• Structural Engineering and Mechanics
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• v.82 no.2
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• pp.133-149
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• 2022

This study investigates the resistance of sustainable ultra-high performance concrete (UHPC) on steel reinforcement corrosion. For enhancing the sustainability of UHPC, concrete mixes were prepared with ordinary Portland cement main binder, and mixes with moderate to high percentages of blast furnace cement (CEM III), fly ash (FA), and slag cement as partial replacements of the full quantity of the used cement. Linear polarization resistance technique was employed to estimate the electrochemical behavior of the concrete specimens. Results showed that the compressive strength and the resistance of steel to corrosion in marine environments can be enhanced by improving the sustainability of UHPC through incorporation of CEM III, FA, and slag cement. FA replacement of up to 50% with the addition of 15% SF content produced better compressive strength and steel corrosion resistance than slag cement whether with the use of ordinary Portland cement or blast furnace cement as the main binder.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.5
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• pp.75-84
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• 2016

This paper presents an investigation of the mechanical properties on non-sintered cement pastes immersed in sea waters at three different temperatures. The non-sintered cement pastes were synthesized using blended binder(Class F fly ash; FA and ground granulated blast furnace slag; GGBFS) and alkali activator(sodium hydroxide and sodium silicate). Binders were prepared by mixing the FA and GGBFS in different blend weight ratios of 6:4, 7:3 and 8:2. The alkali activators were used 5wt% of blended binder, respectively. Calcium carbonate was used as an chemical additive. The compressive strength, bulk density and absorption of alkali-activated FA-GGBFS blends pastes were measured at 3 and 28 days after immersed in sea waters at three different temperatures($5^{\circ}C$, $15^{\circ}C$ and $25^{\circ}C$). The XRD and SEM tests of the pastes were conducted at 28 days. Water-soluble chloride(free chloride) and acid-soluble chloride(total chloride) contents in the pastes were also measured after 28 days immersion in sea water. The experimental results showed that increasing the content of FA in alkali-activated FA-GGBFS blends pastes immersed in sea water increases the absorption, water-soluble chloride content and acid-soluble chloride content, and reduces the compressive strength and bulk density. And it was found that there was a variation of strength change for the alkali-activated FA-GGBFS blends pastes immersed in sea waters at three different temperatures that depends on the blending ratio of FA and GGBFS.

• Journal of the Korea Concrete Institute
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• v.23 no.1
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• pp.99-107
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• 2011

This study is to performed to find the optimum mix proportion of the high strength and self compacting concrete for the above-ground LNG storage tank construction and field application. If LNG storage tank wall thicknesscan be reduced, the construction cost and quality can be improved by using self-compacting high strength concrete with compressive strength 60~80 MPa. For this purpose, low heat cement (Type IV) and class F fly ash are used in concrete mix to control hydration heat, flowability, and viscosity. Mix design variables of unit water, fly ash replacement ratio, water-binder ratio, and fine aggregate ratio are selected and tested for material properties and manufacturing cost of the concrete. Also, fly ash replacement ratio is considered using confined water ratio test. The test results showed that the optimum mix proportion of the self-compacting high strength concrete characteristics are as follows. 1) In case of the concrete with specified compressive strength of 60 MPa, the optimum mix proportion is fly ash replacement ratio of 20% and water- binder ratio of 27~30%. 2) In case of the concrete with the strength of 80 MPa, the optimum mix proportion is fly ash replacement ratio of 10% and water-binder ratio 25%. But unit water and fine aggregate ratio are 165 $kg/m^3$ and $51{\pm}2%$, respectively, regardless of the traget concrete compressive strength range. Also, test results showed that concrete manufacturing cost of 60 MPa and 80 MPa concrete require additional costs of 14~22% and 33%, respectively, compared to the manufacturing cost of 40 MPa concrete. Therefore, application of the self-compacting high strength concrete has proven to be economical in the perspective of the material cost, quality control, and site management.

• Journal of the Korea Concrete Institute
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• v.18 no.6 s.96
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• pp.759-767
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• 2006

This paper presents a method to estimate the setting time of concrete using super retarding agent(SRA) and fly ash(FA) under various curing temperature conditions by applying maturity based on equivalent age. To estimate setting time, the equivalent age using apparent activation energy($E_a$) was applied. Increasing SRA content and decreasing curing temperature leads to retard initial and final set markedly. $E_a$ at the initial set and final set obtained by Arrhenius function showed differences in response to mixture type. It is estimated to be from $24{\sim}35KJ/mol$ in all mixtures, which is smaller than that of conventional mixture ranging from $30{\sim}50KJ/mol$. Based on the application of $E_a$ to Freisleben-Hansen and Pederson's equivalent age function, equivalent age is nearly constant, regardless of curing temperature and SRA contents. This implies that the concept of maturity is applicable in estimating the setting time of concrete containing SRA. A high correlation between estimated setting time and measured setting time is observed. Multi-regression model to determine appropriate dosage of SRA reflecting FA contents and equivalent age was provided. Thus, the setting time estimation method studied herein can be applicable to the concrete containing SRA and FA in construction fields.

• Korean Journal of Environmental Agriculture
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• v.38 no.1
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• pp.10-16
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• 2019

BACKGROUND: Coal ashes generated from thermal power plants have been known as beneficial materials for agricultural use because of their nutrient elements. However, there is limitation to recycle them due to their alkalinity. The objective of this study was to evaluate the effectiveness or safety of the coal ashes for their heavy metals on agricultural recycling when adjusted to pH of 5 with sulfuric acid. METHODS AND RESULTS: Concentration of hydrogen which is needed to adjust pH of coal ash was estimated by using a buffering curve and then the amount of sulfuric acid was changed by the estimation before incubation. Each of fly ash (FA) and bottom ash (BA) was collected from both thermal plants of Yeongdong (YD) and Yeongheung (YH). The pH values of coal ashes increased to 4.76 (from 4.34) after incubation with sulfuric acid for 56 days, closer to the targeted pH. Coal ashes also increased the contents of available phosphorus by 2-fold (165 mg/kg) and 11-fold (1,137 mg/kg) for YDBA and YDFA, respectively, compared to the control. CONCLUSION: The utilization of coal ash with its acidity regulation would be very beneficial to agriculture sector and further suggest promising environmental safety against heavy metals.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.226-227
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• 2017

Basic lot tests via textile and visual examinations are conducted on FA carried into in-service RMCs. The system of evaluating quality by taking samples from each lot and examining them, or evaluating quality based on the score reports submitted by the deliverer during in-service training have on some instances been called into doubt as to their reliability in evaluating the quality of FA. Therefore this study sought to measure the density value of FA that is actually delivered to RMC companies according to the Hydrometer method and analyze its correlation to its test scores, to in turn analyze the reliability of the test reports and the characteristics of the quality of FA. The results led to the conclusion that the fineness and density marked on the score reports were problematic, and therefore accurate experiments and adjustment of significant digits on the test report are necessary.

• Computers and Concrete
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• v.24 no.5
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• pp.453-458
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• 2019

Today, concrete remains the most important, durable, and reliable material that has been used in the construction sector, making it the most commonly used material after water. However, cement continues to exert many negative effects on the environment, including the production of carbon dioxide (CO2), which pollutes the atmosphere. Cement production is costly, and it also consumes energy and natural non- renewable resources, which are critical for sustainability. These factors represent the motivation for researchers to examine the various alternatives that can reduce the effects on the environment, natural resources, and energy consumption and enhance the mechanical properties of concrete. Geopolymer is one alternative that has been investigated; this can be produced using aluminosilicate materials such as low calcium (class F) FA, Ultra-Fine GGBS, and high calcium FA (class C, which are available worldwide as industrial, agricultural byproducts.). It has a high percentage of silica and alumina, which react with alkaline solution (activators). Aluminosilicate gel, which forms as a result of this reaction, is an effective binding material for the concrete. This paper presents an up-to-date review regarding the important engineering properties of geopolymer formed by FA and slag binders; the findings demonstrate that this type of geopolymer could be an adequate alternative to ordinary Portland cement (OPC). Due to the significant positive mechanical properties of slag-FA geopolymer cements and their positive effects on the environment, it represents a material that could potentially be used in the construction industry.

• Journal of the Korea Concrete Institute
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• v.16 no.6 s.84
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• pp.777-783
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• 2004

In this study, for improving of concrete properties, those are used ground granulated blast slag(GGBS) and fly ash(FA). There are some advantage to add the GGBS and FA in plain concrete. The objective of this study is to find the characteristics of fresh and hardened antiwashout underwater concrete which is followed by blended ratio of GGBS and FA. Experimental parameters were chosen that W/C was 50%, S/a was 40% and as the blended ratio of GGBS was set at 0, 10, 20, 30, 40, 50, 60% and FA was set at 0, 10, 15, 20, 25, 30, 35% in order to prove the properties of antiwashout underwater concrete can be changed by blended ratio of GGBS md FA. It was measured pH, suspension and slump flow of fresh antiwashout underwater concrete and compressive strength of hardened antiwashout underwater concrete in age of 7 days, 28 days and 56 days. The experimental results of fresh concrete show that pH, suspension and slump flow were all satisfied with KSCE (Korea Society of Civil Engineering) standard value and mix design standard value. To synthetically consider, the optimum blended ratio is about 30% of GGBS and FA.

• Journal of the Korea Concrete Institute
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• v.23 no.3
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• pp.311-320
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• 2011

Fly ash (FA), byproduct from power plant has been actively used as mineral admixture for concrete. However, since bottom ash (BA) is usually used for land reclaim or subbase material, more active reuse plan is needed. Pond ash (PA) obtained from reclaimed land is mixed with both FA and BA. In this study, 6 PA from different domestic power plant are prepared and 5 different replacement ratios (10%, 20%, 30%, 50%, and 70%) for fine aggregate substitutes are considered to evaluate engineering properties of PA as fine aggregate and durability performance of PA concrete. Tests for fine aggregate of PA for fineness modulus, density and absorption, soundness, chloride and toxicity content, and alkali aggregate reaction are performed. For PA concrete, durability tests for compressive strength, drying shrinkage, chloride penetration/diffusion, accelerated carbonation, and freezing/thawing are performed. Also, basic tests for fresh concrete like slump and air content are performed. Although PA has lower density and higher absorption, its potential as a replacement material for fine aggregate is promising. PA concrete shows a reasonable durability performance with higher strength with higher replacement ratio. Finally, best PA among 6 samples is selected through quantitative classification, and limitation of PA concrete application is understood based on the test results. Various tests for engineering properties of PA and PA concrete are discussed in this paper to evaluate its application to concrete structure.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.457-460
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• 2003

This paper discusses laboratory evaluations to assess the physical properties of antiwashout underwater concrete (AWC) containing pozzolanic materials such as fly ash (FA), blast furnace slag (SG) and metakaolin(MK). For the experiments, pH value, suspended solids, slump flow, efflux time and compressive strength were tested. According to the results from compressive strength test, MK10 showed the very high compressive strength characteristic during the entire curing days, but the rate of strength development was decreased as time goes by.