• 접착 및 계면
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• 제20권3호
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• pp.102-109
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• 2019

PET기재 필름 위에 코팅된 다층박막 필름의 층별성분을 ATR FT-IR과 Pyro GC/MS(Gas Chromatography/Mass Spectroscopy)를 이용하여 분석을 시도하였다. 필름의 단면은 액체질소에 담근 후 파괴시켜 얻었으며 광학 현미경을 이용하여 관찰하였다. 이 결과 코팅층의 총 두께는 $70{\mu}m$였으며 3개의 층으로 관찰되었다. 각 층의 두께는 너무 얇기 때문에 표면층을 제외하고는 직접분석이 어려워 적절한 용매로서 각 층을 드러나게 한 후 ATR FT-IR과 pyro-GC/MS를 이용하여 분석을 시도하였다. 이 결과 3개 층은 공통적으로 우레탄-아크릴레이트 공중합체로 밝혀졌다. 또한 무기 혹은 금속성분의 첨가여부는 XPS와 SEM-EDAX를 이용하여 분석하였으며 도장층 (1)에는 나노크기의 실리카 입자가 도장층 (2)에서는 알루미늄 박편이 존재함을 알게 되었다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2004년도 추계학술대회 논문집 전기물성,응용부문
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• pp.117-119
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• 2004

To improve mean-life and reliability of power cable in this study, we have investigated chemical properties showing by changing the content of carbon black that is semiconductive additives for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Chemical properties of specimens was measured by FT-ATR (Fourier Transform Attenuated Total Reflectance). The condition of specimens was a solid sheet. We could observe functional group (C=O, carbonyl group) of specimens through FT-ATR. From these experimental result, the concentration of functional group (C=O) was high according to increasing the content of carbon black. We could know EEA was excellent more than other specimens from above experimental results.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2010년도 춘계학술대회 논문집
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• pp.475-476
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• 2010

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2009년도 추계학술대회 논문집
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• pp.303-304
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• 2009

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.113-113
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• 2016

반도체 산업이 발전하고 기술이 향상됨에 따라 미세화되고 복잡한 구조의 소자가 개발되고 있으며, 2차원 소재 등 다양하고 새로운 소재들이 발견 및 연구되고 있다. 새로운 소재 또는 기술을 이용한 고품질 소자를 개발하기 위해서는 우수한 특성(높은 순도, 우수한 분해 및 반응 특성)을 지닌 증착소재의 개발 및 평가가 선행되어야 한다. 기존의 증착소재의 기본 물성을 측정하는 방법인 단순 기상 Fourier transform infrared spectroscopy(FT-IR) 분석법은 실제 공정에서의 증착경향을 대변하기 어렵다는 단점이 있다. 이러한 단점을 보완하기 위해 개조된 attenuated total reflection (ATR) 액세서리를 이용하여 실제 공정에서의 증착경향을 대변하고자 하였다. 본 연구에서는 반도체 증착소재의 분해 및 표면 흡착 특성을 분석하기 위해 ATR-FTIR 분석법을 이용하여 수행하였으며, 분산안정도에 따른 nanoparticle을 ATR의 크리스탈 표면에 분포시켜 hexamethyldisilazane(HMDS) source의 흡착 효율을 향상시키는 연구를 수행하였다. Nanoparticle의 분산안정도를 높이기 위하여 suspension 상태에서 pH, sonication, 분산제를 이용하였으며, nanoparticle을 ATR crystal 표면에 분포하여 분석한 결과, 분산안정도에 따라 HMDS의 흡착효율이 달라짐을 확인하였다.

• Applied Science and Convergence Technology
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• 제24권4호
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• pp.90-95
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• 2015

The adsorption behavior of tris (dimethylamino)-cyclopentadienyl-zirconium (Cp-Zr) precursor using an in-situ attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FT-IR) was studied. In attempt to improve the detection intensity of an adsorbed precursor, nanoparticles were uniformly distributed on the Ge ATR crystal surface employing the spray method. The absorption characteristics studies were carried out over the Ge crystal temperature in the range of $30{\sim}50^{\circ}C$. Upon increasing the temperature, a reduction of absorption was observed. Based on the peak intensities of ATR-FT-IR spectroscopy, higher-$ZrO_2$ absorption efficiency occurs when the nano-particles are utilized compared to pure Ge crystal.

• 패션비즈니스
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• 제12권6호
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• pp.23-33
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• 2008

The physico-chemical characteristics by bleaching treatments were assessed by several instrumental analyses such as surface morphology, chemical structural change, color change as well as tensile strength. The change of morphological characteristic was observed through scanning electron microscope(SEM). The observation of the fine structure on hair surface by SEM showed the bleached hair had much damaged to hair cuticle, and some of cuticle surface were worn away. To investigate the chemical structural changes in hair keratin, the cross-sections of hair samples were directly analysed using Fourier transform infrared microspectroscopy(FT-IRM). The results showed the cysteic acid S=O band intensity was distinctively increased by performing the bleaching treatment. The cleavage of cystine was appeared to proceed primarily through the sulfur-sulfur (-S-S-) fission whereby cysteic acid was formed as a principal oxidation products. The distribution of amide I band in hair keratin was determined by attenuated total reflectance(ATR) FT-IR mapping image. The results showed that the outer side of hair cortex was more damaged than the inner side of the hair cortex. Also, during chemical bleaching of the hair with alkaline peroxide, the hair was turned to reddish yellow due to the oxidative degradation of eumelanin. This means the eumelanin is more unstable than pheomelanin in chemical oxidation. With bleaching, the tensile strength was also reduced as a results of the chemical oxidation.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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• pp.156-157
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• 2006

To improve mean-life and reliability of power cable in this study, we have investigated chemical properties showing by changing the content of Carbon nanotube(CNT) that is semiconductive additives for underground power transmission. Specimens were made of sheet form with the three of existing resins and the five of specimens for measurement. Chemical properties of specimens was measured by FT-ATR (Fourier Transform Attenuated Total Reflectance). The condition of specimens was a solid sheet. We could observe functional group (C=O, carbonyl group) of specimens through FT-ATR. From these experimental result, the concentration of functional group (C=O) was high according to increasing the content of Carbon nanotube. We could know CNT/EEA was excellent more than other specimens from above experimental results.

• 농업과학연구
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• 제50권4호
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• pp.675-696
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• 2023

Terpenoids, also referred to as terpenes, are a large family of naturally occurring chemical compounds present in the essential oils extracted from medicinal plants. In this study, a nondestructive methodology was created by combining ATR-FT-IR (attenuated total reflectance-Fourier transform infrared), and Raman spectroscopy for the terpenoids assessment in medicinal plants essential oils from ten different geographical locations. Partial least squares regression (PLSR) and support vector regression (SVR) were used as machine learning methodologies. However, a deep learning based model called as one-dimensional convolutional neural network (1D CNN) were also developed for models comparison. With a correlation coefficient (R²) of 0.999 and a lowest RMSEP (root mean squared error of prediction) of 0.006% for the prediction datasets, the SVR model created for FT-IR spectral data outperformed both the PLSR and 1 D CNN models. On the other hand, for the classification of essential oils derived from plants collected from various geographical regions, the created SVM (support vector machine) classification model for Raman spectroscopic data obtained an overall classification accuracy of 0.997% which was superior than the FT-IR (0.986%) data. Based on the results we propose that FT-IR spectroscopy, when coupled with the SVR model, has a significant potential for the non-destructive identification of terpenoids in essential oils compared with destructive chemical analysis methods.

• 접착 및 계면
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• 제13권1호
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• pp.31-37
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• 2012

본 연구는 UV-LED 경화형 칼라코팅에 대한 경화특성에 관한 것으로, 특히 UV-LED 파장(365, 395, 405 nm), 불활성 기체, 증감제 및 Dual curing에 따른 경화성을 평가하였다. 광경화 과정과 코팅 도막의 Film-air (FA) interface와 Film-substrate (FS) interface에서 존재하는 미반응 아크릴레이트에 대한 평가는 Photo-DSC와 FT-IR/ATR을 이용하여 각각 조사하였다. Photo-DSC 측정 결과 발열량과 전환율은 405 nm UV-LED를 이용한 코팅 시스템의 경우가 395 및 365 nm UV-LED를 사용한 경우보다 높게 나타났다. UV-LED 경화형 시스템은 전반적으로 Film-substrate (FS) interface의 경화도가 높은 것으로 나타나 후막경화가 우수함을 알 수 있었으나, Film-air (FA) interface의 표면 경화도는 산소저해 현상으로 인해 매우 낮음을 FT-IR/ATR 결과를 통해 확인하였다. 이러한 낮은 표면 경화도는 불활성 기체인 질소를 사용하거나 Dual curing 방법을 도입함으로써 개선할 수 있었다.