• Bulletin of the Korean Chemical Society
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• 제25권1호
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• pp.79-84
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• 2004

The existing technological schemes for processing rhenium-containing raw materials involve the recovery of Re from solutions, which can be effectively achieved by anion exchange method. The application of anion exchange also allows to study rhenium state in aqueous solutions and to develop analytical control methods. The present work is focused on investigation of ion exchange equilibrium in the analytical system Re(VII)-HCl-$SnCl_2$-KSCN-anion exchanger by means of sorption-desorption method as well as by electron, IR- and diffuse reflection spectroscopy. It was shown that rhenium can be quantitatively recovered from this system. It is proposed to use the sorption-spectroscopic method for Re(VII) determination in aqueous solutions. The calibration curve is linear in the concentration range of 0.5-20.0 mg/L (sample volume is 25.0 mL) and the detection limit is 0.05 mg/L. The presence of Mo(VI), Cu(II), Fe(II, III), Ni(II), Zn(II) as well as $K^+,\;Na^+$ do not hinder the solid-phase determination of rhenium. Rhenium (VII) determination by diffuse reflection spectroscopy was carried out in model solutions as well as in samples of river-derived water and in solutions obtained after the dissolution of spent catalysts.

• Ocean Systems Engineering
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• 제13권1호
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• pp.43-55
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• 2023

In this study, the SCFs in tubular T-joints stiffened with external ring under axial load are studied and discussed. After verification of the present numerical model with the results of several available experimental tests, 156 FE models were generated and analyzed to parametrically evaluate the effect of the joint geometry and the ring geometry on the SCFs. Results indicated that the SCF of the stiffened T-joints at crown point can be down to 24% of the SCF of the corresponding un-reinforced joint at the same point. Also, the effect of the ring on the SCF at saddle point is more remarkable than the effect of the ring on the SCF at crown point. Moreover, against un-reinforced joints under axial load, the SCF at saddle point of the stiffened joint is smaller than the SCF at crown point of that stiffened joint. The ring results in the redistribution of stresses in the ring and metal substrate. Also, the effect of the ring thickness on the decrease of the SCFs is slight and can be ignored. In final step, the geometric parameters affecting the SCFs of the stiffened T-joints are analyzed by multiple nonlinear regression analyses. An accurate formula is proposed for determining the SCFs.

• Computers and Concrete
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• 제32권6호
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• pp.625-637
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• 2023

The application of ML approaches in determining the resisting capacity of fire damaged RC columns is introduced in this paper, on the basis of analysis data driven ML modeling. Considering the characteristics of the structural behavior of fire damaged RC columns, the representative five approaches of Kernel SVM, ANN, RF, XGB and LGBM are adopted and applied. Additional partial monotonic constraints are adopted in modelling, to ensure the monotone decrease of resisting capacity in RC column with fire exposure time. Furthermore, additional suggestions are also added to mitigate the heterogeneous composition of the training data. Since the use of ML approaches will significantly reduce the computation time in determining the resisting capacity of fire damaged RC columns, which requires many complex solution procedures from the heat transfer analysis to the rigorous nonlinear analyses and their repetition with time, the introduced ML approach can more effectively be used in large complex structures with many RC members. Because of the very small amount of experimental data, the training data are analytically determined from a heat transfer analysis and a subsequent nonlinear finite element (FE) analysis, and their accuracy was previously verified through a correlation study between the numerical results and experimental data. The results obtained from the application of ML approaches show that the resisting capacity of fire damaged RC columns can effectively be predicted by ML approaches.

• Structural Engineering and Mechanics
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• 제28권2호
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• pp.129-152
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• 2008

This paper considers the solution of the stochastic differential equations (SDEs) with random operator and/or random excitation using the spectral SFEM. The random system parameters (involved in the operator) and the random excitations are modeled as second order stochastic processes defined only by their means and covariance functions. All random fields dealt with in this paper are continuous and do not have known explicit forms dependent on the spatial dimension. This fact makes the usage of the finite element (FE) analysis be difficult. Relying on the spectral properties of the covariance function, the Karhunen-Loeve expansion is used to represent these processes to overcome this difficulty. Then, a spectral approximation for the stochastic response (solution) of the SDE is obtained based on the implementation of the concept of generalized inverse defined by the Neumann expansion. This leads to an explicit expression for the solution process as a multivariate polynomial functional of a set of uncorrelated random variables that enables us to compute the statistical moments of the solution vector. To check the validity of this method, two applications are introduced which are, randomly loaded simply supported reinforced concrete beam and reinforced concrete cantilever beam with random bending rigidity. Finally, a more general application, randomly loaded simply supported reinforced concrete beam with random bending rigidity, is presented to illustrate the method.

• 한국공간구조학회논문집
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• 제6권4호
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• pp.53-61
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• 2006

본 연구에서는 임의의 반복하중 작용시 강구조물에 발생하는 대변형 및 반복소성거동을 정확히 예측하기 위하여 유한변위이론과 반복소성이력모델을 적용한 3차원 탄소성 유한요소 해석기법을 개발하였다. 반복소성이력모델은 강재의 단조재하실험 및 반복하중실험 결과에 기초하여 정식화되었다. 개발된 해석기법의 정도는 Bilinear모델 및 미소변위이론을 적용한 해석기법 및 실험결과와 비교하여 검증하였다. 본 연구에서 개발한 유한변위이론과 반복소성이력모델을 적용한 3차원 유한요소 해석기법이 임의의 반복하중을 받는 원형강교각의 대변형 및 반복소성거동을 정확히 예측할 수 있음을 알 수 있었다.

• 한국전산구조공학회논문집
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• 제16권1호
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• pp.43-52
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• 2003

본 논문은 콘크리트 균열방향의 회전 및 철근의 항복에 따른 2차원 R/C 구조물의 극한거동 덴 한계상태설계에 관한 연구를 다룬 것으로, 유한요소모델에 적용하여 비선형 해석 및 한계상태설계가 가능한 수치 해석 및 설계 알고리즘을 소개하였다. 철근의 설계를 위하여, 각 유한요소의 극한거동에 기초한 한계상태설계방정식이 유한요소 알고리즘에 도입되었다. 한편, 하중에 따른 콘크리트 균열방향의 회전 및 철근의 항복을 고려한 2차원 R/C 평면요소의 단순화된 실용적 비선형 응력-변형률 거동의 구성관계모델을 제시하여 비선형 유한요소해석 알고리즘을 구성하였다 제시된 해석 모델을 R/C 전단벽의 실험모델과 비교하여 검증하도록 하였으며, R/C 전단벽에 대한 설계 예를 통하여, 각각의 유한요소에서 얻어진 설계 철근비를 한계상태설계방정식으로부터 산정하였다.

• 한국광물학회지
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• 제4권2호
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• pp.69-89
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• 1991

The anorthositic rocks and the many other plutons which are of different varieties and age were distributed in the northern extremity of the distributed areas of H-S anorthositic rocks. The purpose of this study was to find plutons which had comagmatic relationships, and to make clear the magmatic process of anorthositic magma. The plutons were classified, and the petrological and the geochemical characteristics of the plutons were compared and researched in this study. And, because, like anorthosite, the rocks which intrude in the deep crust accompany assimilation, an AFC model calculation was performed to make the differentiation process of the anorthositic rocks clear. The plutons in this area were classified into three groups, and the three groups were composed of the Precambrian anorthositic rocks and related rocks, the Jurassic gabbro, and the plutons of undnown age. The anorthositic magma was differentiated from the anorthositic rocks through the tonalite to the alkali-feldspar granite, and it was differentiated under K, Mg, Fe free/lack condition. It was found from the result of AFC model that the anorthositic rocks were differentiated by fractional crystallization, but they were assimilated with wall-rocks, and the assimilation was performed at the rate of r$\leq$0.1. The plutons which intruded the anorthositic rocks subsequently consisted of the gabbro, the megacrystic granite, the fine-grained granite, and the gneissose granite. But they were formed by the repeated intrusion of magma, which may, or may not, be of the same origin. According to the result of the RCF model, these plutons were differentiated by simple fractional crystallization, and they were assimilated relatively less than the anorthositic rocks.

• 비파괴검사학회지
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• 제24권1호
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• pp.8-14
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• 2004

증기발생기 세관의 결함을 정량적으로 평가하기 위해서 신경회로망과 전자기 유한요소 모델링을 사용한 모델링기반 와전류 신호해석기법을 개발해왔다. 본 연구에서는 개발된 신호해석 기법을 검증하기 위해서 실제로 얻어진 와전류 신호를 해석하였다. 유한요소 모델링을 이용하여 생성된 모사 와전류 신호로 데이터베이스를 구성하였으며, 이들을 사용하여 PNN 분류기와 BPNN 크기 산정 신경회로망을 학습시켰다. 축대칭 가공 결함에서 실험 와전류 신호를 획득하였으며, 이 신호를 신경회로망에 입력시켜서 신호를 해석하였다. 신호 해석 결과는 매우 우수하여, 모델링을 이용하여 개발한 신호해석기법은 실제 와전류 신호 해석에 활용할 수 있음을 알았다.

• Structural Engineering and Mechanics
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• 제81권5호
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• pp.617-631
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• 2022

In this paper the viscoelastic responses of four experimental steel-concrete composite beams subjected to highly variable environmental conditions are investigated by means of a finite element (FE) model. Concrete specimens submitted to stepped stress changes are also evaluated to validate the current formulations. Here, two well-known approaches commonly used to solve the viscoelastic constitutive relationship for concrete are employed. The first approach directly solves the integral-type form of the constitutive equation at the macroscopic level, in which aging is included by updating material properties. The second approach is postulated from a rate-type law based on an age-independent Generalized Kelvin rheological model together with Solidification Theory, using a micromechanical based approach. Thus, conceptually both approaches include concrete hardening in two different manners. The aim of this work is to compare and analyze the numerical prediction in terms of long-term deflections of the studied specimens according to both approaches. To accomplish this goal, the performance of several well-known model codes for concrete creep and shrinkage such as ACI 209, CEB-MC90, CEB-MC99, B3, GL 2000 and FIB-2010 are evaluated by means of statistical bias indicators. It is shown that both approaches with minor differences acceptably match the long-term experimental deflection and are able to capture complex oscillatory responses due to variable temperature and relative humidity. Nevertheless, the use of an age-independent scheme as proposed by Solidification Theory may be computationally more advantageous.

• 대한의용생체공학회:의공학회지
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• 제31권1호
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• pp.56-66
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• 2010

The various total replacement artificial discs have developed because spinal fusion has shown a lesser mobility of an operated segment and an accelerated degeneration at adjacent discs. But almost artificial discs have not yet been reached on the substitute surgery of fusion because many problems such as those clinical success rates were not more than them of fusion have not solved. In this paper, vertically inserted assemble-screw fixture in vertebrae was proposed to improve the fixed capability of artificial disc. And also, to evaluate the design suitability of newly designed screw-type, including fixtures of commercial discs such as wedge and plate type, the 1/4 finite element model with a vertebra and various implanted fixtures were generated, and next, 3 bending motions such as flexion, bending and twisting under the moment of 10Nm and compression under the force of 1000N were considered, respectively and finally, FE analyses were performed. Results of three fixture types were compared, such as Range of Motion and maximal stress, and so on. For ROM, the screw type was average 58% less than the wedge type and was average 42% less than the plate type under all loading conditions. For average stress ratio at closer nodes between vertebra and each fixture, the wedge type was the lowest as minimum 0.02 in twisting, screw types were the highest as maximum 0.28 in compression. As the results of using cement material, it was predicted that the instability problem of the wedge type was better solved. The screw type which could be increased by implanting depth according to the number of assembling mid screws, showed that the decreased tendency of ROMs and maximal cancellous bone stresses. In further study, controlling the number of assembling screws that was suitable for a patient's bone quality, development of surgical tools and keeping on design supplementations, which will be able to develop the competitive artificial disc.