• Journal of Photoscience
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• v.12 no.2
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• pp.101-107
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• 2005

Infrared multiphoton dissociation of $CHCl_2F$ was studied using $CO_2$ laser excitation. Three products, $C_2Cl_2F_2$, $C_2ClF_3$, and $C_2HClF_2$, were identified by the analysis of the gas mixture from the photoreaction of $CHCl_2F$. The dependence of the reaction probability on added Ar gas pressure and excitation laser pulse energy was investigated. At low pressure (< 10 torr), the reaction probability increased as Ar pressure increased due to the rotational hole-filling effect, while it diminished with the increase of Ar pressure at high pressure (> > 20 torr) due to the collisional deactivation. The ratio of two products $(C_2ClF_3/C_2Cl_2F_2)$ decreased at low pressure (< 10 torr) and increased at high pressure (> 20 torr) with the increase of Ar pressure. The log-log plot of the reaction probability vs. laser pulse energy (${\\phi}$) was found to have a linear relationship, and its slope decreased as the added Ar pressure was increased. The reaction mechanisms for product formation have been suggested and validated by experimental evidences and considering the energetics. Fluorine-chlorine exchange reaction in the intermediate complex has been suggested to explain the formation of $C_2ClF_3$.

• Proceedings of the SAREK Conference
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• 2006.06a
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• pp.1255-1260
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• 2006

This present study analyzed temperature depreciation ratio of window inside surface by KS F 2295 'Procedure for determining fenestration product condensation resistance values'. it estimated window indoor surface condensation due to variable environmental condition. Performance of condensation resistance by using temperature depreciation ratio until applied Low-e and Ar glazing improved about 45% from 24 mm clear. Temperature depreciation ratio by KS F 2295 considers analytic index of window condensation due to variable boundary condition.

• Aerospace Engineering and Technology
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• v.3 no.2
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• pp.81-90
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• 2004

This paper describes the results of combustion performance test of fuel-rich gas generator(GG) using LOx and kerosene as propellant at off-design conditions. The chamber pressure is thought to be a function of O/F ratio and total propellant mass flow rate. The test shows that the spatial temperature deviation at the exit of gas generator remains within 7.5K and that the average gas temperature at the exit is a function of propellant O/F ratio. The results of firing test of gas generator at off-design conditions, especially the relation between gas temperature and O/F ratio, can provide useful data for the design of future gas generator and for the development of low-O/F ratio reaction analysis code.

• Journal of Sericultural and Entomological Science
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• v.18 no.2
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• pp.101-105
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• 1976

The study was carried out to investigate the variations in the fibroin hydrolysis of leading silkworm varieties in Korea, and the relationship between the fibroin hydrolysis of the silkworm varieties with some characteristics and silk morphological property. The results obtained are summarized as follows: 1) The fibroin hydrolyzing ratio of both parent silkworm cocoons was reduced in the F$_1$hybrids. 2) A positive corelation (r=＋0.86) was approved between the mid-parent value and the F$_1$hybrid in the fibroin hydrolysis. 3) It was disclosed that the fibroin hydrolyzing ratio of Jam 103${\times}$Jam 104 was the lowest among the leading silkworm F$_1$hybrids. 4) The fibroin hydrolysis was affected by the silk morphological property, showing a positive corelation between the size of cocoon filament and the fibroin hydrolyzing ratio. 5) It was thought that the determination of the fibroin hydrolyzing ratio was useful as a marker for the selection of its related economical characters in silkworm breeding, because the fibroin hydrolysis of parents silkworm cocoons was heritable in their F$_1$hybrids.

• Journal of the Korean Society of Propulsion Engineers
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• v.20 no.6
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• pp.54-60
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• 2016

Multi-port HDPE and Paraffin firing tests are conducted for hybrid gas generator application of a ducted rocket in the low oxidizer mass flux range. A fuel rich gas of O/F ratio from 0.3 to 0.8, a typical O/F operating range of a ducted rocket gas generator, have been achieved with paraffin fuel implying that the hybrid system can be a potential candidate. It was also found that an almost constant O/F ratio regime exists under $35kg/m^2s$ of the oxidizer mass flux, opening a possibility for the paraffin fuel toward the VFDR gas generator application.

• Journal of the Korea institute for structural maintenance and inspection
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• v.10 no.6
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• pp.105-113
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• 2006

This paper presents the results of an experimental investigation carried out to evaluate the mechanical properties of concrete mixtures in which fine(S) and coarse(G) aggregate was fully replaced with fly ash(FA). And flowability reduction problem in a large amount of fly ash concrete settled addition water($W_f$) in concrete mixture. In the test, water-cement ratio($W_c/C$) was 0.35, 0.45, and water-fly ash ratio($W_f/FA$) was 0.35, 0.45. The fly ash replacement is two different method of P and Q. The P method is mix property that the fly ash and addition water($W_f$) weight is equal to the aggregate weight [ $FA+W_f$ = G (or S)]. The Q method is mix property that fly ash is equal to aggregate weight, and added addition water($W_f$) [$FA+W_f$ > G (or S)]. Test were performed for properties of fresh concrete and compressive strength were determined at 3, 7, 28 and 91 days. The result, compressive strength was improvement that $W_c/C=0.35$, $W_f/FA=0.35$ and fine aggregate replacement in P method series than others. The flowability at Q method was improvement result than P method, but compressive strength was not. Test results indicate significant improvement in the strength properties and flowability of plain concrete by the inclusion of fly ash as fully replacement of fine and coarse aggregate, and can be effectively the fly ash replacement method.

• International Journal of Precision Engineering and Manufacturing
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• v.3 no.2
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• pp.78-86
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• 2002

In general, X-ray diffraction method detects the changes of crystal lattice under material surface using the angle of diffraction 2$\theta$. This technique which deals with in the presented paper can be applied to a behavior on the slipped band or the micro crack cause to material degradation. The relation between half-value breadth and cycle numbers shows three stages, which consist of rapid decrease in the initial cycle, slight decrease in the middle cycle, and then rapid decrease in the final cycle. The ratio of half-value breadth has a constant value on B/B$\_$0/ - N diagram under the loading condition except early part of fatigue life. The ratio of half-value breadth B/B$\_$0/ - log N$\_$f/ with respect to number of cycle to failure N$\_$f/ has linear behavior on B/B$\_$0/ - log N$\_$f/ diagram. Therefore, the evaluation of fatigue life by the average gradient has much less mean error than the estimation of fatigue life by log B/B$\_$0/ - log N/N$\_$f/ relation.

• Macromolecular Research
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• v.17 no.10
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• pp.797-806
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• 2009

The mechanical and thermal behaviors of polyamide-6/clay nanocomposites were studied using the continuum-based, micromechanical models such as Mori-Tanaka, Halpin-Tsai and shear lag. Mechanic-based model prediction provides a better understanding regarding the dependence of the nanocomposites' reinforcement efficiency on conventional filler structural parameters such as filler aspect ratio ($\alpha$), filler orientation (S), filler weight fraction (${\Psi}_f$), and filler/matrix stiffness ratio ($E_f/E_m$). For an intercalated and exfoliated nanocomposite, an effective, filler-based, micromechanical model that includes effective filler structural parameters, the number of platelets per stack (n) and the silicate inter-layer spacing ($d_{001}$), is proposed to describe the mesoscopic intercalated filler and the nanoscopic exfoliated filler. The proposed model nicely captures the experimental modulus behaviors for both intercalated and exfoliated nanocomposites. In addition, the model prediction of the heat distortion temperature is examined for nanocomposites with different filler aspect ratio. The predicted heat distortion temperature appears to be reasonable compared to the heat distortion temperature obtained by experimental tests. Based on both the experimental results and model prediction, the reinforcement efficiency and heat resistance of the polyamide-6/clay nanocomposites definitely depend on both conventional (${\alpha},\;S,\;{\Psi}_f,\;E_f/E_m$) and effective (n, $d_{001}$) filler structural parameters.

• Journal of the Korean Wood Science and Technology
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• v.39 no.2
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• pp.179-186
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• 2011

In an effort to understand the hydrolytic degradation process of cured urea-formaldehyde (UF) resins responsible for the formaldehyde emission of wood-based composite panels, this study analyzed the influence of acid hydrolysis on the morphology of cured UF resins with different formaldehyde/urea (F/U) mole ratios such as 1.6, 1.4, 1.2 and 1.0. Field emission-scanning electron microscopy (FE-SEM) was employed to observe both exterior and fracture surfaces on thin films of cured UF resins before and after the etching with hydrochloric acid as a simulation of the hydrolytic degradation process. FE-SEM images showed that the exterior surface of cured UF resin with the F/U mole ratio of 1.0 had spherical structures after the acid hydrolysis while the other cured UF resins were not the case. However, the fracture surface observation showed that all the samples possessed spherical structures in the cured state of UF resins although their occurrence and size decreased as the F/U mole ratio increased. For the first time, we found the spherical structures in cured UF resins of higher F/U mole ratio of 1.4. After the acid hydrolysis, the spherical structures became a much predominant at the fracture surface. These results indicated that the spherical structures in cured UF resinswere much more resistant to the hydrolytic degradation by the acid than amorphous region.

• Journal of Power System Engineering
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• v.15 no.2
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• pp.31-36
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• 2011

The flow characteristics on the periodically arranged semi-circular ribs in a rectangular channel for turbulent flow have been investigated numerically. The aspect ratio of the rectangular channel was AR=5, the rib height to hydraulic diameter ratio was 0.07 and rib height to channel height ratio was e/H=0.117. The v2-f turbulence model and SST k-${\omega}$ turbulence model were used to find the flow characteristics of near the wall which are suited for realistic phenomena. The numerical analysis results show turbulent flow characteristics and pressure drop at the near the wall as observed experimentally. The results predict that turbulent kinetic energy(k) is closely relative to the diffusion of recirculation flow, and v2-f turbulence model simulation results have a good agreement with experimental.