• Corrosion Science and Technology
• /
• v.9 no.6
• /
• pp.259-264
• /
• 2010

In continuous hot dip galvanizing process, oxide formation on steel surface has an influence on Zn wetting. High strength automotive steel contains high amount of Si and Mn, where Si-Mn composite oxides such as $Mn_2SiO_4$ or $MnSiO_3$ covers the surface after annealing. Zn wetting depends on how the aluminothermia reaction can reduce the Mn-Si composite oxides and then form inhibition layer such as $Fe_2Al_5$ on the steel surface. The outward diffusion of metallic ions such as $Mn^{2+}$, $Si^{2+}$ in the steel matrix is very important factor for the formation of the surface oxides on the steel surface. The surface state and grain boundaries provide an important role for the diffusion and the surface oxide reactions. Some elements such as P, Sb, and B have a strong affinity for the interface precipitation, and it influence the diffusivity of metallic ions on grain boundaries. B oxide forms very rapildly on the steel surface during the annealing, and this promote complex oxides with $SiO_2$ or MnO. P has inter-reacted with other elements on the grain boundaries and influence the diffusion through on them. Small addition of Sb could suppress the decarburization from steel surface and retards the formation of internal and external selective oxides on the steel surface. Interface control by the trace elements such as Sb could be available to improve the Zn wettability during the hot dip galvanizing.

• Journal of the Korean Institute of Gas
• /
• v.14 no.6
• /
• pp.51-56
• /
• 2010

Records of accidents for buried pipeline across the river were gathered and causes were analysed. The results are intended to be utilized as basic data for determining a reasonable criteria for the depth of buried city gas pipeline crossing the river. Accident of river-crossing buried pipeline was mainly caused by flood. Sometimes corrosion was detected at the failed location of the pipe. In order to determine reasonable and efficient depth of burial of the pipeline, hydraulic evaluation of the river and structural analysis of the pipeline are necessary. Published data for the buried natural gas pipeline incidents were also investigated and summarized. Main causes of buried natural gas pipeline incidents were external interference and corrosion. However, the two main causes of incidents showed significant difference in the proportion of the entire incident, depending on burial environment.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.27 no.6
• /
• pp.55-61
• /
• 2023

In this study, a basic research was conducted to establish a maintenance plan considering the environmental factors and deterioration characteristics of port facilities. The precise safety diagnosis reports for Incheon and Busan port facilities were referenced to examine the extent of deterioration and damage. The relationship with the degradation environmental assessment presented in the current guidelines was also analyzed. The analysis of the damage level of Incheon and Busan port facilities revealed that Incheon Port exhibited approximately three times higher damage rate compared to Busan Port. In the case of Incheon Port, reinforcement corrosion and external damage showed similar proportions, while in Busan Port, reinforcement corrosion had a higher proportion compared to external damage. On the other hand, when comparing with the degradation environmental assessment presented in the guidelines, it was found that there were some limitations in performing quantitative evaluation based on the guidelines for assessing port facilities. Therefore, an analysis based on tidal range was conducted by referring to existing literature. The analysis of tidal range in Incheon and Busan regions showed that Incheon had approximately five times higher difference compared to Busan. It is considered that this can be utilized as a differentiated item from existing degradation environmental assessment criteria.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.26 no.1
• /
• pp.1-9
• /
• 2022

De -icing salts have been used commonly in areas where snow or ice is a seasonal safety hazard for roadway, however, the salts is one of main causes on serious deterioration of road infrastructures in crowded urban city like Seoul. In order to establish maintenance strategy of road infrastructures under de-icing salts laden environment, it is necessary to examine environmental characteristics and its response to the existing facilities. The purpose of this study is to evaluate the deterioration environment of road infrastructures. Additional purpose is to develop a design model and details for durability design of infrastructures under de-icing salts laden environment, considering mainly a build-up rate of surface chlorides. Concentration of external chloride solution and surface chloride content were calculated at the level of average de-icing salts for 5 years, ratio of auxiliary road of 17.5 to 30%, and effective exposure area to snow 50 to 80%. The chloride build-up rate was 0.073 ~ 0.077% / year and the maximum surface chloride content was calculated to be 2.2 ~ 2.31% by concrete wt. This study is expected to be used for establishing integrated strategy of road infrastructures, such as predicting chloride profiles or degree of chemical corrosion to exposure concrete.

• Journal of the Korean Institute of Gas
• /
• v.22 no.5
• /
• pp.62-71
• /
• 2018

According to own investigation conducted by Korea Gas Safety Corporation Gas Safety Research Institute in 2017, the length of underground pipes in domestic high-pressure gas pipelines is approximately 770km, of which 84% is buried in Ulsan and Yeosu industrial complexes. In particular, 56% of underground pipelines have been in operation for more than 20 years. This suggests urgent management of buried high pressure gas pipelines. PHMSA in US and EGIG in Europe, major causes of accidents in buried gas pipelines are reported as third party damage, external corrosion and loss of pipe wall thickness. Therefore, it is important to evaluate whether the defects affect the remaining life of the pipe when defects occur in the pipe. DNV and ASME have evaluated the residual strength of pipelines through the hydraulic rupture test using pipe specimens with artifact flaws. Once the operating pressure is known through the residual strength of the pipe, the wall thickness at the point at which the pipe ruptures is calculated. If we know the accurate rate of corrosion growth, we can predict the remaining life of pipe. In the study, we carried out experiments with A53 Grade.B and A106 Grade.B, which account for 80% of domestic buried pipes. In order to modify the existing model equation, specimens with a defect depth of 80% to 90% was tested, and a formula expressing the relationship between defect and residual strength was made.

• Journal of Ocean Engineering and Technology
• /
• v.13 no.3 s.33
• /
• pp.68-76
• /
• 1999

The welding residual stresses produced by the welding frequently caused a crack and promote stress corrosion etc. in HAZ(heat affected zone) contained with external load and weakness of material. Therefore, PWHT(post welding heat treatment) is widely used to reduce wekdubg residuss, to relax hardening of heat affected zone and to get rid of impurity. In this study, in order to define the effect on shappes of T-welded joint, during the post welding heat treatment, we have carried out numerical analyses on the several test pieces by using computer program which was based on thermal-elasto-plato-plasto-creep theories for the study. The main results obtained form this study is as follows: 1) The mechanical difference for change the thickness of plate and groove angle did not appear. 2) The distribution modes of welding residual stresses are same on the all test specimens during the post welding heat treatment. 3) In a mecharical point of view, minimum groove groove angle($40^{circ}$) is more suitable than maximum groove angle($60^{circ}$). 4) Therefore, it is appropriate to minimize the size of groove shape in strength and safety.

• Journal of the Korean Society of Manufacturing Technology Engineers
• /
• v.21 no.4
• /
• pp.532-540
• /
• 2012

In this study, some considerations have been suggested in developing on-site techniques to evaluate the sensitization of stainless steels. Electrochemical potentiokinetic reactivation (EPR) technique is known to be a candidate tool for field applications since it enables quantitative assessment in reasonable test time, compared to oxalic etching (ditch) technique. The on-site application of the test method imposes additional restrictions on the selection of the test method (for example, minimum surface preparation requirement, insensitivity to testing temperature, etc.). The EPR and etching techniques have been compared in order to sensitization of stainless steel structures. It has been widely reported that the maximum sensitivity in the welded structure of stainless steel is shown at heat-affected zone (HAZ) than weldments with cast structure. In this work, sectioned weldments and external surfaces were investigated to reveal the degree of sensitization by the etching and the results were compared with those of EPR test. The EPR test showed little sensitivity to surface roughness and test temperature.

• Journal of Ocean Engineering and Technology
• /
• v.21 no.5
• /
• pp.61-67
• /
• 2007

As part of the government's fishery resource creation policy, fishing ground creation projects have been undertaken in Korea's major seashore fishing spots since the 1970s, where artificial reefs constructed using new materials that make up for the weakness of concrete reefs have been used. In this study, the stability of these artificial reefs when acted upon by external forces, their ability to attract and gather fish, and their economic feasibility were examined. For this purpose, an experimental artificial steel reef was constructed and was installed in an area of the sea. Then the corrosion of the experimental material attached to it was investigated. The efficiency of the artificial steel reef was then verified by examining its functionality, removal, and burying, as well as the speed of insertion of living things into its structure and its ability to attract and gather fish.

• 한국터널공학회:학술대회논문집
• /
• 2005.04a
• /
• pp.251-258
• /
• 2005

In this study, a new concept for simulating a long-term mechanical degradation mechanism of shotcrete in tunnels has been proposed. In fact, it is known that the degradation takes place mainly by internal cracks and reduced stiffness, which results mainly from volume expansion of shotcrete and corrosion of cement materials, respectively. This degradation mechanism of shotcrete in tunnels appears similar to those of the most kinds of chemical reactions in tunnels. Therefore, the mechanical degradation induced by a kinds of chemical reaction was generalized and mathematically formulated in the framework of thermodynamics. The numerical model was implemented to a 3D finite element code, which can be used to simulate behaviour of shotcrete structures undergoing external forces as well as chemical degradation in time. A number of illustrative examples were given to show the feasibility of the model in tunnel designs with consideration of long-term degradation effect of shotcrete quantitatively for increase of long-term safety of tunnels.

• Proceedings of the Korean Nuclear Society Conference
• /
• 1998.05b
• /
• pp.78-83
• /
• 1998

Alloy 600과 Alloy 690의 응력부식파괴(Stress corrosion cracking, SCC)에 미치는 TiO$_2$의 영향을 315$^{\circ}C$의 10%NaOH 수용액에서 RUB(reverse U-bend) 시편, C-Ring 시편과 CT(compact tension)시편을 사용하여 평가하였다. 시편은 alloy 600 MA(mill anneal), alloy 600 TT(thermal treatment) 그리고 alloy 690 TT로 제작하였다. SCC 시험은 탈산된 10%NaOH 수용액에 2 g/1 TiO$_2$를 첨가한 용액과 첨가하지 않은 용액에서 수행하였으며, 이 조건에서 분극곡선도 얻었다. SCC 시험시 시편을 부식전위로부터 +150 ㎷ 양극분극을 가하였다. 기준전극으로 external Ag/AgCl electrode를 사용하였다. Alloy 600 MA로 제작한 RUB 시편은 TiO$_2$가 없는 용액에서 5일 안에 벽 관통 균열을 보였으나 TiO$_2$가 첨가된 용액에서는 균열을 관찰할 수 없었다. TiO$_2$가 첨가됨에 따라 alloy 600과 alloy 690의 임계전류밀도는 크게 감소하였고 또한 부동태 전류밀도도 감소하였다. 부동테 영역에서 TiO$_2$가 있는 용액의 경우 여러 peak가 있는 반면에 TiO$_2$가 없는 용액은 peak가 뚜렷하지 않았다. 이런 결과는 TiO$_2$가 첨가점에 따라 active region에서도 안정한 부동태 피막이 존재한다는 것을 시사한다. 또한 TiO$_2$가 없는 경우 SCC가 잘 일어나는 영역에 존재하는 부동태 피막이 TiO$_2$ 첨가에 따라 repassivation kinetics 등의 성질이 변화한 것으로 판단된다.