• Journal of Photoscience
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• v.11 no.3
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• pp.95-99
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• 2004

Optical absorption and emission studies have been carried out to understand the effect of deuterium on the solvent dependent photophysical properties of curcumin in deuterated solvents such as $CDCl_3,\;(CD_3)_2SO,\;(CD_3)_2CO,\;CD_3OD\;and\;CD_3CN$. Optical absorption spectral studies showed that there is no significant shift in absorption maxima compared to the non-deuterated solvent. The fluorescence maxima shows significant shift with polarity of solvent but not much affected by the deuteration. The fluorescence quantum yield of curcumin increased marginally in almost all the deuterated solvents, indicating reduction in the non-radiative pathways. The fluorescence decay was biexponential in all the solvents and the average fluorescence lifetime was not much affected with deuteration, but showed decrease with increasing solvent polarity. Based on these studies, it is concluded that intermolecular hydrogen transfer is only partially responsible for the excited state deactivation of curcumin.

• Bulletin of the Korean Chemical Society
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• v.7 no.1
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• pp.6-12
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• 1986

Overlap integrals for the case in which the ground and excited states are represented by Morse potential functions were derived. In order to calculate the spectral intensities in Morse wavefunctions, a method of expanding the wavefunctions of one state in terms of the other was developed to allow the ground and the excited state frequencies to be different. From the expansion of Morse wavefunctions, recursion formulas were developed for variational matrix elements of Morse wavefunctions. The matrix elements can be calculated using these recursion formulas and the diagonalized results which eigenvalues (allowed energies) were all successfully satisfied to Morse energy formulas.

• Bulletin of the Korean Chemical Society
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• v.22 no.5
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• pp.455-462
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• 2001

The time-dependent tracking inversion method is studied to extract the potential energy surface of the electronic excited state in the photodissociation of triatomic molecules. Based on the relay of the regularized inversion procedure and time-dependent wave packet propagation, the algorithm extracts the underlying potential energy surface piece by piece by tracking the time-dependent data, which can be synthesized from Raman excitation profiles. We have demonstrated the algorithm to extract the potential energy surface of electronic excited state for NO2 molecule where the wave packet split on a saddle-shaped surface. Finally, we describe the merits of the time-dependent tracking inversion method compared with the time-independent inversion method and discussed several extensions of the algorithm.

• Bulletin of the Korean Chemical Society
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• v.6 no.5
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• pp.291-295
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• 1985

The efficiency of photosensitization of methyl linoleate (ML) oxidation by N-acetyl-L-trypophan(NAT) and 3-methyl indole(scatole) was markedly enhanced by increased concentration of ML in ethanol solution. The fluorescence intensities of sensitizers were observed to be quenched by ML, indicating that ML interacts with the indole excited singlet state. The inhibition of photosensitization by azide demonstrated a possible role of singlet oxygen in the photosensitization. The steady state kinetic treatment of azide inhibition of photosensitization was expected to show linear increase of reciprocal yield of ML oxidation product vs. reciprocal ML concentration at constant azide concentration, but the actual slope was nonlinear. This indicates another competing reaction involved in the photosensitization, As a possible competing reaction, electron transfer from ML to the excited sensitizer was proposed, since the measured fluorescence quenching rate constant closely resembled electron transfer rate constant determined from ML concentration dependence of oxidation product formation.

• Bulletin of the Korean Chemical Society
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• v.27 no.6
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• pp.881-885
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• 2006

We have employed a technique of corona excited supersonic expansion to generate electronically excited but jet-cooled o-tolunitrile. The vibronically well-resolved emission spectrum of the jet-cooled o-tolunitrile in the $S_{1}\rightarrow S_{0}$ transition was recorded in the uv region using a Fourier transform spectrometer equipped with a Quartz-uv beam splitter. The electronic transition and vibrational mode frequencies in the ground electronic state were accurately determined from the analysis of the spectra observed.

• Journal of Electrical Engineering and Technology
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• v.12 no.1
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• pp.145-150
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• 2017

This paper present a unified method of steady state performance analysis and limits characteristics of an autonomous three-phase self-excited induction generator (SEIG) driven by a wind turbine under different types of loads and speeds. The proposed method is based on a new mathematical function to solve for the real and imaginary components of the complex equation of the mathematical model. Performances limits, regulation and characteristics of different configurations will be thoroughly examined and compared. The proposed system will be modeled and simulated and the performance limits characteristics will be compared with variable speed and variable capacity.

• Bulletin of the Korean Chemical Society
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• v.23 no.2
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• pp.271-276
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• 2002

The energy relaxation dynamics of the lowest excited singlet and triplet states of the Zn(II)porphyrin monomer and its directly linked arrays were comparatively investigated with increasing the number of porphyrin moieties. While the fluorescence decay rates and quantum yields of the porphyrin arrays increased with the increase of porphyrin units, their triplet-triplet (T-T) absorption spectra and decay times remained almost the same. The difference in the trends of energy relaxation dynamics between the excited singlet and triplet states has been discussed in view of the electronic orbital configurations.

• Journal of Power Electronics
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• v.4 no.3
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• pp.169-179
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• 2004

This paper presents the steady-state analysis of the three-phase self-excited induction generator (SEIG). The three-phase SEIG with a squirrel cage rotor is driven by a variable-speed prime mover (VSPM) or a constant-speed prime mover (CSPM) such as a wind turbine or a micro gas turbine. Furthermore, a PI closed-loop feedback voltage regulation scheme of the three-phase SEIG driven by a VSPM on the basis of the static VAR compensator (SVC) is designed and evaluated for the stand-alone AC and DC power applications. The simulation and experimental results prove the practical effectiveness of the additional SVC with the PI controller-based feedback loop in terms of its fast responses and high performances

• Journal of information and communication convergence engineering
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• v.7 no.1
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• pp.46-51
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• 2009

In this paper, the two-axis theory is adopted to analyze the secondary excited induction generator applied to random wave input generation system. The analysis by the two-axis theory helps to know the transmitted power of the induction machine. The electric variables, like as primary and secondary currents, voltages, and electric output power, were able to express as equations. These equations are help to simulate the generation system numerical model and to know the transient state of the system. As it is preferred to stabilize the output voltage and frequency in the constant level, microcomputer controlled VSI connected to the secondary windings supplies the secondary current with slip frequency. For testing the appropriateness of this method, the input torque simulator in the laboratory to drive the secondary excited results show the advantage of secondary excited induction generator system for the random input wave generation system.

• Proceedings of the KIEE Conference
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• 2005.04a
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• pp.76-79
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• 2005

This paper describes the performance analysis and design of 1-phase self-excited induction generators. The minimum parallel capacitance of self-excited capacitor connected auxiliary winding and the series capacitance of regulating voltage capacitor connected main winding is proposed the suitable value using circuit equations of main and auxiliary winding. For the steady state analysis, the equivalent circuit of 1-phase induction generators is used as circuit modeling using the double-revolving field theory. The validity of designed generator system will be confirmed by experimental and computed results.