• 제목/요약/키워드: Fe (III)

검색결과 568건 처리시간 0.025초

Monitoring observation of PG0934+013 using The Southern African Large Telescope

  • Park, Dawoo;Woo, Jong-Hak;Romero-Colmenero, Encarni;Crawford, Steven M.;Barth, Aaron J.;Pei, Liuyi
    • 천문학회보
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    • 제38권2호
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    • pp.54-54
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    • 2013
  • We performed spectroscopic and photometric monitoring observations of a QSO, PG0934+013 for a reverberation-mapping analysis, using the 9-m Southern African Large Telescope (SALT) for spectroscopy and the 2-m Faulkes Telescope North and the South for photometry. The monitoring campaign was carried out for 5 month between December 2012 to April 2013, providing 20 spectroscopic epochs and ~40 photometric epochs. Based on the obtained spectra, which typically have a signal-to-noise ratio to 30-60, we performed multicomponent decomposition using various components, i.e., power-law continuum, FeII emission complex, and broad and narrow emission lines, to properly measure the Hbeta line flux. After a flux normalization using [O III] 5007 line luminosity, we obtained a rms spectrum from all epochs, which shows clear variability of Hbeta line. We find that Hbeta line flux decreases by ~20% during the monitoring period while the continuum flux obtained from the aperture photometry based on the imaging data, shows similar variability. The current Hbeta light curve shows monotonic decrease and a reliable cross correlation analysis between Hbeta and continuum light is difficult. Nevertheless, we obtained a preliminary lag measurements as ~24 light days.

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Yonsei Evolutionary Population Synthesis (YEPS) Model -III. Spectrophotometric Evolutions of Simple Stellar Population Models based on Empirical Spectra

  • Chung, Chul;Yoon, Suk-Jin;Lee, Young-Wook
    • 천문학회보
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    • 제38권2호
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    • pp.38.1-38.1
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    • 2013
  • We present the Yonsei evolutionary population synthesis (YEPS) models based on the high-resolution empirical spectral energy distributions (SEDs). We have adopted the MILES library in the optical wavelength, and our new models based on the MILES library show good agreements with our previous models presented in the YEPS I. The effect of hot horizontal-branch (HB) stars on the integrated properties of simple stellar populations (SSPs) is again confirmed by our models based on empirical SEDs. In addition, we have extended our empirical models to the near-IR wavelength and predicted the strengths of the calcium II triplet (CaT) and the Paschen triplet (PaT) based on the INDO-US and the Cenarro library. We find that the effect of HB stars and the age of SSPs on the CaT is almost negligible. On the other hands, the PaT models are very sensitive to the existence of hot stars, e.g., HB stars and young turn-off stars, and show very similar results with Balmer lines. Interestingly, the CaT distribution of GCs in NGC 1407, which is at odds with the optical (B-I) color distribution, can be explained by the unique feature of the CaT-[Fe/H] relations that show almost the same equivalent widths in the metal-rich regime. We will also discuss the impact of the second-generation populations on the strength of the CaT.

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부평광산(富平鑛山)의 금광석(金鑛石)과 선광산물(選鑛産物) (Silver Ore and Floatation Products from the Bupyeong Mine)

  • 박희인;박노영;서규식
    • 자원환경지질
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    • 제19권2호
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    • pp.85-96
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    • 1986
  • The Bupyeong Silver mine which is located approximately 35km west of Seoul is currently the leading silver producer in Korea. The deposits occur as stockwork deposits hosted in Jurassic pyroclastic rocks. Occurrences of ore deposits and mineral paragenesis suggest a division of mineralization into four stages: Stage I, deposition of iron oxide and base metal sulfides; Stage II, deposition of tin oxide and silverm inerals; stage III, deposition of native silver and other silver minerals; Stage IV, formation of pyrite bearing siderite veinlets, Silver minerals in ore are native silver, argentite, freibergite, pyrargyrite, canfieldite, polybasite, dyscrasite and Ag-Fe-S mineral. The most important silver mineral is native silver among them. Chemical composition of important silver minerals were determined by electron probe microanalyser. Assay, size and modal analyses for floatation products were carried out. In floatation products, relative proportion of native silver for total important silver minerals have following ranges: feed, 64.7 to 74.74 wt.%; A-cleaner concentrate, 80.58 to 98.79 wt.%; and final tailing, 28.12 to 72. 57 wt. %. Average degree of liberation for native silver in feed and A-cleaner concentrate are 60.49% and 77.57% respectively. Negative relationship can be recognized between native silver and argentite in their abundance and behavior in floatation precesses.

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아크릴 섬유의 아미도옥심화에 관한 연구(I) -아미도옥심 반응과 천이금속의 흡착능- (Studies on Amidoximated Acrylic Fiber(I) -Amidoximation and Adsorption Capacity to Transition Metals -)

  • Chin, Young Gil;Kim, Kyu Beom
    • 한국염색가공학회지
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    • 제8권6호
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    • pp.40-46
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    • 1996
  • In order to investigate a practical application of fibrous absorbents to transition metals such as copper, nickel, cobalt, chrome, and iron, amidoximated fiber as a particular class of solid chelate agents were prepared from acrylic fibers treatment with hydroxylamine. The adsorption mechanisms of metal ions onto amidoximated acrylic fibers and their complexes were studied. Amidoximation of acrylic fiber with hydroxylamine is found to be first-order reaction, followed by the disappearance of infrared adsorption peaks due to nitrile groups of acrylic fibers. The uptake of metal ions onto amidoximated acrylic fiber is increased with temperature raising and the adsorption is also depended on pH of the soiutions. About 70% of metal ions can be recovered from aqueous solutions of Ni(II), Co(II), Cr(III), and Fe(II) on the concentration below 5x 10$^$^{-4}$ in the range of pH 2.1~10.0. Transition metals are adsorbed to form complex with amidoxime group by the ligand sites such as C=N, NH, NO, NHOH.OH.

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Catalytic Oxidoreduction of Pyruvate/Lactate and Acetaldehyde/Ethanol Coupled to Electrochemical Oxidoreduction of $NAD^+$/NADH

  • Shin, In-Ho;Jeon, Sung-Jin;Park, Hyung-Soo;Park, Doo-Hyun
    • Journal of Microbiology and Biotechnology
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    • 제14권3호
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    • pp.540-546
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    • 2004
  • We deviced a new graphite-Mn(II) electrode and found that the modified electrode with Mn(II) can catalyze NADH oxidation and $NAD^+$ reduction coupled to electricity production and consumption as oxidizing agent and reducing power, respectively. In fuel cell with graphite-Mn(II) anode and graphite-Fe(III) cathode, the electricity of 1.5 coulomb (A x s) was produced from NADH which was electrochemically reduced by the graphite-Mn(II) electrode. When the initial concentrations of pyruvate and acetaldehyde were adjusted to 40 mM and 200 mM, respectively, about 25 mM lactate and 35 mM ethanol were produced from 40 mM pyruvate and 200 mM acetaldehyde, respectively, by catalysis of ADH and LDH in the electrochemical reactor with $NAD^+$ as cofactor and electricity as reducing power. By using this new electrode with catalytic function, the bioelectrocatalysts are engineered; namely, oxidoreductase (e.g., lactate dehydrogenase) and $NAD^+$ can function for biotransformation without electron mediator and second oxidoreductase for $NAD^+$/NADH recycling.

Controlling size and magnetic properties of Fe3O4 clusters in solvothermal process

  • Madrid, Sergio I. Uribe;Pal, Umapada;Jesus, Felix Sanchez-De
    • Advances in nano research
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    • 제2권4호
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    • pp.187-198
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    • 2014
  • Magnetite nanoparticles (MNPs) of different sizes were synthesized by solvothermal process maintaining their stoichiometric composition and unique structural phase. Utilizing hydrated ferric (III) chloride as unique iron precursor, it was possible to synthesize sub-micrometric magnetite clusters of sizes in between 208 and 381 nm in controlled manner by controlling the concentration of sodium acetate in the reaction mixture. The sub-micrometer size nanoclusters consist of nanometric primary particles of 19 - 26.3 nm average size. The concentration of sodium acetate in reaction solution seen to control the final size of primary MNPs, and hence the size of sub-micrometric magnetite nanoclusters. All the samples revealed their superparamagnetic behavior with saturation magnetization ($M_s$) values in between 74.3 and 77.4 emu/g. $M_s$. The coercivity of the nanoclusters depends both on the size of the primary particles and impurity present in them. The mechanisms of formation and size control of the MNPs have been discussed.

온천수가 반죽의 발효와 품질에 미치는 영향

  • 이예경;김순동;이명예;김미영
    • 한국식품저장유통학회:학술대회논문집
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    • 한국식품저장유통학회 2003년도 춘계총회 및 제22차 학술발표회
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    • pp.121.1-121
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    • 2003
  • 증류수, 수도수, 온천수(경산 사이판 온천) 희석액 (55배 희석; I, 4배 희석; II, 2배희석; III을 사용한 반죽의 발효와 빵의 품질에 미치는 영향을 조사하였다. 경산사이판 온천수는 총고형물이 8,765 ppm 이였으며 주요 무기질로는 Na가 2296 ppm, Ca가 287 ppm, Mg와 K가 각각 65 및 8 ppm을 함유하였다. Fe, Cu, Co, F. Zn Al, S, Mo, Se 및 Si 등이 0.002~5.2 ppm을 함유하였다. 온천수를 사용한 반죽의 pH는 6.95~7.68로 증류수의 6.40보다 높았다. 반죽부피는 온천수의 농도가 높아짐에 따라 감소하였다. pH를 5.5로 조정한 온천수를 사용한 반죽의 부피는 대조구 보다 오히려 높았다. 온천수를 사용한 빵의 경도 (hardness)와 신장성(strength)는 대조구 보다 높았으나 pH를 조정한 온천수의 경우는 낮았다. 점착성은 경도 및 신장성과는 역으로 희석 온천수에서 낮았다. pH 조정 없이 구운 빵의 부드러운 정도는 4배로 희석한 온천수가 증류수 및 55배, 2배 희석 온천수보다 높았다. 쫄깃한 맛도 온천수가 대조구에 비하여 높았으며 종합적인 기호도는 4배 희석 온천수가 가장 좋았다.

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대정제법에 의한 전자재료용 indium정제에 관한 연구 (A study on the indium purification for electronic materials by zone refining)

  • 김백년;김선태;송복식;문동찬
    • E2M - 전기 전자와 첨단 소재
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    • 제7권2호
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    • pp.130-137
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    • 1994
  • Indium, element of group III, was refined by using zone refining for high purity refinement. We have found the impurities of T1, Zn, Fe, Cd, Pb, Ni, Cu, Sn in the refined indium with ICP-AES, so that 3.9 weight ppm of T1 was reduced to less than 1 ppm, 1.0 weight ppm of Zn was reduced to 0.7 ppm, 2.8 weight ppm of Cd was reduced to 2.5 ppm and 14.0 weight ppm of Sn was reduced to 6.7 ppm with 5 melten zone passes only. 3.9 weight ppm of T1 was reduced to less than 1 ppm, 1.0 weight ppm of Zn was reduced to 0.3 ppm, 2.8 weight ppm of Cd was reduced to less than 1.0 ppm and 14.0 weight ppm of Sn was reduced to 0.4 ppm after vacuum baking with 5 melten zone passes. The surface morpholgy of metal Indium thin film in each conditions showed that porosities were reduced in the front of sampled ingot after vacuum baking with 5 zone melten zone passes. The average electrical resistivity of Indium thin film was reduced from 1.4*10$^{-3}$ .ohm.-cm in Indium origin ingot to 7.9*10$^{-6}$ .ohm.-cm after zone refined with 5 melten zone passes.

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Laboratory-scale Microcosm Studies in Assessing Enhanced Bioremediation Potential of BTEX and MTBE under Various Electron Acceptors in Contaminated Soil

  • 오인석;이시진;장순웅
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 추계학술발표회
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    • pp.368-371
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    • 2003
  • Accidental release of petroleum products from underground storage tank(USTs) is one of the most common causes of groundwater contamination. BTEX is the major components of fuel oils, which are hazardous substances regulated by many nations. In addition to BTEX, other gasoline consituents such as MTBE(methyl-t-buthyl ether), anphthalene are also toxic to humans. Natual attenuation processes include physic, chemical, and biological trasformation. Aerobic and anaerobic biodegradation are believed to be the major processes that account for both containment of the petroleum-hydrocarbon plum and reduction of the contaminant concentrations. Aerobic bioremediation has been highly effective in the remediation of many fuel releases. However, Bioremediation of aromatic hydrocarbons in groundwater and sediments is ofen limited by the inability to provide sufficient oxygen to the contaminated zones due to the low water solubility of oxygen. Anaerobic processes refer to a variety of biodegradation mechanisms that use nitrate, ferric iron, sulfate, and carbon dioxide as terminal electron accepters. The objectives of this study was to conduct laboratory-scale microcosm studies in assessing enhanced bioremediation potential of BTEX and MTBE under various electron accepters(aerobic, nitrate, ferric iron, sulfate) in contaminated Soil. these results suggest that, presents evidence and a variety pattern of the biological removal of aromatic compounds under enhanced nitrate-, Fe(III)-, sulfate-reducing conditions.

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Energy Generation Coupled to Azoreduction by Membranous Vesicles from Shewanella decolorationis S12

  • Hong, Yi-Guo;Guo, Jun;Sun, Guo-Ping
    • Journal of Microbiology and Biotechnology
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    • 제19권1호
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    • pp.37-41
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    • 2009
  • Previous studies have demonstrated that Shewanella decolorationis S12 can grow on the azo compound amaranth as the sole electron acceptor. Thus, to explore the mechanism of energy generation in this metabolism, membranous vesicles (MVs) were prepared and the mechanism of energy generation was investigated. The membrane, which was fragmentized during preparation, automatically formed vesicles ranging from 37.5-112.5 nm in diameter under electron micrograph observation. Energy was conserved when coupling the azoreduction by the MVs of an azo compound or Fe(III) as the sole electron acceptor with $H_2$, formate, or lactate as the electron donor. The amaranth reduction by the vesicles was found to be inhibited by specific respiratory inhibitors, including $Cu^{2+}$ ions, dicumarol, stigmatellin, and metyrapone, indicating that the azoreduction was indeed a respiration reaction. This finding was further confirmed by the fact that the ATP synthesis was repressed by the ATPase inhibitor N,N'-dicyclohexylcarbodiimide (DCCD). Therefore, this study offers solid evidence of a mechanism of microbial dissimilatory azoreduction on a subcell level.