• 제목/요약/키워드: Fe addition

검색결과 2,008건 처리시간 0.032초

Effect of mechanical alloying on the microstructural evolution of a ferritic ODS steel with (Y-Ti-Al-Zr) addition processed by Spark Plasma Sintering (SPS)

  • Macia, E.;Garcia-Junceda, A.;Serrano, M.;Hong, S.J.;Campos, M.
    • Nuclear Engineering and Technology
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    • 제53권8호
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    • pp.2582-2590
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    • 2021
  • The high-energy milling is one of the most extended techniques to produce Oxide dispersion strengthened (ODS) powder steels for nuclear applications. The consequences of the high energy mill process on the final powders can be measured by means of deformation level, size, morphology and alloying degree. In this work, an ODS ferritic steel, Fe-14Cr-5Al-3W-0.4Ti-0.25Y2O3-0.6Zr, was fabricated using two different mechanical alloying (MA) conditions (Mstd and Mact) and subsequently consolidated by Spark Plasma Sintering (SPS). Milling conditions were set to evidence the effectivity of milling by changing the revolutions per minute (rpm) and dwell milling time. Differences on the particle size distribution as well as on the stored plastic deformation were observed, determining the consolidation ability of the material and the achieved microstructure. Since recrystallization depends on the plastic deformation degree, the composition of each particle and the promoted oxide dispersion, a dual grain size distribution was attained after SPS consolidation. Mact showed the highest areas of ultrafine regions when the material is consolidated at 1100 ℃. Microhardness and small punch tests were used to evaluate the material under room temperature and up to 500 ℃. The produced materials have attained remarkable mechanical properties under high temperature conditions.

Experimental study of graphene oxide on wollastonite induced cement mortar

  • Sairam, V.;Shanmugapriya, T.;Jain, Chetan;Agrahari, Himanshu Kumar;Malpani, Tanmay
    • Advances in concrete construction
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    • 제12권6호
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    • pp.479-490
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    • 2021
  • Present research is mainly focused on, microstructural and durability analysis of Graphene Oxide (GO) in Wollastonite (WO) induced cement mortar with silica fume. The study was conducted by evaluating the mechanical properties (compressive and flexural strength), durability properties (water absorption, sorptivity and sulphate resistance) and microstructural analysis by SEM. Cement mortar mix prepared by replacing 10% ordinary portland cement with SF was considered as the control mix. Wollastonite replacement level varied from 0 to 20% by weight of cement. The optimum replacement of wollastonite was found to be 15% and this was followed by four sets of mortar specimens with varying substitution levels of cementitious material with GO at dosage rates of 0.1%, 0.2%, 0.3% and 0.4% by weight. The results indicated that the addition of up to 15%WO and 0.3% GO improves the hydration process and increase the compressive strength and flexural strength of the mortar due to the pore volume reduction, thereby strengthening the mortar mix. The resistance to water penetration and sulphate attack of mortar mixes were generally improved with the dosage of GO in presence of 15% Wollastonite and 10% silica fume content in the mortar mix. Furthermore, FE-SEM test results showed that the WO influences the lattice framework of the cement hydration products increasing the bonding between silica fume particles and cement. The optimum mix containing 0.3% GO with 15% WO replacement exhibited extensive C-S-H formation along with a uniform densified structure indicating that calcium meta-silicate has filled the pores.

4MW급 풍력발전기용 요 감속기 설계 (Yaw Gearbox Design for 4MW Class Wind Turbine)

  • 이형우;김인환;이재신
    • 융합정보논문지
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    • 제12권2호
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    • pp.142-148
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    • 2022
  • 본 논문은 풍력발전기용 요 감속기를 경량화하여 유한요소해석과 위험속도해석을 통해 안정성검증을 하였다. 제품의 경량화는 엔진의 효율을 높일 수 있으며, 부품의 소재를 절약하여 경제적 이득을 취할 수 있다. IEC 61400-1에서 제시한 풍력발전기 부품의 안전율 1.3이상을 목표로 풍력발전기용 요 감속기를 경량화하였다. 위상 최적화를 수행한 캐리어를 유한요소해석을 수행하여 안전율을 나타냈고, 하우징과 최적화한 캐리어를 MASTA11을 활용하여 작성한 풍력발전용 요 감속기 기어트레인 모델과 부분구조합성법으로 연결하여 고유 모드와 고유진 동수를 파악하여 질량불평형과 치통과 주파수에 대하여 위험속도해석을 수행하였고, 캠벨 선도(Campbell Diagram)를 작성하여 안정성 검증을 하였다.

Effect of dietary salicylic acid supplementation on performance and blood metabolites of sows and their litters

  • Serge, Muhizi;Sungbo, Cho;Thanapal, Palanisamy;In Ho, Kim
    • Journal of Animal Science and Technology
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    • 제64권4호
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    • pp.707-716
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    • 2022
  • The core intention to undertake this experiment for a period of 21 days is to evaluate the effect of salicylic acid (SA) supplemented diet on the performance and blood metabolites of sows and their litters. Sows weighing 208.5 ± 18.34kg and their neonates were used. From day 114 of gestation to 21st day of lactation(weaning), ten multiparous sows (n = 5/treatment) (Landrace × Yorkshire) were assigned randomly into one of two treatments: CON (basal diet) and TRT (CON + 0.05% SA). There was no significant difference in the body weight, backfat thickness, backfat loss, and body condition score in SA treated sows compared to sows fed the CON diet. However, the bodyweight of sow was dramatically reduced by an average of 16kg from farrowing to weaning time. The dietary inclusion of SA in the sow diet slightly improved the survival rate (p = 0.065) and showed a higher body weight (p = 0.009) in piglets. However, there was no significant difference in red blood cell, Fe, Hematocrit, and Hb concentrations between CON and TRT sows' groups, but the total iron-binding capacity (TIBC) was significantly reduced in sows from the TRT group compared with the CON group from the beginning to weaning. The outcome of this trial shows that dietary addition of SA on sows diet from early lactation could increase the birth weight and TIBC of neonates at the end of the trial.

탄소강 및 해드필드강의 파이프 조관에 따른 침식부식 거동에 대한 비교연구 (Comparing Erosion-Corrosion Behaviors of Carbon Steel and Hadfield Steel According to Pipe Forming)

  • 윤덕빈;박진성;이상철;최종교;황중기;김성진
    • Corrosion Science and Technology
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    • 제21권3호
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    • pp.209-220
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    • 2022
  • Erosion-corrosion behaviors of Hadfield steel under a neutral aqueous environment with fine SiO2 particles were examined and compared with those of conventional carbon steel. A range of electrochemical experiments (potentiodynamic polarization, linear polarization, and impedance), immersion test, and slurry pot test (i.e., erosion-corrosion test) were performed. Results showed that the Hadfield steel composed of austenitic matrix with (Fe,Mn)-based carbide had lower corrosion potential and higher corrosion current density than carbon steel with a typical ferrite/pearlite structure. In addition, pipe forming increased total corrosion rates (i.e., pure corrosion and erosion-enhanced corrosion rates). Nevertheless, the erosion-corrosion rate of Hadfield steel was much smaller. Morphological observation showed that local damage in the form of a crater by erosion-corrosion was more noticeable in carbon steel. The higher resistance of Hadfield steel to erosion-corrosion was attributed to its lower total erosion rates (i.e., pure erosion and corrosion-enhanced erosion rates) highly depending on surface hardness. This study suggests that Hadfield steel with higher resistances to flowing erosion-corrosion in an aqueous environment can be applied widely to various industrial fields.

Effects of High-Energy Ball Milling and Sintering Time on the Electric-Field-Induced Strain Properties of Lead-Free BNT-Based Ceramic Composites

  • Nga-Linh Vu;Nga-Linh Vu;Dae-Jun Heo;Thi Hinh Dinh;Chang Won Ahn;Chang Won Ahn;Hyoung-Su Han;Jae-Shin Lee
    • 한국전기전자재료학회논문지
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    • 제36권5호
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    • pp.505-512
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    • 2023
  • This study investigated crystal structures, microstructures, and electric-field-induced strain (EFIS) properties of Bi-based lead-free ferroelectric/relaxor composites. Bi1/2Na0.82K0.18)1/2TiO3 (BNKT) as a ferroelectric material and 0.78Bi1/2(Na0.78K0.22)1/2TiO3-0.02LaFeO3 (BNKT2LF) as a relaxor material were synthesized using a conventional solid-state reaction method, and the resulting BNKT2LF powders were subjected to high-energy ball milling (HEBM) after calcination. As a result, HEBM proved a larger average grain size of sintered samples compared to conventional ball milling (CBM). In addition, the increased sintering time led to grain growth. Furthermore, HEBM treatment and sintering time demonstrated a significant effect on EFIS of BNKT/BNKT2LF composites. At 6 kV/mm, 0.35% of the maximum strain (Smax) was observed in the HEBM sample sintered for 12 h. The unipolar strain curves of CBM samples were almost linear, indicating almost no phase transitions, while HEBM samples displayed phase transitions at 5~6 kV/mm for all sintering time levels, showing the highest Smax/Emax value of 700 pm/V. These results indicated that HEBM treatment with a long sintering time might significantly enhance the electromechanical strain properties of BNT-based ceramics.

남동해 연안 퇴적물 내 미량금속 분포 및 생태위해도 평가 (Trace Metal Distribution and Ecological Risk Assessment in Marine Sediments from the Southeast Coastal Areas of Korea)

  • 황동운;최민규;임재현;이인석;이가람;나수진
    • 한국수산과학회지
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    • 제56권4호
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    • pp.438-448
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    • 2023
  • The concentrations of trace metals and organic matters in marine sediments collected from southeast Korean coastal areas were investigated. The primary purpose of this study was to evaluate the contamination status, spatial distribution and potential ecological risks associated with the physiochemical composition in the studied areas. We found that the concentrations of trace metals in marine sediments were as follows: Fe > Mn > Zn > Cr > Pb > Cu > As > Cd > Hg. According to the sediment quality guidelines (SQGs) of Korea, concentrations of Zn, Cr, Cu and Cd at all sampling sites were below threshold effect levels (TEL). However, concentrations of As, Hg, and Pb (i.e., at the 94-98% of sampling sites), were below the TEL. In addition, concentration factors (CF) in the surveyed area were found to be associated with low ecological risks, whereas As, Hg, and Cu showed moderate to high risk levels in some inner parts of the studied bays. Finally, the pollution load index (PLI) and ecological risk index (ERI) of the elucidated metals were linked to moderate ecological risk, pointing to the possibility of being deleterious to some benthic organisms.

Sources, Components, Structure, Catalytic Mechanism and Applications: a Critical Review on Nicotinate Dehydrogenase

  • Zhi Chen;Xiangjing Xu;Xin Ju;Lishi Yan;Liangzhi Li;Lin Yang
    • Journal of Microbiology and Biotechnology
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    • 제33권6호
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    • pp.707-714
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    • 2023
  • Plant-derived insecticide-neonicotinoid insecticides (NIs) played a crucial role in the development of agriculture and food industry in recent years. Nevertheless, synthesis of these nitrogen-containing heterocyclic compounds with an effective and greener routing remains challenging especially to the notion raise of "green chemistry" and "atom economy". While bio-catalyzed methods mediated by nicotinate dehydrogenase (NDHase) then provide an alternative. The current review mainly focuses on the introduction of sources, components, structure, catalytic mechanism and applications of NDHase. Specifically, NDHase is known as nicotinic acid hydroxylase and the sources principally derived from phylum Proteobacteria. In addition, NDHase requires the participation of the electron respiratory chain system on the cell membrane. And the most important components of the electron respiratory chain are hydrogen carrier, which is mainly composed of iron-sulfur proteins (Fe-S), flavin dehydrogenase (FAD), molybdenum binding protein and cytochromes. Heterologous expression studies were hampered by the plasmid and host with high efficiency and currently only Pseudomonas entomophila L48 as well as Comamonas testosterone was successfully utilized for the expression of NDHase. Furthermore, it is speculated that the conjugate and inductive effects of the substituent group at position 3 of the substrate pyridine ring exerts a critical role in the hydroxylation reactions at position 6 concerning about the substrate molecular recognition mechanism. Finally, applications of NDHase are addressed in terms of pesticide industry and wastewater treatment. On conclusion, this critical review would not only deepen our understanding of the theory about NDHase, but also provides the guideline for future investigation of NDHase.

하천 호안 콘크리트 블록이 수질 및 토양환경에 미치는 영향평가 (Evaluation of the Effect of Bank Protection Concrete Blocks on Water and Soil Environmental Impact)

  • 유재환;박윤식;신현오;이건희;이보현;차상선;박찬기
    • 한국농공학회논문집
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    • 제65권1호
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    • pp.51-59
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    • 2023
  • The study is to evaluate the effect of bank protection concrete block products to streams and soils. The effect on three types of bank protection concrete blocks was evaluated.. The first type was manufactured using fly ash, and the second and third type products used fine blast furnace slag powder. The laboratory and field Experiments test results showed the pHs of 9 or less. Also, any heavy metals were not detected in the heavy metal leaching tests. Although some iron (Fe) was partially detected, it still met the water quality standards. In addition, heavy metal was detected from all blocks by the US drinking water evaluation standards method. An on-site water quality and soil contamination tests were performed at the places that the blocks were implemented in practice. The test results showed that the application of the bank protection concrete block product did not lead to the water and soil quality degradation. Therefore, it was found that the hardened bank protection concrete block product did not elute harmful substances such as heavy metals that affect water and soil quality degradation.

실동이력에 기초한 곡선거더교의 피로균열 특성 및 분석 (Characteristic and Analysis of Fatigue Crack for Curved Girder Bridge based on the Stress Range Histerisis)

  • 권순철;경갑수;김대용;이해성
    • 대한토목학회논문집
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    • 제28권1A호
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    • pp.1-13
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    • 2008
  • 곡선거더교의 복부는 교축방향의 면내응력과 면외 휨응력을 동시에 받는 구조이므로, 직선교에 비하여 플랜지와 복부의 필릿용접이음부에서의 발생응력이 상당히 크며, 또 바닥틀이나 브레이싱을 주거더에 연결시켜주는 거셋플레이트는 구조적으로 더욱 취약한 구조가 된다. 본 연구에서는 23년간 공용된 곡선거더교에서 발생된 피로균열의 발생원인을 조사하기 위하여 실제교통 흐름 하에서의 용접부에서의 응력특성을 파악하기 위하여 일련의 현장측정을 실시하였다. 이들 현장측정으로부터 여러 가지 타입에 대한 피로균열 원인을 분석하였고, 또한 주요 균열에 대한 피로수명을 평가하였다. 또한 곡선거더교 용접이음부의 구조거동 특성을 조사하기 위하여 유한요소해석을 실시하고 이들 결과를 현장측정결과와 비교분석하였다.