• Title/Summary/Keyword: External corrosion

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A Study on the Development and the Verification Experiment of ECDA Equipment (외면부식직접평가 장비 개발 및 실증 시험에 관한 연구)

  • Ryou, Young-Don;Lee, Jin-Han;Jung, Sung-Won;Park, Kyeong-Wan
    • Journal of the Korean Institute of Gas
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    • v.20 no.5
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    • pp.72-81
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    • 2016
  • When the coatings of buried steel pipelines are damaged, corrosion could be occurred on the surface of the damaged areas. Moreover the pinhole occurred by corrosion of pipelines may cause accidents due to gas leakage. To prevent these accidents, foreign countries including UK and USA have carried out coating defect detection on the buried gas pipelines by using a DCVG or a ACVG and have conducted direct assessment of pipelines through digging the ground, and if necessary, have repaired the pipelines. That is called ECDA i.e External Corrosion Direct Assessment which is regulated by NACE standards(SP 0502) and etc. In Korea, the ECDA provisions were included in KGS FS551 in 2014 when the regulations of Safety Validation in Detail for the medium-pressure piping were introduced. We have developed the equipment which can be used to detect external corrosion of the buried gas pipelines. We have also constructed pipeline test bed for empirical test of the developed equipment. In addition, we have carried out the verification experiments of the developed equipment on the test bed to demonstrate the performance of the equipment. The experiments were conducted by comparison tests of the developed equipment and other equipments which have been introduced and used in Korea. As the result, we have found the developed equipment is easier to use and has far superior performance compared to other equipment being used in Korea.

A Study on the Crevice Corrosion for Ferritic Stainless Steel (페라이트 스테인리스강의 틈부식에 대한 연구)

  • Baik Shin-Young
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.10 no.1 s.20
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    • pp.51-54
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    • 2004
  • In recently days, the breed fish farm is increased in the beach side for farming fish. In such a farm, the heater is requested for preventing freezing in cold season. The heating material are requested high corrosion resistance and strength for endurance high corrosive salt and pressure. In case of low corrosion resistance and/or strength, the heating element shall be broke down and eventually make spillage or leaking contaminated salt. In the most cases, crevice corrosion is localized form of corrosion usually associated with a stagnant solution on the micro-environmental level. In this study, the crevice corrosion of Ferritic type 430 stainless steel is investigated. The size of specimen is $15{\times}20{\times}3mmt$. Test solution is 1N H2SO4 + 0.05N NaCl. The artificial crevice gap size is $0.24{\times}3{\times}15mmL$. Crevice corrosion is measured under applied voltage 300mV(SCE) to the external surface. the result of this study showed that 1) the induced time for initiation of crevice is 750seconds, 2) potential is dropped in the crevice from the top of gap opening from -320 to -399mV. The result confirmed that the potential drop(IR mechanism) in the crevice is one of mechanism for crevice corrosion.

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Effect of RuCl3 Concentration on the Lifespan of Insoluble Anode for Cathodic Protection on PCCP

  • Cho, H.W.;Chang, H.Y.;Lim, B.T.;Park, H.B.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.14 no.4
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    • pp.177-183
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    • 2015
  • Prestressed Concrete steel Cylinder Pipe (PCCP) is extensively used as seawater pipes for cooling in nuclear power plants. The internal surface of PCCP is exposed to seawater, while the external surface is in direct contact with underground soil. Therefore, materials and strategies that would reduce the corrosion of its cylindrical steel body and external steel wiring need to be employed. To prevent against the failure of PCCP, operators provided a cathodic protection to the pre-stressing wires. The efficiency of cathodic protection is governed by the anodic performance of the system. A mixed metal oxide (MMO) electrode was developed to meet criteria of low over potential and high corrosion resistance. Increasing coating cycles improved the performance of the anode, but cycling should be minimized due to high materials cost. In this work, the effects of $RuCl_3$ concentration on the electrochemical properties and lifespan of MMO anode were evaluated. With increasing concentration of $RuCl_3$, the oxygen evolution potential lowered and polarization resistance were also reduced but demonstrated an increase in passive current density and oxygen evolution current density. To improve the electrochemical properties of the MMO anode, $RuCl_3$ concentration was increased. As a result, the number of required coating cycles were reduced substantially and the MMO anode achieved an excellent lifespan of over 80 years. Thus, we concluded that the relationship between $RuCl_3$ concentration and coating cycles can be summarized as follows: No. of coating cycle = 0.48*[$RuCl_3$ concentration, $M]^{-0.97}$.

An Experimental Study on the Improvement of City Gas Buried Double Piping Integrity (도시가스 매설이중배관 건전성 향상에 관한 실험적 연구)

  • Lim, Hyung-Duk
    • Journal of the Korean Society of Industry Convergence
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    • v.23 no.5
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    • pp.757-763
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    • 2020
  • City gas buried pipes are managed by corrosion protection to prevent corrosion. In the case of the press-in section, the double pipe and the main pipe may cause corrosion under the influence of stray current, which can shorten the life of the pipes. In addition, if the insulator is filled in the press-in section, the press-in section itself is a single structure, and can be directly affected by external impact, and when the surrounding ground subsidence occurs, the stress may be concentrated, resulting in serious consequences. In this study, a serration-type shock absorber in the form of a sliding support was proposed as a new buried double piping construction method using EPS. The serration-type shock absorber can contribute to the improvement of the integrity of the buried double piping, as it can utilize the gas piping's own ductility and stress distribution characteristics with proper anti-corrosion management and shock-absorbing material properties by preventing contact inside the buried double pipe. However, for application to ground piping, there remains a task to supplement the vulnerability against fire due to the characteristics of EPS materials.

Performance Appraisal of the Ceramic Metal Resin Paints for Waterproof and Anti-Corrosion to Improve the Property of Concrete Structure (콘크리트 구조물의 표층부 내구성 증진을 위한 세라믹 메탈계 방수$\cdot$방식재 도료의 성능 평가 연구)

  • Jun Byung-Hun;Kim Jin-Sung;Kang Hyo-Jin;Oh Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.05a
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    • pp.113-117
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    • 2005
  • The ceramic metal resin paints for waterproof and anti corrosion is not long history in development of materials even many actual result. So far, no standard have been given to construction and maintenance method, Quality and property, it is real state that cannot afford to proper quality control in job site or production. This study has been test for the ceramic metal resin paints for water and anti corrosion, as the result, it have proper performance of job site and mechanical performance of compare to other existing. In particular, tensile strength indicates more high about $14.1N/mm^2$ than epoxy resin paints, and in elongation per unit length is more high It is shows having better adhesive strength than epoxy resin paint for crack on the concrete structure. Moreover, The ceramic metal paint for water and corrosion proofing have to have main performance is watertightness and resistance for external impact, chloride ion permeation, drinkable water elution.

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Regional Cathodic Protection Design of a Natural Gas Distribution Station

  • Yabo, Hu;Feng, Zhang;Jun, Zhao
    • Corrosion Science and Technology
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    • v.16 no.5
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    • pp.235-240
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    • 2017
  • Regional cathodic protection has significant impact on pipeline integrity management. After risk analyses of a newly built gas distribution station constructed in an area with large dwelling density, risk score was high because of potential threat caused by galvanic corrosion. Except reinforced steel in concrete, there are four kinds of metal buried under earth: carbon steel, galvanized flat steel, zinc rod and graphite module. To protect buried pipeline from external corrosion, design and construction of regional cathodic protection was proposed. Current density was measured with potential using potential dynamic test and boundary element method (BEM) was used to calculate current requirement and optimize best anode placement during design. From our calculation on the potential, optimized conditions for this area were that an applied current was 3A and anode was placed at 40 meters deep from the soil surface. It results in potential range between $-1.128V_{CSE}$ and $-0.863V_{CSE}$, meeting the $-0.85V_{CSE}$ criterion and the $-1.2V_{CSE}$ criterion that no potential was more negative than $-1.2V_{CSE}$ to cause hydrogen evolution at defects in coating of the pipeline.

Burst strength behaviour of an aging subsea gas pipeline elbow in different external and internal corrosion-damaged positions

  • Lee, Geon Ho;Pouraria, Hassan;Seo, Jung Kwan;Paik, Jeom Kee
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.7 no.3
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    • pp.435-451
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    • 2015
  • Evaluation of the performance of aging structures is essential in the oil and gas industry, where the inaccurate prediction of structural performance can have significantly hazardous consequences. The effects of structure failure due to the significant reduction in wall thickness, which determines the burst strength, make it very complicated for pipeline operators to maintain pipeline serviceability. In other words, the serviceability of gas pipelines and elbows needs to be predicted and assessed to ensure that the burst or collapse strength capacities of the structures remain less than the maximum allowable operation pressure. In this study, several positions of the corrosion in a subsea elbow made of API X42 steel were evaluated using both design formulas and numerical analysis. The most hazardous corrosion position of the aging elbow was then determined to assess its serviceability. The results of this study are applicable to the operational and elbow serviceability needs of subsea pipelines and can help predict more accurate replacement or repair times.

High Temperature Corrosion Properties of Heat Resistant Chrome Steels in SO2 Atmosphere (고온 이산화황 환경 내 내열 크롬강에 대한 부식특성 연구)

  • Lee, Han-sang;Jung, Jine-sung;Kim, Eui-hyun
    • Korean Journal of Metals and Materials
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    • v.47 no.2
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    • pp.99-106
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    • 2009
  • The high temperature corrosion properties of heat resistant steels were investigated in oxidation atmosphere including sulfur dioxide. The heat resistant steels of T22, T92, T122, T347HFG and T304H were evaluated at 620, $670^{\circ}C$ for 400 hours. The corrosion rates showed a decreasing tendency while chrome contents of those steels increased from 2 mass.% to 19 mass.%. The in crease in temperature increasement has an more effect on the corrosion rates of low chrome steels than high chrome steels. The weight gains of T22, T92, T304H at $670^{\circ}C$ were 3.7, 1.65, 1.23 times compared with those at $620^{\circ}C$. The external scale formed on T22 was composed of hematite, magnetite and Fe-Cr spinel and internal layer including iron oxide mixed with sulfide. The scales formed on T92, T122, T304H consisted of an outer layer of hematite and inner layer of chrome oxide and hematite. The proportion of chrome oxide at inner layer was increased when the chrome contents in heat resistant steels were increased.

A study on the Application Effect of Friction Stir Processing for Enhanced Pitting Corrosion Resistance of Stainless Steel Welds in Chloride Environment (염화물 환경에서 스테인리스강 용접부의 공식저항성 향상을 위한 마찰교반공정 적용효과에 관한 연구)

  • Jong Moon Ha;Deog Nam Shim;Seung Hyun Kim
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.19 no.2
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    • pp.84-92
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    • 2023
  • As temporary storage facilities for spent nuclear fuels in domestic nuclear power plants are expected to be saturated, external intermediate storage facilities would be required in the future. Spent nuclear fuels are stored in metal canisters and then placed in a dry environment within concrete or metal casing for operation. In the United States, the dry storage method for spent nuclear fuels has been operated for an extended period. Based on the corrosion experiences of dry storage canisters in chloride environments, numerous studies have been conducted to reduce corrosion in welds. With the construction of intermediate storage facilities in Korea for spent nuclear fuels expected near coastal areas adjacent to nuclear power plants, there is a need for research on the corrosion occurrence of welds and mitigation methods for canisters in chloride environments. In this paper, we measured and compared the residual stresses in the Heat-Affected Zones (HAZ) after electron beam welding (EBW) and gas tungsten arc welding (GTAW) processes for candidate materials such as 304L, 316L, and duplex stainless steel(DSS). We investigated the possibility of microstructure control through the application of surface modification processes using friction stir processing (FSP). Corrosion tests on each welded specimen revealed a higher corrosion rate in EBW welds compared to GTAW. Furthermore, it was confirmed that corrosion resistance improved due to phase refinement and redistribution of precipitates when FSP was applied.

A New Protection Strategy of Impressed Current Cathodic Protection for Ship

  • Oh, Jin-Seok;Kim, Jong-Do
    • Journal of Mechanical Science and Technology
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    • v.18 no.4
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    • pp.592-596
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    • 2004
  • Corrosion is never avoided in the use of materials with various environments. The underwater hull is normally protected against rusting by several coatings of anti-corrosive paint. The purpose of ICCP(Impressed Current Cathodic protection) system is to eliminate the rusting or corrosion, which occurs on metal immersed in seawater. The anode of ICCP system is controlled by an external DC source with converter. The function of anode is to conduct the protective current into seawater. The proposed algorithm includes the harmonic suppression control strategy and the optimum protection strategy and has tried to test the requirement current density for protection, the influence of voltage, the protection potential. This paper was studied the variation of potential and current density with environment factors, time and velocity, and the experimental results will be explained.