• 제목/요약/키워드: Fast ion

검색결과 318건 처리시간 0.025초

Capillary Electrophoresis Detection of Hydrogen Peroxide by Using Titanium Ion and 4-(2-thiazolylazo)resorcinol

  • Vu Phuong, Dong;Yoo, Hoon
    • International Journal of Oral Biology
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    • 제42권4호
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    • pp.197-201
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    • 2017
  • A novel method for the detection of hydrogen peroxide in aqueous solution was developed via reaction between $H_2O_2$, trivalent titanium ion ($Ti^{3+}$) and 4-(2-thiazolylazo) resorcinol (TAR), resulting in a ternary complex with a maximum UV absorbance at 530 nm. The CE detection of $H_2O_2$ was fast, sensitive and cost-effective without pretreatment procedures. $H_2O_2$ was detected within 15 min at 1 to $100{\mu}M$ range with the lowest detection limit at $1.0{\mu}M$. Under the optimized CE conditions, the concentration of $H_2O_2$ in coffee or tea extract was quantitatively determined. Our results show that CE detection of the ternary complex of $H_2O_2-Ti^{3+}$-TAR has potential applications for the detection of $H_2O_2$ in aqueous sources.

Design and development of less than 1Kw Lithium rechargeable battery pack

  • Kim, Sang-Bum;Lee, Sang-Hyun
    • International Journal of Internet, Broadcasting and Communication
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    • 제10권3호
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    • pp.104-108
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    • 2018
  • Lithium-ion batteries have been used in energy storage systems (ESS), electric vehicles (EVs), etc. due to their high safety, fast charging and long lifecycle. This paper aims to improve the convenience of users by changing the wired battery stack used in the battery pack, wirelessly using RFID, reducing the internal volume of the battery pack, reducing the size of the battery pack. In this paper, we propose a battery management system which can provide the flexibility of battery pack expansion and maintenance by using lithium ion battery, battery management system (BMS) and wireless communication for light weight of 1Kw small battery pack. Also, by flexibly arranging the cell layout inside the battery pack and designing to reduce the size of the outer shape of the battery pack.

제올라이트를 PVA로 고정화한 흡착제에 의한 Cs과 Sr 이온 제거 (Removal of Cs and Sr Ions by Absorbent Immobilized Zeolite with PVA)

  • 이창한;이민규
    • 대한환경공학회지
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    • 제37권8호
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    • pp.450-457
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    • 2015
  • 본 연구에서는 제올라이트를 PVA에 고정화시켜 새로운 흡착제인 PVA-Zeolite 비드를 제조하고, XRD 및 SEM 분석을 통해 제조한 PVA-Zeolite 비드는 내부에 제올라이트가 잘 고정화된 다공성 구조를 가지고 있는 것을 확인할 수 있었다. 제조한 흡착제에 의한 Cs 이온과 Sr 이온에 대한 흡착특성을 살펴보기 위하여 pH의 영향, 흡착속도, 흡착등온을 검토하였다. Sr 및 Cs 이온에 대한 평형흡착시간은 약 540 min으로 나타났으며, 흡착속도는 유사 1차 속도식 보다는 유사 2차 속도식에 더 잘 부합하였다. 흡착평형 실험결과는 Langmuir 등온식에 잘 적용되었으며, Langmuir 등온식으로부터 구한 Sr 이온과 Cs 이온의 최대 흡착량은 각각 52.08 mg/g와 58.14 mg/g이었다. PVA-Zeolite 비드에 의한 Sr 이온과 Cs 이온의 흡착공정은 외부물질전달단계는 매우 빠르게 이루어지며, 내부입자확산에 의한 흡착반응은 느리게 진행되어 내부입자확산 단계가 흡착속도 결정단계인 것으로 판단된다.

Development and Testing of a Prototype Long Pulse Ion Source for the KSTAR Neutral Beam System

  • Chang Doo-Hee;Oh Byung-Hoon;Seo Chang-Seog
    • Nuclear Engineering and Technology
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    • 제36권4호
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    • pp.357-363
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    • 2004
  • A prototype long pulse ion source was developed, and the beam extraction experiments of the ion source were carried out at the Neutral Beam Test Stand (NBTS) of the Korea Superconducting Tokamak Advanced Research (KSTAR). The ion source consists of a magnetic bucket plasma generator, with multi-pole cusp fields, and a set of tetrode accelerators with circular apertures. Design requirements for the ion source were a 120kV/65A deuterium beam and a 300 s pulse length. Arc discharges of the plasma generator were controlled by using the emission-limited mode, in turn controlled by the applied heating voltage of the cathode filaments. Stable and efficient arc plasmas with a maximum arc power of 100 kW were produced using the constant power mode operation of an arc power supply. A maximum ion density of $8.3{\times}10^{11}\;cm^{-3}$ was obtained by using electrostatic probes, and an optimum arc efficiency of 0.46 A/kW was estimated. The accelerating and decelerating voltages were applied repeatedly, using the re-triggering mode operation of the high voltage switches during a beam pulse, when beam disruptions occurred. The decelerating voltage was always applied prior to the accelerating voltage, to suppress effectively the back-streaming electrons produced at the time of an initial beam formation, by the pre-programmed fast-switch control system. A maximum beam power of 0.9 MW (i.e. $70\;kV{\times}12.5\;A$) with hydrogen was measured for a pulse duration of 0.8 s. Optimum beam perveance, deduced from the ratio of the gradient grid current to the total beam current, was $0.7\;{\mu}perv$. Stable beams for a long pulse duration of $5{\sim}10\;s$ were tested at low accelerating voltages.

각형 전기이중층 커패시터의 산업 안전성 (Industry safety characteristic of Prismatic EDLCs)

  • 김경민;장인영;강안수
    • 대한안전경영과학회:학술대회논문집
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    • 대한안전경영과학회 2004년도 춘계학술대회
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    • pp.247-257
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    • 2004
  • Electrodes were fabricated based on activated carbon powder BP-20, conducting agent such as Super P, vapor grown carbon fiber (VGCF) and acetylene black (AB), and the mixed binders of flexible poly(vinylidenefluoridehexafluoropropylene) [P(VdF-co-HFP)] and cross linking dispersion agent of polyvinylpyrrolidone (PVP) to increase mechanical strength. According to impedance measurement of the electrode with the addition of conducting agent, we found that it was possible to charge rapidly by the fast steady-state current convergence due to low equivalent series resistance (AC-ESR, fast charge transfer rate at interface between electrode and electrolyte and low RC time constant. The self-discharge of unit cell showed that diffusion process was controlled by the ion concentration difference of initial electrolyte due to the characteristics of Electric Double Layer Capacitor (EDLC) charged by ion adsorption in the beginning, but this by current leakage through the double-layer at the electrode/electrolyte interface had a minor effect and voltages of curves were remained constant regardless of electrode material. We found that the 2.3V/230F grade EDLC would be applied to industrial safety usage such as uninterrupted power supply (UPS) because of the constant DC-ESR by IR drop regardless of discharge current.

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Staphylococcal Enterotoxin A 의 분리 정제 (Purification of Staphylococcal Enterotoxin A)

  • 이정희;신현길;김종배;김태종;윤화중
    • 한국식품과학회지
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    • 제20권6호
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    • pp.780-786
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    • 1988
  • 본 실험은 Staphylococcus aureus로부터 생성되는 enterotoxin A의 분리를 위하여 각종 분리방법을 조사하였고 그 특성들을 상호 비교하였던 바 다음과 같은 결과를 얻었다. Amberlite 수지는 배지로부터 처음 toxin을 분리 하는 데에는 간편한 수지이나 정제도에 있어서는 약 70%수준으로 다른 방법들에 비해 낮은 편이었다. CM-cellu-lose수지는 0.2M phosphate buffer로 용출했을 때 75% 정도의 정제도를 가진 toxin을 분리할 수 있었으나 stepwise법으로 용출했을 때에는 80% 이상으로 정제도를 높일 수 있었고 Amberlite 수지와 함께 사용했을 때에는 90%정도의 toxin을 얻을 수 있었다. Amberlite나 CM-cellulose수지로 정제한 후 gel filtration을 실시하면 정제도를 더 높일 수 있었다. FPLC는 분리도와 정제도에서 가장 우수하였으며 FPLC의 결과에 따라 Amberlite 수지는 toxin 분획을 중심으로 앞의 분획을 그리고 CM-cellulose 수지는 뒤의 분획을 주로 제거 하는 특징을 가진다. 따라서 위의 column중 하나만 사용한 후 FPLC를 사용하면 95%이상의 toxin을 분리하는 것이 가능하였다.

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오존을 이용한 용존성 망간 제거 특성: 공존이온의 영향 및 최적주입량 (Characteristics of manganese removal by ozonation: Effect of existing co-ion and optimum dosage)

  • 곽연우;이슬기;이용수;홍성호
    • 상하수도학회지
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    • 제32권2호
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    • pp.145-152
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    • 2018
  • This study is focused on manganese (Mn(II)) removal by ozonation in surface water. Instant ozone demand for the water was 0.5 mg/L in the study. When 0.5 mg/L of Mn(II) is existed in water, the optimum ozone concentration was 1.25 mg/L with reaction time 10 minutes to meet the drinking water regulation. The ozone concentration to meet the drinking water regulation was much higher than the stoichiometric concentration. The reaction of soluble manganese removal was so fast that the reaction time does not affect the removal dramatically. When Mn(II) is existed with Fe, the removal of Mn(II) was not affected by Fe ion. However As(V) is existed as co-ion the removal of Mn(II) was decreased by 10%. Adding ozone to surface water has limited effect to remove dissolved organic matter. When ozone is used as oxidant to remove Mn(II) in the water, the existing co-ion should be evaluated to determine optimum concentration.

Effects of ion irradiation on microstructure and properties of zirconium alloys-A review

  • Yan, Chunguang;Wang, Rongshan;Wang, Yanli;Wang, Xitao;Bai, Guanghai
    • Nuclear Engineering and Technology
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    • 제47권3호
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    • pp.323-331
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    • 2015
  • Zirconium alloys are widely used in nuclear reactors as structural materials. During the operation, they are exposed to fast neutrons. Ion irradiation is used to simulate the damage introduced by neutron irradiation. In this article, we briefly review the neutron irradiation damage of zirconium alloys, then summarize the effect of ion irradiation on microstructural evolution, mechanical and corrosion properties, and their relationships. The microstructure components consist of dislocation loops, second phase precipitates, and gas bubbles. The microstructure parameters are also included such as domain size and microstrain determined by X-ray diffraction and the S-parameter determined by positron annihilation. Understanding the relationships of microstructure and properties is necessary for developing new advanced materials with higher irradiation tolerance.