• Title/Summary/Keyword: Eutectic solution

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Numerical Investigation on the Urea Melting Characteristics with Coolant and Electric Heaters (냉각수 및 전기 가열 방식에 따른 요소수 해동 특성에 관한 수치해석 연구)

  • Lee, Seung Yeop;Kim, Man Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.1
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    • pp.1-7
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    • 2016
  • A Urea-SCR(Selective Catalytic Reactor) system, which converts nitrogen oxides into nitrogen and water in the presence of a reducing agent, creates a major exhaust gas aftertreatment system for NOx reduction among other compounds. With regard to vehicle applications, a urea solution was chosen based on its eutectic composition of a 32.5wt% urea-water solution. An important advantage of this eutectic composition is that its melting point of $-11.7^{\circ}C$ is sufficiently low to avoid solidification in cold environments. However, the storage tanks must be heated separately in case of low ambient temperature levels to ensure a sufficient amount of liquid is available during scheduled start ups. In this study, therefore, a numerical investigation of three-dimensional unsteady heating problems analyzed to understand the melting processes and heat transfer characteristics including liquid volume fraction, temperature distributions, and temperature profiles. The investigations were performed using Fluent 6.3 commercial software that modeled coolant and electric heater models based on a urea solution. It is shown that the melting performance with the electric heater is higher than a coolant heater and is more efficient.

Strain Amplitude Dependence of Damping Capacity in Mg-AI-Si Alloy (Mg-Al-Si 합금에서 진동감쇠능의 변형진폭 의존성)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.24 no.3
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    • pp.144-148
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    • 2011
  • Change in damping capacity with strain amplitude was studied in Mg-Al-Si alloy in as-cast, solution-treated and aged states, respectively. The as-cast microstructure of the alloy is characterized by eutectic ${\beta}$($Mg_{17}Al_{12}$) phase and Chinese script type $Mg_2Si$ particles. The solution treatment dissolved the ${\beta}$ phase into the matrix, while the aging treatment resulted in the distribution of continuous and discontinuous type ${\beta}$ precipitates. The solution-treated microstructure showed better damping capacity than as-cast and aged microstructures both in strain-dependent and strain-independent damping regions. The decrease in second-phase particles which weakens the strong pinning points on dislocations and distribution of solute atoms in the matrix, would be responsible for the enhanced damping capacity after solution treatment.

Experimental Study on the freezing of Aqueous Binary Solution Saturated Packed bed in a Square Cavity (다공성 물질이 충전된 정방형 밀폐용기 내에서 수용성 혼합용액의 동결거동에 관한 실험적 연구)

  • Choi, J.Y.;Kim, B.C.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.4 no.3
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    • pp.175-182
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    • 1992
  • Freezing of the binary solution ($H_2O-NaCl$) saturating a packed bed of spheres is investigated experimentally. The system is cooled through its top surface, and the bottom is maintained at a temperature above the liquidus. Experiments are performed on the hypolutectic side, and the cold wall temperature is lower than the eutectic point. The effects of initial mixture concentration, superheat and glass bead diameter on temperature and concentration distributions are investigated. Supercooling was observed only at early times of the freezing process for experiments with 5% initial salt concentration. Flow visualization experiments and mushy-liquid interface position observations revealed natural convection in the liquid region. Remelting phenomena was not observed at both the solid-mushy and mushy-liquid interfaces.

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Effect of Sr and (Ti-B) Additives on Tensile Properties of AC4A Recycled Aluminum Casting Alloys (재활용 AC4A 알루미늄 합금의 인장특성에 미치는 (Ti-B), Sr 첨가제의 영향)

  • Oh, Seung-Hwan;Kim, Heon-Joo
    • Journal of Korea Foundry Society
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    • v.38 no.5
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    • pp.87-94
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    • 2018
  • The effects of Sr and (Ti-B) additives on the tensile properties of AC4A recycled (35% scrap content) aluminum alloys were investigated. An acicular morphology of the eutectic Si phase of as-cast specimens was converted to a fibrous morphology upon the addition of Sr. Moreover, morphology of the Sr modified eutectic Si phase became finer due to a T6 heat treatment. The grain size of the ${\alpha}$-solid solution was decreased by the addition of (Ti-B) additives. Depending on the treatment conditions of the as-cast specimens, i.e., no addition, a Sr addition and a (Ti-B)+Sr addition, the tensile strength levels of the as-cast specimens were 182, 192, and 204MPa, respectively. The corresponding strengths of T6 heat-treated specimens were 293, 308, and 318MPa. Elongations of the as-cast specimens were 2.2, 3.1, and 5.6%, and the corresponding elongations of the T6 heat-treated specimens were 4.6, 6.1, and 7.6%. The percentage of the reduced section area in the tensile specimens was also increased by the Sr and (Ti-B) additives. Sr and (Ti-B) additives changed the microstructure and the distribution of defects in the castings, resulting in an improvement of the tensile properties of AC4A aluminum alloys. According to our test results, recycled (35% scrap content) AC4A aluminum alloy met all of the KS requirements of the tensile strength and elongation values of AC4A aluminum alloy except for the elongation value of the one specimen condition, in this case the as-cast no-addition condition.

A Study on the Zircaloy-4 Brazing with Beryllium Filler Metal for the Nuclear Fuel (베릴륨 용가재를 사용한 핵연료피복재 지르칼로이-4 브레이징에 대한 연구)

  • 고진현;김형수
    • Journal of Welding and Joining
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    • v.11 no.4
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    • pp.70-78
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    • 1993
  • An attempt was made to investigate the effect of brazing time on microstructure, microhardness, and corrosion of Zircaloy -4as well as the beryllium diffusion into its sheet. The sheets were coated with beryllium and brazed at $1020^{\circ}C$ for 20-40 minutes in $2{\times}10^{-5}$ torr vacuum atmosphere. 1. Microstructurally the brazed zone was largely divided into three regions: a region of continuous or partially formed of eutectic liquid films along grain boundaries; a region of precipitation in both grains and grain boundaries; a region of elongated wide structure of .alpha.-laths, which was not affected by beryllium. 2. Due to the precipitates, the beryllium-migrated region was hardened and the width of the hardened region increased with increasing brazing time. 3. Beryllium brazed Zircaloy -4 sheets showed a higher corrosion rate than those of as-received and heat-treated at a brazing temperature. 4. Diffusion coefficient of beryllium into Zircaloy -4 at $1020^{\circ}C$ for 30 minutes was $7.67{\times}10^{-7}cm^2/sec.$ It seemed that Be penetrated Zircaloy -4 by forming eutectic liquid films along grain boundaries in the proximity of Be/Zr interface and it, thereafter, diffused into Zircaloy mainly by interstitial solid solution.

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Wafer Level Package Using Glass Cap and Wafer with Groove-Shaped Via (유리 기판과 패인 홈 모양의 홀을 갖는 웨이퍼를 이용한 웨이퍼 레벨 패키지)

  • Lee, Joo-Ho;Park, Hae-Seok;Shin, Jea-Sik;Kwon, Jong-Oh;Shin, Kwang-Jae;Song, In-Sang;Lee, Sang-Hun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.12
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    • pp.2217-2220
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    • 2007
  • In this paper, we propose a new wafer level package (WLP) for the RF MEMS applications. The Film Bulk Acoustic Resonator (FBAR) are fabricated and hermetically packaged in a new wafer level packaging process. With the use of Au-Sn eutectic bonding method, we bonded glass cap and FBAR device wafer which has groove-shaped via formed in the backside. The device wafer includes a electrical bonding pad and groove-shaped via for connecting to the external bonding pad on the device wafer backside and a peripheral pad placed around the perimeter of the device for bonding the glass wafer and device wafer. The glass cap prevents the device from being exposed and ensures excellent mechanical and environmental protection. The frequency characteristics show that the change of bandwidth and frequency shift before and after bonding is less than 0.5 MHz. Two packaged devices, Tx and Rx filters, are attached to a printed circuit board, wire bonded, and encapsulated in plastic to form the duplexer. We have designed and built a low-cost, high performance, duplexer based on the FBARs and presented the results of performance and reliability test.

Study on the Microstructural Changes with Modification and Cast-forging in Eutectic Al-Si Alloys (공정 Al-Si 합금의 개량처리와 주단조에 의한 조직변화에 관한 연구)

  • Yoon, Ji-Hyun;Seol, Eun-Cheol;Park, Seung-Min;Lee, Kwang-Hak
    • Journal of Korea Foundry Society
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    • v.22 no.1
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    • pp.17-25
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    • 2002
  • Recently, many studies have been carried out to process on the purpose of lightness in a transport parts because of the saving energy, the environmental problem. The cast-forging process can be expected to lower costs without decreasing the mechanical properties. So, the finest microstructure is needed to get for applying the cast-forging process with Al-Si alloy because the microstructure affects to the cast-forging process. For refinement treatment of eutectic Si and Al solid-solution phase, Sr and TiB were added in Al-Si alloys. The finest microstructure could be observed when 0.075 wt.%Sr and 0.1 wt.%TiB were added respectively. In this case, tensile strength and elongation much more increased than as casting. After high temperature deformation simulation test with grain refinement specimens was carried out, about 70N per unit $area(mm^2)$ of specimen was confirmed. After hot forging, tensile strength and elongation were increased. It was considered because casting defect was removed by compressive working.

Effect of Heat Treatment on the Mechanical Properties of Investment Casting Turbo Charger Wheel using A356 Alloy (A356합금을 이용한 정밀주조 Turbo Charger Wheel의 기계적 특성에 미치는 열처리의 영향)

  • Kim, Sang-Mi;Woo, Kee-Do;Kim, Ji-Young;Kim, Sang-Hyuk;Park, Sang-Hoon;Kang, Hwang-Jin;Park, Chan-Sung
    • Journal of Korea Foundry Society
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    • v.31 no.5
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    • pp.262-266
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    • 2011
  • The aim of this study is to investigate aging behavior of A356 alloy for turbo charger part. The specimen was fabricated by investment casting. Solution heat treatment was performed at $525^{\circ}C$ for 8h and followed by aging treated at $160^{\circ}C$, $170^{\circ}C$ for 0.5~20h. And their microstructures and mechanical properties of the aged specimens were analyzed by scanning electron microscope and hardness tester, respectively. All the cast A356 alloy included eutectic Si particles. In the cast A356 alloy, eutectic Si phase mainly was formed along Chinese script phase. Vickers hardness of the cast was improved by aging treatment due to formation of ${\beta}$" phase and ${\beta}$' phase.

Effects of the Solid Solution Treatment Conditions and Casting Methods on Mechanical Properties of Al-Si-Cu Based Alloys (Al-Si-Cu계 합금의 주조법과 용체화처리 조건이 기계적 특성변화에 미치는 영향)

  • Moon, Min-Kook;Kim, Young-Chan;Kim, Yu-Mi;Choi, Se-Weon;Kang, Chang-Seog;Hong, Sung-Kil
    • Journal of Korea Foundry Society
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    • v.38 no.6
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    • pp.111-120
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    • 2018
  • In this study, the effects of two different casting methods (gravity casting and, diecasting) and various solid-solution conditions on the mechanical properties of ASC (Al-10.5wt%Si-1.75wt%Cu) and ALDC12 (Al-10.3wt%Si-1.72wt%Cu-0.76wt%Fe-0.28wt% Mn-0.32wt%Mg-0.9wt%Zn) alloys were investigated. A thermodynamic solidification analysis program (PANDAT) was used to predict the liquidus, solidus, and phases of the used alloys. In the results of an XRD analysis, ${\beta}$-AlFeSi peaks were observed only in the ALDC12 alloy regardless of the casting method or SST (solid-solution treatment) conditions. However, according to the results of a FE-SEM observation, both ${\theta}(Al_2Cu)$ and ${\beta}$-AlFeSi were found to exist besides ${\alpha}$-Al and eutectic Si in the gravity-casted ASC alloy at $500^{\circ}C$ after a SST of 120min. The ${\alpha}$-AlFeSi and ${\beta}$-AlFeSi phases including the eutectic phases were also found to exist in the ALDC12 alloy. The results of a microstructural observation and analyses by XRD, FE-SEM and EDS were in good agreement with the PANDAT results. The gravity-casted ALDC12 and ASC specimens showed the highest Y.S. and UTS values after aging for three hours at $180^{\circ}C$ after a SST at $500^{\circ}C$ for 30min. At longer solid-solution treatment times at $500^{\circ}C$ in the gravity-casted ALDC12 and ASC specimens, the elongations of the ASC alloys increased, whereas they decreased slightly in the ALDC12 alloys.

A Study on the Development for the Vehicle Engine Mountion Bracket Using Squeeze Casting (스퀴즈 캐스팅 제조법에 의한 자동차 엔진 마운틴 브래킷 개발에 관한 연구)

  • Kim, S.H.
    • Journal of Power System Engineering
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    • v.7 no.4
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    • pp.44-48
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    • 2003
  • Alumium alloys casting are gaining increased acceptance in the automotive and electronic industeries and squeeze casting is the most efficient method of manufacturing such mass produced parts. This study has been investigated the microstructures and mechanical properties of Al-7.0Si-0.4Mg(AC4C)alloy fabricated by squeeze casting process for development of Engine Mountain Bracket. The microstructure of squeeze casted specimen were composed of eutectic structure Alumimim solid solution and $Mg_2Si$ precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg alloy revealed 2985MPa. It was found that Al-7.0Si-0.4Mg alloy have good aging hardening effect results are presented to show the validity of the control method.

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