• Title/Summary/Keyword: Exhaust Emission

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A Study on the Effectiveness of Remanufacturing Technology for the Catalyzed Diesel Particulate Filter-trap(DPF) Deactivated by Diesel Exhaust Gas (촉매가 담지된 사용후 경유차 매연저감장치 DPF의 재제조 효과에 관한연구)

  • Choi, Kang-Yong;Park, Hea-Kyung
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.10
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    • pp.957-964
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    • 2010
  • The deactivated catalyzed diesel particulate filter-trap (DPF) was remanufactured by ultrasonic wave treatment with various prepared solutions, followed by active component re-impregnation, and the emission control performance and surface properties of remanufactured DPF were studied at various remanufacturing conditions. The proper ultrasonic wave cleaning time at various prepared solutions and optimal re-impregnation amounts of active component for the best emission control performance of DPF were investigated and its performance tests were also carried out with various temperatures for the conversions of CO, THC (total hydrocarbon) and PM (particulate matter) by catalytic reaction test unit using bypass gas from the diesel engine dynamo system. It was found that the emission control performance of DPF remanufactured with the high-temperature air washing, ultrasonic wave cleaning at acid/base solutions and active component re-impregnation method was recovered to 95% level of its activity compared to that of the fresh DPF, which was caused by removing the deactivating materials from the surface of the DPF, through the analyses of performance test and their surface characterization by Optical microscope, EDX, ICP, TGA, and porosimeter.

A Study on Capacity of Electric Propulsion System by Load Analysis of 6,800TEU Container Ship (6,800TEU 컨테이너선의 부하분석을 통한 전기추진시스템 용량 연구)

  • Jang, Jae-Hee;Son, Na-Young;Oh, Jin-Seok
    • Journal of Navigation and Port Research
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    • v.42 no.6
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    • pp.437-445
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    • 2018
  • IMO (International Maritime Organization) has been strengthening the regulations of ship emission gas such as sulfur oxides (SOX), nitrogen oxides (NOX) and carbon dioxides (CO2) to protect the marine environment. Especially, ECA (Emission Control Area) has been set and operated in the USA and US. As a countermeasure against these environmental regulations, the demand for environmentally, friendly and highly efficient vessels has led to a growing interest in technology related research with respect to electric propulsion systems capable of reducing exhaust gas. Container ships were excluded from the application coverage of the electric propulsion systems for reasons of operation at economical speed. However, in the future, the need for electric propulsion system is expected to rise, because it is easy to monitor and control so that it can be an applicate to smart ship which are represented by fourth industrial revolution technology. In this study, research was carried out to design a generator and battery capacity through the load analysis of the 6,800TEU container ship to apply the electric propulsion system of the container ship. A capacity design based on the load analysis has an advantage that the generator can be operated in a high efficiency section through the load distribution control using the battery.

A Study on the Emission and Particulate Matter of a Heavy Duty Natural Gas Engine According to Gas Composition under certification tests (인증시험 조건에서 가스조성 변화에 따른 대형 천연가스 엔진 배기가스 및 입자상 물질 배출 특성에 관한 연구)

  • Choi, Ji-Seon;Park, Cheol-Woong;Jang, Hyoung-Jun;Kim, Chang-Gi
    • Journal of the Korean Institute of Gas
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    • v.25 no.6
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    • pp.66-73
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    • 2021
  • In this study, The full load test and WHTC mode test were performed to examine the effect on a heavy duty natural gas engine according to the type of standard gas for certification to check engine performance and exhaust characteristics. Two types of standard gas (Gr, G23) and commercially available natural gas were applied as the fuel used. As a result of the test results of three natural gases with different fuel compositions, G23 with a high nitrogen content was inferior in torque, fuel consumption, and thermal efficiency conditions. In addition, when evaluated in the WHTC mode it was possible to obtain a result that satisfies the EURO VI regulation. However, compared to the other two fuels, the emission characteristics of G23 decreased CO2 and CO, but increased CH4, NOx and PN emissions.

Study on the On-Board Test of After-Treatment Systems to Reduce PM-NOx in Low-Speed Marine Diesel Engine (선박용 저속디젤엔진 적용을 위한 PM-NOx 동시저감 배출저감설비 해상실증 연구)

  • Dong-Kyun Ko;Suk-Young Jeong;In-Seob Kim;Gye-Won An;Youn-Woo Nam
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.29 no.5
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    • pp.497-504
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    • 2023
  • In this study, Selective catalytic reduction (SCR) + Diesel particulate filter (DPF) system was installed on a ship with a low-speed engine to conduct the on-board test. The target ship (2,881 gross tons, rated power 1,470 kW@240 rpm ×1) is a general cargo ship sailing in the coastal area. Drawing development, approvals and temporary survey of the ship were performed for the installation of the after-treatment system. For performance evaluation, the gaseous emission analyzer was used according to the NOx technical code and ISO-8178 method of measurement. The particulate matter analyzer used a smoke meter to measure black carbon, as discussed by the International Maritime Organization (IMO). Tests were conducted using MGO (0.043%) and LSFO (0.42%) fuels according to the sulfur content. The test conditions were selected by considering the engine rpm (130, 160 and 180). Gaseous emission and particulate matter (smoke) were measured according to the test conditions to confirm the reduction efficiency of the after treatment system. The results of NOx emission and particulate matter (smoke) revealed that reduction efficiency was more than 90%. The exhaust pressure met the allowable back pressure (less than 50 mbar). This study confirms the importance of the on-board test and the potential of SCR + DPF systems as a response technology for reducing nitrogen oxides and particulate matter.

Analysis of CO2 Emission and Effective CO2 Capture Technology in the Hydrogen Production Process (수소생산 공정에서의 CO2 배출처 및 유효포집기술 분석)

  • Kyung Taek Woo;Bonggyu Kim;Youngseok So;Munseok Baek;Seoungsoo Park;Hyejin Jung
    • Journal of the Korean Institute of Gas
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    • v.27 no.3
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    • pp.77-83
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    • 2023
  • Energy consumption is increased by rapid industrialization. As a result, climate change is accelerating due to the increase in CO2 concentration in the atmosphere. Therefore, a shift in the energy paradigm is required. Hydrogen is in the spotlight as a part of that. Currently 95% of hydrogen is fossil fuel-based reforming hydrogen which is accompanied by CO2 emissions. This is called gray hydrogen, if the CO2 is captured and emission of CO2 is reduced, it can be converted into blue hydrogen. There are 3 technologies to capture CO2: absorption, adsorption and membrane technology. In order to select CO2 capture technology, the analysis of the exhaust gas should be carried out. The concentration of CO2 in the flue gas from the hydrogen production process is higher than 20%if water is removed as well as the emission scale is classified as small and medium. So, the application of the membrane technology is more advantageous than the absorption. In addition, if LNG cold energy can be used for low temperature CO2 capture system, the CO2/N2 selectivity of the membrane is higher than room temperature CO2 capture and enabling an efficient CO2 capture process. In this study, we will analyze the flue gas from hydrogen production process and discuss suitable CO2 capture technology for it.

NOx Emission Characteristics with Operating Conditions of SNCR in SRF Usage Facilities (고형연료제품 사용시설에서의 SNCR의 운전조건에 따른 NOx 배출특성)

  • Seo, Je-Woo;Kim, Younghee
    • Clean Technology
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    • v.27 no.4
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    • pp.350-358
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    • 2021
  • The results of this study shows that the combustor temperature ranged from 848.27 to 1,026.80 ℃, averaging about 976.61 ℃, and the NOx concentration increased as the temperature increased. The urea usage ranged from 291.00 to 693.00 kg d-1, averaging about 542.34 kg d-1, and the NOx concentration decreased as the urea usage increased. Residence time was about 3.38 to 9.17 s, averaging about 5.22 s, about 2.61 times larger than the 2 s of the design details. This is 1,086 kg h-1, averaging about 55.71%, compared to the 1,950 kg h-1 SRF input permission standard. The combustion chamber area is constant, but the residence time is shown to increase with the decrease of exhaust gas. The O2/CO ratio was 847.05 to 14,877.34, averaging about 3,111.30, and the NOx concentration slightly increased as the O2/CO ratio increased. As the combustor temperature and O2/CO ratio increased, the combustion reaction with nitrogen in the air increased and the NOx concentration slightly increased. As the urea usage and residence time increased, the NOx concentration decreased slightly with an increase in reactivity with NOx. The NOx concentration at the stack ranged from 7.88 to 34.02 ppm with an average of 19.92 ppm, and was discharged within the 60 ppm emission limit value. The NOhx emission factor was 1.058 to 1.795 kg ton-1, averaging about 1.450 kg ton-1. This value was about 24.87% of the maximum emission factor of 5.830 kg ton-1 of other solid fuels. Other synthetic resins and industrial wastes were 79.80% and 43.65% compared to 1.817 kg ton-1 and 3.322 kg ton-1, respectively. This value was similar to 1.400 kg ton-1 of RDF in the NIER notice (2005-9), 10.98% compared to the maximum SRF of 13.210 kg ton-1. Therefore, the NOx emission factor had a large deviation.

Emission Reduction Characteristics of Three-way Catalyst with Engine Operating Condition Change in an Ultra-lean Gasoline Direct Injection Engine (초희박 직접분사식 가솔린 엔진용 삼원촉매의 운전조건에 따른 배기저감 특성)

  • Park, Cheol Woong;Lee, Sun Youp;Yi, Ui Hyung;Lee, Jang Hee
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.9
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    • pp.727-734
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    • 2015
  • Recently, because of the increased oil prices globally, there have been studies investigating the improvement of fuel-conversion efficiency in internal combustion engines. The improvements realized in thermal efficiency using lean combustion are essential because they enable us to realize higher thermal efficiency in gasoline engines because lean combustion leads to an increase in the heat-capacity ratio and a reduction of the combustion temperature. Gasoline direct injection (GDI) engines enable lean combustion by injecting fuel directly into the cylinder and controlling the combustion parameters precisely. However, the extension of the flammability limit and the stabilization of lean combustion are required for the commercialization of GDI engines. The reduction characteristics of three-way catalysts (TWC) for lean combustion engines are somewhat limited owing to the high excess air ratio and low exhaust gas temperature. Therefore, in the present study, we assess the reaction of exhaust gases and their production in terms of the development of efficient TWCs for lean-burn GDI engines at 2000 rpm / BMEP 2 bar operating conditions, which are frequently used when evaluating the fuel consumption in passenger vehicles. At the lean-combustion operating point, $NO_2$ was produced during combustion and the ratio of $NO_2$ increased, while that of $N_2O$ decreased as the excess air ratio increased.

Effect of Containing Promoter on SCR Catalysts (SCR 촉매에 포함된 조촉매 영향)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.474-481
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    • 2018
  • The policy-making and technological development of eco-friendly automobiles designed to increase their supply is ongoing, but the internal combustion engine still accounts for approximately 95% of automobiles in use. To meet the stricter emission regulations of internal combustion engines based on fossil fuels, the proportion of after-treatments for vehicles and (ocean going) vessels is increasing continuously. As diesel engines have high power and good fuel economy in addition to less CO2 emissions, their market share is increasing not only in commercial vehicles, but also in passenger cars. Because of the characteristics of the diesel combustion, however, NOx is generated in localized high-temperature combustion regions, and particulates are formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for the after-treatment of exhaust gas to reduce NOx in diesel vehicles. This study examined the effect of a containing promoter on SCR catalysts to cope with the severe exhaust gas regulation. The de-NOx performance of the Mn-SCR catalyst was the best, and the de-NOx performance was improved as the ion exchange rate between Mn ion and Zeolyst was good and the activation energy was low. The de-NOx performance of the 7Cu-15Ba/78Zeoyst catalyst was 32% at $200^{\circ}C$ and 30% at $500^{\circ}C$, and showed the highest performance. The NOx storage material of BaO loaded as a promoter was well dispersed in the Cu-SCR catalyst and the additional de-NOx performance of BaO was affected by the reduction reaction of the Cu-SCR catalyst. Among the three catalysts, the 7Cu-15Ba/Zeolyst SCR catalyst was resistant to thermal degradation. The same type of CuO due to thermal degradation migrates and agglomerates because BaO reduces the agglomeration of the main catalyst CuO particles.

A Study on the Safety Code Development of Gas Engine Micro Combined Heat and Power System (소형 가스엔진 열병합 발전시스템 안전기준 개발)

  • Kwon, Jun-Yeop;Kim, Min-Woo;Lee, Jung-Woon
    • Journal of the Korean Institute of Gas
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    • v.25 no.4
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    • pp.27-35
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    • 2021
  • Recently, as a solution to the sharp drop in "power reserve ratio", it is being converted to a microgrid that enables bi-directional transmission and distribution. A microgrid is composed of a small-scale distributed power supply and a load. As a representative technology of distributed power generation, there is a Micro Combined Heat and Power system applied to homes and buildings. In this study, a safety standard was developed by dividing the power generation system, cooling system, lubrication system, and exhaust system to derive safety standards for a small gas engine power generation system with a gas consumption less than 232.6kW (200,000 kcal/h). In the case of the power generation system, a filter was installed and the system was stopped by detecting gas leakage and abnormalities in engine speed or output and the cooling system is stipulated to stop the system in case of insufficient cooling water or overheating. The lubrication system monitors the pressure and temperature of the lubricating oil and stops the system when an abnormality occurs, and the exhaust gas emission concentration regulation value was specified in accordance with domestic and foreign standards. Through the results of this study, it is judged that the safety of the gas engine power generation system can be improved and it can contribute to the commercialization of products.

Evaluation of ammonia emission reducing effect by adding waste cooking oil in pilot-scale composting of dairy cattle manure

  • Kazutaka Kuroda;Akihiro Tanaka;Kenichi Furuhashi;Naoki Fukuju
    • Animal Bioscience
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    • v.36 no.10
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    • pp.1612-1618
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    • 2023
  • Objective: In our previous study, we observed that the addition of waste cooking oil (WCO) reduced ammonia (NH3) emissions during laboratory-scale composting of dairy cattle manure under low-aeration condition. Therefore, this study aimed to evaluate the effect of addition of WCO on NH3 emissions reduction during pilot-scale composting of dairy cattle manure, which is close to the conditions of practical composting treatment. Methods: Composting tests were conducted using pilot-scale composting facilities (1.8 m3 of capacity). The composting mixtures were prepared from manure, sawdust, and WCO. Two treatments were set: without WCO (Control) and with WCO added to 3 wt% of manure (WCO3). Composting was conducted under continuous aeration at 40 L/min, corresponding to 22.2 L/(min·m3) of the mixture at the start of composting. The changes in temperatures, NH3 concentrations in the exhaust gases, and contents of the composted mixtures were analyzed. Based on these analysis results, the effect of WCO addition on NH3 emissions and nitrogen loss during composting was evaluated. Results: During composting, the temperature increase of the composting mixture became higher, and the decreases of weight and water content of the mixture became larger in WCO3 than in Control. In the decrease of weight, and the residual weight and water content of the mixture, significant differences (p<0.05) were detected between the two treatments at the end of composting. The NH3 concentrations in the exhaust gases tended to be lower in WCO3 than in Control. Nitrogen loss was 21.5% lower in WCO3 than in Control. Conclusion: Reduction of NH3 emissions by the addition of WCO under low aeration condition was observed in pilot-scale composting, as well as in laboratory-scale composting. This result suggests that this method is effective in reducing NH3 emissions in practical-scale composting.