• 제목/요약/키워드: Excess properties

검색결과 496건 처리시간 0.023초

화학적처리 양돈폐수 잉여오니와 톱밥 혼합물 퇴비화 및 퇴비탈취처리 (Composting Chemical Treated Hog Wastewater Excess Sludge Amended with Sawdust and Compost Biofiltration)

  • 홍지형;박금주
    • 한국축산시설환경학회지
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    • 제12권1호
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    • pp.29-34
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    • 2006
  • The effects of turning frequency were examined on the efficiency of composting lime treated excess sludge amended with sawdust from the activated sludge process after a liquid/solids separation process. The raw and excess sludge from the activated sludge process associated with the hog wastewater treatment system is a significant problem and composting is an effective method far reducing the pollution potential of hog wastewater sludge. The coagulant used sludge composting and ammonia emissions from composting are not well established. The effect of compost properties such as high total carbon, C/N ratio and pH value on performance of composting sludge and biofiltration of ammonia from composting process were investigated. The ammonia emission was not significantly increased during composting. The ammonia concentrations of the exhaust air of composter were ranged from 0.5 and 7 ppm about 12 days after composting. The performance of the hog wastewater sludge composting was the most sensitive to chemical treated sludge properties such as high total carbon and high C/N ratio of the initial compost mixes. Temperature in compost and ammonia emission were not greatly affected by the turning frequency.

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Thermophysical Properties of Acetophenone with Ethylchloroacetate at Temperatures of 303.15, 313.15 and 323.15 K

  • Saravanakumar, K.;Baskaran, R.;Kubendran, T.R.
    • 대한화학회지
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    • 제56권4호
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    • pp.424-430
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    • 2012
  • Densities, viscosities, refractive indices and speed of sounds of the binary mixtures of Acetophenone with Ethylchloroacetate were measured over the entire mole fractions at (303.15, 313.15 and 323.15) K. From these experimental results, excess molar volume $V^E$, viscosity deviation ${\Delta}{\eta}$, refractive index deviation ${\Delta}n_D$, deviations in speed of sound ${\Delta}u$, deviations in isentropic compressibility ${\Delta}k_s$ and excess intermolecular free length ${\Delta}L_f$ were calculated. The viscosity data have been correlated with the equations of Grunberg and Nissan, Hind et al., Tamura and Kurata, Katti and Chaudri, Sedgwick, Krishnan-Laddha and McAllister. The thermo physical properties under study were fit to the Jouyban-Acree model. The excess values were correlated using Redlich-Kister polynomial equation to obtain their coefficients and standard deviations. It was found that in all cases, the data obtained fitted with the values correlated by the corresponding models very well. The results are interpreted in terms of molecular interactions occurring in the solution.

$91PbO-9WO_3$가 과잉첨가된 $40Pb(Mg_{1/3}Nb_{2/3})O_3-30PbTiO_3-30Pb(Mg_{1/2}W_{1/2})O}3$계 세라믹스의 미세구조와 유전특성 (Microstructure and Dielectric Properties in $40Pb(Mg_{1/3}Nb_{2/3})O_3-30PbTiO_3-30Pb(Mg_{1/2}W_{1/2})O}3$ Ceramics with Excess $91PbO-9WO_3$ Addition)

  • 길영배;이응상
    • 한국세라믹학회지
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    • 제34권3호
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    • pp.281-288
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    • 1997
  • 유전율이 높고 온도안정성이 우수하다고 알려져 있는 40Pb(Mg1/3Nb2/3)O3-30PbTiO3-30Pb(Mg1/2W1/2)O3계 세라믹스에 소결온도를 낮추기 위하여 저온에서 액상을 형성하는 91PbO-9WO3를 과잉첨가하여 소결성, 미세구조 및 유전성의 변화에 대하여 조사하였다. 91PbO-9WO3의 첨가량이 증가함에 따라 소결온도가 저하하였으며 6 mol%첨가시는 875$^{\circ}C$에서 소결이 가능하였다. 유전율은 기본조성에서 16,400이었고, 첨가제가 1 mol% 과잉첨가된 경우 18,500으로 최대값을 나타냈으며 이후 첨가량이 증가함에 따라 감소하였다. 첨가제의 첨가량이 2~4mol%인 시편의 온도에 따른 유전율 변화곡선에서 double peak maxima가 나타났으나, 첨가량이 5 mol% 이상인 시편에서는 입계에 텅스텐을 많이 포함하고 있는 결정상이 생성되었고 double peak maxima는 나타나지 않았다.

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MOD-TFA 공정에 의한 YBCO박막제조시 과잉 yttrium첨가 효과에 관한 연구 (Effects of Excess Yttrium Addition on YBCO Thin Films Prepared by TFA-MOD Process)

  • 이승이;송슬아;김병주;박진아;김호진;이희균;홍계원;장석헌;주진호;유재무
    • Progress in Superconductivity
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    • 제7권1호
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    • pp.87-91
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    • 2005
  • [ $YBa_{2}Cu_{3}O_{7-x}$ ] thin films were fabricated on $LaAlO_3$(100) substrate by TFA-MOD process. Yttrium-excess (0, 2.5, 5, 10, 15, 20 $at\%$) coating solution was prepared by adding extra amount of yttrium into a stoichiometric(Y:Ba:Cu=1:2:3) TFA precursor solution. Results are presented concerning the influence of excess yttrium additions on the microstructure development and superconducting properties of $YBa_{2}Cu_{3}O_{7-x}$ film. Large sized CuO particles was observed by SEM EDS investigation. The addition of excess yttrium affected little on $T_c$ of $YBa_{2}Cu_{3}O_{7-x}$ film. $J_c$ of YBCO film was enhanced with excess yttrium addition. Jc maximum of $2.21\;MA/cm^2$ (77 K, self field) appeared with the $15\;at\%$ addition of excess yttrium. With further yttrium addition up to $20\;at\%$, Jc decreased down to $0.9\;MA/cm^2$.

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Ti 조성이 (Ba, Sr) $TiO_3$계 반도체 세라믹에 미치는 영향 (The Effect of Ti Compositions on (Ba, Sr) $TiO_3$ Semiconducting Ceramics)

  • 박금덕;조상희
    • 한국세라믹학회지
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    • 제22권3호
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    • pp.46-52
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    • 1985
  • (Ba0.8. Sr0.2) $TiO_3$ semiconducting ceramic with and without Ti-excess composition were prepared by various sintering temperature. The effects of Ti compositions on the samples were discussed in terms of color micro-structure resistivity at room temperature and the positive temperature coefficient resistivity(PTCR). The 1.02mol Ti-excess composition provides better PTCR properties and has uniform micrositructures with 5-7${\mu}{\textrm}{m}$.

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Methanol+Dimethyl Carbonate 혼합계의 333.15 K 등온 기-액 평형과 열역학 과잉 물성 (Isothermal Vapor-Liquid Equilibria at 333.15K and Thermodynamic Excess Properties for the Binary System of Methanol+Dimethyl Carbonate)

  • 한규진;박소진
    • Korean Chemical Engineering Research
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    • 제43권3호
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    • pp.387-392
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    • 2005
  • Dimethyl carbonate(DMC)는 낮은 독성과 빠른 생분해성으로 인해 MTBE(methyl tert-butyl ether)를 대체할 수 있는 무연가솔린의 첨가제로 주목받는 물질로, 주로 methanol의 carbonylation에 의해 합성되고, 원가절감을 위해 methanol을 출발물질로 한 새로운 DMC 제조공정의 개발이 진행 중에 있다. 이에 필요한 다양한 조건하의 DMC 관련 혼합계의 상평형 자료 및 물성은 Dortmund Data Bank(DDB)검색 결과, 매우 부족하며 무한희석 활동도계수에 대한 자료는 전무한 것으로 나타났다. 이 글에서는 methanol+DMC계의 333.15 K에서의 이성분계 등온 기-액 평형과, 혼합물성으로써 methanol+DMC계의 과잉부피 및 점도편차를 298.15 K에서 측정하였다. 또한, 무한희석상태에서 DMC 용매에서의 methanol의 무한희석 활동도계수를 303.15, 313.15, 323.15 K에서 각각 측정하였으며, 측정값은 modified UNIFAC(Dortmund)식에 의한 계산 값과도 비교하였다.

초과엔탈피 화염의 점근 해석 (An Asymptotic Analysis of Excess Enthalpy Flame)

  • 이대근
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.135-137
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    • 2014
  • Excess enthalpy flame propagating an porous inert medium, which recirculate exhaust heat to the upstream cold mixture, is theoretically analyzed. Using the activation-energy asymptotics, the flame structure is divided into the thin reaction and the gas-phase preheat zone, as is traditionally done. Ahead and behind of the two, there exist an outer preheat zone, where heat is convectively transferred from solid to gas, and a downstream re-equilibrium zone, where thermal equilibrium between phases is established. Asymptotic solutions of species and energy equations in each zone are obtained and then matched to each other, and finally the mass burning rate is obtained as a function of the flame propagation velocity with respect to the solid phase and physical properties of gas and solid.

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복합 Ni-Zn Ferrite의 제조 및 전파흡수특성 (Preparation and Microwave Absorbing Characteristics of Ni-Zn Ferrite Composite)

  • 최경구;오재희;김성수;김재묵
    • 한국세라믹학회지
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    • 제29권7호
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    • pp.505-510
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    • 1992
  • The influence of excess iron content (x) and reaction atmosphere on permittivity, permeability and microwave absorbing properties has been investigated in composite specimens embeded with (Ni0.4Zn0.6O)1-x(Fe2O3)1+x powders. A nitrogen atmosphere used for the reaction of the ferrite with excess iron composition (x>0) enhances spinel formation, and thereby increases both the magnetic and the dielectric loss of the ferrite composite. We also investigated the relation between the electromagnetic constants and the absorbing properites using impedance-matching solution maps for zero reflection. It is suggested that a superior microwave absorber can be fabricated through atmosphere and excess iron control during the powder process.

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깊이 식각된 다중모드 간섭 영역으로 구성된 광전력 분배기 및 결합기의 설계 (Design of optical power splitters and couplers composed of deeply etched multimode interference section)

  • 김정욱;정영철
    • 전자공학회논문지D
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    • 제34D권4호
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    • pp.62-72
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    • 1997
  • The optical power splitter/couplers based on MMI(multimode interference) in GaAs/AlGaAs are studied. We presetn a design of optical power splitter/couplers, which have deeply etched multimode waveguide. The properties and fabrication tolerance on the etching depth, multimode waveguide width are simulatedusing a FD-BPM (finite difference beam propgation method). Proposed 1*N optical of designed device is 0.7dB smaller than the optical power splitter with a shallowly etched MMI section. For 0.5dB excess loss, the predicted fabrication tolerance is 0.6.mu.m on the multimode waveguide width of the 14 optical power splitter with a deeply etched MMI section. Also excess loss and uniformity of poposed 32*32 optical power coupler are below 0.3dB. The excess loss of proposed 32*32 optical power coupler is 2dB smaller than the optical power coupler with a shallowly etched MMI section. It is shown that the optical power splitters/couplers with a deeply etched mMI section have low loss, good uniformity, and improved fabriction tolerance.

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혼합된 정공 수송 층을 이용한 유기발광소자의 효율 및 수명 개선 (Improved Efficiency and Lifetime for Organic Light-emitting Devices based on Mixed-hole Transporting Layer)

  • 서지현;박정현;박일흥;김준호;김영관
    • 한국전기전자재료학회논문지
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    • 제20권3호
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    • pp.257-262
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    • 2007
  • Organic light-emitting diodes (OLEDs) with the high efficieney and long lifetime are of growing interest in next-generation displays. Among the factors influencing OLEDs properties, one of unstable factor is $Alq_3$ cationic species caused by the excess holes resided in $Alq_3$ layer. Therefore, we suppressed the accumulation of excess holes by using the mixed-hole transporting layer (MHTL) of NPB and CBP in multilayer green OLEDs. The devices with MHTL showed improved characteristics in the luminous efficiency and lifetime. More characteristics and the carrier transport mechanism will be discussed.