• 제목/요약/키워드: Exhaust Gas After-Treatment

검색결과 73건 처리시간 0.022초

선박디젤기관용 SCR 시스템의 NOx 저감율에 관한 연구 (Investigation of NOx Reduction Ratio on SCR System for a Marine Diesel Engine)

  • 최재성;조권회;이재현;이진욱;김정곤;양희성;고준호;박기용;장성환
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제27권7호
    • /
    • pp.832-838
    • /
    • 2003
  • IMO NOx levels are generally possible to meet by means of primary on-engine measures. Nevertheless further significant follow-on reductions are likely to require a secondary after-treatment technique. SCR system is currently the only available technology proven at full scale to meet the 90% NOx reduction levels. Accordingly, maybe the use of an SCR system on board ship provides the solution to minimize this primary pollutant without increasing fuel consumption. In order to develop a practical SCR system for marine application on board ship, a primary SCR system using urea was made. The SCR system was set up on the ship. employed a two-stroke diesel engine as a main propulsion. which is a training ship in KMU (Korea Maritime Univ.). The purpose of this paper is to report the results about the basic effects of the above system parameters which is investigated from practical application through its trial use. The degree of NOx removal depends on some parameters. such as the amount of urea solution added, space velocity. reaction gas temperature and activity of catalyst. The preliminary results from trial run are presented.

벽유동 방식 담체를 사용하는 SCR 촉매 반응기에서 재 퇴적이 변환 효율에 미치는 영향에 대한 연구 (Impact of Ash Deposit on Conversion Efficiency of Wall Flow Type Monolithic SCR Reactor)

  • 박수열
    • 동력기계공학회지
    • /
    • 제17권1호
    • /
    • pp.27-35
    • /
    • 2013
  • SCR (Selective Catalytic Reduction) on DPF (Diesel Particulate Filter) is a multi-functional after-treatment device which integrates soot filtration and DeNOx function into a single can. Because of its advantage in package and cost, the SCR on DPF is considered as a potential candidate for future application. It inherently employes wall flow type monolithic reactor so ash included in exhaust gas may deposit inside the inlet channel of this device. This study is intended to identify the impact of ash deposit on SCR reaction under wall flow type monolithic reactor. Simulation approach is used so relevant species transport equations for wall flow type monolith is derived. These equations can be solved together with momentum conservation equations and give solution for conversion performance. Both ash deposit and clean catalyst case are simulated and comparison of these two cases gives an insight for the impact of ash deposit on conversion performance. Ash deposit can be classified as ash layer and ash plug. and impact of ash deposit is described along with different morphology of ash deposit.

Urea-SCR 단홀 Injector 노즐형상 변화에 따른 비정상유동특성의 해석적 연구 (Analytical Study on Unsteady Flow Characteristics of Urea-SCR Single Hole Injector depend on Nozzle Shape Change)

  • 황준환;박성영
    • 한국분무공학회지
    • /
    • 제24권3호
    • /
    • pp.105-113
    • /
    • 2019
  • In this paper, a study of Urea-SCR System for Dosing Injector for responding to enhanced environmental regulations has been conducted. There is a limit to the experimental approach due to the structural characteristics of the injector. In order to overcome this problem, The analysis was performed assuming unsteady turbulent flow through computational fluid analysis and the internal flow characteristics of the injector were analyzed. By changing the nozzle shape of the injector, the performance factors of the swirl injector by shape were selected and compared. The design parameters were modified by changing the diameter of the nozzle at a constant ratio compared to the base model. Swirl coefficient, outlet mass flow, and sac volume were selected as performance parameters of the injector. The Conv. model to which the taper was applied showed the dominance in mass flow rate, discharge coefficient and swirl because of the smooth fluid flow by shape. Swirl coefficient, outlet mass flow, and sac volume were selected as performance parameters of the injector. As a result of the comparison coefficient derivation with those performance parameters for comparing the performance of the model-specific injector, the Conv-140 model with the nozzle diameter expanded by 140% showed the best value of the comparison coefficient.

폐 2,4,6-trinitrotoluene의 환경 친화적 연소처리공정 개발 (Development of Eco-friendly Combustion Process for Waste 2,4,6-trinitrotoluene)

  • 김태호;안일호;김종민
    • 청정기술
    • /
    • 제27권3호
    • /
    • pp.247-254
    • /
    • 2021
  • 본 연구에서는 폐 2,4,6-트리나이트로톨루엔(2, 4, 6-trinitrotoluene, TNT)의 친환경 연소처리 공정을 개발하고, 이를 이용한 연소조건 최적화를 통한 연소 잔유물 중 유기물 최소화에 대한 기초연구의 데이터를 제시하였다. TNT는 자체적으로 완전연소가 어려운 물질로 외부에서 열을 가해주는 조건인 버너의 가열시간 변화, 추진제(가연물)와 혼합하여 소각, 연소 후 잔유물에 대한 2차 고온처리의 방법으로 실시하였다. 실험결과 잔유물 내 유기물 함량 감소를 확인하였으며, 각 방법별 최소 7 ~ 10%의 유기물 함량을 나타내었다. 최적의 연소시간 조건에서 폐TNT의 연소 잔유물 중 유기물 함량은 1차 소각로만 사용한 경우 9% 수준을 보였으며, 동시에 폐가스의 환경친화성도 폐가스 실시간 분석에서 확인 되었다. 1차 소각이후 소각 잔유물을 외부의 전기로를 이용하여 추가적으로 고온처리 처리할 경우 유기물 함량을 2% 정도 추가적으로 감소시킬 수 있었다. 추진제가 포함된 연소공정에서는 추진제 함량에 따른 잔유물 중 유기물의 함량 감소가 가능함이 나타나 다양한 TNT 폐기물을 처리할 수 있음을 알 수 있었다. 폐기물관리법에서 소각 후 잔유물 내 유기물 함량 15% 미만을 충족하는 수치이다.

휘발성 유기 화합물 및 암모니아 직접 연소를 통한 배기가스 특성 (Characteristics of Flue Gas Using Direct Combustion of VOC and Ammonia)

  • 김종수;최석천;정수화;목진성;김두범
    • 청정기술
    • /
    • 제28권2호
    • /
    • pp.131-137
    • /
    • 2022
  • 현재 반도체 공정에서 다양한 by-product 및 미사용 가스가 배출되고 있다. 오염물질을 함유한 배기는 일반적으로 유기, 산, 알칼리, 열, 캐비넷 배기 등으로 분류하며, 각각의 배기 특성에 맞는 대기 방지설비에서 처리 후 배출된다. 유기 배기 물질로서 휘발성 유기 화합물(volatile organic compound, VOC)은 산소 함유 탄화수소, 유황 함유 계 탄화수소 및 휘발성 탄화수소를 총칭하는 물질이고, 알칼리 배기의 주요성분은 암모니아(NH3), 수산화테트라메틸암모늄(Tetramethylammonium hydroxide, TMAH)등이 있다. 본 연구의 목적은 유기와 알칼리 배기가스를 동시에 처리하기 위해 직접 연소 및 로 내 온도를 일정하게 유지하여 연소 특성 파악하고 NOX 저감률을 분석하고자 진행하였다. VOC는 Acetone, IPA(isopropyl alcohol), PGMEA(propylene glycol methyl ether acetate)을 사용하였으며, 알칼리 배기 대표 물질로는 암모니아를 사용하였다. 실험 변수로는 온도와 당량 비(equivalence ratio, ER)로 배기가스 특성을 살펴보았다. 물질별 단독 및 혼합 연소테스트를 진행하였다. VOC 단독 테스트 결과 당량 비 1.4 조건에서 완전 연소가 일어남을 확인하였다. 암모니아는 당량 비 감소에 따라 산소 및 질소산화물의 농도가 감소하였다. 혼합 연소 운전 결과 배기가스 조성 내 질소산화물의 대부분은 일산화질소였으며 이산화질소는 10 ppm 부근으로 검출되었다. 전체적으로 질소산화물의 농도는 반응온도가 증가하면서 산화반응이 활성화되어 감소하는 경향을 나타나지만 이산화탄소의 농도는 증가하는 경향을 확인하였다. 전기열원을 적용한 무 화염 연소 기술을 적용하였을 때 VOC 및 암모니아 연소가 원활하게 일어남으로써 현재 별도로 운전되는 유기 및 알칼리 배기 시스템보다 경제성 및 공간적인 측면에서 장점이 있다고 판단된다.

연료비 절감을 위한 선박용 연료유 균질기 개발에 관한 연구 (A Study on the Development of Marine Fuel Oil Homogenizer for Fuel Costs Saving)

  • 한상구;최정식;박노성;김대헌;류경부;천강우;윤석훈;최재혁
    • 해양환경안전학회지
    • /
    • 제18권6호
    • /
    • pp.584-590
    • /
    • 2012
  • 본 연구에서는 고정자와 회전자에 의해 발생하는 전단력(Shearing force)을 이용한 선박용 연료유 균질기(Homogenizer) 개발에 관한 연구를 수행하였다. 균질기의 균질화 및 미립화 정도에 대한 성능을 조사하기 위하여 IFO 380 cSt Bunker-C 시료에 전처리(Pre-treatment)를 시행하였다. 전처리한 시료의 슬러지(Sludge) 저감 효과를 확인하기 위하여 유청정기(Oil purifier)를 이용하였다. 실험결과 균질기로 전처리한 시료에서 슬러지양이 약 13 % 감소하는 것을 확인하였다. 또한, 전처리 후 유청정한 시료를 실제 보일러 시스템에서 연소시켜 CO가 감소하는 연소특성 경향을 확인하였다. 이와 같은 결과를 통해 개발된 선박용 연료유 균질기를 실선에 적용할 경우 연료비 및 운항비용 절감 효과가 있을 것으로 판단된다.

Ag/$Al_2O_3$ 촉매하의 HC-SCR에서 수소 풍부 에탄올의 반응 특성 (Kinetics of Hydrogen Rich Ethanol as Reductant for HC-SCR over $Al_2O_3$ Supported Ag Catalyst)

  • 이주헌;박정환;김성수;유승준;김진걸
    • 한국수소및신에너지학회논문집
    • /
    • 제21권6호
    • /
    • pp.519-525
    • /
    • 2010
  • Ethanol was used as reductant to remove $NO_x$ over Ag/$Al_2O_3$ catalyst via SCR from stationary emission source. Among the tested hydrocarbon reductants, ethanol showed highest de-$NO_x$ performance over the Ag/$Al_2O_3$ catalyst. De-$NO_x$ efficiency of about 83% was obtained in the condition of GHSV 20,000 $hr^{-1}$, $NO_x$ 200 ppm, CO 200 ppm, $O_2$ 13%, $H_2O$ 5% and mole ratio of ethanol/$NO_x$ = 2 between temperature of $300^{\circ}C$ and $400^{\circ}C$. While $SO_2$ presence in the $NO_x$ exhaust suppressed the catalytic activity, catalyst with acid (0.7% $H_2SO_4$) treatment of catalyst showed higher catalytic activity, where In-Situ DRIFT showed S presence over catalyst surface was increased after acid treatment of catalyst. From in-situ DRIFT and SCR results, it was concluded that sulfur presence over the surface of Ag/$Al_2O_3$ catalyst was the dominant factor to control the de-$NO_x$ reaction yield via HC-SCR from the exhausted gas including $SO_2$.

서울시(市) 대기오염(大氣汚染)이 시민보건(市民保健)에 미치는 영향(影響)에 관(關)한 조사연구(調査硏究) (Epidemiological Study of Air Pollution and Its Effects on Health of Urban Population)

  • 정규철
    • Journal of Preventive Medicine and Public Health
    • /
    • 제2권1호
    • /
    • pp.5-22
    • /
    • 1969
  • The urban population of our country is rapidly increasing due to many factors of social structure, and sociologists are predicting that the increase rate of the urban population will be over 50% in 1980's. Above all, the population of the capital city of Seoul, is at present more than four millions. Such centring of people in cities, together with the improvement of the standards of living, caused rapid increase in the amount of fuel consumption, and this consumption of fuels became one of the primary sources of the air pollution in cities. Moreover, the heavy traffic, construction of many tall buildings, and the increasing number of new factories due to the industrial development-all these are contributing to make the matter of air pollution worse and worse in the Metropolitan, whose geographical location is quite unfavorable considered from the view point of air pollution. Most homes in Seoul use briquet as fuel, while oils are used in tall buildings. The CO, $SO_2$, and smoke that come from burning of these fuels are a great threat to the health of the urban population. With the purpose of examining the influence of air pollution upon the public health, written inquiries were made upon respiratory diseases, and the carboxyhemoglobin saturation in the blood was measured to determine whether the air pollution may affect the health of the urban population. Method of Health Examination (1) Investigation of Respiratory Diseases Patients' records were examined to figure out the monthly ambulance rate of respiratory patients to the total number of patients treated. On the other hand, by using the questionnaire form approved by the Medical Research Council's Committee on Research into Chronic Bronchitis, investigators interviewed the examinees and inquired into the respiratory symptoms. (2) Measuring of Carboxyhemoglobin Saturation From the ear lobe of the examinees, with the use of the melangeur for the white blood cell counting, blood was taken, and after diluting it ten times with 0.1% $Na{2}CO_{3}$, again diulting it 20 times with 0.5% $Na_{2}\;CO_{3}$, its absorbancy was measured. The following results are obtained from the investigation. (1) It was found out that 7.7% of the total patients under treatment were suffering from upper respiratory infection, acute or chronic bronchitis, bronchial asthma, pulmonary emphysema and bronchiectasis. Of them all, patients with upper respiratory infection numbered the greatest with 4.8% and patients with acute or chronic bronchitis the next with 2.1%, and their monthly ambulance rate was high from December to February during the winter, and from April to May and from September to October during the changeable seasons. (2) The daily ambulance rate of respiratory patients, it was revealed, had a close connection with the concentration of $SO_2$ and CO in the air. (3) It was found out that men were more subject to respiratory disease than women, and both men and women were more liable to the diseases with the advancing of age. (4) People living at Choong-ku with the heavy traffic and in the industrial zones of Yeungdungpo had high frequency of respiratory symptoms. (5) Considered from the view point of occupations, high frequency was found among those without job, with jobs unknown, merchants and intdustrial workers, whose social status was rather low and traffic policemen who were always exposed to the exhaust gas of cars. As for women, the frequency was detected in the order of those from high to low, housewives who were exposed to briquet gas, women with jobs unknown, women without jobs, whose social status was low. (6) Ex-smokers rather than smokers, of both sexes, had higher frequency. As for men, heavy smokers had high frequency, while in women light smokers had rather high frequency which was presumed to be due to their average old age. (7) Men's average of carboxyhemoglobin saturation was 9.48%, while women's was 11.3%, higher than men's. (p<0.05). Age meant no difference in the case of men, but as for women, the saturation was remarkably high between the ages from 20 to 60. (8) No regional difference was detected in the carboxyhemoglobin saturation. (9) The carboxyhemoglobin saturation was found, in the case of men, in the order of office workers, traffic policemen, students, the unemployed, merchants and industrial workers, drivers; and as for women, the order was housewives, office workers, merchants and industrial workers. (10) No significant correlation was found between the carboxyhemoglobin saturation and the concentration of CO detected in kitchens, or between the carhoxyhemoglobin saturation and the passing of time after exposure to briquet gas. No difference of carboxyhemoglobin saturation was detected between smokers and non-smokers, and the degrees of smoking; only, significant negative correlation was found between the passing of time after smoking and the carboxyhemoglobin saturation. It is ture that air pollution causes or aggravates the respiratory diseases, increases the carboxyhemoglobin saturation in the blood, but what seems to be more hazardous to the health is the air polluted by the briquet gas in the kitchens and on-dol rooms rather than the atmospheric air pollution.

  • PDF

마찰용접된 국산내열 강 (SUH3-SUS303 )의 시효열처리가 고온피로강도 및 파괴거동에 미치는 영향에 관한 연구 (The Effect of Aging Treatment on the High Temperature Fatigue Fracture Behavior of Friction Welded Domestic Heat Resisting Steels (SUH3-SUS 303))

  • 이규용;오세규
    • 수산해양기술연구
    • /
    • 제17권2호
    • /
    • pp.93-103
    • /
    • 1981
  • Si-Cr계 내열강 SUH3와 Cr-Ni계 stainless강 SUS 303 및 이들이 마찰용접재 SUH3-SUS303을 $1,060^{\circ}C$에서 용체화처리하고 다시 $700^{\circ}C$에서 10, 100시간 시효열처리한 각 시험편의 고온 피로강도에 대한 시효열처리의 효과를 알기 위하여 $700^{\circ}C$에서 고온 회전굽힘 피로시험을 하고 파약거동을 미시적으로 관찰하여 다음과 같은 결과를 얻었다. 1) SUH3재와 SUS303재의 최적마찰용접조건은 회전수 2420rpm, 마찰가압력 $8kg/mm^2$, 전 upset량 7mm(마찰가압시간 3sec, upset시간 2sec)이었다. 2) $700^{\circ}C$ 고온에서 장시간 이루어지는 고온피로시험에 있어, 용체화처리재의 S-N 곡선 경사부의 기울기가 가장 급하게 나타났다. 3) SUH3-SUS303 마찰용접재는 $1,060^{\circ}C$에서 1시간용체화 처리하고, $700^{\circ}C$에서 시효처리하는 경우 최적시효시간은 10시간이었다. 4) 10시간 시료재의 고온피로한도는 모재보다 SUH3은 75.4%, SUS303은 28.5% 높았으며, 용접재 SUH3-SUS303은 44.2% 정도 높았다. 100시간 시효재는 모재보다 SUH3은 64.91% SUS303은 30.4% 높았으며, SUH3-SUS303은 30.4% 높았으며, SUH3-SUS303은 36.6% 높았다. 5) 마찰용접재의 상온 및 고온의 피로파단은 모두 SUS303의 모재측에 발생하였으며, 용접면에서의 파단은 전혀 없었다. 6) SUS303재와 마찰용접재 SUH3-SUS303재의 크랙은 입내파양형이었으나 SUH3은 입계크랙의 전파로 파양한다.

  • PDF

Cu-SCR 촉매의 De-NOx 성능 향상을 위한 연구 (Research for Performance Improvement of De-NOx of Cu-SCR Catalysts)

  • 서충길
    • 한국산학기술학회논문지
    • /
    • 제19권3호
    • /
    • pp.112-118
    • /
    • 2018
  • 화석연료를 기반으로 하는 내연기관의 엄격한 배기가스규제를 충족시키기 위해 자동차와 선박용 후처리장치의 비중이 점차로 증가하고 있다. 디젤엔진은 $CO_2$ 배출량이 적고 강력한 파워와 연료의 경제성을 가지고 있으며, 상용차뿐만 아니라 승용차에서도 시장의 수요가 증가하고 있다. 디젤 연료 특성으로 인하여 질소산화물은 국부적인 고온연소 영역에서 생성되며, 입자상물질은 확산연소 영역에서 생성이 된다. LNT와 urea-SCR 촉매는 디젤엔진에서 NOx를 저감시키기 위한 후처리장치로 개발되어져왔다. 이 연구는 가혹해지고 있는 배기가스 규제 대응을 위해 소형과 중 대형 디젤기관에 많이 사용되고 있는 Cu SCR 촉매의 NOx 저감 성능 향상을 목적으로 한다. $5Cu-2ZrO_2$/Zeolyst(Si/Al=13.7)SCR 촉매는 $5Cu-2ZrO_2$/93Zeolite(Si/Al=2.9) 촉매에 비해 촉매온도 $300^{\circ}C$ 이상에서 약 5-50% 수준으로 de-NOx 성능이 높았다. Zeolite는 zeolyst에 비해 금속의 분산도가 낮고 평균 입경이 커짐에 따라 촉매의 반응속도가 저하되었다. 10wt% Cu가 담지된 $10Cu-2ZrO_2$/88Zeolyst 촉매는 $200^{\circ}C$에서 40%, $350^{\circ}C$에서 약 65%로 NOx 정화성능이 가장 높았고, Cu의 이온이 제올라이트의 결정화합물인 Al과의 이온교환율이 증가함에 따라 다른 촉매에 비해 20-40% de-NOx 성능이 향상되었다.