• Title/Summary/Keyword: Fe

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Magnetic and Magneto-Optical Properties of FeCo/Pd Multilayers (FeCo/Pd 초격자 다층박막의 자기 및 자기광학적 특성)

  • 김진홍;신성철
    • Journal of the Korean Magnetics Society
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    • v.3 no.1
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    • pp.56-60
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    • 1993
  • We have investigated the dependence of the magnetization, anisotropy, coercivity, and Kerr rotation on the Fe concentration in FeCo/Pd multilayer thin films, where the Fe concentration in the FeCo sublayer varied between 0 and 100% with maintaining the same sublayer thickness of $2.5\;{\AA}$ FeCo and $10.5\;{\AA}$A Pd. The maximum saturation magnetization was observed at the Fe concentration of about 48at.% in the FeCo sublayer. Perpendicular magnetic anisotropy and coercivity of the FeCo/Pd multilayer thin film decreased monotonically with increasing the Fe con-centration. The Kerr rotation angle also decreased with increasing the Fe concentration and the amount of vari-ation was remarkably changed with decreasing the light wavelength.

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Study of Magnetic Property of Fe-N Nanoparticle Using Mössbauer Spectroscopy (뫼스바우어 분광기법을 이용한 Fe-N 나노입자의 자기특성연구)

  • Oh, Sei-Jin
    • Journal of the Korean Magnetics Society
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    • v.17 no.2
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    • pp.76-80
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    • 2007
  • Three nano-sized Fe-N particle samples synthesized by Chemical Vapor Condensation (CVC) were analyzed using $M\"{o}ssbauer$ spectroscopy, XRD and BET. The synthesized nanoparticles consisted of ${\epsilon}-Fe_{2.12}N,\;{\gamma}'-Fe_4N,\;{\alpha}-Fe\;and\;{\gamma}-Fe.\;{\gamma}'-Fe_4N$ was mainly formed at the low decomposition temperature. With increasing decomposition temperature, the phase was changed to ${\gamma}-Fe$ via ${\epsilon}-Fe_{2.12}N$. For synthesizing Fe-N phases, this study implies that the low decomposition temperature is better than high temperature during Chemical Vapor Condensation.

Synthesis and Characterization of Transition Metal Doped $TiO_2$ Thin Films: $Fe_xTi_{1-x}O_2$ (전이금속이 도핑된 $TiO_2$ 박막의 제조와 특성 규명: $Fe_xTi_{1-x}O_2$)

    • Journal of the Korean Vacuum Society
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    • v.11 no.4
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    • pp.240-248
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    • 2002
  • $Fe_xTi_{l-x}O_2$ films (x=0.07 and 0.16) were grown by oxygen-plasma-assisted molecular beam epitaxy on rutile $TiO_2$(110). The same growth conditions were applied for both films in order to determine surface characteristics of grown films as a function of Fe composition. The films were characterized by several surface analysis techniques. The oxidation states of Ti and Fe in $Fe_xTi_{l-x}O_2$ films were found to be +4 and a mixture of +2 and +3, respectively. More $Fe^{3+}$ species exist in higher Fe doped film of $Fe_{0.16}Ti_{0.84}O_2$. The morphology of $Fe_{0.07}Ti_{0.93}O_2$ film shows tall rectangular and cylinderical islands growth on flat substrate-like surface. On the other hand, $Fe_{0.16}Ti_{0.84}O_2$ film consists of round shaped small islands showing somewhat rougher surface compared to the surface of $Fe_{0.16}Ti_{0.84}O_2$ film.

$Fe_2O_3$ Aggregation and Sintering of Ba-Ferrite ($Fe_2O_3$ 응집상태와 Ba-Ferrite의 소결성)

  • Hyo-Duk Nam;Sang-Hee Cho
    • Journal of the Korean Chemical Society
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    • v.25 no.5
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    • pp.318-324
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    • 1981
  • The effects of$ Fe_2O_3$ aggregation on the sintering of Ba-ferrite (BaFe$_{12}O_{19}$) were studied. $BaCO_3-Fe_2O_3$ mixtures were prepared by partial precipitation mixing and ball-mill mixing method using two different $Fe_2O_3 $powders. Techniques employed were TG, XRD and SEM. X-ray diffraction analysis showed that the over all reaction basically consists of the two consecutive reaction; $BaCO_3 + 6Fe_2O_3\;{\longrightarrow}\;BaFe_2O_3 + 5Fe_2O_3 + CO_2{\uparrow}\;BaFe_2O_4 + 5Fe_2O_3 \;{\longrightarrow}\;BaFe_{12}O_{19}$ It is also shown that the aggregation state of $Fe_2O_3$ raw materials, as well as the mixing method, has a remarkable effect on solid state reaction between $BaCO_3\;and\;Fe_2O_3$.

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pH Dependence on the Degradation of Rhodamine B by Fe-ACF/$TiO_2$ Composites and Effect of Different Fe Precursors (Fe-ACF/$TiO_2$ 복합체에 의한 로다민 B 용액의 분해에 있어서 pH 의존성 및 여러 가지 Fe 전구체의 효과)

  • Zhang, Kan;Oh, Won-Chun
    • Elastomers and Composites
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    • v.44 no.4
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    • pp.408-415
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    • 2009
  • Iron-loaded activated carbon fibers (Fe-ACF) supported titanium dioxide ($TiO_2$) photocatalyst (Fe-ACF/$TiO_2$) was synthesized using a sol-gel method. Three different types of Fe-ACF/$TiO_2$ were obtained by treatment with different precursor of Fe, and characterized using BET, SEM, XRD and EDX analysis. The photocatalytic activity of Fe-ACF/$TiO_2$ was investigated by the degradation of Rhodamine B (Rh.B) solution under UV irradiation. From the experimental results, it was revealed that Fe-ACF/$TiO_2$ composites show considerable photocatalytic ability for the removal of Rh.B by comparing non-treated ACF/$TiO_2$ composites. And photo-Fenton reaction with Fe element was incoordinately influenced due to different precursor of Fe. It clearly indicates that Fe-ACF/$TiO_2$ composites prepared using $FeCl_3$ provided the highest photo-Fenton activity, then, which was affected by pH changes on the degradation of Rh.B.

Electronic Structures and Magnetic Properties of Fe/Si/Fe Trilayer

  • Park, Jin-Ho;Youn, Suk-Ju;Min, Byung-Il;Yi, Jae-Yel
    • Journal of Magnetics
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    • v.1 no.1
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    • pp.4-8
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    • 1996
  • Employing the LMTO band method, we have studied electronic and magnetic properties of Fe/Si/Fe trilayer in which the z-direction is chosen to be (111) direction of FeSi with B2 phase, We have also determined electronic structure of bulk FeSi, as a reference material. The ground state of FeSi is paramagnetic insulator with a band gap of 0.05 eV. Band structures of Fe/Si/Fe with varying the thickness of the spacer layer reveal that the spacer layer is metallic, and the states along the growth direction do not disperse much reflecting a two-dimensional nature. Magnetic moment of Fe atom in the interfacial layer of Fe/Si/Fe is reduced a lot as compared to the bulk value, suggesting a strong hybridization between Fe and Si states. The geometry of the Fermi surface indicates that the magnetic coupling period of ~8ML (monolayers) in Fe/Si/Fe is explained with a short Fermi wave vector of bcc Si.

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Analysis of Giant Magnetoresistance Behavior of NiFeCo/Cu/NiFeCo/FeMn Valves (NiFeCo/Cu/NiFeCo/FeMn 스핀밸브 구조의 자기저항 거동 해석)

  • 배성태;김진영;민경익;신경호
    • Journal of the Korean Magnetics Society
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    • v.6 no.2
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    • pp.112-116
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    • 1996
  • 스퍼터링법으로 제조한 NiFeCo/Cu/NiFeCo/FeMn 스핀밸브 자성 다층막의 자기적 성질과 자기저항에 대해 연구하였다. Cu 사잇층 두께가 15 .angs. 인 경우 약 6%의 자기저항을 얻을 수 있었다. NiFeCo/FeMn에서 교환이방성 자계는 약 20 Oe 정도였는데, 이는 NiFe/FeMn 계 스핀밸브 구조에서 보고된 값(100 Oe 이상) 보다 현저히 작은 것이다. 3 mTorr에서 제조한 NiFeCo 박막은 약 10 Oe 정도의 큰 보자력을 보임으로써 비슷한 조건에서 제조한 NiFe 박막의 경우(약 2 Oe)보다 상당히 큰 값을 갖는 것으로 관찰되었다. 작은 교환이방성 자계와 큰 보자력으로 인해 음 .rarw. 양 방향과 양 .rarw. 음 방향의 자화거동에 있어서 비대칭적인 자기저항 이력곡선 거동을 보이는 것으로 나타났다.

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Tissue Distribution of Divalent Metal Transporter 1 and Regulation by Dietary Iron in Rats (흰쥐에서 Divalent Metal Transporter 1의 조직내 분포와 Iron에 의한 조절)

  • Choi Jae-Hyuck;Park Jung-Duck
    • Environmental Analysis Health and Toxicology
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    • v.19 no.4
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    • pp.359-366
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    • 2004
  • Iron (Fe) is an essential metal in biological processes, which maintains a homeostasis in the human body. Divalent metal transporter 1 (DMT1) has been known as an iron transporting membrane protein, which is involved in the uptake Fe at the apical portion of intestinal epithelium, and may transport Fe across the membrane of acidified endosome in peripheral tissues. In this study, we studied the tissue distribution of DMT1 in the Fe supplemented (FeS) diet fed rats, and the regulation of DMT1 expression by depleting body Fe. Sprague-Dawley rats were divided into two groups, and fed FeS (120 mg Fe/kg) diet or Fe deficient (FeD, 2∼6 mg Fe/kg) diet for 4 weeks. The evaluation of body Fe status was monitored by measuring sFe, UIBC and tissue Fe concentration. Additionally, DMT1 mRNA levels were analyzed in the peripheral tissues by using the quantitative real time RT-PCR method. In the FeS diet fed rats, the tissue Fe was maintained at a relatively high level, and DMT1 was eventually expressed in all tissues studied. DMT1 was highly expressed in the testis, kidney and spleen, while a moderate levels of DMT1 expression was detected in the brain, liver and heart. In the digestive system, the highest level of DMT1 was found in the duodenum. Feeding the FeD diet caused a reduced body weight gain and depletion of body Fe with finding of decreased sFe, increased UIBC and decreased tissue Fe concentration. The depletion of body Fe upregulated DMT1 expression in the peripheral tissue. The expression of DMT1 was very sensitive to the body Fe depletion in the small intestine, especially in the duodenum, showing dramatically higher levels in the FeD rats than those of the FeS group. In the FeD diet fed animals, the expression of DMT1 was low significantly in other tissues compared with the duodenum. The expression of DMT1, however, was 60∼120% higher in the testis, kidney and spleen, and 30∼50% higher in the lung, liver and heart, compared to the FeS diet fed rats. In summary, DMT1 expression was ubiquitous in mammalian tissue, and the level of expression was the organ-dependent. The expression of DMT1 in peripheral tissues was upregulated by depletion of body Fe. Duodenum was the most sensitive tissue among organs studied during Fe depletion, and expressed the greatest level of DMT1, while other tissues were less higher than in duodenum. This study supports that DMT1 plays a role in maintaining the body Fe level through intestinal uptake as well as homeostasis of Fe in the peripheral tissue.

Microstructure and Magnetic Properties of Rapidly Solidified Nd-Fe(-Co) and Sm-Co(-Fe) Laves Compounds (급속냉각된 Nd-Fe(-Co)와 Sm-Co(-Fe)계 Laves 화합물의 미세조직과 자기특성)

  • 이우영;최승덕;양충진
    • Journal of the Korean Magnetics Society
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    • v.1 no.1
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    • pp.17-24
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    • 1991
  • Laves phases of $NdFe_2$, $Nd{(Fe_{0.5})}_2$, $SmCo_2$ and $Sm{(Fe_{0.5}Co_{0.5})}_2$ stoichiometry were prepared using a rapid solidification technology. Low temperature magnetic properties show ferromagnetic behaviors for the $Nd{(Fe_{0.5}Co_{0.5})}_2$, $SmCo_2$ and $Sm{(Fe_{0.5}Co_{0.5})}_2$Nd(Feo,Coo,) Laves compounds while a sort of spin reorientation has been suggested for the supposed composition of $NdFe_2$ alloy. This rapidly solidified $NdFe_2$ alloy is believed to consist of metastable rhombohedral $NdFe_7$ phase plus fine particles of Nd-rich phase. Some evidence of phase transition from the mixture of unstable $NdFe_7$ compound plus Nd-rich to $Nd_2Fe_{17}$ plus Fe-Nd-O phase was obtained after annealing the $NdFe_2$, alloy. The pseudo-binary Laves compound, $Sm{(Fe_{0.5}Co_{0.5})}_2$ exhibits a high coercivityof 4 kOe at room temperature with Curie temperature of $400^{\circ}C$ while the $Nd{(Fe_{0.5}Co_{0.5})}_2$ compound shows a magnetic moment of $2.8\;{\mu}_B/f.u.$.

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The Magnetoresistance Properties of Spin Valves with CoFe/Ru/CoFe/FeMn Synthetic Antiferromagnet (Synthetic antiferromagnet CoFe/Ru/CoFe/FeMn을 이용한 스핀 밸브 구조의 자기저항 특성)

  • Jang, S.H.;Kang, T.;Kim, M.J.;Kim, H.J.;Kim, K.Y.
    • Journal of the Korean Magnetics Society
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    • v.10 no.5
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    • pp.196-202
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    • 2000
  • Top synthetic spin valves with structure Ta/NiFe/CoFe/Cu/CoFe(P1)/Ru/CoFe(P2)/FeMn/Ta on Si(100) substrate with natural oxide were prepared by dc magnetron sputtering system, and investigated on the magnetoresistance properties and effective exchange bias field. As the thickness of FeMn increased above 150 $\AA$, MR ratio was decreased due to the current shunting effect. As the thickness of free layer decreased below 40$\AA$, MR ratio was reduced rapidly. In case of 40 $\AA$ thick of free layer, spin valve film with a structure Si(100)/Ta(50 $\AA$)/NiFe(27 $\AA$)/CoFe(13 $\AA$)/Cu(26 $\AA$)/CoFe(30 $\AA$)/Ru(7 $\AA$)/CoFe(15 $\AA$)/FeMn(100 $\AA$)/Ta(50 $\AA$) exhibited maximum MR ratio of 7.5 % and an effective exchange bias field of 600 Oe, respectively. Thickness difference dependence in this synthetic spin valve structure on effective exchange field was investigated and interpreted by the analytical method. It should be noted that thickness increase of CoFe(P 1) and decrease of CoFe(P2) in synthetic antiferromagnet leaded to the decrease in effective exchange bias field by experimentally and analytically.

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