FeS2 surface with the addition of Li2O

  • Cheong, Hae-Won;Kang, Seung-Ho;Kim, Jong-Myong;Cho, Sung-Baek
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.198-201
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    • 2012
  • The electrolytes in thermal batteries are nonconductive solids at ambient temperature, which prevent the self-discharge and corrosion. To meet severe environmental requirements and guarantee acceptable handling yields, all the pellets in cells should have adequate strength, especially for the cathodes due to their poor binding properties among FeS2 particles. By modifying the surface microstructure of FeS2 through molten-salt heat treatment, the inter-particle binding strength is greatly increased, resulting in the enhanced pellet strength and yield. The addition of Li2O also promoted the soft salt coating coverage of hard FeS2 particles, which can be explained by the enhanced wettability of the molten salt.

Effects of $Ti^{+4}$ Addition to Ni-Cu-Co Ferrite on Microstructure, Magnetocrystalline Anisotropy and Magnetostriction ($Ti^{+4}$의 첨가가 Ni-Cu-Co Ferrite의 미세구조, 자기이방성, 자왜특성에 미치는 영향)

  • 정용무;주웅길
    • Journal of the Korean Ceramic Society
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    • v.16 no.4
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    • pp.225-236
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    • 1979
  • The effect of $Ti^{+4}$ addition on the sinterability, microstructure, and temperature dependence of electromechanical coupling factor of magnetostrictive Ni-Cu-Co ferrite was investigated. The density of Ni-Cu-Co ferrite slightly increased by 2.0 mole % addition of either $TiO_2$ or $Fe_2TiO_4$, but tended to decrease by more than 2.0 mole % addition of $TiO_2$ or $Fe_2TiO_4$. As the content of either $TiO_2$ or $Fe_2TiO_4$ increased, the magnetocrystalline anisotropy compensation temperature also increased. Microstructure studies showed the stable grains when Ni-Cu-Co ferrite was sintered above 1, 20$0^{\circ}C$.

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Effects of Additives on the Microstructure and Mechanical Properties in Porous Aluminum Titanate Ceramics (각종 첨가제가 다공성 Aluminum Titanate Ceramics의 미세구조 및 기계적 특성에 미치는 영향)

  • 김병훈;나용한
    • Journal of the Korean Ceramic Society
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    • v.31 no.2
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    • pp.137-146
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    • 1994
  • This experiments were focused on a modification of mechamical properties and structure in porous aluminum titanate ceramics by new additives which have been not researched yet. These were consisted of four kinds of additives i.e. Bi2O3, FeO, ZnO and NiO by addition amount of 1 wt% and 5 wt% respectively. The addition of Bi2O3 retarded a degree of syntehsis of aluminum titanate and accelerated in FeO, ZnO, NiO additives. Also, the most effective accelerator in synthesis of alunium titanate was FeO. A additives for the most effective of modification of microstructure, sharp distribtion of pore size and mechanical proterties was on ZnO addition and showed the lowest average pore size and narrowed pore size distribution. In order to improve of microstructure and pore size distribution in porous aluminum titanate ceramics was desired the addition amount of 1 wt% compare to 5 wt%.

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Effects of Cr and Fe Addition on Microstructure and Tensile Properties of Ti-6Al-4V Prepared by Direct Energy Deposition

  • Byun, Yool;Lee, Sangwon;Seo, Seong-Moon;Yeom, Jong-taek;Kim, Seung Eon;Kang, Namhyun;Hong, Jaekeun
    • Metals and materials international
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    • v.24 no.6
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    • pp.1213-1220
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    • 2018
  • The effects of Cr and Fe addition on the mechanical properties of Ti-6Al-4V alloys prepared by direct energy deposition were investigated. As the Cr and Fe concentrations were increased from 0 to 2 mass%, the tensile strength increased because of the fine-grained equiaxed prior ${\beta}$ phase and martensite. An excellent combination of strength and ductility was obtained in these alloys. When the Cr and Fe concentrations were increased to 4 mass%, extremely fine-grained martensitic structures with poor ductility were obtained. In addition, Fe-added Ti-6Al-4V resulted in a partially melted Ti-6Al-4V powder because of the large difference between the melting temperatures of the Fe eutectic phase (Ti-33Fe) and the Ti-6Al-4V powder, which induced the formation of a thick liquid layer surrounding Ti-6Al-4V. The ductility of Fe-added Ti-6Al-4V was thus poorer than that of Cr-added Ti-6Al-4V.

A Study for Magnetic Orientation Enhancement in Nd-Fe-B Sintered Magnets (Nd-Fe-B계 소결자석의 이방화율 향상을 위한 연구)

  • 김동환;임광윤;김효준;조재완;서응석;김승호;김상면
    • Journal of the Korean Magnetics Society
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    • v.11 no.1
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    • pp.8-13
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    • 2001
  • Effects of casting Processes and lubricant addition were studied to improve remanence of 31RE-68TM-lB based sintered magnet by using axial pressing process. Strip casting was effective to get the fine and homogeneous microstructure without ${\alpha}$-Fe segregation. The strip cast flake resulted in narrower particle size distribution after jet milling with respect to the conventional cast ingot. During pressing step with a magnetic field, the particle alignment was increased by appropriate addition of liquid lubricant. In this study, it was revealed that narrow particle size distribution and appropriate addition of liquid lubricant were essential to improve the grain alignment and thus the remanence of Nd-Fe-B sintered magnet.

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Effects of Fe2O3 Addition on Optical and Electrical Properties of MgO Films as a Protective Layer for AC PDPs (Fe2O3 첨가에 따른 AC PDP 보호막용 MgO 박막의 광학적.전기적 특성)

  • Kim, Chang-II;Jeong, Young-Hun;Lee, Young-Jin;Paik, Jong-Hoo;choi, Eun-Ha;Jung, Seok;Kim, Jeong-Seok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.9
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    • pp.760-765
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    • 2009
  • The effects of $Fe_2O_3$ addition on optical and electrical properties of MgO films as a protective layer for AC plasma display panels were investigated. Doped MgO films prepared by the e-beam evaporation have a higher ${\gamma}$ (secondary electron emission coefficient) than pure MgO protective layer. Roughness increased with amount of $Fe_2O_3$ up to 100 ppm and then decreased further addition. These results showed that discharge properties and optical properties of MgO protective layers seemed to be closely related with microstructure factors such as roughness. Good optical and electrical properties of ${\gamma}$ of 0.120, surface roughness of 14.1 nm and optical transmittance of 94.55% were obtained for the MgO + 100 ppm $Fe_2O_3$ protective layer sintered at $1700^{\circ}C$ for 5 hrs.

NiSO4 Supported on FeO-promoted ZrO2 Catalyst for Ethylene Dimerization

  • Sohn, Jong-Rack;Kim, Young-Tae;Shin, Dong-Cheol
    • Bulletin of the Korean Chemical Society
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    • v.26 no.11
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    • pp.1749-1756
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    • 2005
  • The $NiSO_4$ supported on FeO-promoted $ZrO_2$ catalysts were prepared by the impregnation method. FeOpromoted $ZrO_2$ was prepared by the coprecipitation method using a mixed aqueous solution of zirconium oxychloride and iron nitrate solution followed by adding an aqueous ammonia solution. The addition of nickel sulfate (or FeO) to $ZrO_2$ shifted the phase transition of $ZrO_2$ (from amorphous to tetragonal) to higher temperatures because of the interaction between nickel sulfate (or FeO) and $ZrO_2$. 10-$NiSO_4$/5-FeO-$ZrO_2$ containing 10 wt % $NiSO_4$ and 5 mol % FeO, and calcined at 500 ${^{\circ}C}$ exhibited a maximum catalytic activity for ethylene dimerization. $NiSO_4$/FeO-$ZrO_2$ catalysts was very effective for ethylene dimerization even at room temperature, but FeO-$ZrO_2$ without $NiSO_4$ did not exhibit any catalytic activity at all. The catalytic activities were correlated with the acidity of catalysts measured by the ammonia chemisorption method. The addition of FeO up to 5 mol % enhanced the acidity, surface area, thermal property, and catalytic activities of catalysts gradually, due to the interaction between FeO and $ZrO_2$ and due to consequent formation of Fe-O-Zr bond.

Growth and community response of phytoplankton by N, P and Fe nutrient addition in around water of Ulleungdo and Dokdo in East Sea (동해 울릉도-독도해역에서 질소, 인, 철 첨가실험에 따른 식물플랑크톤의 성장 및 군집반응)

  • Baek, Seung Ho;Lee, Minji;Kim, Yun-Bae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.11
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    • pp.186-195
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    • 2016
  • We investigated phytoplankton and vertical inorganic nutrients at two stations around water of Ulleungdo and Dokdo in the East Sea, Korea. Nutrient addition experiments (+N, +P, +NP and +Fe) were also conducted to determine the growth response and nutrient consumption of the phytoplankton assemblage using the surface water of St. UD3 and St.50. In the field, although inorganic nutrients were low in the euphotic layer, these nutrients were increased at depths below 100 m. The total phytoplankton abundances in St. UD3 and St.50 were $4.9{\times}10^5cells\;L^{-1}$ and $1.9{\times}10^5cells\;L^{-1}$, respectively. The dominant species at St. UD3 was observed to be Raphidophyta Heterosigma akashiwo, Cryptophyta Crytomonas spp., and diatom Leptocylindrus danicus, while L. danicus and H. akashiwo including small diatom species Chaetoceros socialis were dominant at St. 50. In the nutrient addition experiments, phytoplankton growth (in vivo flourescence) in the +N and +NP treatment was 2-3 times higher than that in the +P treatment, indicating that the natural phytoplankton can respond to pulsed nutrient loading events. In addition, in vivo fluorescence in +Fe treatment was not statistically (p>0.05) different from that of the non-Fe treatments, indicating that the phytoplankton growth response in +Fe treatment was not significant. Dominant H akashiwo and L. danicus in the field showed a rapid response in nutrient additional bio-algal assay, particularly L. danicus in the +Fe treatments.

Study on the HDDr Characteristics of $Nd_{16}Fe_{76-x}B_8Zr_x$ (x0-2.0) Alloys and the Magnetic Properties of the HDDR Materials

  • Kwon, H.W.
    • Journal of Magnetics
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    • v.1 no.2
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    • pp.75-81
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    • 1996
  • Study on the HDDr Characteristics of Nd16Fe76-xB8Zrx (x=0-2.0) Alloys and the Magnetic Properties of the HDDR Materials Nd16Fe76-xB8Zrx (where x=0-2.0) have been studied to see the effect of Zr addition on HDDR characteristics. A particular emphasis was place upon the anisotropy of the HDDR material. Anisotropy of the HDDR powder material has been evaluated by comparing the remanence values of the aligned sample measured along the aligning direction and the direction perpendicular to it. The HDDR characteristics of the alloys were investigated by means of DAT and TPA. Magnetic chracterisation of the HDDR processed materials was performed using a VSM and a TMA. The magnetic domain structure of the HDDR materials was examined by means of polarised microscope using a solid HDDR processed material. It has veen found that small addition (0.1 at %) of Zr to Nd-Fe-B-type alloy retards thedisproportionatio kinetics of the hydrogenated material. Desorption characteristic of the disproportionated materials has been found not to be affected significantly by the Zr addition. The Zr addition has been found to facilitate size of the powder. As the particle size decreases, the intrinsic coercivity decreases radically, and this is explained in terms of structural damage and/or oxidation caused during mechanical milling. It has also been found that the degree of alignment representing the anisotropic character of the HDDR powder is enhanced with decreasing particle size. Alloys with compositions based on

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Effect of DyFeO3 Addition on Crystal Structure and Ferrcelectricity of the BiFeO3-PbTiO3 System

  • Kim, Seong-Seog;Kwon, Jong-Uk;Cheon, Chae Il
    • Journal of the Korean Ceramic Society
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    • v.42 no.5 s.276
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    • pp.299-303
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    • 2005
  • The crystal structure and ferroelectricity of the $(1-x)BiFeO_3\;(BF)-xPbTiO_3$ (PT) ceramic system with the addition of $DyFeO_3$ (DF) have been investigated for attaining a high temperature piezoelectric material. This study is focused on the relation between crystal structure and ferroelectric property with the addition of DF over the phase boundary in the (1-x)BF-xPT system. Hysteresis curves of polarization-electric field at room temperature have been measured. The X-ray and neutron diffraction data were analyzed by the rietveld refinement method. The addition of 0.1 mole DF into BF-PT system greatly increases the ferroelectric remanant polarization Pr values, e.g. 17 ${\mu}C/cm^2$ in 0.6BF-yDF-(0.4-y)PT and 31${\mu}C/cm^2$ in 0.5BF-yDF-(0.5.y)PT, respectively. The improved Pr value has been discussed in relation with crystal structure and electrical property.