• 한국안전학회지
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• 제17권2호
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• pp.39-44
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• 2002

This study was investigated the thermal decomposition characteristics of azo type sponge blowing agent azodicarbonamide(ADCA) using differential scanning calorimeter(DSC). The experimental results showed that the exothermic onset $temperatures(T_{o})$ for ADCA were about $201{\sim}206^{\circ}C$ and evolution heats(Q) were about $144{\sim}150cal/g$. The exothermic onset $temperatures(T_{o})$, exothermic maximum $temperature(T_{m})$ and exothermic final $temperature(T_{f})$ were decreased by decreasing particle size of ADCA and evolution heats(Q) were increased with it. $T_{o}$ and Q for $6.1{\sim}7.2{\mu}m$ ADCA were increased by increasing heating rate at constant sample weight and activation energy was about 37.29kcal/mol. A positive gas pressure was employed in the elucidation of the decomposition behavior of ADCA because it sublimes during linear heating at atmospheric pressure. $T_{o}$ and Q of ADCA tended to increase with a pressure in air or nitrogen. In the case of azo dye, experimental results showed that $T_{o}$ were about $280{\sim}420^{\circ}C$ and Q were about $2{\sim}30cal/g$.

• 한국안전학회지
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• 제16권2호
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• pp.75-79
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• 2001

For handling and storage of reactive chemicals, the hazard evaluations have been extremely important. In the chemical industry, the most concerns are focused on the thermal harzards such as runaway reactions and thermal decompositions, which are mostly governed by thermodynamics and reaction kinetics or these reactive chemical in the system. This study no investigated the thermal decomposition characteristics of nitrophenylhydrazine isomers by using differential scanning calorimeter(DSC) and accelerating rate calorimeter(ARC). Experimental results showed that exothermic onset-temperatures in nitrophenylhydrazine(NPH) isomers were about 160-$210^{\circ}C$ by DSC and 100-$150^{\circ}C$ by ARC. The decomposition temperature acquired by ARC was about 50-$60^{\circ}C$ lower than that by DSC. Reaction heats were about 40-100cal/g by DSC and 330-750ca1/g by ARC. While ortho isomer of NPH show two distinct exothermic peaks, para isomer shows a single peak in DSC curves. The first exothermic peak for 2-NPH is mainly due to intramolecular dehydration forming 1-hydroxybenzotriazole(HOBT) and the second exothermic peak is mainly due to the decomposition of HOBT formed in the first step of decomposition. The exothermin peak in the DSC curve for 4-NPH is mainly due to dissociation of hydrazino and nitro groups.

• Archives of Metallurgy and Materials
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• 제64권3호
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• pp.931-934
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• 2019

Al-CuO is a thermite material exhibiting the exothermic reaction only when aluminum melts. For wide spread of its application, the reaction temperature needs to be reduced in addition to the enhancement of total reaction energy. In the present study, a thermite nanocomposite with a large contact area between Al and CuO was fabricated in order to lower the exothermic reaction temperature and to improve the reactivity. A cryomilling process was performed to achieve the nanostructure, and the effect of composition on the microstructure and its reactivity was studied in detail. The microstructure was characterized using SEM and XRD, and the thermal property was analyzed using DSC. The results show that as the molar ratio between Al and CuO varies, the fraction of uniform nanocomposite structure was changed affecting the exothermic reaction characteristics.

• 한국전기전자재료학회논문지
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• 제35권1호
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• pp.37-43
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• 2022

In this study, we investigated the optical, electrical and exothermic characteristics of ITO/Ag/ITO multilayer structures prepared with various Ag thicknesses on quartz and PI substrates. The transparent conducting properties of the ITO/Ag/ITO multilayer films depended on the thickness of the mid-layer metal film. The ITO/Ag (14 nm)/ITO showed the highest Haccke's figure of merit (FOM) of approximately 19.3×10^-3 Ω^-1. In addition, the exothermic property depended on the substrate. For an applied voltage of 3.7 V, the ITO/Ag (14 nm)/ITO multilayers on quartz and PI substrates were heated up to 110℃ and 200℃, respectively. The bending tests demonstrated a comparable flexibility of the ITO/Ag/IT multilayer to other transparent electrodes, indicating the potential of ITO/Ag/ITO multilayer as a flexible transparent conducting heater.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제53권1호
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• pp.1-7
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• 2004

This paper describes the carbonization characteristics of a phenolic resin deteriorated by tracking under the environment of a fire. In the experiment, a liquids droplet of 1[％] NaCl was dripped on the phenolic resin to cause a tracking with 110[V], 220[V] voltages applied. It can be addressed from the experimental results that when an insulator is carbonized by an external fire, its structure is amorphous. If an insulator is carbonized by electrical cause, on the other hand, its structure would be crystalline. In order to observe the surface change of the phenolic resin, the tracking process was analyzed by using SEM. In the case that the materials are carbonized under heat or fire, the exothermic peak appears around 500[$^{\circ}C$]. This is one of the important factors to determine the cause of fires. As a result of DTA, the exothermic peaks of an untreated sample showed at 333.4[$^{\circ}C$], 495.7[$^{\circ}C$] but those of a sample deteriorated by tracking appeared at 430.6[$^{\circ}C$], 457.6[$^{\circ}C$] in a voltage of 110[V], and at 456.2[$^{\circ}C$], 619.7[$^{\circ}C$] in a voltage of 220[V]. It is possible, therefore, to distinguish a virgin sample from carbonized samples(graphite) by the exothermic peak.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.509-512
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• 2004

This research is targeting that estimate the effect on cement concrete pavement with type of chloride deicers. In order to this study objective, when chloride deicers were spread on road surface, thermal characteristics test was conducted. Also, skid resistance test according to types and concentration of chloride deicier, road surface conditions were investigated. As a test results, thermal characteristics with kind of chloride deicier could know that sodium chloride(NaCl) is exothermic reactive material, calcium chloride$(CaCl_2)$ is endothermic reactive material. And, in case of mixed salt of the calcium and sodium chloride, it could know that can change to the exothermic or endothermic reaction according to dosage ratios. Skid value by British Pendulum Tester(BPT) has shown that it is seldom difference between the types($CaCl_2$, NaCl, mixed salt) and solution concentrations(0.5, 0.8, 1.0, 4.0, $10\%$) of chloride deicier comparing with tap water except mixed salt($10\%$ solution concentration).

• 한국화재소방학회논문지
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• 제34권1호
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• pp.66-71
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• 2020

리튬-이온 배터리를 폐기하는 방법으로 흔히 사용되고 있는 염수를 이용한 방전 방법은 자칫 화재로 이어질 개연성이 있음에도 불구하고 배터리의 염수 방전 과정의 화재 위험성에 대한 연구는 많지 않다. 본 연구에서는 리튬-이온 배터리 중 휴대폰 배터리를 대상으로 하여 염수에 배터리를 담가 방전 시킬 때 방전특성과 발열에 의한 화재 발생 가능성을 확인하고자 염수농도와 배터리의 개수를 변화시킨 여러 조건에서 실험을 수행하였다. 각 조건에서 방전전압 및 배터리의 발열온도를 측정하여 방전 과정 및 발열에 의한 화재 위험성을 예측하였다. 실험 결과로는, 염수농도가 높을수록 휴대폰 배터리의 방전이 더 잘 되었으며, 발열온도 또한 높게 측정 되었고, 염수에 침수된 배터리 1개의 발열온도보다 중첩된 배터리의 발열온도가 더 높게 측정되었다. 또한, 배터리의 가장 높은 발열이 발생하는 부분은 (+),(-)전극에서 발생하는 것을 알 수 있었다.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 2003년도 춘계학술논문발표회논문집
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• pp.164-170
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• 2003

In this paper, we studied on the firing characteristics and electrical fire analysis of power cord deteriorated by thermal stress. The cross section of PVC insulating cord deteriorated by indirect flame decreased through heat convection. PVC insulating cord deteriorated by direct flame was bumpy shape. The exothermic peak of normal cord was shown at ($526.7^{\circ}C$), but the peaks or on(heat treatment temperature) ($150^{\circ}C$) cord was shown at ($299.6^{\circ}C$) and [$502.2^{\circ}C$]. The exothermic peaks according to high temperature were similar to those of amorphous carbon. In the FT-IR analysis, the absorption peak of normal cord indicated double bond of oxygen and carbon in benzene ring at 1720.0$cm^{1}$. As the HTT was high, the height of characteristic peak decreased and the peak of carbonyl group was shown at about 1625.7$cm^{-1}$. The characteristic peak of single bond(O-H) was shown at about 3479.2$cm^{-1}$. In case of the internal part of wire covering deteriorated by over current, the characteristic peak were shown at about 3417.3$cm^{-1}$ and 1600.2$cm^{-1}$. The above results show that we can distinguish the differences according to the fire pattern through the internalㆍexternal analysis of wire covering deteriorated by heat.

• 한국화재소방학회논문지
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• 제17권4호
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• pp.13-19
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• 2003

본 논문은 누전차단기 외함 전원측 단자사이에서 발생하는 전기화재 원인에 대한 분석을 연구하였다. 누전차단기는 보호범위의 전기시설물에서 누전 또는 과부하에 의한 차단을 목적으로 한다 누전차단기의 전원측 단자는 트래킹에 의해 화재로 쉽게 이어질 수 있다. 따라서, 누전차단기의 재현실험을 통해 트래킹시료($E_1$)와 화재현장에서 트래킹된 것($S_1$)을 비교분석하여 전기화재의 원인을 밝히는데 중요한 자료가 되도록 하였다. 실험은 IEC Publ. 112법을 응용하여 실시하였고 누전차단기에서 미소방전과 건조대가 발생한 후 소손되는 것을 확인하였다. $_1$에서 전원측 단자간의 절연저항은 약 25.7Ω이고 $S_1$의 절연저항은 약 58.6Ω이었다. $E_1$의 발열피크는 $491.0^{\circ}C$와 $603.2^{\circ}C$였다. $603.2^{\circ}C$에서의 발열피크는 트래킹에 의한 것이다. $S_1$의 발열피크는 $593.1^{\circ}C$에서 나타났다. 트래킹에 의해 변화된 시료는 IR 흡수스펙트럼에서 $1590 cm^{-1}$ 에서 흡광피크가 나타나지 않았다.

• 한국안전학회지
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• 제25권3호
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• pp.61-65
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• 2010

Most of the chemical reactions performed in the chemical industry are exothermic, meaning that thermal energy is released during the reaction. It is also important to understand the thermal hazards such as thermal stabilities and runaway reactions, which are governed by thermodynamics and reaction kinetics of the mixed materials. The paper was described the evaluation of thermal behavior caused by an exothermic batch process in manufacture of the vinyl acetate resin. The aim of the study was to evaluate the thermal stabilities of raw materials with operating conditions such as a reaction inhibitor, heating rate, reaction atmosphere and the mount of methanol charged in the vinyl acetate polymerization process. The experiments were performed in the differential scanning calorimeter(DSC), C 80 calorimeter, and thermal screening unit($TS^u$). It was suggested that we should provide the thermal characteristics for raw materials to present safe precautions with operating conditions in the vinyl acetate polymerization process.