• Journal of Korean Society for Atmospheric Environment
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• v.34 no.2
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• pp.223-232
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• 2018

As the Seoul metropolitan city has the largest numbers of population and vehicles, the citizens can be exposed to hazardous air pollutants(HAPs) mainly from the vehicular exhaust and human activities. In this study, we proposed a systematic method for the selection of priority monitoring areas for HAPs using Geographic Information System (GIS). First, emission parameters(emission data, vehicle registration, monitoring data, and so on) and population parameters (population and population density) were plotted using the inverse distance weighted (IDW) interpolation. Then, the interpolation data for individual parameters, which were normalized between 1 and 5 points, were compiled for 270 grids with a resolution of $2km{\times}2km$. The total score of each grid was calculated using weights(1~5) for the individual parameters. The final ranking of each grid was assigned by four scenarios with varying fractions of the emission and population parameters from 50 : 50 to 80 : 20. Consequently, nine grids were suggested as priority monitoring areas, and all of them are located in the southwestern part of Seoul.

• Proceedings of the IEEK Conference
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• 2009.05a
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• pp.347-349
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• 2009

Air quality of indoor space environment is affected by various pollutants like as particles and chemical stuffs. The indoor air pollution affects directly the human respiration organs to cause consequently unpleasant mental status. The $CO_2$ concentration level is one of the harmful components of air pollutants. Major factor to increase the $CO_2$ concentration level is the people's breath amount in indoor. The car exhaust gas diffused from the around road also has strong affect on $CO_2$ concentration. There are some other reasons to affect the $CO_2$ concentration change, such as, real-time change of the population movement, closeness to the indoor air flow inlet window and changes in road car traffic amount. A remote monitoring system to measure environmental indoor air pollution concerning on the $CO_2$ concentration was studied and installed realized set-up model. Zigbee network configuration was applied for this system and the $CO_2$ concentration data were collected through USN network. A software program was developed to assure systematic analysis and to display real-time data on web pages. For the experimental test various condition was set up, like as, window opening, stopping air condition operation and adjusting fan heater work, etc. The analysis result showed the relation of various environmental conditions to $CO_2$ concentration changes. The causes to increase $CO_2$ concentration were experimentally defined as windows closing, the stopping air condition system, fan heater operation. To keep the $CO_2$ concentration under the legally required ppm level in public access indoor space, the developed remote measurement system will be usefully applied.

• Applied Chemistry for Engineering
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• v.29 no.2
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• pp.229-236
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• 2018

A customized cleaning agent was investigated for improving the performance decreased by the pollution of collecting plates in an electric fume collector (EFC) which was developed and applied for the purification of effluent gas including oil mist from the textile industry. The pollutants on the surface of collecting plates were blackened by the condensation of oil mist for a long time and difficult to remove by general cleaning agents. The composition of an optimized cleaning agent consisted of alkali, alcohol, glycol and non-ionic surfactant sources was determined by considering the pollutant properties and effect on the damage of the basic metal of collecting plate and so on. The developed cleaning agent solution diluted by 9.1% was applied to the field test, and also the pollutants strongly adhered on collecting plate surfaces were successfully removed by a simple spraying method. The effluent gas purification efficiency of EFC increased significantly by cleaning of collecting plates.

• Asian Journal of Atmospheric Environment
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• v.2 no.2
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• pp.90-101
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• 2008

The chemical compositions of $PM_{2.5}$ and $PM_{10}$ and associated high-molecular-weight polycyclic aromatic hydrocarbons (PAHs) were investigated during winter and summer at a roadside and an urban background site in Saitama, Japan. The average concentrations of $PM_{2.5}$ exceeded the United States Environmental Protection Agency standards during both periods. Carbonaceous components were abundant in both the observed and calculated (by means of a mass closure model) chemical composition of $PM_{2.5}$. Traffic-related pollutants (elemental carbon and high-molecular-weight PAHs) were strongly associated with $PM_{2.5}$ rather than with larger particles. The mass concentrations of $PM_{2.5}$, as well as those of EC and PAHs associated with the particles, at the two sites were strongly correlated. Comparison of our data with source profile ratios indicates that diesel-powered vehicles were probably the main source of the measured PAHs. The PAHs concentrations were affected by meteorological conditions during our study. Our results highlight the need for the establishment of standards for $PM_{2.5}$ in Japan.

• Clean Technology
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• v.24 no.3
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• pp.212-220
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• 2018

Oxy-fuel combustion is considered as a promising greenhouse gas reduction technology in power plant. In this study, the behaviors of NO and $SO_2$ were investigated under the condition that in-furnace $deNO_x$ and $deSO_x$ methods are applied in oxy-fuel circulating fluidized bed combustion condition. In addition, the generation trends of $SO_3$, $NH_3$ and $N_2O$ were observed. For the purpose, limestone and urea solution were directly injected into the circulating fluidized bed combustor. The in-furnace $deSO_x$ method using limestone could reduce the $SO_2$ concentration in exhaust gas from ~403 to ~41 ppm. At the same experimental condition, the $SO_3$ concentration in exhaust gas was also reduced from ~3.9 to ~1.4 ppm. This trend is mainly due to the reduction of $SO_2$. The $SO_2$ is the main source of the formation of $SO_3$. The negative effect of $CaCO_3$ in limestone, however, was also appeared that it promotes the NO generation. The NO concentration in exhaust gas reduced to ~26 - 34 ppm by appling selective non-catalytic reduction method using urea solution. The $NH_3$ concentration in exhaust gas was appeared up to ~1.8 ppm during injection of urea solution. At the same time, the $N_2O$ generation also increased with increase of urea solution injection. It seems that the HNCO generated from pyrolysis of urea converted into $N_2O$ in combustion atmosphere. From the results in this study, the generation of other pollutants should be checked as the in-furnace $deNO_x$ and $deSO_x$ methods are applied.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.4
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• pp.409-416
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• 2011

A mobile emission laboratory (MEL) was designed to measure the amount of traffic pollutants with high temporal and spatial resolution under real conditions. Equipment for gas-phase measurements of quantity of CO, NOx, $CO_2$, and THC and for the measurement of the number density and size distribution of fine and ultra-fine particles by a FMPS and a CPC were placed in a mini-van. The exhaust of different type of vehicles can be sampled by MEL. This paper describes the construction and technical details of the MEL and presents data from the experiment in which a car chases city buses fuelled by diesel, CNG, and LPG. The diameters of most particles in the exhaust of the diesel city bus were less than 300 nm and most of the particles had a diameter of 30-60 nm. However, most particles in the exhaust of the CNG and LPG city buses were nanoparticles (diameter: less than 50 nm).

• Clean Technology
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• v.20 no.2
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• pp.171-178
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• 2014

In this study we have examined the health risk factors and analyzing data of laborers working at the welding operation at large-sized casting process. In order to improve the working environment of workplace, an effective ventilation method was proposed after performing CFD (computational fluid dynamics) modeling and measurement of pollutants. As a result of examining the health risk factors of workers, oxidized steel dust is the main pollution source in the company A, welding fume in the companies B and C, and welding fume and oxidized steel dust in the company D. The fume concentration in the workers' breathing zone was $0.05{\sim}4.37mg/m^3$, and the fume concentration in the indoor air at the welding process was $0.13{\sim}7.54mg/m^3$. From a result of CFD, a local exhaust with an exhaust duct adjacent to welding point was found to be most effective in case of the exhaust process. In case of air supply, we found that a desired location of air supply fan would be at the end of the opening. If a standardizing the ventilation system for tunnel-type semi-enclosed space at a large-sized casting process is introduced in welding work places in the future, it would be more effective to protect the health of welding workers working at the casting industry and shipbuilding industry and improve the work environment.

• Journal of Environmental Health Sciences
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• v.36 no.5
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• pp.402-410
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• 2010

The objectives of this study were to evaluate the air quality surrounding an indoor swimming pool, to estimate the cancer risk based on the airborne exposure to trihalomethanes (THMs), and to examine the ventilation efficiency by Computational Fluid Dynamics (CFD). Chlorine and THMs were measured poolside, and in the staff room and reception area. The indoor swimming pool was modeled using the Airpak program, with ventilation drawings and actual survey data. Temperature, flow and mean age of the air were analyzed. Levels of chlorine poolside, and in the staff room, and reception area were $203\;{\mu}g/m^3$, $5\;{\mu}g/m^3$, and $10\;{\mu}g/m^3$, respectively. Chloroform was the dominant THM in all sampling sites and mean concentrations were $16.30\;{\mu}g/m^3$, $0.51\;{\mu}g/m^3$, and $0.06\;{\mu}g/m^3$ poolside, in the staff room and reception area, respectively. Bromodichloromethane and Dibromochloromethane levels were respectively estimated as $10.3\;{\mu}g/m^3$ and $1.7\;{\mu}g/m^3$ poolside, $1.3\;{\mu}g/m^3$ and $0.1\;{\mu}g/m^3$ in the staff room, and were not detected in the reception area. The cancer risks from inhalation exposure to THMs were estimated between $3.37{\times}10^{-7}$ and $1.84{\times}10^{-5}$. A short circulation phenomenon was observed from the supply air vents to the exhaust air vents located in the ceiling. A high temperature layer was formed within one meter of the ceiling, and a low temperature layer was formed under this layer due to the low velocity and high temperature of the supply air, and the improper locations of the supply air vents and exhaust air vents. The stagnation was evident at the above adult pool and the mean age of the air was 22 minutes. Disinfection by-products in the indoor swimming pool were present in higher concentrations than in the outdoor air. In order to increase the removal of pollutants, adjustment was required of the supply air volume and the supply/exhaust position.

• Clean Technology
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• v.28 no.2
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• pp.131-137
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• 2022

The semiconductor process currently emits various by-products and unused gases. Emissions containing pollutants are generally classified into categories such as organic, acid, alkali, thermal, and cabinet exhaust. They are discharged after treatment in an atmospheric prevention facility suitable for each exhaust type. The main components of organic exhaust are volatile organic compounds (VOC), which is a generic term for oxygen-containing hydrocarbons, sulfur-containing hydrocarbons, and volatile hydrocarbons, while the main components of alkali exhaust include ammonia and tetramethylammonium hydroxide. The purpose of this study was to determine the combustion characteristics and analyze the NO_X reduction rate by maintaining a direct combustion and temperature to process organic and alkaline exhaust gases simultaneously. Acetone, isopropyl alcohol (IPA), and propylene glycol methyl ether acetate (PGMEA) were used as VOCs and ammonia was used as an alkali exhaust material. Independent and VOC-ammonia mixture combustion tests were conducted for each material. The combustion tests for the VOCs confirmed that complete combustion occurred at an equivalence ratio of 1.4. In the ammonia combustion test, the NO_X concentration decreased at a lower equivalence ratio. In the co-combustion of VOC and ammonia, NO was dominant in the NO_X emission while NO₂ was detected at approximately 10 ppm. Overall, the concentration of nitrogen oxide decreased due to the activation of the oxidation reaction as the reaction temperature increased. On the other hand, the concentration of carbon dioxide increased. Flameless combustion with an electric heat source achieved successful combustion of VOC and ammonia. This technology is expected to have advantages in cost and compactness compared to existing organic and alkaline treatment systems applied separately.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3335-3340
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• 2007

The government have been tightening EM regulation gradually but the effect is not good because of rapid increase of vehicles. And medium & heavy duty diesel vehicles, even though the number is small, exhaust very large pollutants(about over 50%). Especially it is more severe about old trucks and buses. Accordingly, CNG vehicle and the retrofit of diesel to CNG must be an alternative in order to protect the atmospheric environment and improve the air quality in the metropolitan area. The main object of this study is to secure the retrofit technology of diesel to CNG vehicle and the management system of CNG engine. we passed the government emission certification test. In addition to this, the mass production for retrofit is also studied. Results of emission and durability test for certification are as follows; there was no problem during 30,000km vehicle durability test and good emission levels satisfying the regulation.