• Title/Summary/Keyword: Exhaust gas composition

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Determination of Air Fuel Ratio according to Fuel Composition (I) -Eltinge Chart as a Reference Exhaust Composition- (연료 조성에 따른 공연비 산정 (I) -기준 배기 조성으로서 Eltinge 차트-)

  • Ohm, In-Yong;Park, Chan-Jun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.11
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    • pp.1548-1562
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    • 2003
  • This paper is the first of several companion papers which compare the methods of Air-fuel ratio determination. There are many methods which calculate Air-Fuel ratio from exhaust emission. Most of them are based on the simple chemical equations, which use balance of atom, and the error of the calculation is negligible as far as the instrumentation accuracy is guaranteed. They assume homogeneous mixture and complete combustion to the extent of oxygen availability. Because of these simple assumptions, they cannot offer the information about the fuel distribution state and the malfunction of instrument. For these limitations, Eltinge offered new one based on stricter mathematical model. This result coincides with the others very well and gives more information about the mixture state and instrumentation. Consequently this might be a general solution for Air-fuel ratio determination and exhaust composition. The objects of the calculation, however, were not commercial fuels except gasoline and the compensation method of unburned hydrocarbon was not appropriate to recent analyzer. Moreover he did not consider the fuel which contains oxygen, such as methanol, ethanol and blend of gasoline-alcohol. In this paper, Eltinge chart is expanded to the arbitrary fuel composition as the reference exhaust compositions for the purpose of further discussions about Air-fuel ratio determination methods and the charts fur gasoline, diesel, methanol, M85, liquefied petroleum gas(LPG), natural gas(NG), propane, butane are illustrated.

Comparison on Exhaust Gas of Heavy Duty Diesel Trucks; THC and CO Emission Affected by NOx Control Devices (EGR, SCR) (대형 경유트럭의 NOx 저감장치에 따른 배출가스 특성비교)

  • Mun, SunHee;Yoo, Heung-Min;Son, JiHwan;Yun, Changwan;Park, Gyu Tae;Kim, JeongSoo;Lee, Jongtae
    • Journal of ILASS-Korea
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    • v.20 no.3
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    • pp.149-155
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    • 2015
  • With increasing of GDP, the registration number of passenger cars has exceeded 20 million last year in Korea. Especially, the registration number of the diesel engine vehicles has been increasing. However, the WHO(World Health Organization) IARC (International Agency for Research on Cancer) has reported that diesel engine exhaust gas is an one of HAPs, which has carcinogenic for human, and they have designated it to Group 1. To solve this problem, exhaust gas from diesel engines has to be controlled. Thus, it has been controlling by European regulatory standard in Korea. On the other hand, in order to meet the enhanced emission regulations, all manufacturing company applied $NO_x$ control device to vehicles such as EGR (Exhaust Gas Recirculation), SCR (Selective Catalytic Reduction) and so on. However, these devices (EGR, SCR) were operated by difference reaction mechanism respectively, and the composition of exhaust gas would be differenced from that of them. In this study, it was conducted to evaluate variety characteristics on changing of exhaust gas composition by each $NO_x$ control device, and the heavy duty diesel trucks were chosen as experimental vehicles. From the result, it revealed that vehicles (with EGR) were discharged higher THC as 52.5% than that of others (with SCR). However, it did not followed that trend, in the case of CO; it was discharged as 57.2% lower than that of others (with SCR). In the future, these data would be used to apply to efficient $NO_x$ control device for meeting to EURO 6.

The Development of Emission Factors of Greenhouse Gas from Middle and Small-Scaled RPF Incineration Facility by Concentration Measurement and Fuel Composition (농도실측 및 연료 성분조성에 의한 중소형 RPF 소각시설의 온실가스 배출계수 개발)

  • Na, Kyung-Ho;Song, Il-Seok;Choi, Si-Lim;Yoo, Jae-In;Park, Ik-Beom;Kim, Jin-Gil
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.4
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    • pp.423-434
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    • 2012
  • This study was carried out to develop for the emission factor of greenhouse gas (GHG) from medium and smallscaled incineration facility using RPF which is considering as a part of renewable energy in UNFCC. The actual concentration of the exhaust gas and the fuel composition of RPF were measured for the calculation of GHG emission factor in RPF incinerators, and were compared with the IPCC guideline. The $CO_2$ and $N_2O$ emission factors by the actual concentration of exhaust gas were $2.3575{\pm}1.0070tCO_2/tRPF$ and $0.0014{\pm}0.0014tN_2O/tRPF$ respectively. Also, $CO_2$ emission factor by the RPF composition was $2.7057{\pm}0.0540tCO_2/tRPF$. The GHG emission factor per energy by the actual concentration was $83.0867{\pm}26.0346tCO_2e/TJ$ which showed higher consistency with the GHG emission factor ($80.3967tCO_2e/TJ$) of waste plastic in the IPCC guideline (2006b). The $CO_2$ and $N_2O$ emission factor calculated in this study is considered as a meaningful data for GHG emission factor of RPF incineration facility because of not being developed in ROK.

A Study on the Source Profile of Volatile Organic Compounds from Major Emission Sources (휘발성 유기화합물의 주요 배출원의 배출물질 구성비에 관한 연구-오존 생성 전구물질을 중심으로-)

  • 김소영;한진석;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.3
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    • pp.233-240
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    • 2001
  • The composition of volatile organic compounds (VOCs) was anlyzed for major emission sources such as vehicle exhaust, gasoline and diesel vapor, organic solvent vapor, and butane fuel gas. Low carbon-numbered hydrocarbons were found to be the dominant components of gasoline vehicle exhaust. In gasoline evaporative vapor, the predominant constituents were found to be butane and iso-pentane regardless of ambient air temperature. In case of diesel evaporative vapor was similar to those of gasoline evaporative vapor. The composition of organic solvent vapor from painting, ink and petroleum consisted mostly or aromatic compounds such as toluene and m, p, o-xylene. The hydrocarbon fraction of butane fuel gas. which is used by portable bunner, consisted mainly of propane (34%) and butane(70%).

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The experimental study on the emission characteristics of the coal gas in the condition of high pressure combustion (석탄가스 고압연소시 배기가스 배출특성에 관한 실험적 연구)

  • Hong, Sung Joo;Lee, Min Chul;Kim, Ki Tae
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.134-134
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    • 2010
  • Recently, the interest of the study about IGCC(Integrated Gasification Combined Cycle), one of New & Renewable Energy technologies, bas been increased due to the United Nations Framework Convention on Climate Change, the Low Carbon Green Growth policy, etc. Also, with this interest of IGCC, the study on the gas turbine utilizing the synthetic gas is performing actively. In the study of the gas turbine characteristic, the power performance and the combustion efficiency are mainly discussed and also the concern about the exhaust gas is being taken care of due to the increasing awareness of the environment. With this, we would like to go over the exhaust gas emission characteristic by the synthetic gas inflow in this test. In order to conduct such a test, we constructed a synthetic gas supplying system to supply the synthetic gases ($H_2$: hydrogen, $N_2$: nitrogen, CO: carbon monoxide, $CO_2$: carbon dioxide, and $H_2O$: steam) quantitatively and this combustion test was conducted by controlling the supplied synthetic gases artificially. The concentration of the exhaust gases appeared variously depending on the differences of the inflow nitrogen amount and the steam amount, whether or not the carbon dioxide flow in and so on. The results of the test can be able to be utilized for the IGCC study by understanding the exhaust gas emission characteristic of the coal gas turbine by synthetic gas composition.

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An Experimental Study on Individual HC Emission Characteristics and Startability for Various Composition Ratio of LPG Fuel on LPLi Engine (LPLi엔진에서의 LPG 연료 조성비가 개별탄화수소 배출특성과 시동성에 미치는 영향에 대한 연구)

  • Choi, Seong-Won;Kwak, Ho-Chul;Myung, Cha-Lee;Park, Sim-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.3 s.258
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    • pp.234-241
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    • 2007
  • The regulations for hydrocarbon emission from vehicles have become much more stringent in recent years. These more stringent regulations request vehicle manufacturers to develop the advanced exhaust system for reducing exhaust emissions. The exhaust emissions has many sources in vehicle. In order to investigate the characteristics of hydrocarbon(HC) in the exhaust manifold, concentrations of individual HC species were measured in exhaust process. Using sampling valve, the light hydrocarbon emissions were captured in the exhaust manifold(catalyst before and after) and analyzed from LPLi engine exhaust manifold(catalyst before and after) using different fuel properties. Then exhaust samples were measured by gas chromatography(GC) and exhaust gas analyzer. Catalyst conversion efficiency for fuel properties of Butane 100% was better than Propane 100%. Start delay of LPLi engine was observed as increment of propane contents in LPG fuels.

Thermal Fatigue Properties of Synthetic Beat Affected Zone in Ferritic Stainless Steel (페라이트계 스테인리스강의 재현 용접열영향부 열피로 특성)

  • Hong, S.G.;Cho, M.H.;Kang, K.B.
    • Journal of Welding and Joining
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    • v.27 no.1
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    • pp.79-84
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    • 2009
  • Ferritic stainless steel, which has been used as material for decoration parts in automobile, is recently used as material for the exhaust system due to its good performance at high temperature. To improve the fuel efficiency and purify automotive exhaust gas, it is needed to increase the temperature of exhaust gas. However, it is frequently reported that the rising of the temperature of exhaust gas increases thermal stress at exhaust manifold, which results in thermal fatigue failure in welded joints. Therefore, in this study, effects of chemical composition of steel and welding parameters on thermal fatigue properties of synthetic heat affected zone in ferritic stainless steel have been investigated. It has been found that thermal fatigue life in heat affected zone is affected by bead shape of welded joint and amount of soluble Nb in steel. Especially, Nb-Ti added steel has higher thermal fatigue life in comparison to Nb added steel, which is attributed to difference of precipitation behavior in both steels.

A Study on Performance and Exhaust Gas Prediction in dedicated CNG Engine (CNG 전소기관의 성능 및 배출가스 예측에 관한 연구)

  • 오용석;김경배;한영출
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.4
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    • pp.178-185
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    • 1998
  • To reduce the particulate matter and nitrogen oxides from diesel engine, many studies are proceeding and being accomplished practically. In this situation CNG engine has important meaning both as a clean fuel and an alternative energy. In order to present the direction and application of CNG, we simulated various operating conditions, that is, spark timing, compression ratio and fuel composition etc. Thus we try to understand how those affect performance and exhaust characteristics. The simulation program results found that the optimum combustion start angle was 21$^{\circ}$ at 1800rpm and fuel composition affects performance and emissions, also we could understand the formation of emission as crank angle is changed.

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The Development and Performance Test of a Small Wood Boiler (소형 화목보일러의 개발 및 성능시험)

  • Kim, Sa-Ryang;Lee, Jong-Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.3
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    • pp.491-497
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    • 2002
  • In the present study, a new wood boiler was developed through the performance test. The efficiency of the boiler was obtained up to about 63.7%, which is 67% higher than that of conventional wood boiler, about 38.2%. The structure of the new boiler is more complicated than the conventional boiler. The passage of combustion gas is sufficiently long to exchange heat well with heating water. Therefore, the obtained efficiency is so high, and the temperature of exhaust gas was lower than 200$^{\circ}C$, which is as low as that of light oil boiler. The composition of exhaust gas was measured, and the CO gas concentration was obtained more than 3000 ppm. So, it seems that more study is needed to lower the concentration of CO gas.

EXPERIMENTAL STUDY ON EMISSION CHARACTERISTICS AND ANALYSIS BY VARIOUS OXYGENATED FUELS IN A D.I. DIESEL ENGINE

  • CHOI S. H.;OH Y. T.
    • International Journal of Automotive Technology
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    • v.6 no.3
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    • pp.197-203
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    • 2005
  • This paper investigates the effect of oxygen composition in mixed fuel on the exhaust emissions for the direct injection diesel engine. These effects were tested to estimate the change in engine performance and exhaust emission characteristics when commercial diesel fuel and oxygenates blended fuels at a certain fuel and mixed ratio are used. Individual hydrocarbons $(C_1-C_6)$ in exhaust gases, as well as the total amount of hydrocarbons, were analyzed by using gas chromatography to find the mechanism by which smoke emission was remarkably reduced for various oxygenated fuels. The chromatograms between a diesel fuel and a diesel fuel blended DGM (diethylene glycol dimethyl ether), MTBE (methyl tert-butyl ether) and EGBE (ethylene glycol mono-n-butyl ether) were compared. The results showed that the number of individual hydrocarbons as well as the total number of hydrocarbons of oxygenated fuel reduced more remarkably than those of diesel fuel.