• 제목/요약/키워드: Fatty acids, Volatile

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강원도산 잡화벌꿀의 유기산 및 지방산 특성에 관한 연구 (Organic Acids and Fatty Acids of Honey Harvested in Kangwon Area)

  • 김복남;김택제;최홍식
    • 한국식품영양과학회지
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    • 제20권1호
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    • pp.52-58
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    • 1991
  • Physico-chemical properties including the composition of organic acids and fatty acids in native bee-honey and foreign bee-honey harvested in Kangwon area were studied with the emphasis on the honey which was collected form wild flowers nd mixed flowers sources for honey nectars. the major organic acids were considered as acetic acid formic acid and valeric acid in volatile acids and gluconic acid maleic acid malic acid quinic acid and citric acid in non-volatile fraction in both of native bee-honey and foreigr bee-honey. Some naturally occuring fatty acids({{{{ { C}_14{ } }}}}-{{{{ {C }_{20 } }}}}) were observed with the principal fatty acids of myristic aicd linolenic acid and palmitic acid and palmitic acid in the various honey, The characteristics of moisture content pH viscosity free acidity lactone and total acidity were also analyzed and discussed.

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Fatty Acid Composition and Volatile Constituents of Protaetia brevitarsis Larvae

  • Yeo, Hyelim;Youn, Kumju;Kim, Minji;Yun, Eun-Young;Hwang, Jae-Sam;Jeong, Woo-Sik;Jun, Mira
    • Preventive Nutrition and Food Science
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    • 제18권2호
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    • pp.150-156
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    • 2013
  • A total of 48 different volatile oils were identified form P. brevitarsis larvae by gas chromatography/mass spectrometry (GC/MS). Acids (48.67%) were detected as the major group in P. brevitarsis larvae comprising the largest proportion of the volatile compounds, followed by esters (19.84%), hydrocarbons (18.90%), alcohols (8.37%), miscellaneous (1.71%), aldehydes (1.35%) and terpenes (1.16%). The major volatile constituents were 9-hexadecenoic acid (16.75%), 6-octadecenoic acid (14.88%) and n-hexadecanoic acid (11.06%). The composition of fatty acid was also determined by GC analysis and 16 fatty acids were identified. The predominant fatty acids were oleic acid ($C_{18:1}$, 64.24%) followed by palmitic acid ($C_{16:0}$, 15.89%), palmitoleic acid ($C_{16:1}$, 10.43%) and linoleic acid ($C_{18:2}$, 4.69%) constituting more than 95% of total fatty acids. The distinguished characteristic of the fatty acid profile of P. brevitarsis larvae was the high proportion of unsaturated fatty acid (80.54% of total fatty acids) versus saturated fatty acids (19.46% of total fatty acids). Furthermore, small but significant amounts of linoleic, linolenic and ${\gamma}$-linolenic acids bestow P. brevitarsis larvae with considerable nutritional value. The novel findings of the present study provide a scientific basis for the comprehensive utilization of the insect as a nutritionally promising food source and a possibility for more effective utilization.

Fatty Acid and Volatile Oil Compositions of Allomyrina dichotoma Larvae

  • Youn, Kumju;Kim, Ji-Young;Yeo, Hyelim;Yun, Eun-Young;Hwang, Jae-Sam;Jun, Mira
    • Preventive Nutrition and Food Science
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    • 제17권4호
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    • pp.310-314
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    • 2012
  • Thirty-two different volatile oils were identified from Allomyrina dichotoma (A. dichotoma) larvae by gas chromatography/mass spectrometry (GC/MS). The major volatile components were 2,2,4-trimethyl-3-carboxyisopropyl pentanoic acid isobutyl ester (5.83%), phenol,2,6-bis(a,a-dimethyl ethyl)-4-(1-methyl-1-phenylethyl) (5.72%), heptacosane (5.49%) and phenol,2,4-bis(1-methyl-1-phenylethyl) (5.47%). The composition of the fatty acids in A. dichotoma larvae was also determined by gas chromatography (GC) and fourteen constituents were identified. Oleic acid (19.13%) was the most abundant fatty acid followed by palmitic acid (12.52%), palmitoleic acid (3.71%) and linoleic acid (2.08%) in 100 g of A. dichotoma larvae on a dry weight basis. The quantity of unsaturated fatty acids (64.00%) were higher than that of saturated ones (36.00%). The predominant fatty acids in A. dichotoma consist of monounsaturated fatty acid (MUFA, 57.70%) such as oleic acid, myristoleic acid and palmitoleic acid, followed by saturated fatty acids (36.00%) and polyunsaturated fatty acids (PUFA, 6.50%). In particular, the presence of essential fatty acids, such as linoleic (5.30%) and linolenic acid (0.40%) give A. dichotoma larvae considerable nutritional and functional value and it may be a useful source for food and/or industrial utilization.

Mixotrophic microalgae에 의한 음폐수 소화액 고도처리에 있어 유기산이 microalgae의 성장 및 질소, 인 제거에 미치는 영향 (Effects of volatile fatty acids on microalgae growth and N, P consumption in the advanced treatment process of digested food waste leachate by mixotrophic microalgae)

  • 장산;황선진
    • 상하수도학회지
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    • 제31권4호
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    • pp.357-362
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    • 2017
  • Acetate, propionate, butyrate are the major soluble volatile fatty acids metabolites of fermented food waste leachates. This work investigate the effects of volatile fatty acid on the growth rate and $NH_4-N$, $PO_4-P$ removal efficiency of mixotrophic microalgae Chlorella vulgaris to treat digested food waste leachates. The results showed that acetate, propionate and butyrate were efficiently utilized by Chlorella vulgaris and microalgae growth was higher than control condition. Similar trends were observed upon $NH_4-N$ and $PO_4-P$ consumption. Volatile fatty acids promoted Chlorella vulgaris growth, and nutrient removal efficiencies were highest when acetate was used, and butyrate and propionate showed second and third. From this work it could be said that using mixotrophic microalgae, in this work Chlorella vulgaris, fermented food waste leachates can be treated with high efficiencies.

Dynamic SPME를 이용한 공기 중 지방산 분석 (Analysis of Volatile Fatty Acids in Air by Dynamic SPME)

  • 유미선;양성봉;하남기
    • 한국환경과학회지
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    • 제19권12호
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    • pp.1447-1454
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    • 2010
  • In this study, the detection limits of lower fatty acids in air were investigated by using Dynamic SPME(Solid Phase Micro-Extraction), i.e. improved Head Space - SPME method(HS-SPME). This Dynamic SPME, called SPDE(Solid Phase Dynamic Extraction), is the analytical method for volatile compounds in air with the extraction by using a stainless steel needle of which inner surface is coated with adsorption material and following the gas chromatographic analysis by inserting the needle into a injection port of GC and subsequently, desorption of the volatile compounds into a gas-chromatographic column. Extraction was carried out by passing the sample air through the needle with a suction pump which has been used for a detection tube. The result of measurement for the 6 lower fatty acids showed that the detection limits ranged from 0.10 ppm to 0.44 ppm and the linear correlation coefficients were over 0.99. Relative standard deviations obtained from 5 analytical repetition of a ca. 1.6 ppm standard mixture were in the range of 1.87%~2.47%. This method has been shown to be a adequate for the measuring C2~C5 fatty acids in air in the concentrations of over several hundreds ppb.

버어리엽 건조과정에서 비휘발성 유기산, 지방산 및 폴리페놀화합물의 함량변화 (Changes in the Contents of Non-Volatile Organic Acids, Fatty Acids and Poly phenolic Compounds during Air-Curing in Burley Tobacco)

  • 김도연;배성국;이정일;지상운;김영회
    • 한국연초학회지
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    • 제22권2호
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    • pp.107-113
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    • 2000
  • This study was carried out to investigate the changes in composition of the non-volatile organic acid, fatty acid and polyphenolic compounds during air-curing in burley tobacco leaves, and the effect of curing methods on the contents in air-cured leaves. The air-cured variety, (Nicotiana tabacum cv KB108) was normally grown at the Chonju tobacco experiment station in 1998. Plants designated for the each curing methods were harvested on the same date, and the ripe leaves for primed curing were harvested at the tenth leaf position from the top on the stalk. The major compounds of non-volatile organic acid and fatty acid were malic, citric, oxalic, palmitic, and linolenic acid. The concentrations of malic acid, unsaturated fatty acids, chlorogenic acid and rutin in cured leaves were remarkably decreased during curing, while citric acid was increased. The changes of these compounds showed the similar pattern during both primed and stalk curing. In connection with curing methods, the contents of malic, linoleic and linolenic acid were higher in excessive cured leaves than those in primed cured or stalk cured leaves, while the content of citric acid was lower in excessive cured leaves than that in primed cured or stalk cured leaves.

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Effect of Unsaturated Fatty Acids on Cellulose Degradation and Fermentation Characteristics by Mixed Ruminal Microbes

  • Hwang, I.H.;Kim, H.D.;Shim, S.S.;Lee, Sang S.;Ha, J.K.
    • Asian-Australasian Journal of Animal Sciences
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    • 제14권4호
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    • pp.501-506
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    • 2001
  • This experiment was conducted to evaluate the effects of supplemental unsaturated fatty acids (UFA) on fermentation characteristics, especially on gas production, cellulose degradation and volatile fatty acid (VFA) concentration by mixed ruminal microorganisms. In order to attain this objective, unsaturated fatty acids including oleic acid (C 18:1), linoleic acid (C18:2) and arachidonic acid (C22:4) were added at varying level. Mixed ruminal microbes used in this experiment were obtained from the rumen of a cannulated Holstein cow. Medium pH values after 7 d incubation were significantly affected by type and level of unsaturated fatty acids (p<0.01). All of UFA inhibited total gas production, and especially treatment of arachidonic acid at the levels of 0.01% gave the lowest gas. production after 7 d incubation (p<0.01). Comparison of the population of protozoa revealed that UFA did not have any significant effect on the total protozoa number. The addition of UFA did not effect dry matter degradation. Volatile fatty acid (VFA) composition of the culture was influenced little by UFA, although the considerable amount of iso-type VFA were detected in UFA supplemented incubations. The ratio of acetic acids to propionic acids, however, was lower than control in all the treatments after 7 d incubation (p<0.01).

유기성 액상 슬러지로부터 휘발성 지방산의 회수를 위한 혐기성 막-발효기의 적용 (Application of Anaerobic Membrane-Fermenter for the Recovery of Volatile Fatty Acids from Organic Liquid Sludge)

  • 김종오;정종태
    • 멤브레인
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    • 제14권1호
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    • pp.37-43
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    • 2004
  • 휘발성 지방산의 생성 및 회수를 위한 분리막의 유효성을 실험적으로 검토한 결과, 분리막의 적용에 의해 발효조 내의 부유고형물 농도, 유기산 생성균수 및 유기산 농도가 증가하였다. 혐기성 발효액의 고액분리 및 발효 효율향상을 위한 분리막의 적용은 발효조 내의 관련 미생물 농도를 증가시키고 따라서 분리막을 적용하지 않은 경우에 비해 유기산 생성효율이 훨씬 증가하였다. 분리막이 결합된 산 발효조의 적용은 유기성 슬러지로부터 휘발성 지방산의 회수 효율증대에 효과적인 적용기술이라 판단된다.

백일주 양조중 알코올, 유리아미노산, 비휘발성유기산 및 지방산조성의 변화 (Changes of Alcohol, Free Amino Acid, Non-Volatile Organic Acid and fatty Acid Composition during Brewing of Backilju)

  • 박석규;박필숙;김귀영;강우원;이영근
    • 동아시아식생활학회지
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    • 제4권3호
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    • pp.103-109
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    • 1994
  • Changes in taste components of Backilju, an traditional alcoholic beverage of Korea, were investigated. Ethanol(17%) was the most abundant, and then isoamylalcohol(23mg%) and methanol(8mg%) were also detected in a small amount in Backilju. Major non-volatile organic acids were lactic and malic acid, followed by citric, fumaric and succinic acid. Arginine, phenylalanine and glutamic acid were major free amino acids and essential amino acid content was 230∼560 mg%, which was 45∼48% of total free amino acids. The major fatty acid of total lipid was palmitic acid(37∼43%). It has been found that the Backilju contained more free amino acids and alcohols than other Korean Yokjus.

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산초열매의 채집 시기별 일반성분, 지방산 및 정유성분 조성 변화 (Studies on Proximate Composition, Fatty Acids and Volatile Compounds of Zanthoxylum schinifolium Fruit According to Harvesting Time)

  • 배성문;진영민;정은호;김만배;신현열;노치웅;이승철
    • 한국약용작물학회지
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    • 제19권1호
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    • pp.1-8
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    • 2011
  • Biological characteristics of 5 Zanthoxylum schinifolium (Zs) fruits such as Z1 (early August), Z2 (middle August), Z3 (middle September), Z4 (early October) and Z5 (middle October) according to harvesting time were evaluated. As fruits ripened, average weight of Zs increased from 4.8mg (Z1) to 50.7mg (Z5), while moisture contents decreased from 74.6% (Z1) to 55.2% (Z5). Crude fat contents of the fruits during ripening increased from 1% (Z1) to 10.6% (Z5). The major fatty acids in Zs were palmitic (C16:0), palmitoleic (C16:1), oleic (C18:1), and linoleic (C18:2) acids. Linoleic acid (C18:2) was a main fatty acid in Z1 and Z2, whereas oleic acid (C18:1) was found as a main one in the other Zs. The ratio of unsaturated fatty acid to total fatty acids increased from 60% (Z1) to 80% (Z3~Z5) during ripening. Among ripening stages, Z4 had the highest contents of total fatty acids ($3,355{\mu}g/g$) and total unsaturated fatty acids ($2,753{\mu}g/g$). Forty six volatile compounds in Zs were also identified. The major volatile compounds were ${\alpha}-pinene$, ${\beta}-myrcene$, ${\beta}-ocimene$, 2-nonanone, estragole, 2-undecanone, and ${\beta}-caryophyllene$. Major volatile components of Z1 were ${\beta}-ocimene$ (20.8 peak area %) and ${\alpha}-pinene$ (9.7 peak area %). In Z2, estragole (30.1 peak area %) was a main volatile compound, but the contents of ${\alpha}-pinene$ (0.4 peak area %), ${\beta}-myrcene$ (0.3 peak area %), and ${\beta}-ocimene$ (0.6 peak area %) were lower than those in Z1. Especially, estragole used as perfumes and as a food additive for flavor was drastically increased to 91.2 (Z3) and 92% (Z4) as fruits ripened.