• 대한환경공학회지
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• 제35권9호
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• pp.675-680
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• 2013

본 연구는 도시하수에서 퍼클로레이트 분해의 잠재성을 알아보기 위해 수행되었다. 3 L 생하수를 포함하는 플라스크를 이용한 실험이 수행되었다. 하수에 일정농도의 퍼클로레이트와 다양한 첨가물이 혼합되었다. 하수에서 퍼클로레이트의 제거가 일어났으나, 교반 72시간 동안 0에서 72%의 매우 다양한 제거율을 보였다. 퍼클로레이트로 순응된 미생물의 미량(167 mg/L SS) 주입만으로도 퍼클로레이트 분해 지체시간은 현저하게 감소되었으며 하수에서 퍼클로레이트가 완전히 제거되었다. 용존산소농도가 2 mg/L 이상 그리고 염분농도가 비교적 높은(전기전도도 14 mS; TDS 8 g/L) 조건의 하수/brine 혼합수에서 퍼클로레이트 제거는 방해를 받았다. 퍼클로레이트와 질산염이 공존하는 하수/brine 혼합실험에서 퍼클로레이트 환원에 비해 질산염 환원이 우선적으로 진행되었으며, 초기 질산성 질소의 약 66%에 해당되는 많은 양의 아질산염이 축적되었다.

• 한국안전학회지
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• 제26권3호
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• pp.15-22
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• 2011

Explosion and fire cause about 30 reported industrial major accidents a year by ignition source which discharge of electrostatic generated to flammable gas, vapor, dust and mixtures. It brings economically and humanly very large loss that accident was caused by fire and explosion from electrostatic discharge. Thus, it is very important that electrostatic discharge energy is to be control below not to be igniting flammable mixtures. There are two kinds of analysis model for electrostatic discharge, human body model and machine model. Human body model is available the parameter of human's electrical equivalent that capacitance is 100 pF, resistance is $1.5k{\Omega}$. To simulate and visualize the electrostatic discharge from human body need a very expensive and high voltage simulator. In this paper, we measured the value of capacitance and resistance concerned with test materials and sizing of specimen and the value of charged voltage concerned with test specimen and distance to develop an electrostatic charge/discharge simulating tool for teaching with which concerned industrial employee and students. The result of experiments, we conformed that the minimum ignition energy of methane-oxygen mixtures meets well the equation $W=1/2CV^2$, and found out that the insulating material and sizing of equivalent value having human body mode are the poly ethylene of 200 mm and 300 mm of diameter. Developed electrostatic charge/discharge simulating tool has many merits; simple mechanism, low cost, no need of electric power and so on.

• Mass Spectrometry Letters
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• 제2권3호
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• pp.65-68
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• 2011

The effects of column length and particle size on the efficiency of separation and characterization of phospholipids (PLs) are investigated using nanoflow liquid chromatography-electrospray ionization-tandem mass spectrometry (nLC-ESI-MS-MS). Since PLs are associated with cell proliferation, apoptosis, and signal transduction, it is of increasing interests in lipidomics to establish reliable analytical methods for the qualitative and quantitative profiling of PLs related to biomarker development in adult diseases. Due to the complexity of PLs, the preliminary separation of PLs is necessary prior to MS analysis. In this study, length of capillary column and the particle size of reversed phase ($C_{18}$) packing materials are varied to find a reliable condition for the high speed and high resolution separation using 8 PL standard mixtures. From experiments, it was found that a capillary column of nLC-ESI-MS-MS analysis for PL mixtures can be minimized to a 5 cm long pulled tip column packed with 3 ${\mu}m$ $C_{18}$ particles without losing resolution.

• KSBB Journal
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• 제13권5호
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• pp.615-620
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• 1998

The readily fermentable carbon sources in swine were acetic acid, propionic acid and butyric acid at the average concentrations of 7.2 g/L, 2.2 g/L and 2.7 g/L, respectively. The swine waste also contained excess nitrogen and other mineral sources. In shake flask experiments, the optimal range of cell growth for Azotobacter vinelandii UWD were 1.0∼3.5 g/L of acetic acid, 0.7∼2.0 g/L of propionic acid and 0.5∼2.0 g/L of butyric acid. A mixture of these three acids simulating two times diluted swine waste supported the best cell growth but the amount of carbon sources was limited. In shake flask and fermentor experiments, an addition of 30 g/L of glucose increased the final cell dry weight 8 times while the final poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) concentration increased 86 times compared with using acid mixture only. A. vinelandii UWD preferred organic acids in the sequence of acetic acid, propionic acid, butyric acid, and valeric acid.

• 한국도로학회논문집
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• 제4권3호
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• pp.43-49
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• 2002

국내 아스팔트 포장은 중차량 교통량의 증가와 겨울철 및 여름철의 온도차이가 크게나는 환경조건하에서 공용되고 있다. 이러한 요인으로 인하여 포장 조기파손의 대부분인 소성변형의 문제점이 심각하며, 이에 대한 개선책으로 개질 아스팔트의 적용에 대한 연구들이 활발하게 진행되고 있다. 그러나, 대부분의 개질 아스팔트의 사용이 표층을 절삭하고 택코팅후 시공되고 있으며, 신설도로의 포장이 아닌 유지보수에서 많이 사용되고 있다. 본 연구는 부산지방국토관리청 산하의 신설국도의 도로포장현장에 개질 아스팔트 혼합물이 적용된 기층 위에 표층용 개질 아스팔트인 SBS PMA 혼합물과 PSMA 혼합물에 대하여 2차로로 200m를 시험 시공하였으며. 나머지 구간은 일반밀입도 아스팔트 혼합물로 시공하였으며, 시공에 사용된 재료에 대한 실내시험을 통한 공용성 및 장기 공용성 평가를 실시하고자 하였다. 실내 실험은 마샬안정도시험, 강도시험과 휠트랙킹 시험을 하여 분석하였으며, 현장의 시험 시공시 온도관리 및 평탄성에 대한 평가를 기초로 향후 장기 공용성 평가와 LCC 분석을 실시하여 가장 경제적인 개질 아스팔트를 평가하여 설계에 반영하고자 한다.

• 토지주택연구
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• 제11권2호
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• pp.95-104
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• 2020

This study aims to explore a purely mechanistic pavement analysis approach where viscoelasticity and fracture of asphalt mixtures are considered to accurately predict deformation and damage behavior of flexible pavements. To do so, the viscoelastic and fracture properties of designated pavement materials are obtained through experiments and a fully mechanistic damage analysis is carried out using a finite element method (FEM). While modeling crack development can be done in various ways, this study uses the cohesive zone approach, which is a well-known fracture mechanics approach to efficiently model crack initiation and propagation. Different pavement configurations and traffic loads are considered based on three main functional classes of roads suggested by FHWA i.e., arterial, collector and local. For each road type, three different material combinations for asphalt concrete (AC) and base layers are considered to study damage behavior of pavement. A concept of the approach is presented and a case study where three different material combinations for AC and base layers are considered is exemplified to investigate progressive damage behavior of pavements when mixture properties and layer configurations were altered. Overall, it can be concluded that mechanistic pavement modeling attempted in this study could differentiate the performance of pavement sections due to varying design inputs. The promising results, although limited yet to be considered a fully practical method, infer that a few mixture tests can be integrated with the finite element modeling of the mixture tests and subsequent structural modeling of pavements to better design mixtures and pavements in a purely mechanistic manner.

• Korean Chemical Engineering Research
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• 제62권1호
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• pp.27-35
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• 2024

메탄, 프로판 등을 주성분으로 하는 연료가스는 폭발위험장소에서 사용될 수 있으며, 누출로 인한 공정조건의 영향으로 불균일한 혼합기를 형성할 수 있다. 균일한 혼합기를 대상으로 측정된 문헌 데이터를 이용한 화재 폭발 위험성 평가, 손상 예측은 가스 누출에 의한 실제 폭발 사고와 다른 결과를 얻을 수 있다. 본 연구에서는 가스 누출시 나타날 수 있는 농도 변화에 있어서 불균일성 혼합기의 폭발압력, 화염속도 등의 폭발특성을 조사하였다. 길이 0.82 m의 스테인리스 재질의 밀폐 배관에서 수행하였으며 컬러 초고속 카메라 및 압력 센서를 사용하여 관찰하였다. 또한 배관 내의 시간에 따른 농도차이 변화에 대해 회귀분석 모델을 사용하여 불균일 혼합물의 정량화 방법을 제안하였다. 본 연구의 농도 불균일성 조건에 있어서 메탄 폭발 시 전파화염은 불균일성 농도가 높아짐에 따라 화염 면적의 증가가 관찰되었고 이는 난류 화염의 주름진 화염 구조와 유사하였다. 메탄의 최대압력까지 걸리는 소요시간은 불균일성이 클수록 감소하였고, 폭발압력은 불균일성이 클수록 증가하였다. 농도가 불균일한 메탄의 K_G(폭연지수)의 범위는 1.30~1.58 [MPa·m/s]으로서 메탄의 농도가 균일성에서 불균일성로 변화하면서 17.7% 증가하였다.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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• pp.71-77
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• 2008

Microstructural changes may arise due to the particle vanishing, fluid diffusion, heating, etc. This study focuses on the changes in small-strain shear stiffness in k0 loading produced by local straining in particular system made of sand-salt mixtures. Local strains were induced by dissolution of salt particles. Experiments were carried out in a conventional oedometer cell equipped with bender elements. Axial displacement and shear wave signals are recorded at each loading stage and during saturation process. Experimental data showed that microstructural changes due to particle vanishing were clearly captured by using shear wave measurement. Saturation of sand-salt mixture at a larger axial stress did not always create a more condense soil at the end of loading stage. Sand-salt mixture is useful for laboratory test on controlled artificial specimen.

• 대한화학회지
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• 제26권1호
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• pp.24-30
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• 1982

란탄족 화합물인 Ln$(fod)_3$ (Ln = Pr, Nd, Eu 및 Yb)를 사용하여 contact-only (COM) 및 dipolar-only (DOM) 2성분계 혼합물을 만든 후 기질인 4-picoline의 $F_i$ 및 $G_i$값을 핵자기공명 이동으로 부터 측정하였다. 그 결과 Pr$(fod)_3$ 및 Eu$(fod)_3$의 혼합물인 COM 1 및 DOM 1으로 얻은 값들을 단일 Ln$(fod)_3$로 얻은 값들과 잘 일치하였다. 그러나 $(fod)_3$ 및 Yb$(fod)_3$의 혼합물인 COM 2 및 DOM 2로 얻을 값들을 단일 Ln$(fod)_3$로 얻은 값들과 상당한 오차를 나타내었다. 그 오차는 이테르븀(Yb) 착물에 기인하는 것으로 추정되었다.

• Asian-Australasian Journal of Animal Sciences
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• 제25권10호
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• pp.1404-1410
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• 2012

In vitro experiments were conducted to evaluate the suitability of several mixtures of high tanniniferous non legumes with low tanniniferous legumes on in vitro gas production (IVGP), dry matter degradation, Ammonia-N, methane production and microbial population. Eight treatments were examined in a randomized complete block design using four non-legumes and two legumes (Carallia integerrima${\times}$Leucaena leucocephala (LL) (Trt 1), C. integerrima${\times}$Gliricidia sepium (GS) (Trt 2), Aporosa lindeliyana${\times}$LL (Trt 3), A. lindeliyana${\times}$GS (Trt 4), Ceiba perntandra${\times}$LL (Trt 5), C. perntandra${\times}$GS (Trt 6), Artocarpus heterophyllus${\times}$LL (Trt 7), A. heterophyllus${\times}$GS (Trt 8). The condensed tannin (CT) content of non legumes ranged from 6.2% (Carallia integerrima) to 4.9% (Ceiba perntandra) while the CT of legumes were 1.58% (Leucaena leucocephala) and 0.78% (Gliricidia sepium). Forage mixtures contained more than 14% of crude protein (CP) while the CT content ranged from 2.8% to 4.0% respectively. Differences (p<0.05) were observed in in vitro gas production (IGVP) within treatments over a 48 h period dominated by C. perntandra${\times}$G. sepium (Trt 6). The net gas production (p<0.05) was also high with Trt6 followed by A. heterophyllus${\times}$L. leucocephala (Trt 7) and A. heterophyllus${\times}$G. sepium (Trt 8). Highest (p>0.05) NH3-N (ml/200 mg DM) production was observed with the A. heterophyllus${\times}$G. sepium (Trt 8) mixture which may be attributed with it's highest CP content. The correlation between IVGP and CT was 0.675 while IVGP and CP was 0.610. In vitro dry matter degradation (IVDMD) was highest in Trt 8 as well. Methane production ranged from 2.57 to 4.79 (ml/200 mg DM) to be synonimous with IVGP. A higher bacteria population (p<0.05) was found in C. perntandra${\times}$G. sepium (Trt 6) followed by Artocarpus heterophyllus+G. sepium (Trt 8) and the same trend was observed with the protozoa population as well. The results show that supplementing high tannin non leguminous forages by incremental substitution of legume forage increased gas production parameters, NH3-N, IVDMD and microbial population in the fermentation liquid. Methane production was not significantly affected by the presence of CT or different levels of CP in forage mixtures. Among non legumes, Ceiba perntandra and Artocarpus heterophyllus performed better in mixture with L. leucocephala and G. sepium.