• 한국응용과학기술학회지
• /
• 제28권2호
• /
• pp.247-250
• /
• 2011

The excess volumes of mixing of benzyl alcohol and halothane in vesicle and in suspensions of several lipids have been determined at $25^{\circ}C$ it using a excess volume dilatometer. The potency of general anesthetics has long been known to correlate with lipid solubility. Denaturations of the vesicle, which is a sole membrane protein in the purple membrane of Halobacteriun Halobium, were studied by absorption changes at 280 nm and fluorescence changes at 330 nm and excess volume dilatometer. The particle size analysis of viscous polymer solutions by diffusional interchange is the key step by measurement. The excess volume of mixing in chitosan was found to be negative, whereas them of purple membrane, Halobacteriun Halobium and red membrane were positive in benzyl alcohol and halothane. This result was confirmed as Miller's supposition.

• 한국응용과학기술학회지
• /
• 제35권2호
• /
• pp.472-477
• /
• 2018

전신마취제의 잉여 몰부피는 Halobacteriun Halobium에서 추출분리된 Purple membrane과 Red membrane에서 vesicle의 현탁액에서 $25^{\circ}C$ 잉여부피 dilatometer로 측정되었다. 우리의 연구에 의해 전신마취제인 Propofol은 잉여몰부피와 상관 관계가 있는 것으로 밝혔다. Halobacteriun Halobium에서 비중 차이에 의해 추출 분리된 Purple membrane과 Red membrane의 잉여몰 부피는 vesicle의 아미노산과 지질의 영향이다. 이들은 잉여 몰부피 dilatometer로 잉여 몰 부피를 측정되었으며, 흡광세기는 280 nm 330 nm 에서 연구되었다. Purple membrane과 Red membrane이 Propofol에 의한 입자크기 분석, 상대적 혼탁도가 기계적 특성을 위해 연구되었다. 확산 교환에 의한 점성 중합체 용액의 입자 크기 분석은 측정에 의한 중요한 단계이다. Propofol이 vesicle에서 재구성된 시료들 중에서, 특히 PM+RM+Propofol의 잉여 몰 부피가 PM, RM의 잉여 몰 부피보다 가장 크게 측정되었다.

• East Asian mathematical journal
• /
• 제29권2호
• /
• pp.241-254
• /
• 2013

In this paper, we investigate the contents of Rule of Excess and Deficit in the second volume of San Hak Jeong Ui (Arithmetic Definition) compiled by Nam Byong Kil and corrcted by Lee Sang Hyok in the Choson Dynasty period.(Emperor Ko Jong, 1867).

• 대한화학회지
• /
• 제56권1호
• /
• pp.20-27
• /
• 2012

Complex permittivity spectra of Allyl Chloride (AC), 2-Butanone (2-BU) and their binary mixtures over the entire range of concentration were obtained using the Time Domain Reflectometry (TDR) technique in microwave frequency range at various temperatures. Static dielectric constant and relaxation time are obtained from complex permittivity spectra. Density ($\rho$) and refractive index ($n_D$) are also measured. These parameters are used to determine excess dielectric constant, excess inverse relaxation time, excess molar volume, excess molar refraction, polarity, Bruggeman factor and thermodynamic parameters viz. enthalpy of activation and entropy of activation. The values of static dielectric constant and relaxation time increases while density and refractive index decreases with the percentage of 2-Butanone in Allyl Chloride increases. Excess parameters were fitted to a Redlich-Kister equation.

• 대한금속재료학회지
• /
• 제46권2호
• /
• pp.53-57
• /
• 2008

This study examined the role of excess free volume on the corrosion resistance of an amorphous alloy. Corrosion behaviors were monitored on the amorphous alloys, of which amount of free volume was controlled via the isothermal annealing below the glass transition temperature, using immersion tests and potentiodynamic polarization tests in HCl aqueous solutions. It was found that the corrosion resistance of the amorphous alloy is improved by reducing the amount of excess free volume. The possible reason explaining the experimental result was discussed from the viewpoint of the internal energy associated with the annihilation of excess free volume.

• 대한화학회지
• /
• 제54권1호
• /
• pp.71-76
• /
• 2010

298.15~318.15 K 온도에서 디지탈 진동 U-tube densimeter 와 Ubbelohde 모세관 점성계을 사용하여 2-브로모프로판/메탄올 이성분 혼합물의 밀도와 점성도를 측정하였다. 온도와 농도에 대한 밀도와 점성도 상호 의존 관계를 조사하였다. 이성분 혼합물의 여분 몰부피와 여분 점성도를 실험으로 얻어진 밀도와 점성돌로부터 계산하여 구하였다. 모델이 실험치와 잘부합됨을 발견하였다.

• 대한수학회보
• /
• 제33권4호
• /
• pp.613-618
• /
• 1996

In this paper, M will always denote an n- dimensional complete Riemannian manifold and $\omega_n$ is the volume of $S^n$.

• 한국자동차공학회논문집
• /
• 제11권3호
• /
• pp.48-57
• /
• 2003

A cylindrical constant volume combustion chamber was used to investigate the flow characteristics at spark plug and the combustion characteristics of homogeneous charge methane-air mixture under various initial pressure, excess air ratio and ignition times in quiescent mixture. The flow characteristics such as mean velocity and turbulence intensity was analyzed by hot wire anemometer. Combustion pressure development measured by piezoelectric pressure transducer and flame propagation acquired by ICCD camera were used to investigate the effect of initial pressure, excess air ratio and ignition times on pressure, combustion duration, flame speed and burning velocity. Mean velocity and turbulence intensity had the maximum value at 200 or 300ms and then decreased to near 0 value gradually after 3 seconds. Combustion duration, flame speed and burning velocity were observed to be promoted with excess air ratio of 1.1, lower initial pressure and ignition time of 300ms.

• 한국연소학회지
• /
• 제13권3호
• /
• pp.9-16
• /
• 2008

In this study, a cylindrical constant volume combustion chamber is used to investigate the flow and combustion characteristics of methane-air homogeneous mixture under various initial charge pressure, excess air ratios and ignition times. The flame and burning speed, mean gas speed are calculated by numerical analysis to analyze the combustion characteristics. It is found that the mean gas velocity during combustion has the maximum value around 300 ms and then decreased gradually on the condition of 10000 ms, and that the combustion duration is shorten and flame speed and burning velocity have the highest value under the conditions of an excess air ratio 1.1, an initial charge pressure of 0.2 MPa and an ignition time of 300 ms in the present study. And, the initial pressure and burning speed are in inverse proportion, so that it is in agreement with Strehlow who presented that the initial pressure and burning speed are in inverse proportion when the burning speed is under 50cm/s.

• Korean Chemical Engineering Research
• /
• 제59권4호
• /
• pp.644-651
• /
• 2021

Alkyl amines are widely used in various industries. Nowadays these are also used in CO₂ capture technology because amines react with CO₂ and remove it from the flue gas. To make the amines more compatible towards this technology, physico chemical properties may be altered by mixing with other solvents. In the present report, we measured the refractive properties of pure diisopropylamine (DIPA) (1) + isomeric butanol (2) at 298.15 K to 308.15 K. The 𝚫n values were positive for DIPA + n-butanol or sec-butanol or isobutanol or tert-butanol mixtures. The measured data was correlated with Redlich-Kister equation. The excess molar volume data were predicted from refractive index data using Nakata and Sakurai model. The experimental data were also predicted by various correlations, and the prediction capability of these correlations was reported through standard deviation. Further, the deviation in refractive index (𝚫n) data was interpreted by the consideration of specific molecular interactions between DIPA and isomeric butanol.