• Journal of Soil and Groundwater Environment
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• v.20 no.7
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• pp.90-102
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• 2015

To understand the hyrogeochemical variation of bedrock aquifer during underground space construction, various graphical methods including multiple-component plots and chemical trends were used to estimate the mixing rate between seawater and freshwater and to investigate the evolution of water quality. The water chemistry and mixing rate between fresh and sea waters, which are generally localized in the construction area (MW-7, in land), shows typical characteristics of freshwater that doesn’t affect its validity as seawater intrusion. Especially, the water chemistry of a MW-4 (coastline) was classified as Na-Cl type, Na-HCO₃ type, and Ca-Cl type due to the influence of the seawater intrusion. And hydrogeochemical and isotopic data show that local freshwater is subjected to geochemical processes, such as reverse ion-exchange. Throughout the Chadha’s diagrams, four different case histories with the temporal and spatial variation of groundwaters in the study area were proposed, which is recommended to interpret the hydrogeochemical reactions effectively.

• Korean Journal of Materials Research
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• v.32 no.10
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• pp.408-413
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• 2022

The oxygen evolution reaction (OER) is very sluggish compared to the hydrogen evolution reaction (HER). Considering this difference is essential when designing and developing a cost-effective and facile synthesis method for a catalyst that can effectively perform OER activity. The material should possess a high surface area and more active sites. Considering these points, in this work we successfully synthesized sheets of cobalt phosphate hydrate (CP) and sulphurated cobalt phosphate hydrate (CPS) material, using simple successive ionic layered adsorption and reaction (SILAR) methods followed by sulfurization. The CP and CPS electrodes exhibited overpotentials of 279 mV with a Tafel slope of 212 mV dec^-1 and 381 mV with a Tafel slope of 212 mV dec^-1, respectively. The superior performance after sulfurization is attributed to the intrinsic activity of the deposited well-aligned nanosheet structures, which provided a substantial number of electrochemically active surface sites, speeded electron transfer, and at the same time improved the diffusion of the electrolyte.

• Journal of Hydrogen and New Energy
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• v.29 no.6
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• pp.549-558
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• 2018

The overall efficiency depend on the overpotential of the oxygen evolution reaction in alkaline water electrolysis. Therefore, it is necessary to research to reduce the oxygen evolution overpotential of electrodes. In this study, Ni-Zn-Fe electrodes were prepared by electroplating and the surface area was increased by Zn leaching process. Electroplating variables were studied to optimize the plating parameters(electroplating current density, pH value of electroplating solution, Ni/Fe content ratio). Ni-Zn-Fe electrode, which is electroplated in a modified Watts bath, showed 0.294 V of overpotential at $0.1A/cm^2$. That result is better than that of Ni and Ni-Zn plated electrodes. As the electroplating current density of the Ni-Zn-Fe electrode increased, the particle size tended to increase and the overpotential of oxygen evolution reaction decreased. As reducing pH of electroplating solution from 4 to 2, Fe content in electrode and activity of oxygen evolution reaction decreased.

• Journal of Electrochemical Science and Technology
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• v.15 no.3
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• pp.353-364
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• 2024

Through component regulation and morphological construction, it is of considerable significance to develop high-activity and high-stability electrocatalyst for hydrogen evolution in electrolytic water. In the hydrothermal process, Mo-doped nickel-based sulfide catalysts (Mo-NiS-Fx) with a variety of morphologies (prisms, rods, flakes, and cones) were created by adding NH₄F with varying masses. Among these, the flaky Mo-NiS-F1.2 exhibited exceptional performance towards electrochemical hydrogen evolution reaction, surpassing most similar catalysts with an overpotential of 79 mV at 10 mA cm^-2 and a Tafel slope of 49.8 mV dec^-1. Significantly, Mo-NiS-F1.2 maintained its high activity for hydrogen evolution over 60 h at a current density of 10 mA cm^-2, making it suitable for widespread commercial application. According to the experimental findings, an electrocatalyst with a high surface area and a porous structure is better suited to exposing more gas transfer routes and active sites, which would encourage the hydrogen evolution reaction. This study presents a straightforward procedure for creating electrocatalysts with a range of morphologies, which can serve as a model for the creation of catalysts for use in industrial manufacturing.

• Journal of the Korean Operations Research and Management Science Society
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• v.24 no.2
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• pp.69-80
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• 1999

A genetic algorithm to determine the optimal signal sequence and double cycle pattern is described. The signal sequence and double cycle pattern are used as the input for TRANSYT to find optimal signal timing at each junction in the area traffic networks, In the genetic process, the partially matched crossover and simple crossover operators are used for evolution of signal sequence and double cycle pattern respectively. A special conversion algorithm is devised to convert the signal sequence into the link-stage assignment for TRANSYT. Results from tests using data from an area traffic network in Leicester region R are given.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.31 no.1
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• pp.11-18
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• 2018

Two-dimensional (2D) materials such as transition metal dichalcogenides have attracted tremendous scientific interests owing to their potential of solving the zero band-gap issue of graphene. In this work, the research areas and technology evolutionary dynamics of the 2D materials were identified using the scientometric method focusing on keyword mapping and clustering. The time-series analysis showed that the technological progress of 2D material is in the early growth period. The overlay mapping analysis were carried out to investigate the technology evolution of 2D materials with time. The strategic diagram of co-word analysis classifying the topological positions of keyword was derived to support the analysis results. It is conjectured that extensive research will be conducted widely on the application of 2D materials not only in electronic and optoelectronic devices, but also in various other fields such as biomedical applications, and that their development will be more rapid based on accumulated results of extant graphene research.

• Molecules and Cells
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• v.41 no.3
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• pp.161-167
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• 2018

Chloroplasts are present in organisms belonging to the kingdom Plantae. These organelles are thought to have originated from photosynthetic cyanobacteria through endosymbiosis. During endosymbiosis, most cyanobacterial genes were transferred to the host nucleus. Therefore, most chloroplast proteins became encoded in the nuclear genome and must return to the chloroplast after translation. The N-terminal cleavable transit peptide (TP) is necessary and sufficient for the import of nucleus-encoded interior chloroplast proteins. Over the past decade, extensive research on the TP has revealed many important characteristic features of TPs. These studies have also shed light on the question of how the many diverse TPs could have evolved to target specific proteins to the chloroplast. In this review, we summarize the characteristic features of TPs. We also highlight recent advances in our understanding of TP evolution and provide future perspectives about this important research area.

• Journal of the Economic Geographical Society of Korea
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• v.15 no.4
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• pp.628-641
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• 2012

This research investigates a dynamic mechanism underlying the co-evolution between network and space by applying hype-curve model, typical phenomenon which shows how new technologies and ideas initially adapted in the society. This study analysis the knowledge intensive industry of digital contents using social network analysis (SNA) in terms of structural, spatial, and temporal aspects, year of 2000, 2005, and 2010 focused on Seoul area. First of all, network and space establish 'inter-feedback' as a result of evolution and differentiation process. Second, it happen temporal 'delay' through the learning process stage of 'peak of inflated expectation' and 'trough of disillusionment.' As a result, Seoul develops with the technology commercialized-orient strategy affect government policy. This trend changes to technology-oriented development in Seoul area in the late of 2000 established 'self-organization' with geographical proximity organizations through learning process.

• The Bulletin of The Korean Astronomical Society
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• v.46 no.1
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• pp.53.2-53.2
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• 2021

Quasar luminosity function (QLF) shows the active galactic nucleus (AGN) demography as a result of the combination of the growth and the evolution of black holes, galaxies, and dark matter halos along the cosmic time. The recent wide and deep surveys have improved the census of high-redshift quasars, making it possible to construct reliable ultraviolet (UV) QLFs at 2 < z < 6 down to M1450 = -23 mag. By parameterizing these up-to-date observed UV QLFs that are the most extensive in both luminosity and survey area coverage at a given redshift, we show that the UV QLF has a universal shape, and their evolution can be approximated by a pure density evolution (PDE). In order to explain the observed QLF, we construct a model QLF employing the halo mass function, a number of empirical scaling relations, and the Eddington ratio distribution. We also include the outshining of AGN over its host galaxy, which made it possible to reproduce a moderately flat shape of the faint end of the observed QLF (slope of ~ -1.1). This model successfully explains the observed PDE behavior of UV QLF at z > 2, meaning that the QLF evolution at high redshift can be understood under the framework of halo mass function evolution. The importance of the outshining effect in our model also implies that there could be a hidden population of faint AGNs (M1450 > -24 mag), which are buried under their host galaxy light.

• Korean Journal of Materials Research
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• v.30 no.5
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• pp.217-222
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• 2020

The design and fabrication of catalysts with low-cost and high electrocatalytic activity for the oxygen evolution reaction (OER) have remained challenging because of the sluggish kinetics of this reaction. The key to the pursuit of efficient electrocatalysts is to design them with high surface area and more active sites. In this work, we have successfully synthesized a highly stable and active NiCo₂S₄ nanowire array on a Ni-foam substrate (NiCo₂S₄ NW/NF) via a two-step hydrothermal synthesis approach. This NiCo₂S₄ NW/NF exhibits overpotential as low as 275 mV, delivering a current density of 20 mA cm^-2 (versus reversible hydrogen electrode) with a low Tafel slope of 89 mV dec^-1 and superior long-term stability for 20 h in 1 M KOH electrolyte. The outstanding performance is ascribed to the inherent activity of the binder-free deposited, vertically aligned nanowire structure, which provides a large number of electrochemically active surface sites, accelerating electron transfer, and simultaneously enhancing the diffusion of electrolyte.