• 제목/요약/키워드: Existence of solution

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Structural and Molecular Characterization of Extracellular Polysaccharides Produced by a New Fungal Strain, Trichoderma erinaceum DG-312

  • JOO JI-HOON;YUN JONG-WON
    • Journal of Microbiology and Biotechnology
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    • v.15 no.6
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    • pp.1250-1257
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    • 2005
  • Two groups of exopolysaccharides (designated as Fr-I EPS and Fr-II EPS) were isolated from the culture filtrate of new fungal strain Trichoderma erinaceum DG-312 by Sepharose CL-6B chromatography. The structures of the exopolysaccharides were investigated using gas chromatography (GC), Fourier transform-infrared (FT-IR) spectroscopy, GCMS analysis, and NMR. GC analysis indicated that Fr-I EPS was composed of mainly mannose ($78.9\%$) and galactose ($21.1\%$), whereas Fr-II EPS contained mannose ($68.4\%$), galactose ($26.2\%$), and glucose ($5.4\%$). In the anomeric region ($950-700cm_{-1}$) of the FT-IR spectrum, both EPSs exhibited obvious characteristic absorption of $810\;cm_{-1}$, indicating the existence of mannose. The spectra of $\alpha-and\;\beta$-configurations were assigned at 880 and $914\;cm_{-1}$, respectively. The results of GC-MS analyses confirmed that both EPSs were complex heteropolysaccharides with a ($1{\rightarrow}3$)-linked mannan backbone. The C-1 region that appeared in the $^{13}C-NMR$ spectra of these EPSs indicated a typical anomeric carbon signal. The Fr-I EPS showed two anomeric carbon signals at 102.6 and 99.6 ppm, whereas the Fr-II EPS displayed four anomeric carbon signals at 102.5, 99.6, 98.5, and 94.3 ppm. The molecular characteristics of the EPSs were further investigated using a size exclusion chromatography/multi-angle laser light scattering (SEC/MALLS) system. The SEC/MALLS system revealed that the average molar masses of the EPSs were $6.592{\times}10^{4}$ (Fr-I EPS) and $1.920{\times}10^{4}$ (Fr-II EPS) g/mol, and the molecular conformation of both EPSs in aqueous solution was random coils.

Radiation Grafting of Hydrophilic Monomers onto Polyester

  • Park, Jae-Ho;Lee, Chong-Kwang;Lee, Kwang-Jin
    • Nuclear Engineering and Technology
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    • v.5 no.2
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    • pp.103-114
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    • 1973
  • Radiation grafting of acrylic acid and 4-vinylpyridine at room temperature has been studied by an impregnation method to improve the hygroscopic properties, the antistatic behavior and the dyeability of polyester fabric. Polyester fabric was impregnated with acrylic acid or aqueous emulsion of acrylic acid-4-vinylpyridine by immersion at 25$^{\circ}$or 7$0^{\circ}C$. The impregnated fabric was irradiated under nitrogen gas with ${\gamma}$-rays from Co-60. When acrylic acid grafted polyester fabric was treated with sodium carbonate, calcium acetate and potassium persulfate, tne rate of water absorption was increased and most parts of polyacrylic acid formed were extracted off from the fabric with 0.1% solution of sodium hydroxide at 10$0^{\circ}C$. In the case of the impregnation of a mixture of acrylic acid and 4-vinylpyridine the petcent of grafting has been shown to be proportional to the ratio of 4-VP/AA and radiation dost. Estimating by contact angle measurements of water on the various polymer surfaces, the antistatic behavior was decreased with the increase of grafting percent. The investigation of electron micrograph disclosed the existence of certain type of discontinuities in the acrylic acid grafted polyester fiber which was treated with various salts.

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The Analytic and Numerical Solutions of the 1$\frac{1}{2}$-layer and 2$\frac{1}{2}$-layer Models to the Strong Offshore Winds.

  • Lee, Hyong-Sun
    • Journal of the korean society of oceanography
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    • v.31 no.2
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    • pp.75-88
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    • 1996
  • The analytic and numerical solution of the 1$\frac{1}{2}$-layer and 2$\frac{1}{2}$-layer models are derived. The large coastal-sea level drop and the fast westward speed of the anticyclonic gyre due to strong offshore winds using two ocean models are investigated. The models are forced by wind stress fields similar in structure to the intense mountain-pass jets(${\sim}$20 dyne/$cm^{2}$) that appear in the Gulfs of Tehuantepec and Papagayo in the Central America for periods of 3${\sim}$7 days. Analytic and numerical solutions compare favorably with observations, the large sea-level drop (${\sim}$30 cm) at the coast and the fast westward propagation speeds (${\sim}$13 km/day) of the gyres. The coastal sea-level drop is enhanced by several factors: horizontal mixing, enhanced forcing, coastal geometry, and the existence of a second active layer in the 2$\frac{1}{2}$-layer model. Horizontal mixing enhances the sea-level drop because the coastal boundary layer is actually narrower with mixing. The forcing ${\tau}$/h is enhanced near the coast where h is thin. Especially, in analytic solutions to the 2$\frac{1}{2}$-layer model the presence of two baroclinic modes increases the sea-level drop to some degree. Of theses factors the strengthened forcing ${\tau}$/h has the largest effect on the magnitude of the drop, and when all of them are included the resulting maximum drop is -30.0 cm, close to observed values. To investigate the processes that influence the propagation speeds of anticyclonic gyre, several test wind-forced calculations were carried out. Solutions to dynamically simpler versions of the 1$\frac{1}{2}$-layer model show that the speed is increased both by ${\beta}$-induced self-advection and by larger h at the center ofthe gyres. Solutions to the 2$\frac{1}{2}$-layer model indicate that the lower-layer flow field advects the gyre westward and southward, significantly increasing their propagation speed. The Papagayo gyre propagates westward at a speed of 12.8 km/day, close to observed speeds.

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Effect of Solvent Content on Morphology and Rubber Particle Size Distribution of High Impact Polystyrene (용매 함량이 내충격성 폴리스티렌의 형태구조 및 고무 입도분포에 미치는 영향)

  • 정한균;박정신;장대석;이성재
    • Polymer(Korea)
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    • v.26 no.3
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    • pp.307-315
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    • 2002
  • Major factors affecting the impact resistance of high impact polystyrene (HIPS), the rubber-toughened grade of polystyrene, are rubber-phase particle size and size distribution, molecular weight, morphology, and degree of grafting. Accordingly, it is important to control or investigate these factors. In this study, the effect of solvent content was analyzed by the morphology and particle size distribution of rubber phase, and final properties in bulk-solution polymerization of HIPS. The prepolymerization time was, first, determined by measuring the evolution of particle size distribution of dispersed phase to explain the phase inversion with time. As the solvent content increased, the size of rubber particle increased and then gradually decreased. Rubber-phase morphology was likely to have higher degree of grafting as the solvent content increased. Rheological and mechanical properties decreased as the solvent content increased because of the decrease of matrix molecular weight due to the chain transfer reaction to solvent and the existence of residual solvent. Nevertheless, the impact resistance seemed to increase when the rubber particle size increased.

"Knownism"-Bridge-Building Philosophy Between Science and Religion (가지론("Known 사상")-과학과 종교의 가교)

  • 김항묵
    • Journal of the Korean Professional Engineers Association
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    • v.21 no.2
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    • pp.51-57
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    • 1988
  • The writer has worked out his original philosophy both scientific and religious, which he calls "Knownism" The new thought states; the word "known" in "knownism" means "already well-informed in the providence" about the essence of the things, and the true state of the reality, hence the knownism, as the existence of God is set forth as a premise. The knownism is a philosophy unified reasonably the science and the faith into one, for the humans can perceive and realize the essence and the true state, and authorize the truth transcending the experience by the scientific method. The new thought of the knownism is a bridge-building between the natural science and the religious faith. The idea explains that the life is the process to pursue the essence of the things and the god, and the truth is immanent in the original nature of things and in God′s sphere. This thought is a philorophy of possibility to solve the paradigms-to-be such as thinking, faith experience, and supernatural power, so that it presents a vision in the human life as a profitable religious science philosophy. The knownism is much different from agnosticism, skepticism, empiricism, and agnosticism. The grace of God may be detected differently from the supernatural power. The new dark clouds overspread abruptly the summer sky are not new ones but originally derived frosm worn-out water drops. Thus those are called the old clouds. The Korean word "known"(노운) of which pronunciation is same with the English "known" means the old clouds, hence also the name, Knownism. The root of the new clouds is detectable from the preserved old clouds. The old clouds symbolized in the paper indicate the essence and the principles of the things and the fittest, or the key for the solution of the problem in the epistemology, believing that everything has its own, proper nature, the writer sums up his theory by insisting that the humans have to find out the "old clouds" or the "known" in knownism to live eternally either in this world or in other dimensions, though the human beings are transformed into the other phases of life. The writer proclaims through the ideas for the United Nations to fortify the Confederate System of World Nations in order to ensure the world peace and the future of the humans.

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Flow of Non-Newtonian Fluids in an Annulus with Rotation of the Inner Cylinder (안쪽축이 회전하는 환형관내 비뉴튼유체 유동 연구)

  • 김영주;우남섭;황영규
    • Tunnel and Underground Space
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    • v.12 no.4
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    • pp.277-283
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    • 2002
  • This experimental study concerns the characteristics of a helical flow in a concentric annulus with a diameter ratio of 0.52, whose outer cylinder is stationary and inner one is rotating. The pressure losses and skin friction coefficients have been measured for the fully developed flow of Non-Newtonian fluid, aqueous solution of sodium carbomethyl cellulose (CMC) and bentonite with inner cylinder rotational speed of 0~400 prm. Also, the visualization of helical flows has been performed to observe the unstable waves. The results of present study reveal the relation of the Reynolds number Re and Rossby number Ro with respect to the skin friction coefficients. In somehow, they show the existence of flow instability mechanism. The pressure losses increase as the rotational speed increases, but the gradient of pressure losses decreases as the Reynolds number increases in the regime of transition and turbulence. And the increase of flow disturbance by Taylor vortex in a concentric annulus with rotating inner cylinder results in the decrease of the critical Reynolds number with the increase of skin friction coefficient.

Preparation and Characterization of Multiferroic $0.7BiFeO_3-0.3BaTiO_3$ Thin Films by Pulsed Laser Deposition (펄스 레이저 증착법으로 제작된 다강체 $0.7BiFeO_3-0.3BaTiO_3$ 박막의 특성 연구)

  • Kim, Kyung-Man;Yang, Pan;Zhu, Jinsong;Joh, Young-Gull;Lee, Hee-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.88-88
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    • 2009
  • $BiFeO_3$(BFO), when forming a solid solution with $BaTiO_3$(BTO), shows structural transformations over the entire compositional range, which not only gives a way to increase structural stability and electrical resistivity but also applies a means to have better ferromagnetic ordering. In this respect, we have prepared and studied 0.7BFO-0.3BTO thin films on $Pt(111)/TiO_2/SiO_2/Si$ substrates by pulsed laser deposition. Various deposition parameters, such as deposition temperature and oxygen pressure, have been optimized to get better quality films. Based on the X-ray diffraction results, thin films were successfully deposited at the temperature of $600^{\circ}C$ and an oxygen partial pressure of 10mTorr. The dielectric, ferroelectric, and magnetic properties have then been characterized. It was found that the films deposited under lower oxygen pressure corresponded to lower leakage current. Magnetism measurement showed an induced ferromagnetism. The microstructures associated with. the magnetic and dielectric properties of this mixed-perovskite solid solutions were observed by transmission electron. microscopy, which revealed the existence of complicated ferroelectric domains, suggested that the weak spontaneous magnetization was closely associated with the decrease in the extent of rhombohedral distortion by a partial substitution of $BaTiO_3$ for $BiFeO_3$.

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A Study on the melting Characteristics of Fuse Element by Repeating Overcurrent (반복과전류에 의한 퓨즈 엘리먼트의 용단특성에 관한 연구)

  • Kim, Youn-Hyun
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.2
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    • pp.120-126
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    • 2010
  • This paper propose analysis and examination of the melting characteristic of fuse elements by repeating overcurrent as a depletion factor of high pressure current limiting fuse through test following existence and nonexistence of extinction material and various configuration of elements. To examine deterioration progress rate by repeating overcurrent we analyzed heat for various element notching configuration, designed plate type, ring type element and estimated the relationship with life span by analyzing breaking characteristic through repeating overcurrent test with adjusting load factor at Silicon Dioxide(SiO2) filled state or in air. A Crack by repeat stress, decrease of section and transformation by friction with extinction material by repeating overcurrent causes a problem which shortens life span based on fuse repeating frequency. Since the contents of this paper might be useful to research the correlation between friction of materials and repeating life span based on load factor of repeating current, the quality of product would be improved through solution of the problem.

Growth of Axenic Rotifer Brachionus rotundiformis (무균 로티퍼 Brachionus rotundiformis의 증식)

  • Jung, Min-Min;Rho, Sum;Kim, Pil-Yun
    • Journal of Aquaculture
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    • v.11 no.1
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    • pp.91-97
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    • 1998
  • This paper introduces to a simple culture method and growth of axenic (bacteria-free) rotifer Brachionus rotundiformis for seed stock of rotifer mass culture. This rotifer axenic culture method is based on the washing and transferring with sterilized sea water and modified antibiotic mixture AM9 solution. Population growth (final density on day 16) of axenic cultured rotifer were maintained with a high density and stable growth compared with the control of non-axenic culture (general culture style) through the 3 times-rerunning experiments (trial 1, 2 and 3). But the egg carrying rates of amictic females were not different between the axenic-and non-axenic culture condition. Although, rotifer density was higher in axenic culture, the food (Nannochloropsis oculata) was still remained unutilized than that of the non-axenic culture in third trial culture. These results suggest the possible existence of harmful bacteria for the rotifer population growth in the trial 1 and 3 of non-axenic culture compared to the trial 2. This axenic rotifer culture method is valuable for seed stock of the stable rotifer mass cultures.

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PREPARATION AND CHARACTERIZATION OF MULTIFERROIC 0.8 $BiFeO_3$-0.2 $BaTiO_3$ THIN FIMLS BY PULSED LASER DEPOSITION

  • Kim, K.M.;Yang, P.;Zhu, J.S.;Lee, H.Y.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.313-313
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    • 2010
  • $BiFeO_3$ (BFO), when forming a solid solution with $BaTiO_3$ (BTO), shows structural transformations over the entire compositional range, which not only gives a way to increase structural stability and electrical resistivity but also applies a means to have better ferromagnetic ordering. In this respect, we have prepared and studied 0.8 BFO-0.2 BTO thin films on Pt(111)/$TiO_2/SiO_2$/Si substrates by pulsed laser deposition. Various deposition parameters, such as deposition temperature and oxygen pressure, have been optimized to get better quality films. Based on the X-ray diffraction results, thin films were successfully deposited at the temperature of $700^{\circ}C$ and an oxygen partial pressure of 10mTorr and 330mTorr. The dielectric, ferroelectric, and magnetic properties have then been characterized. It was found that the films deposited under lower and higher oxygen pressure corresponded to lower leakage current. Magnetism measurement showed an induced ferromagnetism. The microstructures associated with the magnetic and dielectric properties of this mixed-perovskite solid solutions were observed by transmission electron microscopy, which revealed the existence of complicated ferroelectric domains, suggested that the weak spontaneous magnetization was closely associated with the decrease in the extent of rhombohedral distortion by a partial substitution of $BaTiO_3$ for $BiFeO_3$.

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