• Title/Summary/Keyword: Excess properties

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Nutrient dynamics study of overlying water affected by peroxide-treated sediment

  • Haque, Niamul;Kwon, Sung-Hyun
    • Journal of Ecology and Environment
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    • v.41 no.9
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    • pp.235-245
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    • 2017
  • Background: Loading of excess nutrient via bioremediation of polluted sediment to overlying water could trigger anoxia and eutrophication in coastal area. The aim of this research was to understand the changes of overlying water features such as dissolved oxygen (DO); pH; oxidation reduction potential (ORP); $chlorophyll-{\alpha}$ ($Chl-{\alpha}$); and nitrogen nutrients ammonia ($N-NH_4{^+}$), nitrate ($N-NO_3{^-}$), and nitrite ($N-NO_2^-$) when the sediment was not treated (control) and treated by calcium peroxide for 5 weeks. Methods: The water samples were analyzed for measuring physical and chemical properties along with the sediment analyzed by polymerase chain reaction (PCR) including denaturing gradient gel electrophoresis (DGGE) for identifying the phylogenetic affiliation of microbial communities. Results: Results showed that due to the addition of calcium peroxide in sediment, the overlying water exposed the rise of dissolve oxygen, pH, and ORP than control. Among the nitrogen nutrients, ammonia inhibition was higher in calcium peroxide treatment than control but in case of nitrate inhibition, it was reversed than control. $Chlorophyll-{\alpha}$ was declined in treatment column water by 30% where it was 20% in control column water. Actibacter and Salegentibacter group were detectable in the calcium-peroxide-treated sediment; in contrary, no detectable community ware found in control sediment. Both phylogenetic groups are closely related to marine microflora. Conclusions: This study emphasizes the importance of calcium peroxide as an oxygen release material. Interaction with peroxide proved to be enhancing the formation of microbial community that are beneficial for biodegradation and spontaneity of nutrient attenuation into overlying water.

A Study on the Diverse Roles of Sugar in Confectionery and Bread-making. (제빵 제과에 다양한 설탕 이용에 관한 연구)

  • 이명호
    • Culinary science and hospitality research
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    • v.4
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    • pp.249-269
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    • 1998
  • What satisfies the desire of human beings about taste most easily is sweet taste, and it has seemed that the pronoun of sweet taste is sugar. Sugar is used in confectionery and bread-making essentially, and it has influence on the structure and touch of baked confectionery. In addition, if we soften the and apply heat, coloring is made. Thus, it colors good. It doesn't have a sweet taste, but it has the effect to emit fragrance variously, balance and soften the product. The kinds of sugar are very diverse, and it is sugar to be referred to as white sugar is used most frequently. In this study, this researcher examined the classification of physicochemical property and melting point etc. of sugar in confectionery and bread-making through theoretical study, about the simple classification of sugar. In addition, this researcher approached about the role of sugar in confectionery and bread-making and about the influence to have when it is more or less than proper quantity, centering around function. As the result, this researcher extracted the importance of sugar in confectionery and bread-making. It means that the increase of 5% of sugar quantity decreases the absorption quantity of moisture by 1% in bread-making and that the excess of 8% of sugar slow the action of yeast in straight method. Besides, there are the properties such as absorptive property, permeability, storage nature, aging prevention of starch, oxidation restraint of oils and fats, the gelation action of pectin, the fermentation acceleration of yeast, and the emulsification-maintaining-nautre and antiseptics effect of fat-soluble material. And in confectionery, sugar makes fragrance and peel color, increases the storage nature with moisture maintenance and has the softening effect. So, it is considered that the attitude to study and make efforts continuously on the basis of the role of sugar will have to be unfolded in confectionery and bread-making.

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A Novel Atomic Layer Deposited Al2O3 Film with Diluted NH4OH for High-Efficient c-Si Solar Cell

  • Oh, Sung-Kwen;Shin, Hong-Sik;Jeong, Kwang-Seok;Li, Meng;Lee, Horyeong;Han, Kyumin;Lee, Yongwoo;Lee, Ga-Won;Lee, Hi-Deok
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.14 no.1
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    • pp.40-47
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    • 2014
  • In this paper, $Al_2O_3$ film deposited by thermal atomic layer deposition (ALD) with diluted $NH_4OH$ instead of $H_2O$ was suggested for passivation layer and anti-reflection (AR) coating of the p-type crystalline Si (c-Si) solar cell application. It was confirmed that the deposition rate and refractive index of $Al_2O_3$ film was proportional to the $NH_4OH$ concentration. $Al_2O_3$ film deposited with 5 % $NH_4OH$ has the greatest negative fixed oxide charge density ($Q_f$), which can be explained by aluminum vacancies ($V_{Al}$) or oxygen interstitials ($O_i$) under O-rich condition. $Al_2O_3$ film deposited with $NH_4OH$ 5 % condition also shows lower interface trap density ($D_{it}$) distribution than those of other conditions. At $NH_4OH$ 5 % condition, moreover, $Al_2O_3$ film shows the highest excess carrier lifetime (${\tau}_{PCD}$) and the lowest surface recombination velocity ($S_{eff}$), which are linked with its passivation properties. The proposed $Al_2O_3$ film deposited with diluted $NH_4OH$ is very promising for passivation layer and AR coating of the p-type c-Si solar cell.

Effect of Ti substitution on electrochemical properties $Li_{0.44}MnO_2$ synthesized by solid state reaction (고상반응법에 의해 제조된 $Li_{0.44}MnO_2$의 전기화학적 성질에 미치는 Ti 치환의 영향)

  • ;Marca M. Doeff;Abraham Anapolsky;Thomas J. Richardson
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.5
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    • pp.362-366
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    • 2000
  • $Li_{0.44}MnO_2$cathode material has high reversibility during lithium insertion processes and is not easily damaged through over-charging or over-discharging. $Mn_2O_3$is often present as an impurity phase, and reduce the electrochemical capacity of electrode because this phase is electrochemically inert. Adding of excess NaOH reduced the $Mn_2O_3$to the content under undetectable by X-ray diffraction. Because the capacity can be increased in the cathode materials with larger unit cell, some of the manganese was replaced with titanium having larger ion size, and powders with the formula $Li_{0.44}T_{iy}Mn_{1-y}O_2$(where y = 0.11, 0.22, 0.33, 0.44, and 0.55) was synthesized and characterized. A maximum reversible capacity of 150 mAh/g was obtained for $Li/P(EO)_8$LiTFSI/$Li_{0.44}Ti_{0.22}Mn_{0.78}O_2$cells in electrochemical potential spectroscopy (ECPS) experiments. Cells with the titanium-doped manganese oxides exhibited a fade rate of 0.12 % or less per cycle.

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Mineral Distribution of Soil at Different Depth in a Fairway Slope (훼어웨이 경사의 토양 깊이별 무기성분 분포)

  • Choi, B. J.;Ju, Y. H.;Park, H.
    • Asian Journal of Turfgrass Science
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    • v.11 no.2
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    • pp.89-95
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    • 1997
  • Soil chemical properties were investigated to elucidate vertical movement of mineral nutrients in a fairway slope of 27 year-old golf course. Soil samples were taken at every 10cm depth to 4Ocm on 4 sites 20m apart each along two parallel lines 60m apart on the slope(15˚) in August. Accord-ing to the similarity of vertical distribution pattern they could be classified into 6 distinctive groups(magnesium, nitrate, phosphorus, ammonium, manganese and copper) and the slope tended to affect the vertical movement of minerals. The contents of Ca and Mg increased with depth while NO$_3$-N and Zn decreased and correlated positively. Soil pH showed significant positive correlation with depth, Ca and Mg. Phosphorus content was highest in 10~20cm depth and decreased resulting in relatively high content in 30~40cm depth of the bottom site of slope. Iron distribution pattern was similar to phosphorus. Potassium and $NH_4$showed various(irregular) patterns. Mn was highest in the deep layer at the lower sites of slope but it was reverse at the upper sites and negatively correlated with Fe. Cu content incresed with depth and heighest in 20~30cm depth. Electroconductivity showed significant positive correlation with $NO_3$-N. Magnesium, cal-cium and copper seem to be prone to defficiency due to fast leaching, and nitrate and phosphorus prone to excess problem. Preventive measures on acidification of surface soil should be taken.

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Effect of Ionic Polymers on Sodium Intake Reduction (이온성 고분자를 이용한 나트륨 섭취 감소 효과)

  • Park, Sehyun;Lee, YoungJoo;Lee, Jonghwi
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.533-538
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    • 2013
  • Sodium chloride is present in our body fluids, and the blood contains approximately 0.9 wt% salt, which plays an important role in maintaining the osmotic pressure. However, the amount of salt intake has consistently increased, and an excessive intake can be the cause of high blood pressure, etc. In this study, it was investigated in vivo and in vitro whether biocompatible ionic polymers with K or Ca ions can be replaced by Na ions through an ion exchange process to be excreted. Among the polymers, Ca-polystyrene sulfonate, K-polystyrene sulfonate, Ca-carrageenan, and Ca-tamarind had an excellent Na exchange ability in the body temperature, simulated gastric fluid and also simulated intestinal fluid. The mechanism of Na removal by absorption and excretion without changing food taste in the mouth through the insolubility properties of these polymers is expected to be a solution for the current problems related with excess sodium intake.

Effect of $N_2$ and $O_2$ Properties of STS304 Stainless Steel Films Synthesized by Unbalanced Magnetron Sputtering Process (비대칭 마그네트론 스퍼터링법에 의해 합성된 STR304 스테인리스강 박막에서의 질소와 산소의 첨가 효가)

  • 김광석;이상율;김범석;한전건
    • Journal of the Korean institute of surface engineering
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    • v.34 no.2
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    • pp.89-96
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    • 2001
  • N- or O-doped STS304 stainless films were synthesized by an unbalanced magnetron sputtering process with various argon and reactive gas ($N_2$, $O_2$) mixtures. These films were examined by scanning electron microscopy (SEM), X-ray diffraction (XRD), Auger electron spectroscopy (AES) and Knoop microhardness tester. The Results from X-ray diffraction (XRD) analysis showed that a STS304 stainless steel film synthesized without reactive gas using a bulk STS304 stainless steel target had a ferrite bcc structure ($\alpha$ phase), while the N-doped STS304 stainless film was consisted of a nitrogen supersaturated fcc structure, which hsa a strong ${\gamma}$(200) phase. In the O-doped films, oxide Phases ($Fe_2$$O_3$ and $Cr_2$$O_3$) were observed from the films synthesized under an excess $O_2$ flow rate of 9sccm. AES analysis showed that nitrogen content in N-doped films increased as the nitrogen flow rate increased. Approximately 43 at.%N in the N-doped film was measured using a nitrogen flow rate of 8sccm. In O-doped film, approximately 15 at.%O was detected using a $O_2$ flow rate of 12sccm. the Knoop microhardness value of N-doped film using a nitrogen flow rate of 8 sccm was measured to be approximately $H_{ k}$ 1200 and this high value could be attributed to the fine grain size and increased residual stress in the N-doped film.

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Low-Firing Pb(Zr,Ti)O3-Based Multilayer Ceramic Actuators Using Ag Inner Electrode

  • Han, Hyoung-Su;Park, Eon-Cheol;Lee, Jae-Shin;Yoon, Jong-Il;Ahn, Kyoung-Kwan
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.6
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    • pp.249-252
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    • 2011
  • We investigated the low firing of $Li_2CO_3$ added $0.2Pb(Mg_{1/3}Nb_{2/3})O_3$ - 0.3Pb($Fe_{1/2}Nb_{1/2}$) - $0.5Pb(Zr_{0.475}Ti_{0.525})O_3$ (PMN-PFN-PZT) ceramics and multilayer actuators (MLAs) using Ag inner electrodes. It was found that 0.1 wt% $Li_2CO_3$ was quite effective in lowering the sintering temperature of PMN-PFN-PZT ceramics from $1,100^{\circ}C$ down to $900^{\circ}C$ without deteriorating their piezoelectric ceramics ($d_{33}$ = 425 pC/N and $k_p$ = 61.9%). However, excess $Li_2CO_3$ up to 0.3 wt% brings about unwanted problems such as the formation of a $LiPbO_2$ secondary phase and subsequent degradation in the piezoelectric properties. Using 0.1 wt% $Li_2CO_3$ added PMN-PFN-PZT ceramics, MLAs with Ag inner electrodes were successfully fabricated, resulting in a normalized strain of 580 pm/V at an electric field of 1.5 kV/mm.

Effect of molecular and crystalline structure on phase transition behaviors of rice starches (쌀전분의 분자 및 결정구조가 상전이에 미치는 영향)

  • Jeong, Duyun;Lee, Su-Jin;Chung, Hyun-Jung
    • Korean Journal of Food Science and Technology
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    • v.51 no.5
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    • pp.432-437
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    • 2019
  • The objective of this study was to determine the molecular/crystalline structures and phase transition properties of starches isolated from six rice cultivars grown in Korea. Apparent amylose content was highest in starch obtained from the Saemimyeon cultivar (30.8%) and lowest in that obtained from the Sheonhyangheukmi cultivar (20.3%). Starch from the Saemimyeon cultivar had a lower proportion of short chains (DP 6-12) and a the higher proportion of long chains (DP${\geq}37$) than that seen in other rice starches. Saemimyeon had relatively higher pasting temperature ($86.5^{\circ}C$), gelatinization temperature ($72.1^{\circ}C$) and gelatinization enthalpy (14.2 J/g) than these values found for other rice starches. The onset temperature and enthalpy for ice crystallization of rice starch ranged from $-27.1{\sim}-20.2^{\circ}C$ and 241.1~264.8 J/g, respectively. The ice melting enthalpy measured in excess water (67% water content) of rice starches was 282.4~310.1 J/g. Among the rice starches examined, starch obtained from Sheonhyangheukmi, with the lowest amylose content, showed the lowest glass transition temperature (${T_g}^{\prime}$).

Evaluation of Low-temperature Thermal Pre-treatment and Biogas Characteristics using Waste Activated Sludge (잉여슬러지를 이용한 저온 열적전처리 및 바이오 가스 특성 평가)

  • Choi, Jae-Hoon;Jeong, Seong-Yeob;Kim, Ji-Tae
    • Journal of Korean Society on Water Environment
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    • v.35 no.4
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    • pp.299-307
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    • 2019
  • The purpose of this study was to investigate the effect of low temperature thermal pre-treatment on biodegradation of waste activated sludge for anaerobic digestion as a countermeasure for increasing sludge generation. The experimental condition was accomplished in 2 %, 4 %, and 6 % TS concentration, and $70^{\circ}C$, $80^{\circ}C$, $90^{\circ}C$ of temperature for a maximum of 120 minutes retention time. Then, it was followed by analysis of physical/chemical properties, BMP test and composition of biogas. The biogas characteristic was evaluated by applying the modified Gomperz model. As a result, solubility of dissolved substrate, such as $SCOD_{Cr}$, soluble carbohydrate, and soluble protein, and biogas production increased as temperature increased. Solubilization efficiency at $90^{\circ}C$ was 18.4 %, 17.03 % and 16.88% in 2 %, 4 %, and 6 % TS concentration respectively. Also, solubilization rates of carbohydrate and protein similarly increased. BMP test results also showed that methane production in excess sludge increased to 0.194, 0.187 and $0.182m^3/kg$ VS. respectively, and lag phase decreased to 0.145, 0.220, 0.351 day due to acceleration of the hydrolysis step. Consequently, low-temperature thermal pre-treatment could increase biodegradability of sludge, positively affecting biogas production and sludge reduction.