• 제목/요약/키워드: Fe/Ni layer

검색결과 337건 처리시간 0.025초

Zn-0.18Al 도금욕에서 Ni첨가에 따른 아연 도금강의 계면반응 (Interfacial Reaction of Galvanized Steel in Ni Added Zn-0.18Al Bath)

  • 이경구;기회봉;이도재
    • 한국표면공학회지
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    • 제32권4호
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    • pp.547-554
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    • 1999
  • The interfacial reaction, spangle and coating thickness of galvanized steel in Ni added Zn-0.18Al bath have been investigated. The size of spangle and thickness of reaction layer were observed under an optical microscope, SEM and EDS. Analysing the experimental results concerning spangle size of galvanized steel it was found that Ni addition in Zn-0.18Al bath tended to be minimized spangle size. For Zn-0.18Al bath, addition of 0.1Ni suppressed the formation of Fe-Zn intermetallic compounds but increased with Ni content above 0.1%. The coating thickness of galvanized steel was reduced with Ni addition in Zn-0.18Al bath, especially in Zn-0.18Al-0.05Ni bath. Addition of Al in Ni containing bath resulted in forming the Al-Ni intermetallic compounds such as $Al_3$Ni$_2$ and $Al_2$Ni which consist most of top precipitates.

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An SOFC Cathode Composed of LaNi0.6Fe0.4O3 and Ce(Ln)O2 (Ln=Sm, Gd, Pr)

  • Chiba, Reiichi;Komatsu, Takeshi;Orui, Himeko;Taguchi, Hiroaki;Nazawa, Kazuhiko;Arai, Hajime
    • 한국세라믹학회지
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    • 제45권12호
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    • pp.766-771
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    • 2008
  • We fabricated single cells with a cathode consisting of a $LaNi_{0.6}Fe_{0.4}O_3-Ce_{0.8}Sm_{0.2}O_{1.9}$ composite (LNF-S20DC composite) active layer and an LNF current collecting layer on a ${0.89ZrO_2}-{0.10Sc_2}{O_3}-0.01{Al_2}{O_3}$ electrolyte sheet. The cathode layers were prepared by the screen-printing method. The cathode properties of these cells were measured by the AC impedance method at $800^{\circ}C$. The cathodes with the ceria-LNF composite active layer exhibited high power performance prior to current loading. We investigated the influence of the mixture ratio of LNF and S20DC on the cathodes properties. The Sm in the ceria particles of the composite cathode was substituted with other rare-earth elements. Cathodes with Pr and Gd co-doped ceria in the active layer provided the better performance than those with Sm- or Gd-doped ceria.

Design of Advanced Weathering Steel with High Corrosion Resistance for Structural Applications

  • Choi, B.K.;Jung, H.G.;Yoo, J.Y.;Kim, K.Y.
    • Corrosion Science and Technology
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    • 제4권4호
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    • pp.121-129
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    • 2005
  • Basic design concept of the future steel structure requires environmental compatibility and maintenance free capability to minimize economic burdens. Recent trends in alloy design for advanced weathering steel include addition of various alloying elements which can enhance formation of stable and protective rust layer even in polluted urban and/or high $Cl^{-}$ environment. The effects of Ca, Ni, W, and Mo addition on the corrosion property of Ca-modified weathering steel were evaluated through a series of electrochemical tests (pH measurement and electrochemical impedance spectroscopy: EIS) and structural analysis on rust layer formed on the steel surface. Ca-containing inclusions of Ca-Al-Mn-O-S compound are formed if the amount of Ca addition is over 25 ppm. Steels with higher Ca content results in higher pH value for condensed water film formed on the steel surface, however, addition of Ni, W, and Mo does not affect pH value of the thin water film. The steels containing a high amount of Ca, Ni, W and Mo showed a dense and compact rust layer with enhanced amount of ${\alpha}-FeOOH$. Addition of Ni, W and Mo in Ca-modified weathering steel shows anion-selectivity and contributes to lower the permeability of $Cl^{-}$ ions. Effect of each alloying element on the formation of protective rust layer will be discussed in detail with respect to corrosion resistance.

Proximity Effect in Nb/Gd Layers

  • Jung, Dong-Ho;Char, K.
    • Progress in Superconductivity
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    • 제12권2호
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    • pp.110-113
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    • 2011
  • We have grown a Nb/Gd bilayer on a$SiO_2$/Si substrate by using a DC magnetron sputtering system, which was fabricated in situ with silicon stencil masks. In order to investigate proximity effect of the Nb/Gd bilayer, we used a planar tunnel junction with an AlOx tunnel barrier by oxidizing the Al ground electrode at the bottom. A $Co_{60}Fe_{40}$ backing of Al was deposited so as to reduce the superconductivity of the Al, ensuring a normal counterelectrode. With a 50-nm-thick Nb layer, we have measured dI/dV (dynamic conductance) by varying the thickness of Gd, which can reveal the density of states (DOS) of the Nb/Gd bilayer as a function of the Gd thickness resulting from the proximity effect of a superconductor/ferromagnet bilayer (S/F). The SF proximity effect in Nb/Gd will be discussed in comparison to our previous results of the CoFe/Nb, Ni/Nb and CuNi/Nb proximity effect; Gd is expected to show different effects since Gd has f-electrons, while CoFe, Ni, and CuNi have only d-electrons. Our studies will focus on the triplet correlation in a superconducting pair.

[Co/Cu/NiFe/Cu] 다층박막의 자기저항효과에 관한 연구 (Magnetoresistance effects in [Co/Cu/NiFe/Cu] Spin-valve Multilayers)

  • 정진봉;박창만;이기암;황도근;이상석
    • 한국자기학회지
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    • 제5권3호
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    • pp.203-209
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    • 1995
  • 보자력이 다른 NiFe와 Co를 자성층으로 하고 Cu를 사잇층으로 하는 $glass\[Cu_{x\AA}\NiFe_{50\AA}\Cu_{x\AA}\Co_{50\AA}](X;\=\;8,\;10,\;14,\;18,\;22,\;26,\;28,\;38,\;48,\;58\;\AA)$ 다층박막을 D.C magnetron sputtering 방법으로 제작하여 사잇층인 Cu 두께, 적층횟수 및 열처리가 자기저항비에 미치는 영향과 자기 곡선의 변화에 대해 연구하였다. 자기저항 측정시 인가 자장은 전류의 방향과 수평, 수직하게 인가하여 측정하였다. Cu 두께가 대략 $10\;\AA$에서 최대 자기저항비를 보이고 있으며, 두께가 증가함에 따라 진동하는 경향은 나타냈다. 적층횟수에 따라서는 적층횟수가 증가함에 따라 증가하였으며, 단지 4층의 경우에는 오히려 3층 보다 감소하였다. 열처리의 경우 온도의 증가에 따라 증가하다가 $250^{\circ}C$ 이상에서는 다시 감소하는 것을 나타났다.

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$Fe_2O_3$가 첨가된 $Pb(Ni_{1/3}Nb_{2/3})O_3$ - $PbTiO_3$ - $PbZrO_3$ 세라믹의 바이몰프 액츄에이터를 이용한 에너지 하베스팅 (Energy Harvesting from the Bimorph Actuator using $Fe_2O_3$ Added $Pb(Ni_{1/3}Nb_{2/3})O_3$ - $PbTiO_3$ - $PbZrO_3$ Ceramics)

  • 징영훈;김창일;이영진;백종후
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.330-330
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    • 2008
  • $Fe_2O_3$ added Pb$(Ni_{1/3}Nb_{2/3})O_3-PbTiO_3-PbZrO_3 $ (PNN-PT-PZ) ceramics were produced in order to use them as a bimoph acturator for energy harvesting. Especially, the 0.25 wt% $Fe_2O_3$ added 0.4PNN-0.357PT-0.243PZ, having the composition of morphotropic phase boundary, showed good piezoelectric properties of $d_{33}$ of 810 pC/N, $k_p$ of 77% and $Q_m$ of 55 along with a high Curie temperature of $210^{\circ}C$. A bimorph actuator, composed of the two piezoelectric layers bonded together with a phosphorous bronze layer as a central metallic electrode, was successfully fabricated. The bimorph actuator, vibrated with a 1.3 mm amplitude at 68 Hz, produced high electric power of approximately 60 mW.

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ANALYSIS OF THE PHASE STABILITY OF FINE $Fe_{90}Ni_{10}$ ALLOY PARTICLES

  • Widatallah, H.M.;Huang, R.S.;Hsia, Y.F.;Lee, X.M.;Wang, J.H.;Lu, H.X.
    • 한국자기학회지
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    • 제5권5호
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    • pp.543-547
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    • 1995
  • A set of $Fe_{1-x}Ni_{x}$ (x=0.10, 0.25, 0.30, 0.35, 0.50, 0.60, 0.75, 0.85) fine particles prepared by the gas evaporation technique was studied by $M\"{o}ssbauer$, XRD and other techniques. The XRD and $M\"{o}ssbauer$ patterns of the sample with x=0.10 ($Fe_{90}Ni_{10}$) were found to be exceptionally different, showing an austenite phase stability when the particles are quenched. This phase stability is quite different from that of the corresponding bulk alloy. Using binomial distrbution fits of the $M\"{o}ssbauer$ spectra of the particles in terms of nearest and next nearest neighbour configurations around the Fe atoms, an analysis of this phase stability is given. The changes in the relative intensities of the resulting magnetic sextets are used to determine the increase in martensite following the austenite-martensite transformation process. The stable austenite can, therefore, be determined. This stability may be related to the oxide surface layer and the small number of atoms of these fine particles.

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Computer Simulation of Sensing Current Effects on the Magnetic and Magnetoresistance Properties of a Crossed Spin-Valve Read

  • Lim, S.H;Han, S.H;Shin, K.H;Kim, H.J
    • Journal of Magnetics
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    • 제5권2호
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    • pp.44-49
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    • 2000
  • Computer simulation of sensing current effects on the magnetic and magnetoresistance properties of a crossed spin-valve head is carried out. The spin-valve head has the following layer structure: Ta (8.0 nm)/NiMn (25 nm)/NiFe (2.5 nm)/Cu (3.0 nm)/NiFe (5.5 nm)/Ta (3.0 nm), and it is 1500 nm long and 600 nm wide. Even with a high pinning field of 300 Oe and a high hard-biased field of 50 Oe, the ideal crossed spin-valve structure, which is essential to the symmetry of the output signal and hence high density recording, is not realized mainly due to large interlayer magnetostatic interactions. This problem is solved by applying a suitable magnitude of sensing currents along the length direction generating magnetic fields in the width direction. The ideal spin-valve head is expected to show good symmetry of the output signal. This has not been shown explicitly in the present simulation, however, The reason for this is possibly related to the simple assumption used in this calculation that each magnetic layer consists of a single domain.

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Effects of the Hard-Biased Field on the Magnetic and Magnetoresistive Properties of a Crossed Spin-Valve Bead by Computer Simulation

  • S. H. Lim;K. H. Shin;Kim, K. Y.;S. H. Han;Kim, H. J.
    • Journal of Magnetics
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    • 제5권1호
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    • pp.19-22
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    • 2000
  • The effects of a hard-biased Held on the magnetic and magnetoresistive properties of a crossed spin-valve head are investigated by computer simulation with particular emphasis on the asymmetry of the output signal. The spin-valve considered in this work is NiMn (25 nm)/NiFe (2.5 m)/Cu (3 nm)/NiFe (5.5 m), with a length of 1500 m and a width of 600 nm. A simple model is used where each magnetic layer consists of a single domain, and the magnetoresistance is a function of the angle between the magnetization directions of the two magnetic layers. The ideal crossed spin-valve structure is not realized with the present model and magnetic parameters, but the deviation from ideality is decreased by the hard-biased field. This results in the improvement of the linearity of the output signal with the use of the bias field. The magnetoresistance ratio and magnetoresistive sensitivity, however are reduced. The magnetic properties including the magnetoresistance are found to be strongly affected by magnetostatic interactions, particularly the inter-layer magnetostatic field.

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