• Title/Summary/Keyword: Fe/Mn contents

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Effects of Heavy Metals Pollution in Soil and Plant in the Industrial Area, West ALGERIA

  • Tahar, Kebir;Keltoum, Bouhadjera
    • Journal of the Korean Chemical Society
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    • v.55 no.6
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    • pp.1018-1023
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    • 2011
  • Alzinc is a ursine situated in the Ghazaouet town western part of the republic of Algeria. The purpose of this study was to determine the degree of contamination which soil and plants are burdened with some heavy metals: Pb, Zn, Ni, Cu, Cd, Mn, Cr, Fe and As, then the accumulation of heavy metals in the soil and plant adjacent of area the alzinc ursine was detected and the interdependence of pollution among all three regions of the environment determined. This paper analyzes the heavy metal contents within a 2-years period in the soil and plants at the beginning of the vegetation period. The presence of Pb, Zn, Ni, Cu, Cd, Mn, Cr, Fe and As, in the samples were analyzed using Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES). Measurements of heavy metal contents were performed at three locations in soil and vegetative parts of three-plant types (plant alimentary) period during summer. The plant samples from the immediate environment of the dumpsite were highly contaminated with Zn, Cd and Mn. Three plants species: grape, artichoke and pepper, particularly, grape met some of the conditions to be classified as accumulators for Zn, Cu, Cd and Fe, consequently, she revealed a health risk for human and livestock due to the spread of the metal pollution from waste dumpsites to agricultural areas.

Analysis of Cracking Phenomenon Occurring During Hot Rolling of Fe-23Mn High-manganese Steels with Different Aluminium and Carbon Contents (알루미늄과 탄소 함량에 따른 Fe-23Mn계 고망간강의 열간 압연 시 발생하는 균열 현상 분석)

  • Lim, Hyeon-Seok;Lee, Seung-Wan;Hwang, Byoungchul
    • Journal of the Korean Society for Heat Treatment
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    • v.29 no.4
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    • pp.176-180
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    • 2016
  • In this study, a microstructural investigation was conducted on the cracking phenonmenon occurring during hot rolling of Fe-23Mn high-manganese steels with different aluminium and carbon contents. Particular emphasis was placed on the phase stability of austenite and ferrite dependent on the chemical composition. An increase in the aluminum content promoted the formation of ferrite band structures which were easily deformed or cracked. In the steels containing high carbon contents of 0.4 wt.% or higher, on the other hand, the volume fraction and thickness of ferrite bands decreased and thus the cracking frequency was significantly reduced. Based on these findings, it is said that the microstructural evolution occurring during hot rolling of high-manganese steels with different aluminium and carbon contents plays an important role in the cracking phenomenon. To prevent the cracking, therefore, the formation of second phases such as ferrite should be minimized during the hot rolling by the appropriate control of the chemical composition and process parameters

Heavy Metal Contamination in Surface Water Used for Irrigation: Functional Assessment of the Turag River in Bangladesh

  • Arefin, M. Taufique;Rahman, M. Mokhlesur;Wahid-U-Zzaman, M.;Kim, Jang-Eok
    • Journal of Applied Biological Chemistry
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    • v.59 no.1
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    • pp.83-90
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    • 2016
  • The aim of the present study was to evaluate the degree of metal contamination of the Turag River water and its suitability for irrigation. Twenty water samples were analyzed for physicochemical parameters and metals viz., calcium, magnesium, potassium (K), sodium, copper (Cu), zinc (Zn), iron (Fe), manganese (Mn), lead (Pb), cadmium (Cd), chromium (Cr), and nickel (Ni). All water samples were slightly alkaline to alkaline. Regarding electrical conductivity (EC), all samples were suitable for crop in soils with moderate permeability and leaching. Water samples were medium salinity and low alkalinity hazard classes. In terms of total dissolved solids (TDS), all samples were classified as freshwater. As per sodium adsorption ratio (SAR) and soluble sodium percentage (SSP), all samples were classified as excellent. No residual sodium carbonate (RSC) was detected in any of the samples, indicating suitability for irrigation; and all samples were considered very hard. Cr and Mn contents in all samples were above FAO guideline values and, therefore, these metals were considered toxic. Zn, Cu, Pb, Cd, and Ni concentrations were below acceptable limit for irrigation and do not pose a threat to soil environment. Significant relationships were found between EC and TDS, SAR and SSP, SAR and RSC, and SSP and RSC. The combinations of ions such as K-Zn, K-Fe, K-Cu, K-Mn, K-Pb, Zn-Fe, Zn-Cu, Zn-Mn, Fe-Mn, Cu-Mn, Cu-Pb and Mn-Pb exhibited significant correlation. This study revealed that Turag River water samples are contaminated with Cr and Mn. This fact should not be ignored because water contamination by metals may pose a threat to human health through food chain.

Heavy Metal Retention by Secondary Minerals in Mine Waste Rocks at the Abandoned Seobo Mine (서보광산 폐광석 내 2차 광물에 의한 중금속 고정화)

  • 이평구;강민주;최상훈;신성천
    • Economic and Environmental Geology
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    • v.36 no.3
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    • pp.177-189
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    • 2003
  • The main purposes of this study are to utilize mineralogical studies such as optical microscope, XRD and SEM/EDS analyses to characterize the oxidation of sulfide minerals and the mechanisms controlling the movement of dissolved metals from waste rocks at the abandoned Seobo mine. Mineralogical research of the waste rocks confirms the presence of anglesite, covellite, goethite, native sulfur and nsutite as secondary minerals, suggesting that these phases control the dissolved concentrations of As, Cu, Fe, Mn, Pb and Zn. The dissolved metals are precipitated, adsorbed and/or coprecipitated with(or within) Fe(Mn)-hydroxides and Mn(Fe)-hydroxides. The main phases of secondary mineral, Fe-hydroxide, can be classified as amorphous or poorly crystalline and more crystallized phases(e.g. goethite) by crystallinity. Amorphous or poorly crystalline Fe-hydroxide has relatively high As contents(9-24 wt.%). This poorly crystalline Fe-hydroxide changes toward more crystallized phase(e.g. goethite) which contains relatively low As(0.6-7.7 wt.%). These results are mainly due to the progressive release of As with the crystallization evolution of the As-trapping poorly crystalline Fe-hydroxides. It is also attributed to the differences of specific surface areas between the poorly crystalline Fe-hydroxides and well crystallized phases. The dissolved metals from waste rocks at Seobo mine area are naturally attenuated by a series of precipitation(as Fe, Mn, Cu, Pb), coprecipitation(Fe, Mn) and adsorption(As, Cu, Pb, An) reactions. The results of mineralogical researches permit to assess the environmental impacts of mine waste rocks in the areas, and can be used as a useful data to lay available mine restoration plan.

A Study on the General Components and Minerals in Parts of Omija (Schizandra Chinensis Baillon) (오미자의 부위별 일반성분과 무기질함량에 관한 연구)

  • Lee, Joung-Sook;Lee, Mi-Gyeung;Lee, Sung-Woo
    • Journal of the Korean Society of Food Culture
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    • v.4 no.2
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    • pp.173-176
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    • 1989
  • This study was carried out to comparison of the contents of general and mineral components between the original sample and water extract in each part of omija. The content of Carbohydrate was highest in endocarps, and that the crude protein and crude lipid in seeds. The contents of K and Mn in the fruits, endocarps, and seeds were all higher than those of the other cations. The content of K and Zn in endocarps were three to four times as much as those of seeds. and the content of Na, Ca, and Cu in endocarps were 1.5 to 1.75 times of seeds. Mineral contents by water extract in each part were ordered as K, Mg, Ca, and Fe. As the percentage of each ion in water extract on the basis of original sample, Fe was the highest ratio of behavior, and Mn was lowest.

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Effects of low-dose organic trace minerals on performance, mineral status, and fecal mineral excretion of sows

  • Ma, Lianxiang;He, Junna;Lu, Xintao;Qiu, Jialing;Hou, Chuanchuan;Liu, Bing;Lin, Gang;Yu, Dongyou
    • Asian-Australasian Journal of Animal Sciences
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    • v.33 no.1
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    • pp.132-138
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    • 2020
  • Objective: To investigate the effects of low-dose trace mineral proteinates on reproductive performance, mineral status, milk immunoglobulin contents and fecal mineral excretion of sows. Methods: Eighty crossbred sows (Landrace×Large White) were randomly allocated to two groups in a 135-day trail, from breeding through 21 d postpartum. The two treatments were inorganic trace minerals (ITM): a basal diet+inorganic iron (Fe), copper (Cu), manganese (Mn), and zinc (Zn) at 90, 15, 25 and 90 mg/kg, respectively and organic trace minerals (OTM): a basal diet+proteinates of Fe, Cu, Mn, and Zn at 72, 12, 20, and 72 mg/kg, respectively. Results: Compared with ITM, OTM significantly increased (p<0.05) the number of piglets with birthweight >1 kg, the litter weaning weight, and milk Fe, Cu contents. No significant differences (p>0.05) were observed on sow hair mineral contents or immunoglobulin M (IgM), IgG, and IgA contents in colostrum and milk. In comparsion to ITM, OTM decreased fecal Fe, Cu, Mn, and Zn contents of gestating sows (p<0.01) and Fe, Mn, and Zn in lactating sows (p<0.01). Conclusion: These results indicate that low-dose mineral proteinates can increase the number of piglets with birthweight >1 kg, the litter weaning weight and certain milk mineral concentrations while reducing fecal mineral excretion.

Establishment of Critical Ranges of Inorganic Nutrition Contents in Leaves of Watermelon(Cucurbita citrullus L.) in Protected Cultivation (시설재배 수박 엽 적정양분함량 설정)

  • Lee, Ju-Young;Park, Jae-Hong;Jang, Byoung-Choon;Lee, Ki-Sang;Hyun, Byung-Keun;Hwang, Seon-Woong;Yoon, Young-Sang;Song, Beom-Heon
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.3
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    • pp.158-163
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    • 2008
  • This study was carried out to elucidate the relationship between yields and inorganic nutrient contents, and then establish of critical range of inorganic nutrient contents in leaves of watermelon in protected cultivation in Gochang from 2004 to 2006. In considering the yields and nutrient contents of watermelon, the critical ranges of macro-nutrient contents in leaves of watermelon at 20 days after transplanting were in N 5.0~6.6%, P 0.30~0.57%, K 3.5~4.2%, Ca 1.7~3.8% and Mg 0.20~0.42%, respectively. The critical ranges of micronutrient content, such as Fe, Mn, Zn, Cu and B, were not found the regular trend with different growth stages. However, the critical range of micronutrient contents in leaves of watermelon at 20 day after transplanting were in Fe 96~128, Mn 67~201, Zn 40~60, Cu 6~9 및 B $41{\sim}82mg\;kg^{-1}$, respectively. Finally, these results might be used at the indicator for critical nutrient contents for diagnosis of nutritional disorder in watermelon in protected cultivation.

The Establishment of Critical Ranges of Inorganic Nutrition Contents in Leaves of Net Melon(Cucumis melo L.) in Protected Cultivation (시설재배 멜론 엽의 적정양분함량 설정)

  • Lee, Ju-Young;Park, Jae-Hong;Jang, Byoung-Choon;Lee, Ki-Sang;Hyun, Byung-Keun;Hwang, Seon-Woong;Yoon, Young-Sang;Song, Beom-Heon
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.6
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    • pp.471-475
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    • 2007
  • This study was carried out to elucidate the relationship between yields and inorganic nutrient contents, and then establish of critical range of inorganic nutrient contents in leaves of net melon in protected cultivation in Naju from 2004 to 2006. In considering the yields and nutrient contents of net melon, the critical ranges of macro-nutrient contents in leaves of net melon at 25 days after transplanting were in N 3.4~4.8%, P 0.4~0.7%, K 3.4~5.1%, Ca 2.7~4.1% and Mg 0.6~0.8%, respectably. The critical ranges of micronutrient content, such as Fe, Mn, Zn, Cu and B, were not found the regular trend with different growth stages. However, the critical range of micronutrient contents in leaves of net melon at 25 days after transplanting were in Fe 102~164, Mn 52~116, Zn 28~98, Cu 7~15 and B $36{\sim}72mg\;kg^{-1}$, respectably. Finally, these results might be used at the indicator for critical nutrient contents for diagnosis of nutritional disorder in net melon in protected cultivation.

Influence of P, Ca, Zn, Mg, Fe, K, Mn, or Se in the Dietary Mineral Premix on Growth and Body Composition of Korean Rockfish (Sebastes schlegeli) (사료의 P, Ca, Zn, Mg, Fe, K, Mn과 Se이 조피볼락의 성장 및 체성분에 미치는 영향)

  • LEE Sang-Min;PARK Sung-Real
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.2
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    • pp.245-251
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    • 1998
  • A 10-week feeding experiment was conducted to determine the influence of several minerals from dietary mineral premix on growth and body composition in juvenile Korean rockfish. Three replicate groups of fish Initially averaging 4.2 g were fed one of the ten experimental diets. Korean rockfish muscle and casein as protein sources were used in the basal diet, and deleted one of each mineral (P, Ca, Zn, Mg, Fe, K, Mn, Se or all) in the control mineral premix, Weight gain, feed efficiency and nutrient retention in fish fed the diet not containing mineral premix were significantly lower than those in fish fed other diets (P<0.01). Weight gain in fish fed the diets deleted each mineral (P, Ca, Zn, Hg, Fe, K, Mn or Se) was lower than that of control diet (P<0.01), Feed efficiency and protein retention in fish fed the diets deleted each of P, Ca, Zn or Mn were lower than those ot control diet (P<0.01). Daily feed intake and lipid retention were not affected by dietary mineral premixes ( P>0.01). Proximate analysis and mineral contents in the whole body, muscle, liver or bone of fish fed the diets deleted each mineral were not different to control diet ( P>0.01). The data obtained in this study indicate that each of the P, Ca, Zn, Mg, Fe, K, Mn or Se is essential for normal growth of Korean rockfish.

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Comparison of Metal Contents in Respirable Particulate Mass by Particle Size and Season in Seoul and Asan City (서울.아산지역 호흡성먼지의 금속함량에 관한 연구)

  • Choi, Yun-Na;Jeon, Yong-Taek;Jang, Bong-Ki;Yang, Won-Ho;Yom, Yoon-Ki;Son, Bu-Soon
    • Journal of environmental and Sanitary engineering
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    • v.23 no.1
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    • pp.33-48
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    • 2008
  • The purpose of this study was to characterize background mass concentration of $PM_{10},\;PM_{2.5}$ and metallic composition from June 2004 to June 2005 in comparison with Seoul and Asan city. The results were as follows: 1. Annual mean of $PM_{10}$ concentrations in Seoul and Asan were $56.95({\pm}25.63){\mu}g/m^3,\;57.02({\pm}27.22){\mu}g/m^3$ respectly. 2. Annual mean of $PM_{2.5}$ concentrations in Seoul and Asan were $46.97({\pm}40.36){\mu}g/m^3,\;42.16({\pm}21.79){\mu}g/m^3$ respectly. 3. The average $PM_{2.5}/PM_{10}$ ratio was 0.82 in Seoul and 0.74 in Asan city. 4. The concentration of $PM_{10},\;PM_{2.5}$ were the highest in spring and the lowest in summer. Asan was higher than Seoul in spring and summer. 5. The results showed that average $PM_{10}$ composition order as Si>Fe>Pb>Zn>Mn in Seoul and Si>Fe>Zn>Pb>Mn in Asan. The concentration of metals in $PM_{10}$ of Seoul that Cr, Cu, Fe, Mn were high in spring and Zn was low in Fall. Fe, Mn were high in spring of Asan. 6. The results showed that average $PM_{2.5}$ composition order as Si>Pb>Fe>Zn>Mn in Seoul and Si>Fe>Pb>Zn>Cr in Asan. The concentration of metals in $PM_{2.5}$ of Seoul that Cr was high in spring. 7. The result showed that relation between Cr and Cu, Cu and Fe, Fe and Mn, Mn and Zn, Zn and Si in Seoul, Cr and Zn, Cu and Pb, Zn and Pb, Pb and Mn in Asan. The result showed that $PM_{10}$ concentration exceeding $50{\mu}g/m^3$(US-EPA Standard) and $PM_{2.5}$ concentration exceeding $15{\mu}g/m^3$(US-EPA Standard). In urban area, the monitoring of $PM_{2.5}$ permits the anthropogenic sources and the interference of natural sources with respect to $PM_{10}$ measurements.