• Biotechnology and Bioprocess Engineering:BBE
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• v.5 no.6
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• pp.441-448
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• 2000

Experimental work was carried out on nitrogen and phosphorus removal from real wastewater using a bench-scale SBR process. The phosphorus removal was stable and the phosphorus concentration remaining in the reactor was maintained within 1.5ppm, regardless of the addition of an external carbon source. In the case of nitrogen, an external carbon source was necessary for denitrification. The effect on denitrification with the addition of various carbon sources, such as glucose, methanol, acetate, and propionate, was also investigated. Acetate was found to be the most effective among those tested in this study. When 100ppm (theoretical oxygen demand) of sodium acetate was added, the average rate of denitrifiaction was 2.73mg NO$_3$-N (g MLSS)(sup)-1 h(sup)-1, which was ca. 4 times higher than that with the addition of 200 ppm of methanol. The phosphorus and nitrogen concentrations were both maintained within 1.5ppm by the addition of an appropriate amount of a carbon source during a long-term operation of the SBR. The mathematical modeling was performed using Monod kinetics, other microbial kinetics, mass balances, and stoichiometry. The modeling was found to be useful for predicting the SBR operation and optimizing the HRT.

• Proceedings of the Korean Institute of Intelligent Systems Conference
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• 2000.11a
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• pp.452-455
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• 2000

There are increasingly important financial incentives and environmental consideration to improve the effluent quality of wastewater from domestic and industrial users. The activated sludge process is a widely used biological wastewater treatment process. The activated sludge process is complicated due to the many factors such as the variation of influent flowrate and concentration, the complexity of biological reactions and the various operation conditions. Nowadays, not only suspended solids and residual carbon, but also nitrogen and phosphorous concentration of the effluent water must be taken into account for the design and operation of wastewater treatment plants. Also, the effluent quality to be met are more stringent. Therefore, an intelligent control approach is required in order to successful biological nitrogen removal. In this paper, the strategies for dosage of extra carbon in the anoxic zone and DO concentration in the aerobic zone are presented and evaluated through the simulation using the denitrification layout of the IWA simulation benchmark implemented by Matlab$\^$/5.3/Simulink$\^$/3.0. The control strategy to achieve sufficient denitrification rates in an anoxic zone. Methanol is used as an external extra carbon source. The external extra carbon source is required for the nitrogen removal process because nitrogen and organic concentration are fluctuated in the influent flowrate. The dissolved oxygen is calculated by So concentration in the activated sludge model NO.1. The air flowrate of each aerobic reactor is intelligently controlled to achieve the predefined setpoints. Air flowrate is adjusted by the fuzzy logic controller that includes two inputs and one output. The objective function for the optimization procedure is designed to improve effluent quality and reduce the operating cost.

• Applied Chemistry for Engineering
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• v.29 no.4
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• pp.369-375
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• 2018

Batch experiments were conducted to investigate the effects of operating parameters such as the temperature, initial concentration, contact time and adsorbent dosage on the adsorption of antibiotics amoxicillin (AMX) by waste citrus peel based activated carbon (WCAC). The kinetics and isotherm experiment data can be well described with the pseudo-second order model and the Langmuir isotherm model, respectively. The maximum adsorption capacity of AMX by WCAC calculated from the Langmuir isotherm model was 125 mg/g. The adsorption of AMX by WCAC shows that the film diffusion (external mass transfer) and the intraparticle diffusion occur simultaneously during the adsorption process. The adsorption rate is more influenced by the intraparticle diffusion than that of the external mass transfer as the particle size of WCAC increases, and the intraparticle diffusion is the rate controlling step. The thermodynamic parameters indicated that the adsorption reaction of AMX by WCAC was an endothermic and spontaneous process.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.39-41
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• 2012

The influence of coal blending methods such as out-furnace (external or pre-mixed) blending and in-furnace (initially non-mixed) blending with different excess oxygen (highest, medium, and lowest stoichiometric conditions) on unburned carbon and NOx emissions of blend combustion in an entrained flow reactor (EFR) has been analyzed, using experimental and numerical approaches for binary coals used by Korean power plants. The results confirm that under the medium condition, contrasting processes such as reactive and un-reactive effects occur with SBRs in the out-furnace blending method. The in-furnace blending method results in an improvement in the efficiency of unburned carbon fractions and a further reduction in the NOx emission. Under the highest condition, the unburned carbon fraction in both the out-furnace and the in-furnace blending methods corresponds with the tendency under the medium condition with contrasting processes of lower magnitude, whereas the NOx emission in the highest condition increases slightly. Under the lowest conditions, the unburned carbon fraction in the out-furnace blending method gradually decreases as SBR decreases, without a competition effect. The reduction of NOx emission under the lowest conditions is more effective than those under other conditions for the two blending methods because of a homogeneous and heterogeneous NOx reduction mechanism.

• Carbon letters
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• v.10 no.4
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• pp.329-334
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• 2009

In this work, the effect of carbon nanofibers (CNFs) addition on physicochemical characteristics of CNFs-reinforced epoxy matrix nanocomposites was studied. Poly(amide imide) solutions in dimethylformamide were electrospun into webs consisting of $250{\pm}50$ nm fibers which were used to produce CNFs through stabilization and carbonization processes. As a result, the CNFs with average diameter of $200{\pm}20$ nm were obtained after carbonization process. The nanocomposites with CNFs showed an improvement of thermal stability parameters and fracture toughness factors, compared to those of the specimen without CNFs, which could be probably attributed to the higher specific surface area and larger aspect ratio of CNFs, resulting in improving the mechanical interlocking in the nanocomposites. Also, the applied external loading can effectively transfer to CNFs because strong interactions are resulted between the epoxy matrix and the CNFs.

• Journal of the Korean Society of Safety
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• v.37 no.4
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• pp.11-19
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• 2022

This paper presents the effects of high temperature and water absorption on the mechanical behaviors of carbon-aramid fiber composites, specifically their strength, elastic modulus, and fracture. These composites are used in industrial structures because of their high specific strength and toughness. Carbon fiber composites are vulnerable to the impact force of external objects despite their excellent properties. Aramid fibers have high elongation and impact absorption capabilities. Accordingly, a hybrid composite with the complementary properties and capabilities of carbon and aramid fibers is fabricated. However, the exposure of aramid fiber to water or heat typically deteriorates its mechanical properties. In view of this, tensile and flexural tests were conducted on a twill woven carbon-aramid fiber hybrid composite to investigate the effects of high temperature and water absorption. Moreover, a multiscale analysis of the stress behavior of the composite's microstructure was implemented. The results show that the elastic modulus of composites subjected to high temperature and water absorption treatments decreased by approximately 22% and 34%, respectively, compared with that of the composite under normal conditions. The crack behavior of the composites was well identified under the specimen conditions.

• Carbon letters
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• v.11 no.1
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• pp.38-40
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• 2010

Carbon supported electrocatalysts are commonly used as electrode materials for polymer electrolyte membrane fuel cells(PEMFCs). These kinds of electrocatalysts provide large surface area and sufficient electrical conductivity. The support of typical PEM fuel cell catalysts has been a traditional conductive type of carbon black. However, even though the carbon particles conduct electrons, there is still significant portion of Pt that is isolated from the external circuit and the PEM, resulting in a low Pt utilization. Herein, new types of carbon materials to effectively utilize the Pt catalyst are being evaluated. Carbon nanofiber/activated carbon fiber (CNF/ACF) composite with multifunctional surfaces were prepared through catalytic growth of CNFs on ACFs. Nickel nitrate was used as a precursor of the catalyst to synthesize carbon nanofibers(CNFs). CNFs were synthesized by pyrolysising $CH_4$ using catalysts dispersed in acetone and ACF(activated carbon fiber). The as-prepared samples were characterized with transmission electron microscopy(TEM), scanning electron microscopy(SEM). In TEM image, carbon nanofibers were synthesized on the ACF to form a three-dimensional network. Pt/CNF/ACF was employed as a catalyst for PEMFC. As the ratio of prepared catalyst to commercial catalyst was changed from 0 to 50%, the performance of the mixture of 30 wt% of Pt/CNF/ACF and 70wt% of Pt/C commercial catalyst showed better perfromance than that of 100% commercial catalyst. The unique structure of CNF can supply the significant site for the stabilization of Pt particles. CNF/ACF is expected to be promising support to improve the performance in PEMFC.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.165-168
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• 2006

Carbon fiber reinforced polymer(CFRP) have superior mechanical and chemical properties in comparison with conventional materials. And post-tensioning method has been used for structural reinforcement of RC structures due to easy installation and good effect of resisting capacity of structures. But the higher cost of CFRP and the loss of prestressing force with time are considered the major problems to use it. In this study, CFRP Strips and external post tensioning for rehabilitation of old concrete structures were adapted and optimal combination of these methods is considered. A total of 17 concrete members were made and tested. The types and numbers of CFRP strips and post-tensioning types were selected as major test variables. From test results, it is shown that the concrete members that post tensioned and bonded CFRP strips has a pronounced effect on the strength and deformational behavior. This present study indicates that external temporally post tensioning can reduce the amount of CFRP strips required and the combination of temporally post tensioning and CFRP strips may meet the strength and ductility requirements of old structures.

• Proceedings of the Materials Research Society of Korea Conference
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• 2006.11a
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• pp.31.1-31.1
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• 2006

• Journal of Radiation Protection and Research
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• v.28 no.3
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• pp.207-213
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• 2003

Carbon-14 is one of the major radionuclides released by CANDU Nuclear Power Plants(NPPs). It is almost always emitted as gas through the stack. From CANDU NPPs about 95% of all carbon-14 is released as carbon dioxide. Carbon-14 is a low energy beta emitter which, therefore, gives only a small skin dose from external radiation. As carbon dioxide Is physiologically rather inert gases for man's metabolism, the inhalation dose is probably less than 1 % of the ingestion dose. But this source of carbon-14, formed in a closed, nor-oxidative environment, was subsequently released into the workplace as an insoluble particulate when these systems were opened lip for re-tubing at CANDU NPPs. As a part of the improvement of dosimetry program at Wolsong Nuclear Power Plants, the carbon-14 metabolism based on references was investigated and studied to setup the internal dosimetry program due to inhalation of carbon-14.