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Ore Minerals, Fluid Inclusions, and Isotopic(S.C.O) Compositions in the Diatreme-Hosted Nokdong As-Zn Deposit, Southeastern Korea: The Character and Evolution of the Hydrothermal Fluids (다이아튜림 내에 부존한 녹동 비소-아연광상의 광석광물, 유체포유물, 유황-탄소-산소 동위원소 : 광화용액의 특성과 진화)

  • Park, Ki-Hwa;Park, Hee-In;Eastoe, Christopher J.;Choi, Suck-Won
    • Economic and Environmental Geology
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    • v.24 no.2
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    • pp.131-150
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    • 1991
  • The Weolseong diatreme was temporally and spatially related to the intrusion of the Gadaeri granite, and was -mineralized by meteoric aqueous fluids. In the Nokdong As-Zn deposit, pyrite, aresenopyrite and sphalerite are the most abundant sulfide minerals. They are associated with minor amount of magnetite, pyrrhotite, chalcopyrite and cassiterite, and trace amounts of Pb-Sb-Bi-Ag sulphosalts. The AsZn ore probably occurred at about $350^{\circ}C$ according to fluid inclusion and compositional data estimated from the arsenic content of arsenopyrite and iron content of sphalerite intergrown with pyrrhotite + chalcopyrite + cubanite. Heating studies of fluid inclusions in quartz indicate a temperature range between 180 and $360^{\circ}C$, and freezing data indicate a salinity range from 0.8 to 4.1 eq.wt % NaCl. The coexisting assemblage pyrite + pyrrhotite + arsenopyrite suggests that $H_2S$ was the dominate reduced sulfur species, and defines fluid parameter thus: $10^{-34.5}$ < ${\alpha}_{S_2}$ < $10^{-33}$, $10^{-11}$ < $f_{S_2}$ < $10^{-8}$, -2.4 < ${\alpha}_{S_2}$ < -1.6 atm and pH= 5.2 (sericte stable) at $300^{\circ}C$. The sulfur isotope values ranged from 1.8 to 5.5% and indicate that the sulfur in the sulfides is of magmatic in origin. The carbon isotope values range from -7.8 to -11.6%, and the oxygen isotope values from the carbonates in mineralized wall rock range from 2 to 11.4%. The oxygen isotope compositions of water coexisting with calcite require an input of meteoric water. The geochemical data indicate that the ore-forming fluid probably was generated by a variety of mechanisms, including deep circulation of meteoric water driven by magmatic heat, with possible input of magniatic water and ore component.

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Study on the Optoelectronic Design for Korean Mobile Satellite Laser Ranging System

  • Lim, Hyung-Chul;Bang, Seong-Cheol;Yu, Sung-Yeol;Seo, Yoon-Kyung;Park, Eun-Seo;Kim, Kwang-Dong;Nah, Ja-Kyoung;Jang, Jeong-Gyun;Jang, Bi-Ho;Park, Jang-Hyun;Park, Jong-Uk
    • Journal of Astronomy and Space Sciences
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    • v.28 no.2
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    • pp.155-162
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    • 2011
  • Korea Astronomy and Space Science Institute has been developing one mobile and one stationary satellite laser ranging system for the space geodesy research and precise orbit determination since 2008, which are called as ARGO-M and ARGO-F, respectively. They will be capable of daytime laser ranging as well as nighttime and provide the accurate range measurements with millimeter level precision. Laser ranging accuracy is mostly dependent on the optics and optoelectronic system which consists of event timer, optoelectronic controller and photon detectors in the case of ARGO-M. In this study, the optoelectronic system of ARGO-M is addressed and its critical design is also presented. Additionally, the experiment of the integrated optoelectronic system was performed in the laboratory to validate the functional operation of each component and its results are analyzed to investigate ARGO-M performance in advance.

A first-principles theoretical investigation of the structural, electronic and magnetic properties of cubic thorium carbonitrides ThCxN(1-x)

  • Siddique, Muhammad;Rahman, Amin Ur;Iqbal, Azmat;Azam, Sikander
    • Nuclear Engineering and Technology
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    • v.51 no.5
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    • pp.1373-1380
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    • 2019
  • Besides promising implications as fertile nuclear materials, thorium carbonitrides are of great interest owing to their peculiar physical and chemical properties, such as high density, high melting point, good thermal conductivity. This paper reports first-principles simulation results on the structural, electronic and magnetic properties of cubic thorium carbonitrides $ThC_xN_{(1-x)}$ (X = 0.03125, 0.0625, 0.09375, 0.125, 0.15625) employing formalism of density-functional-theory. For the simulation of physical properties, we incorporated full-potential linearized augmented plane-wave (FPLAPW) method while the exchange-correlation potential terms in Kohn-Sham Equation (KSE) are treated within Generalized-Gradient-Approximation (GGA) in conjunction with Perdew-Bruke-Ernzerhof (PBE) correction. The structural parameters were calculated by fitting total energy into the Murnaghan's equation of state. The lattice constants, bulk moduli, total energy, electronic band structure and spin magnetic moments of the compounds show dependence on the C/N concentration ratio. The electronic and magnetic properties have revealed non-magnetic but metallic character of the compounds. The main contribution to density of states at the Fermi level stems from the comparable spectral intensity of Th (6d+5f) and (C+N) 2p states. In comparison with spin magnetic moments of ThSb and ThBi calculated earlier with LDA+U approach, we observed an enhancement in the spin magnetic moments after carbon-doping into ThN monopnictide.

Shear Performance of Post and Beam Construction by Pre-Cut Process (프리컷 방식을 적용한 기둥-보 공법의 수평전단내력)

  • Hwang, Kweonhwan;Park, Joo-Saeng;Park, Moon-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.6
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    • pp.1-12
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    • 2007
  • For the purpose of effective utilization of domestic second-grown larch as structural members, post and beam construction applying traditional construction to Japanese larch glulam members was adopted with processing by machine pre-cut method. In general, horizontal shear test by KS F 2154 is conducted to assess the horizontal shear properties of the wooden structure by post and beam construction. The frame was consisted of post and beam member with appropriate fasteners, and members have their own processed parts (notch, hole, etc.) that can be well-connected each other. The shear wall was consisted of the frame with screw-nail sheathed panel (OSB). The results of horizontal shear loading tests without vertical loads conducted on the frame and the shear wall structures, the maximum strengths were about 1.9 kN/m and about 9.7 kN/m, the shear rigidities were about 167 kN/rad, 8198 kN/rad, respectively. The strength proportion of the frame specimen was about 20% of the wall's and about 2% in initial stiffness. Nail failures are remarkable on the shear wall specimen with punching shears and shear failures. The shear load factor for the shear wall specimen by the method of Architectural Institute of Japan was 1.5, which was obtained by the bi-linear method. Loading method should be considered to obtain smooth load-deformation relationship. For the better shear performance of the structures, column base and post and beam connections and sheathed panel should be further examined as well.

Distribution and Management of Spatial Dose Rate in Neuro Angio Room (두개부 혈관조영실에서 공간산란선량의 분포와 관리)

  • Lee, Mi-Hwa;Jung, Hong-Ryang;Lim, Cheong-Hwan;Hong, Dong-Hee;Kim, Ki-Jeong;Kim, Sang-Hyun
    • Journal of Digital Convergence
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    • v.12 no.4
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    • pp.427-435
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    • 2014
  • This study is performed in the intervention unit, during interventional procedures and in accordance with the direction and distance during the exposure indoor space is to measure the dose. I was classified at an angle of $45^{\circ}$ counterclockwise from the phantom. Seven(A, B, C, D, E, F, G) were classified as direction. Length was measured from the center of the phantom. Each direction 50cm, 100cm, 150cm, 200cm were classified. I was analyzed by measuring of frontal, lateral, Bi-plan fluoroscopic Spatial dose rate in all 28 points. Measured dose was the highest at 50cm and over 200cm, dose was rapidly decreasing as increased distance. Dose was different more than nine times depending on the distance and direction, Installation of shielding wall can reduce exposure about 84.52% to 93.54%.

Design, Analysis, and Equivalent Circuit Modeling of Dual Band PIFA Using a Stub for Performance Enhancement

  • Yousaf, Jawad;Jung, Hojin;Kim, Kwangho;Nah, Wansoo
    • Journal of electromagnetic engineering and science
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    • v.16 no.3
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    • pp.169-181
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    • 2016
  • This work presents a new method for enhancing the performance of a dual band Planer Inverted-F Antenna (PIFA) and its lumped equivalent circuit formulation. The performance of a PIFA in terms of return loss, bandwidth, gain, and efficiency is improved with the addition of the proposed open stub in the radiating element of the PIFA without disturbing the operating resonance frequencies of the antenna. In specific cases, various simulated and fabricated PIFA models illustrate that the return loss, bandwidth, gain, and efficiency values of antennas with longer optimum open stub lengths can be enhanced up to 4.6 dB, 17%, 1.8 dBi, and 12.4% respectively, when compared with models that do not have open stubs. The proposed open stub is small and does not interfere with the surrounding active modules; therefore, this method is extremely attractive from a practical implementation point of view. The second presented work is a simple procedure for the development of a lumped equivalent circuit model of a dual band PIFA using the rational approximation of its frequency domain response. In this method, the PIFA's measured frequency response is approximated to a rational function using a vector fitting technique and then electrical circuit parameters are extracted from it. The measured results show good agreement with the electrical circuit results. A correlation study between circuit elements and physical open stub lengths in various antenna models is also discussed in detail; this information could be useful for the enhancement of the performance of a PIFA as well as for its systematic design. The computed radiated power obtained using the electrical model is in agreement with the radiated power results obtained through the full wave electromagnetic simulations of the antenna models. The presented approach offers the advantage of saving computation time for full wave EM simulations. In addition, the electrical circuit depicting almost perfect characteristics for return loss and radiated power can be shared with antenna users without sharing the actual antenna structure in cases involving confidentiality limitations.

Comparative Antioxidant Enzyme Activity of Diploid and Tetraploid Platycodon grandiflorum by Different Drying Methods

  • Boo, Hee-Ock;Shin, Jeoung-Hwa;Kim, Young-Seon;Park, Hee-Jeong;Kim, Hag-Hyun;Kwon, Soo-Jeong;Woo, Sun-Hee
    • Korean Journal of Plant Resources
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    • v.26 no.3
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    • pp.389-396
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    • 2013
  • The antioxidant enzyme and DPPH radical scavenging activity with variations in drying methods of diploid and tetraploid in Platycodon grandiflorum were determined. Antioxidant enzyme activities were measured as superoxide dismutase (SOD), catalase (CAT), peroxidase (POX), and ascorbate peroxidase (APX). The roots of Platycodon grandiflorum were freeze-dried, indoor-dried, hot-air dried, and microwave dried. The root extract of P. grandiflorum have shown the highest SOD enzyme activity of 92% in tetraploid of freeze-dried and indoor-dried while diploid of microwave dried showed the lowest SOD enzyme activity of 47.5%. The activity of CAT showed higher values in the root of tetraploid than in the diploid of P. grandiflorum in all drying methods. The APX activity showed relatively higher values in the root extract of freeze-dried both the diploid and tetraploid, but the difference in comparison with other extracts was not significant. The POX activities according to drying methods of diploid and tetraploid in P. grandiflorum showed relatively high values in freeze-dried and indoor-dried compared with other drying methods, and the POX activity between the diploid and tetraploid was not significant difference in each drying method. The DPPH radical scavenging activity with variation in drying methods of diploid and tetraploid in P. grandiflorum was the highest in the freeze-dried, and was higher in tetraploid than diploid in all the concentrations. In conclusion, the root of P. grandiflorum had the potent biological activities in both diploid and tetraploid. In particular, the tetraploid root of P. grandiflorum showing high antioxidant enzyme activity could be good materials for development of source of functional healthy food.

Effects of Nitrogen Addition on Soil Respiration (상수리나무림 임상에 공급한 무기질소가 토양호흡에 미치는 영향)

  • 최주섭;문형태
    • The Korean Journal of Ecology
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    • v.27 no.3
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    • pp.155-159
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    • 2004
  • In order to gain a better understanding of how forests participate in the cycling of carbon, effects of nitrogen addition on soil respiration were investigated on the oak forest in Kongju, Korea. Study site was divided into control, treatment f and treatment 2 plots, with 5 replication in each plot. In each replicate of treatment 1 and treatment 2 were fertilized with ammonium nitrate (NH$_4$NO$_3$), 30 g/$m^2$ and 60 g/$m^2$, respectively. Soil respiration, soil temperature, ammonium-N and nitrate-N were measured during the experimental period. Ammonium-N and nitrate-N in Ta were higher than those in control and T$_1$. Ammonium-N and nitrate-N in top-soil and sub-soil decreased sharply in August after bi9 rainfall in July in T$_1$ and T$_2$, however, those in control plot increased. Soil respiration in T$_2$ Plot showed consistently higher than those in control and T$_1$ until the end of July. However, soil respiration was similar among the control, T$_1$ and T$_2$ in mid-August and September The amount of Co$_2$ released from soil respiration in control, T$_1$ and T$_2$ in mid-August was 8.0$\pm$0.4, 9.3$\pm$0.6 and 10.2$\pm$0.5 $\mu$mol$^{-1}$ ㆍm$^{-2}$ ㆍs$^{-1}$ , respectively. However, those in control, T$_1$ and T$_2$in mid-August was 13.0$\pm$0.4, 13.5$\pm$0.5, 13.3$\pm$0.6 $\mu$mol$^{-1}$ ㆍm$^{-2}$$^{-1}$ , respectively. The results suggest that nitrogen addition in this oak forest has a positive effect on soil respiration.

Involvement of leaf characteristics and wettability in retaining air particulate matter from tropical plant species

  • Barima, Yao Sadaiou Sabas;Angaman, Djedoux Maxime;N'gouran, Kobenan Pierre;Koffi, N'guessan Achille;Tra Bi, Fidele Zamble;Samson, Roeland
    • Environmental Engineering Research
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    • v.21 no.2
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    • pp.121-131
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    • 2016
  • In most African urban areas, Particulate Matters (PM) concentration exceeds by far the WHO limits. In these areas, plants can play a key role in removing particles. In this study, we evaluated three ornamental species (Jatropha interrigima, Ficus benjamina, Barleria prionitis) used in Abidjan (Ivory Coast). Leaf-encapsulated saturation isothermal remnant magnetisation (SIRM) were measured and the relationship between PM captured and leaf wettability were done. The sampling were performed at roadsides and Parks. Firstly, Leaf-encapsulated and total leaf SIRM were quantified and the wettability was determined by drop contact angles (DCA). Secondly, the relationship between leaf SIRM and wettability was found. Results showed that leaf SIRM was two to ten times higher at roadsides than in Parks. Total leaf SIRM was also higher on mature leaves in Main roads suggesting a particle accumulation in leaves over time especially in waxy species (Ficus benjamina). This species encapsulated other than 20% of total leaf SIRM. All tested species were highly-wettable ($40^{\circ}$ < DCA < $90^{\circ}$). Thus, Jatropha interrigima with its leaf trichomes and F. benjamina with its leaf waxes were more wettable. A significantly positive correlation was found between wettability intensity and leaf SIRM.

Crystal Structure, Fluorescence Property and Theoretical Calculation of the Zn(II) Complex with o-Aminobenzoic Acid and 1,10-Phenanthroline

  • Zhang, Zhongyu;Bi, Caifeng;Fan, Yuhua;Zhang, Xia;Zhang, Nan;Yan, Xingchen;Zuo, Jian
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1697-1702
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    • 2014
  • A novel complex [$Zn(phen)(o-AB)_2$] [phen: 1,10-phenanthroline o-AB: o-aminobenzoic acid] was synthesized and characterized by elemental analysis and X-ray diffraction single-crystal analysis. The crystal crystallizes in monoclinic, space group P2(1)/c with $a=7.6397(6){\AA}$, $b=16.8761(18){\AA}$, $c=17.7713(19){\AA}$, ${\alpha}=90^{\circ}$, ${\beta}=98.9570(10)^{\circ}$, ${\gamma}=90^{\circ}$, $V=2.2633(4)nm^3$, Z = 4, F(000) = 1064, S = 1.058, $Dc=1.520g{\cdot}cm^{-3}$, $R_1=0.0412$, $wR_2=0.0948$, ${\mu}=1.128mm^{-1}$. The Zn(II) is six coordinated by two nitrogen and four oxygen atoms from the 1,10-phenanthroline and o-aminobenzoic acid to furnish a distorted octahedron geometry. The complex exhibits intense fluorescence at room temperature. Theoretical studies of the title complex were carried out by density functional theory (DFT) B3LYP method. CCDC: 898291.