• 한국막학회:학술대회논문집
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• 한국막학회 2003년도 추계 총회 및 학술발표회
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• pp.51-54
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• 2003

• 한국막학회:학술대회논문집
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• 한국막학회 2003년도 춘계 총회 및 학술발표회
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• pp.110-113
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• 2003

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2002년도 봄 학술발표회 논문집
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• pp.462-465
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• 2002

물에 용해되어 있는 금속이온의 분리를 위한 선택성이 있는 분리 막의 개발은 환경오염이 날로 심각해지고 있는 오늘날에 환경오염의 개선, 에너지절약, 자원의 재활용 등 문제를 해결함에 있어서 아주 중요한 작용을 하게 될 것이다. 물에 용해되어 있는 금속이온을 선택적으로 분리하기 위해 일반적으로 캐리어(carrier)를 함유한 Carrier-Facilitated Transport Membrane (CFM)을 이용하게 되는데, 이 방면에 대한 연구는 주로 유기 상에 용해되어 있는 캐리어를 microporous한 필름에 지지하게 하는 방식으로 만들어진 Supported Liquid Membrane (SLM) 혹은 Elusion Liquid Membrance (ELM)의 개발에 대한 팽대한 연구가 이루어 졌다(1). (중략)

• 한국막학회:학술대회논문집
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• 한국막학회 1999년도 The 7th Summer Workshop of the Membrane Society of Korea
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• pp.15-18
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• 1999

A simple mathematical model for facilitated mass transport through a fixed site carrier membrane was derived by assuming an instantaneous, microscopic concentration (activity) fluctuation. The current model demonstrates that the facilitation factor depends on the extent of concentration fluctuation, the time scale ratios of diffusion to chemical reaction and the ratio of the carrier concentration to the solute solubility in matrix. The model was examined against the experimental data on oxygen transport in membranes containing metallo-porphyrin carriers, and the agreement was exceptional (within 10% error). The basic concept of this approach was applied to separate olefin from olefin/paraffin mixtures. A proprietaty carrier, developed here, resulted that the selectivity of propylene over propane was more than 120 and the propylene permeance exceed 40 gpu.

• 한국막학회:학술대회논문집
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• 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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• pp.152-154
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• 2004

A new model of selectively preferential sorption-facilitated transport with fixed site carriers was advanced in this paper. A number of experiments were arranged to demonstrate the ideal above. Preliminary results were obtained from the experiments, and shown the model was applicable for many membrane processes, such as RO, ED, gas separation and liquid membranes etc.

• 한국막학회:학술대회논문집
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• 한국막학회 2003년도 춘계 총회 및 학술발표회
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• pp.71-74
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• 2003

• 한국막학회:학술대회논문집
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• 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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• pp.136-139
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• 2004

Olefin/paraffin separation by the facilitated transport membrane using silver salts as carriers has been considered as a promising alternative to the conventional energy intensive distillation process. The basis for the separation is the ability of silver ions to react reversibly with olefin forming silver-olefin complexes.(omitted)

• Macromolecular Research
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• 제8권1호
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• pp.1-5
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• 2000

The valiclity of the simple mathematical model for facilitated transport in a solid state membrane developed previously has been examined againsts the carrier concentration and membrane thick-ness. Membranes are prepared with copolymer of styrene and 4-vinylpyridine as a matrix and Co(salen) as a carrier. 4-Vinylpyridine is incorporated to provide the coordination site for Co(salen) carrier. Oxygen permeability through the facilitated transport membrane is linearly increased with the square of its thick-ness, as predicted by the mathematical model. However, the oxygen permeability does not increase linearly with the carrier concentration. This seems to be due to the deactivation of the carrier by dimerization at high carrier concentrations as well as the reduced chain mobility by coordination of bulky Co(salen) carrier.

• Macromolecular Research
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• 제12권2호
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• pp.145-155
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• 2004

Facilitated transport membranes for the separation of olefin/paraffin mixtures have long been of interest in separation membrane science because olefins, such as propylene and ethylene, which are important chemicals in petrochemical industries, are currently separated by energy-intensive cryogenic distillation processes. Recently, solid polymer electrolyte membranes containing silver ions have demonstrated remarkable performance in the separation of olefin/paraffin mixtures in the solid state and, thus, they can be considered as alternatives to cryogenic distillation. Here, we review recent progress, and critical issues affecting in the use of facilitated olefin transport membranes; in particular, we provide a general overview with reference to carrier properties, transport mechanisms, and separation performance.

• 멤브레인
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• 제13권2호
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• pp.125-129
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• 2003

은염이 함유된 고분자 전해질을 이용한 올리핀 촉진수송 분리막은 고체상에서 높은 올레핀/파라핀 분리 성능을 나타내었다 본 연구에서는, 프로필렌/프로판 분리 선택도와 투과도의 성능을 향상시키기 위해 아미노산의 일종인 valine을 고분자 전해질막에 첨가하였다. FT-lR 분광학을 통해 valine의 양이온과 은염의 음이온이 상호작용을 하고, 그 결과 valine은 은이온의 활성도를 증가시킴을 알 수 있었다. 따라서 valine을 포함하고 있는 촉진수송 분리막은 valine이 없을 때보다 더 높은 선택도와 투과도를 나타내었다.