• Title/Summary/Keyword: Fast reactor design

Search Result 175, Processing Time 0.02 seconds

An Experimental and Modeling Study on the Oxidation Kinetics of Nitric Oxide over Platinum-based Catalysts (백금계 촉매상에서 산화질소(NO)의 산화반응속도에 관한 실험 및 모델링 연구)

  • Kim, Young-Deuk;Jeong, Soo-Jin;Kim, Woo-Seung
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.20 no.5
    • /
    • pp.71-80
    • /
    • 2012
  • To improve the $NO_X$ conversion over a SCR (selective catalytic reduction) catalyst, the DOC (diesel oxidation catalyst) is usually placed upstream of the SCR catalyst to enhance the fast SCR reaction ($4NH_3+2NO+2NO_2{\rightarrow}4N_2+6H_2O$) using equimolar amounts of NO and $NO_2$. Here, a ratio of $NO_2/NO_X$ above 50% should be avoided, because the reaction with $NO_2$ only ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$) is slower than the standard SCR reaction ($4NH_3+4NO+O_2{\rightarrow}4N_2+6H_2O$). In order to accurately predict the performance characteristics of SCR catalysts, it is therefore desired to develop a more simple and reliable mathematical and kinetic models on the oxidation kinetics of nitric oxide over a DOC. In the present work, the prediction accuracy and limit of three different chemical reaction kinetics models are presented to describe the chemicophysical characteristics and conversion performance of DOCs. Steady-state experiments with DOCs mounted on a light-duty four-cylinder 2.0-L turbocharged diesel engine then are performed, using an engine-dynamometer system to calibrate the kinetic parameters such as activation energies and preexponential factors of heterogeneous reactions. The reaction kinetics for NO oxidation over Pt-based catalysts is determined in conjunction with a transient one-dimensional (1D) heterogeneous plug flow reactor (PFR) model with diesel exhaust gas temperatures in the range of 115~$525^{\circ}C$ and space velocities in the range of $(0.4{\sim}6.5){\times}10^5\;h^{-1}$.

THREE-DIMENSIONAL FLOW PHENOMENA IN A WIRE-WRAPPED 37-PIN FUEL BUNDLE FOR SFR

  • JEONG, JAE-HO;YOO, JIN;LEE, KWI-LIM;HA, KWI-SEOK
    • Nuclear Engineering and Technology
    • /
    • v.47 no.5
    • /
    • pp.523-533
    • /
    • 2015
  • Three-dimensional flow phenomena in a wire-wrapped 37-pin fuel assembly mock-up of a Japanese loop-type sodium-cooled fast reactor, Monju, were investigated with a numerical analysis using a general-purpose commercial computational fluid dynamics code, CFX. Complicated and vortical flow phenomena in the wire-wrapped 37-pin fuel assembly were captured by a Reynolds-averaged Navier-Stokes flow simulation using a shear stress transport turbulence model. The main purpose of the current study is to understand the three-dimensional complex flow phenomena in a wire-wrapped fuel assembly to support the license issue for the core design. Computational fluid dynamics results show good agreement with friction factor correlation models. The secondary flow in the corner and edge subchannels is much stronger than that in an interior subchannel. The axial velocity averaged in the corner and edge subchannels is higher than that averaged in the interior subchannels. Three-dimensional multiscale vortex structures start to be formed by an interaction between secondary flows around each wire-wrapped pin. Behavior of the large-scale vortex structures in the corner and edge subchannels is closely related to the relative position between the hexagonal duct wall and the helically wrapped wire spacer. The small-scale vortex is axially developed in the interior subchannels. Furthermore, a driving force on each wire spacer surface is closely related to the relative position between the hexagonal duct wall and the wire spacer.

ANALYSES OF ANNULAR LINEAR INDUCTION PUMP CHARACTERISTICS USING A TIME-HARMONIC FINITE DIFFERENCE ANALYSIS

  • Seong, Seung-Hwan;Kim, Seong-O
    • Nuclear Engineering and Technology
    • /
    • v.40 no.3
    • /
    • pp.213-224
    • /
    • 2008
  • The pumping of coolant in a liquid metal fast reactor may be performed with an annular linear induction electro-magnetic (EM) pump. Linear induction pumps use a traveling magnetic field wave created by poly-phase currents, and the induced currents and their associated magnetic field generate a Lorentz force, whose effect can be the pumping of the liquid metal. The flow behaviors in the pump are very complex, including a time-varying Lorentz force and pressure pulsation, because an induction EM pump has time-varying magnetic fields and the induced convective currents that originate from the flow of the liquid metal. These phenomena lead to an instability problem in the pump arising from the changes of the generated Lorentz forces along the pump's geometry. Therefore, a magneto-hydro-dynamics (MHD) analysis is required for the design and operation of a linear induction EM pump. We have developed a time-harmonic 2-dimensional axisymmetry MHD analysis method based on the Maxwell equations. This paper describes the analysis and numerical method for obtaining solutions for some MHD parameters in an induction EM pump. Experimental test results obtained from an induction EM pump of CLIP-150 at the STC "Sintez," D.V. Efremov Institute of Electro-physical Apparatus in St. Petersburg were used to validate the method. In addition, we investigated some characteristics of a linear induction EM pump, such as the effect of the convective current and the double supply frequency (DSF) pressure pulsation. This simple model overestimated the convective eddy current generated from the sodium flow in the pump channel; however, it had a similar tendency for the measured data of the pump performance through a comparison with the experimental data. Considering its simplicity, it could be a base model for designing an EM pump and for evaluating the MHD flow in an EM pump.

Comparison of Crack Growth Test Results at Elevated Temperature and Design Code Material Properties for Grade 91 Steel (Grade 91 강의 고온 균열진전 실험 결과와 설계 물성치의 비교)

  • Lee, Hyeong-Yeon;Kim, Woo-Gon;Kim, Nak-Hyun
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.39 no.1
    • /
    • pp.27-35
    • /
    • 2015
  • The material properties of crack growth models at an elevated temperature were derived from the results of numerous crack growth tests for Mod.9Cr-1Mo (ASME Grade 91) steel specimens under fatigue loading and creep loading at an elevated temperature. These crack growth models were needed for defect assessment under creep-fatigue loading. The mathematical crack growth rate models for fatigue crack growth (FCG) and creep crack growth (CCG) were determined based on the test results, and the models were compared with those of the French design code RCC-MRx to investigate the conservatism of the code. The French design code RCC-MRx provides an FCG model and a CCG model for Grade 91 steel in Section III Tome 6. It was shown that the FCG model of RCC-MRx is conservative, while the CCG model is non-conservative compared with the present test data. Thus, it was shown that further validation of the property was required. Mechanical strength tests and creep tests were also conducted, and the test results were compared with those of RCC-MRx.

Investigation on the Allowable Transient Power Levels to Maintain the Mechanical Integrity of the 17$\times$17 KOFA Fuel Rod During the ANS Conditions I and II (ANS과도조건 I 및 II에서 17x17 KOFA 핵연료봉의 기계적 건전성이 유지되는 과도상태 허용 출력준위에 관한 연구)

  • Lee, Chan-Bock;Kim, Ki-Hang;Kim, Kyu-Tae
    • Nuclear Engineering and Technology
    • /
    • v.26 no.1
    • /
    • pp.119-125
    • /
    • 1994
  • Transient power level of the fuel rod is one of the key parameters for the transient fuel behavior. Through the analysis of the fuel performance data bases and sensitivity analyses of such parameters as rod power history, fast neutron flux, fuel enrichment and cycle length, which can affect the transient fuel behavior, a methodology generally applicable to find the allowable transient power level during the ANS Conditions I and II below which the mechanical integrity of the fuel rod is maintained was derived, and allowable transient power levels for the 17$\times$17 KOFA fuel rod have been determined as a function of the burnup. With the introduction of this methodology, design analysis of the transient fuel behavior currently being calculated every cycle can be replaced by the simple check of the peak transient power level achievable during the cycle, and an operational flexibility of the reactor can be obtained by allowing higher transient power level up to 689.5 w/cm at low burnup range than current maximum allowable transient power level, 591 w/cm for the 17$\times$17 KOFA fuel.

  • PDF