• 제목/요약/키워드: Ex-situ

검색결과 242건 처리시간 0.037초

Physical Property Change of the Gapless Semiconductor $PbPdO_2$ Thin Film by Ex-situ Annealing

  • Choo, S.M.;Park, S.M.;Lee, K.J.;Jo, Y.H.;Park, G.S.;Jung, M.H.
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
    • /
    • pp.371-372
    • /
    • 2012
  • We have studied lead-based gapless semiconductors, $PbPdO_2$, which is very sensitive to external parameters such as temperature, pressure, electric field, etc[1]. We have fabricated pure $PbPdO_2$, Co- and Mn-doped $PbPdO_2$ thin films using the pulsed laser deposition. Because of the volatile element of Pb, it is very difficult to grow the films. Note that in case of $MgB_2$, Mg is also volatile element. So in order to enhance the quality of $MgB_2$, some experiments are carried out in annealing with Mg-rich atmosphere [2]. This annealing process with volatile element plays an important role in making smooth surface. Thus, we applied such process to our studies of $PbPdO_2$ thin films. As a result, we found the optimal condition of ex-situ annealing temperature ${\sim}650^{\circ}C$ and time ~12 hrs. The ex-situ annealing brought the extreme change of surface morphology of thin films. After ex-situ annealing with PbO-rich atmosphere, the grain size of thin film was almost 100 times enlarged for all the thin films and also the PbO impurity phase was smeared out. And from X-ray diffraction measurements, we determined highly crystallized phases after annealing. So, we measured electrical and magnetic properties. Because of reduced grain boundary, the resistivity of ex-situ annealed samples changed smaller than no ex-situ sample. And the carrier densities of thin films were decreased with ex-situ annealing time. In this case, oxygen vacancies were removed by ex-situ annealing. Furthermore, we will discuss the transport and magnetic properties in pure $PbPdO_2$, Co- and Mn-doped $PbPdO_2$ thin films in detail.

  • PDF

미생물을 이용한 원유 회수증진법에 대한 동향연구 (Brief Review on Microbial Enhanced Oil Recovery)

  • 오경석
    • 한국응용과학기술학회지
    • /
    • 제38권4호
    • /
    • pp.1010-1019
    • /
    • 2021
  • 유전에 매장된 석유는 1차, 2차, 그리고 3차에 걸쳐 회수된다. 3차 회수로 분류된 공법 중 미생물을 이용한 원유 회수증진법은 크게 in-situ와 ex-situ 공법으로 나눌 수 있다. In-situ 공법은 미생물을 저류층에 직접 투입하여 미생물의 대사활동을 통한 원유의 회수를 유도하는 공법이다. 대사물질 중 바이오 계면활성제는 저류층 잔존 유분의 유동화에 큰 역할을 한다. 한편, ex-situ 공법은 외부에서 미생물의 대사물질을 추출하여 저류층에 투입하여 원유를 회수하는 방법이다. 두 가지 공법 모두 친환경적이지만, 보다 경제적인 in-situ 공법이 선호된다. 미생물을 이용한 원유 회수증진법은 오랜기간 검토되었음에도, 현재까지도 파일럿 규모에서 여전히 평가가 진행 중이다. 본 논문에서는, in-situ 공법에 적용가능한 미생물 중 박테리아의 종 특성과 대사물질에 대해서 살펴보았다.

기계적 합금화 및 in-situ와 ex-situ의 혼합공정을 통한 C 도핑된 ex-situ $MgB_2$ 선재 제조 (Mechanical Alloying and Combined Process of in-situ and ex-situ to Fabricate the ex-situ C-doped $MgB_2$ Wire)

  • 황수민;이창민;임준형;최준혁;박진현;주진호;전병혁;김찬중
    • Progress in Superconductivity
    • /
    • 제10권2호
    • /
    • pp.79-86
    • /
    • 2009
  • We successfully fabricated C-doped ex-situ $MgB_2$ wires using two different methods such as mechanical alloying(MA) and combined process(CP) of in-situ and ex-situ. In the MA, the precursor powder was prepared with a mixture of $MgB_2$ and 1 at% C powders by planetary ball milling for 0-100 h. In the CP, on the other hand, C-doped $MgB_2$ powder was prepared with Mg, B, and C powders by in-situ process via compaction, sintering, and crushing. The powders prepared by two methods were loaded into Fe tube and then the assemblages were drawn by a conventional powder-in-tube technique. The MA treatment of C-added $MgB_2$ decreased the particles/grains size and resulted in C-doping into $MgB_2$ after sintering, improving the critical current density($J_c$) in high external magnetic field. For the C-doped $MgB_2$ wire by MA for 25 h, the $J_c$ was $4.1{\times}10^3A/cm^2$ at 5 K and 6.4 T, which was 5.9 times higher than that of pure and untreated $MgB_2$ wire. The CP also provided C-doping into $MgB_2$ and improved the $J_c$ in high magnetic field; the C-doped $MgB_2$ wire fabricated by CP exhibited a $J_c$ being 2.3 times higher than that of the ex-situ wire used commercial $MgB_2$ powder at 5 K and 6.0 T($2.7{\times}10^3A/cm^2\;vs.\;1.2{\times}10^3A/cm^2$).

  • PDF

Ex-situ Reductive Dechlorination of Carbon Tetrachloride by Iron Sulfide in Batch Reactor

  • Choi, Kyung-Hoon;Lee, Woo-Jin
    • Environmental Engineering Research
    • /
    • 제13권4호
    • /
    • pp.177-183
    • /
    • 2008
  • Ex-situ reductive dechlorination of carbon tetrachloride (CT) by iron sulfide in a batch reactor was characterized in this study. Reactor scaled-up by 3.5 L was used to investigate the effect of reductant concentration on removal efficiency and process optimization for ex-situ degradation. The experiment was conducted by using both liquid-phase and gas-phase volume at pH 8.5 in anaerobic condition. For 1 mM of initial CT concentration, the removal of the target compound was 98.9% at 6.0 g/L iron sulfide. Process optimization for ex-situ treatment was performed by checking the effect of transition metal and mixing time on synthesizing iron sulfide solution, and by determining of the regeneration time. The effect of Co(II) as transition metal was shown that the reaction rate was slightly improved but the improvement was not that outstanding. The result of determination on the regeneration time indicated that regenerating reductant capacity after $1^{st}$ treatment of target compound was needed. Due to the high removal rates of CT, ex-situ reductive dechlorination in batch reactor can be used for basic treatment for the chlorinated compounds.

Ex-situ Stabilization and Utility Prospects of 'Jata' Ecorace of Tropical Tasar Silkworm Antheraea mylitta Drury

  • Hansda, G.;Reddy, R. Manohar;Sinha, M. K.;Ojha, N. G.;Prakash, N. B. Vijaya
    • International Journal of Industrial Entomology and Biomaterials
    • /
    • 제17권2호
    • /
    • pp.169-172
    • /
    • 2008
  • Indian tropical tasar silkworm, Antheraea mylitta D is reported to have forty four ecoraces by way of their adoption to different topographical and vegetational conditions. Of late, another ecorace 'JATA' - univoltine under in-situ condition has been explored which is localized in Thakurmunda area of the foot hills of Simlipal biosphere (Mayurbhanj district) of Orissa, India. The ecorace 'Jata' exhibits superior economic characters over widely commercialized ecoraces of Daba and Sukinda. The cocoon production of localized 'Jata' ecorace is depleting day by day in in-situ condition. In the present study, efforts were made to stabilize the ecorace 'Jata' under ex-situ condition at Ranchi (Jharkhand), where the 'Jata' ecorace silkworms were reared on Terminalia tomentosa for four successive generations during 2006 and 2007 and the cocoons were preserved in grainage house under prevailing climatic conditions. The results indicated change in voltinism behaviour of the 'Jata' ecorace from univoltine to bivoltine. The rearing performance and grainage efficiencies indicate the tendency of 'Jata' ecorace towards acclimatization and stabilization under Ranchi climatic conditions. The 'Jata' ecorace manifests the prospects for acclimatization, stabilization and commercial exploitation.

Determination of the minimum population size for ex situ conservation of water-shield (Brasenia schreberi J.F. Gmelin) inferred from AFLP analysis

  • Kim, Changkyun;Na, Hye Ryun;Jung, Jongduk;Kim, Hojoon;Hyun, Jin-Oh;Shin, Hyunchur;Choi, Hong-Keun
    • Journal of Ecology and Environment
    • /
    • 제35권4호
    • /
    • pp.301-306
    • /
    • 2012
  • Determination of the minimum population size is an important component for the ex situ conservation of an endangered species. Here, we present the identification of collection strategies that most efficiently captured the genetic diversity of Brasenia schreberi J.F. Gmelin (water-shield) in natural populations from the mainland (MGC) and Jeju Island (JNS) of South Korea, using amplified fragment length polymorphism (AFLP) markers. A total of 313 and 383 polymorphic bands were detected in the MGC and JNS populations, respectively. All of the 140 sampled ramets were distinguishable by the presence of distinct AFLP phenotypes. According to the simulation of the individual sampling by maximization sampling, 25 and 28 individuals captured all of the genetic diversity in the MGC population (mainland of South Korea) and the JNS population (Jeju Island), respectively. The level of genetic diversity of the core collections was similar to the entire collection, indicating that the core collections very well represent the diversity of the entire collection. We therefore suggest a management unit of B. schreberi based on the genetic information for assessing the minimum population size for its ex situ conservation.

해양동물 보전을 위한 서식지외 보전기관에 대한 대중의 인식조사에 관한 연구 - 국립해양박물관사례를 중심으로 (A Study on Public Perception of the Ex-suit Conservation Institution for Conserving Marine Animals: Case of the Korea National Maritime Museum)

  • 이범석;권석재;김태균
    • 한국항해항만학회지
    • /
    • 제43권6호
    • /
    • pp.475-482
    • /
    • 2019
  • 해양에 대한 인간의 이용과 활동의 증가는 해양오염, 해양생태계 및 서식지 파괴로 이어지고 있다. 이러한 결과, 특히 생애주기가 길고 개체수가 적은 해양동물은 멸종위기에 내몰리고 있는 실정이다. 따라서, 우리나라 정부는 2010년부터 수족관이나 해양박물관과 같이 인공적인 서식장소 11개를 서식지외 보전기관으로 지정하여 멸종위기에 처한 해양생물들을 보전하기 위해 노력하고 있다. 그러나, 해양생물의 보전 서비스를 제공하는 서식지외 보전기관에 대한 중요성과 그 경제적 가치를 추정한 연구는 아직 이루어지지 않고 있다. 따라서 본 연구의 목적은 우리나라 해양동물의 보호와 증식을 위한 관리방안인 서식지외 보전기관의 운영정책에 대한 일반시민들의 정량적 지지도를 추정하는 것이다. 이를 위해 우리나라 푸른바다거북의 보전을 위해 시식지외 보전기관으로 운영되고 국립해양박물관의 해양동물 보전역할에 대한 경제적 가치를 추정하였다. 연구의 결과, 서식지외 보전기관과 같은 비시장재인 공공재에 대한 대표적인 가치추정법인 조건부가치추정법을 적용하여 추정된 서식지외 보전기관(국립해양박물관)의 경제적 가치는 약 418억원에서 최대 약 781억원으로 나타났다. 이러한 본 연구의 결과는 해양동물관리 정책자들에게 우리나라 연안해역에 서식하는 멸종위기에 처한 해양동물의 효율적인 관리방안 수립에 유용한 기초자료로 활용될 수 있을 것이다.