• 제목/요약/키워드: F-ratio

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Influence of Initial Molar Ratios on the Performance of Low Molar Ratio Urea-Formaldehyde Resin Adhesives

  • LUBIS, Muhammad Adly Rahandi;PARK, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • 제48권2호
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    • pp.136-153
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    • 2020
  • In this paper, the influence of initial formaldehyde/urea (F/U) molar ratios on the performance of low molar ratio (1.0) urea-formaldehyde (UF) resin adhesives has been investigated. Two initial F/U molar ratios, i.e., the first and second initial molar ratios were used for the alkaline addition reaction. Three levels of the first initial F/U molar ratios (2.0, 3.0, and 4.0) and two levels of the second initial molar ratios (2.0 and 1.7) were employed to prepare a total of six UF resins with an identical final molar ratio (1.0). The basis properties, functional groups, molecular weight, crystallinity, and thermal curing properties of the UF resins were characterized in detail. Higher levels (3.0 and 4.0) of the first initial F/U molar ratio provided the UF resins with better properties (non-volatile solids content, viscosity, gelation time, pH, and specific gravity) than those of the resins prepared with the conventional level F/U molar ratio of 2.0. Statistical analysis suggested that combining the first and second initial molar ratio of 4.0 with 1.7 would result in UF resins with greater adhesion strength and lower formaldehyde emission than those of the resins prepared with other molar ratios. The results showed that higher levels of the first initial molar ratio resulted in a more branched structure, as indicated by GPC, FTIR, DSC, XRD, and greater adhesion strength than those of the other UF resins with an identical final molar ratio of 1.0.

Development of Modified Flexibility Ratio - Racking Ratio Relationship of Box Tunnels Subjected to Earthquake Loading Considering Rocking

  • Duhee Park;Van-Quang Nguyen;Gyuphil Lee;Youngsuk Lee
    • 한국지반환경공학회 논문집
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    • 제24권2호
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    • pp.13-24
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    • 2023
  • Tunnels may undergo a larger or a smaller response compared with the free-field soil. In the pseudo-static procedure, the response of the tunnel is most often characterized by a curve that relates the racking ratio (R) with the flexibility ratio (F), where R represents the ratio of the tunnel response with respect to the free-field vibration and F is the relative stiffness of the tunnel and the surrounding soil. A set of analytical and empirical curves that do not account for the depth and the aspect ratio of the tunnel are typically used in practice. In this study, a series of dynamic analyses are conducted to develop a set of F-Rm relations for use in a frame analysis method. Rm is defined as an adjusted R where the rocking mode of deformation is removed and only the racking deformation is extracted. The numerical model is validated against centrifuge test recordings. The influence of aspect ratio, buried depth of tunnel on results is investigated. The results show that Rm increases with the increase of the buried depth and the aspect ratio. The widely used F-R relations are highlighted to be different compared with the obtained results in this study. Therefore, the updated F-Rm relations with proposed equations are recommended to be used in practice design. The rocking response decreases with either the decrease of the difference of stiffness between surrounding soil and tunnel or the larger aspect ratio of the tunnel section.

MEASUREMENT OF $CO_2$ CONCENTRATION AND A/F RATIO USING FAST NDIR ANALYZER ON TRANSIENT CONDITION OF SI ENGINE

  • Lee, S.W.;Kim, W.S.;Lee, J.H.;Park, J.I.;Yoo, J.S.
    • International Journal of Automotive Technology
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    • 제7권4호
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    • pp.385-390
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    • 2006
  • A fast response $CO_2$ analyzer has been developed to study transient characteristics on an SI engine. The analyzer has the delay time of 4.5 ms and time constant of 2.8 ms, which is fast enough to measure $CO_2$ concentration on a transient condition. Wide range of A/F(Air/Fuel) ratio can be estimated using the analyzer with an additional switch type oxygen sensor. The results of measurement of $CO_2$ concentration and A/F ratio on a transient condition including rapid acceleration/deceleration and EGR(Ehxaust Gas Recirculation) on/off are presented and compared with a commercial exhaust gas analyzer and UEGO(Universial Exhaust Gas Oxyzen) sensor.

P/S 비율과 n-6/n-3 비율을 달리한 식이지방이 흰쥐의 Thromboxane B2 와 6-Keto prostaglandin F1$\alpha$ 합성에 미치는 영향 연구 (Effects of n-6/n-3 and P/S Ratio of Dietary Lipid on Thromboxane B2 and 6-Keto prostaglandin F1$\alpha$ Production in Rat)

  • 김우경
    • Journal of Nutrition and Health
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    • 제27권6호
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    • pp.574-582
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    • 1994
  • The effects of age and dietary fatty acid composition on prostagladin production was investigated in Sprague-Dawley strain male rats. Animals weighing 88.6$\pm$2.2g were fed 10% dietary fat(W/W, 20% of total energy). The P/S ratios of dietary lipid were three levels(0.5, 1, 2) and there were three different levels of n-6/n-3 fatty acid ratio(2, 4, 8) in each P/S ratio. The experimental period were 1 month and 12 months, respectively. The results of this study were as follows. As the age of rats increased, the plasma thromboxane B2 production increased, but aorta 6-keto prostaglandin F1$\alpha$ decreased. When a higher amount of n-3 fatty acid was fed in each P/S ratio, the relative percentage of linolenic acid and EPA in platelet increased.

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가잠의 이면교잡에 의한 유용 형질의 유전분석 (Genetic Analysis on Quantitative Characters of Silkworm (Bombyx mori.) by Diallel Crosses)

  • 정원복;이상풍
    • 한국잠사곤충학회지
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    • 제31권1호
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    • pp.25-36
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    • 1989
  • 누에 품종 육성을 위한 기초자료를 얻기 위해 7개 품종을 이면교잡하여 얻은 F1, F2세대에 대한 유전자의 분포상태와 우성정도, 분산성분과 성분비 등을 분석한 결과를 요약하면 다음과 같다. Vr-Wr graph는 F1세대에서 견장의 자, 단견중의 자웅, 견층 연감율의 자웅, 견사량이 모두 초우성이었다. 또 5령경과와 견층중, 견층비율의 각 자웅, 견사장 등은 불완전 우성으로 표현되었다. F2세대는 5령경과, 전령경과와 견장, 견폭, 단견중, 견층중, 견사량은 모두 불완전 우성으로 나타났다. 유전 분산성분에서 F1세대의 5령경과와 견폭, 견층중, 견층비율, Fibroin량의 각 자웅은 유전지의 상가적 효과가 우성 효과보다 크게 평가되었다. F2세대의 견촉, 견층중, 견층비율, fibroin량의 각 자웅도 상가적 효과가 우성 효과보다 크게 표현되었다.

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13C-NMR Spectroscopy of Urea-Formaldehyde Resin Adhesives with Different Formaldehyde/Urea Mole Ratios

  • Park, Byung-Dae;Lee, Sang M.;Park, Jong-Young
    • Journal of the Korean Wood Science and Technology
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    • 제36권2호
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    • pp.63-72
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    • 2008
  • As a part of abating formaldehyde emission of urea-formaldehyde (UF) resin adhesive, this study was conducted to investigate chemical structures of UF resin adhesives with different formaldehyde/urea (F/U) mole ratios, using carbon-13 nuclear magnetic resonance ($^{13}C$-NMR) spectroscopy. UF resin adhesives were synthesized at four different F/U mole ratios such as 1.6, 1.4, 1.2, and 1.0 for the analysis. The analysis $^{13}C$-NMR spectroscopy showed that UF resin adhesives with higher F/U mole ratios (i.e., 1.6 and 1.4) had two distinctive peaks, indicating the presence of dimethylene ether linkages and methylene glycols, a dissolved form of free formaldehyde. But, these peaks were not detected at the UF resins with lower F/U mole ratios (i.e., 1.2 and 1.0). These chemical structures present at the UF resins with higher F/U mole ratios indicated that UF resin adhesive with higher F/U mole ratio had a greater contribution to the formaldehyde emission than that of lower F/U mole ratio. Uronic species were detected for all UF resins regardless of F/U mole ratios.

듀얼­밴드 정삼각형 마이크로스트립 안테나 설계에 관한 연구 (A Study on the Design of Dual­Band Equilateral­Triangular Microstrip Antennas)

  • 문정군;이종철;황호순;이문수
    • 한국정보통신학회논문지
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    • 제7권8호
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    • pp.1604-1611
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    • 2003
  • 듀얼­밴드 마이크로스트립 안테나를 설계하기 위해, 정삼각형 패치에 두 쌍의 슬릿(slit)을 두며, 그중 한 쌍은 패치의 양 빗변에 두고 다른 한 쌍은 밑변에 둔다. 두 공진주파수 비는 패치의 밑변에 둔 두 슬릿의 위치와 길이에 따라 변화시킬 수 있다 Ensemble 5.0으로 설계된 안테나의 두 공진주파수 비는 $1.66 ({f_10}=1.928GHz, {f_20}=3.2GHz)$인데 반해, 측정치는 2.04 $({f_10}=1.6806 GHz, {f_20}=3.435 GHz)$이며, 오차의 원인은 제작 및 급전위치 오차와 유전율 분산 효과를 들 수 있다.

게이지 R&R 연구에서 근사 F검정과 EMS를 이용한 측정 정밀도의 평가 (Evaluation of Measurement Precisions Using Approximate F Tests and EMS in the Gauge R&R Studies)

  • 최성운
    • 대한안전경영과학회지
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    • 제11권3호
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    • pp.209-216
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    • 2009
  • A development in method of evaluating the measurement precisions using approximate F tests and variance components from expected mean square (EMS) is investigated. The research proposes three-factor mixed measurement models with the fixed and random factors. Unrestricted and unconstrained design work was rarely studied, while restricted and constrained designs have been significantly discussed. The unrestricted and unconstrained designs assume to be an independence of interaction. The proposed evaluation method about the measurement precisions can be extended to four-factor random measurement model or mixed measurement model. The study also presents the three evaluation indexes of precisions such as R&RTR (Reproducibility & Repeatability-To-Total Precision Ratio), PTR (Precision-To-Tolerance Ratio), and SNR (Signal-To-Noise Ratio). Numerical examples are proposed to evaluate the approximate F tests with Satterthwaite degrees of freedom and three indexes using the measurement precisions from EMS.

Methane Production Potential of Food Waste and Food Waste Mixture with Swine Manure in Anaerobic Digestion

  • Islam, Mohammad Nazrul;Park, Keum-Joo;Yoon, Hyung-Sun
    • Journal of Biosystems Engineering
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    • 제37권2호
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    • pp.100-105
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    • 2012
  • Purpose: Methane production potential in aerobic digestion was assessed according to feed to inoculum (F/I) ratio for food waste only, and mixing ratio of two materials for food waste and swine manure to give a basic data for the design of anaerobic digestion system. Methods: Anaerbic digestion test was performed using a lab scale batch reactor at $35^{\circ}C$ for six different feed to inoculum (F/I) ratios (0.50, 0.72, 1.14, 1.50, 2.14 and 3.41), three food waste to swine manure ratios (100:0, 60:40 and 40:60) with two different loading concentrations (10g VS/L and 30g VS/L). Results: For food waste only, the highest biogas yield of 1008 mL/gVS was obtained at 0.50 of F/I. For the co-digestion of food waste and swine manure mixture, the highest biogas yield of 1148 mL/gVS was obtained at a mixing ratio of 40:60 with loading concentration of 10g VS/L. Conclusions: F/I ratio for the food waste only, mixing ratio of food waste and swine manure, and co-substrate loading rate affected the biogas production rate. For the low loading rate, there was not so much difference according to the mixing ratio of food waste and swine manure, but for the high loading rate higher biogas yield was acquired for the co-digestion of food waste and swine manure than for the food waste alone (mixing ratio, 100:0).

PSN-PMN-PZT 세라믹스의 Zr/Ti 비에 따른 전기적 특성과 공진주파수의 온도안정성 (Electrical Properties and Temperature Stability of resonant Frequency with Zr/Ti ratio in PSN-PMN-PZT Ceramics)

  • 류주현;윤광희;민석규;이명수;서성재
    • 한국전기전자재료학회논문지
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    • 제13권8호
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    • pp.675-680
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    • 2000
  • In this study the temperature coefficient of resonant frequency(TC $F_{r}$) dielectric and piezoelectric properties of Pb[(S $b_{1}$2//N $b_{1}$2/)$_{0.065}$)-(Z $r_{x}$, $Ti_{1-x}$ )$_{0.90}$] $O_3$ceramics were investigated with Zr/Ti ratio. The compositions near the morphotropic phase boundary (MPB) appeared when Zr/Ti ratio was 49.5/50.5 The dielectric constant and electromechanical coupling factor( $k_{p}$) also showed the highest values of 1,257, 0.653 respectively when the Zr/Ti ratio was 49.5/50.5 Moreover the mechanical quality factor( $Q_{m}$) showed th lowest value of 713 when the Zr/Ti ratio. The temperature coefficient of resonant frequency(TC $F_{r}$) abruptly change at the morphotropic phase boundary(MPB) which existed between the rhombohedral phase with highly negative TC $F_{r}$ of -106ppm/$^{\circ}C$ and the tetragonal phase with highly positive TC $F_{r}$ of +64pp $m^{\circ}C$ as Zr/Ti ratio varied from 50/50 to 49.5/50.5.50.5..50.5.

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