• Title/Summary/Keyword: Eutectic alloy

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On the Micro-structures of Rapidly Solidified Al-Si Alloy Powder and Growth Direction of Eutectic Silicon (급속응고된 Al-Si 합금분말의 미세조직과 공정 Si 의 성장방향)

  • Ra, Hyung-Yong;Lee, Joo-Dong
    • Journal of Korea Foundry Society
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    • v.8 no.4
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    • pp.453-458
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    • 1988
  • Al-Si alloy powder produced by the gas atomizer showed fine eutectic structure between ${\alpha}-dendrites$, that was grown by coupled growth, and there remained small amount of ${\alpha}$ in Al - 20 wt% Si alloy. The morphology of Si in the eutectic structure was largely influenced by the recalescence caused by solidification latent heat, and that was thought to be due to decrement of the surface energy of Si. In modified eutectic Si by rapid solidification, fine twin about $0.01\;{\mu}m$ was observed and growth direction of eutectic Si was <112>. This fact implied that the growth mechanism of eutectic Si in rapid solidification was related to TPRE mechanism. Due to rapid solidification Si was soluble in ${\alpha}-phase$ in Al - 12.6wt%Si alloy up to about 3.4wt%, and the solubility of Si in ${\alpha}-phase$ reaches the equilibrium solubility stare after 60min, holding when it was held isothermally at $253-296^{\circ}C$.

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Molecular Dynamics Simulation of Nano-Deformation Behavior of the Grain-Size Controlled Rheology Material (분자동력학을 이용한 결정립 제어 레오로지 소재의 나노 변형거동 전산모사)

  • Kim J. W.;Youn S. W.;Kang C. G.
    • Transactions of Materials Processing
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    • v.14 no.4 s.76
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    • pp.319-326
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    • 2005
  • In this study, the nano-deformation behavior of semi-solid Al-Si alloy was investigated using a molecular dynamics simulation as a part of the research on the surface crack behavior in thixoformed automobile parts. The microstructure of the grain-size controlled Al-Si alloy consists of primary and eutectic regions. In eutectic regions the crack initiation begins with initial fracture of the eutectic silicon particles and inside other intermetallic phases. Nano-deformation characteristics in the eutectic and primary phase of the grain-size controlled Al-Si alloy were investigated through the molecular dynamics simulation. The primary phase was assumed to be single crystal aluminum. It was shown that the vacancy occurred at the zone where silicon molecules were.

A Study on the Nano-Deformation Characteristics of Grain-Size Controlled Rheology Material Surfaces for Surface Crack Prediction (표면크랙 예측을 위한 결정립 제어 레오로지 소재 표면의 나노 변형특성에 관한 연구)

  • 윤성원;김현일;강충길
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.355-358
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    • 2004
  • In this study, the deformation characteristics of grain-size controlled rheology materials surfaces were investigated as a part of the research on the surface crack prediction in semi-solid formed automobile components. The microstructure of rheology Al-Si alloys consists of primary and eutectic regions. In eutectic regions the crack initiation begins with initial fracture of the eutectic silicon particles and inside other intermetallic phases. Nano-deformation characteristics in the eutectic and primary region of semi-solid aluminum alloys (356 alloy and 319 alloy) were investigated through the nanoindentation/scratch experiments and the AFM observation.

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Microstructure and Tensile Properties in Low Pressure Cast Al-Si Alloy through Cooling Rate Control

  • Suh, Jun-Young;Park, Sung Jin;Lee, Hee-Kwon;Chang, Si Young
    • Korean Journal of Materials Research
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    • v.30 no.2
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    • pp.51-56
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    • 2020
  • In this study, three kinds of metal chills such as SS400, AC4CH and brass, with different thicknesses of 40 ~ 80 mm, were applied for low pressure casting of Al-Si alloy to control cooling rate. The microstructural characteristics with increasing cooling rate were represented using factors including D1, D2, size of primary α phases and shape factor and size of eutectic Si. The tensile properties were investigated and additionally analyzed based on the microstructural characteristics. As the cooling rate increased, D1, D2, and sizes of primary α phases and eutectic Si apparently decreased and the shape factor of eutectic Si increased to over 0.8. The ultimate tensile strength (UTS) and yield strength (YS) increased with decreasing D1, D2, and size of primary α phases, while elongation increased with decreasing size of eutectic Si and concurrently increasing shape factor of eutectic Si. This indicated that the primary α phases and eutectic Si in Al-Si alloy were refined with increasing cooling rate, resulting in improvement of UTS and YS without sacrificing elongation. After the tensile test, preferential deformation of primary α phases was observed in the Al-Si alloy produced at higher cooling rates of more than 0.1 K/s.

Microstructure and Wear Properties in an Engine Oil Environment of Extruded Hyper-eutectic Al-15wt.%Si Alloy and Gray Cast Iron (과공정 Al-15wt.%Si 압출재와 회주철의 미세조직 및 엔진 오일 환경에서의 마모 특성)

  • Kang, Y.J.;Kim, J.H.;Hwang, J.I.;Lee, K.A.
    • Transactions of Materials Processing
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    • v.27 no.6
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    • pp.339-346
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    • 2018
  • This study investigated the microstructure and wear properties of extruded hyper-eutectic Al-Si (15wt.%) alloy in an engine oil environment. The wear mechanism of the material was also analyzed and compared to conventional gray cast iron. In microstructural observation results of Al-15wt.%Si alloy, primary Si phase ($45.3{\mu}m$) and eutectic Si phase ($3.1{\mu}m$) were found in the matrix, and the precipitations of $Mg_2Si({\beta}^{\prime})$, $Al_2Cu({\theta}^{\prime})$ and $Al_6(Mn,Fe)$ were also detected. In the case of gray cast iron, ferrite and pearlite were observed. It was also observed that flake graphite ($20-130{\mu}m$) were randomly distributed. Wear rates were lower in the Al-Si alloy as compared to those of gray cast iron in all load conditions, confirming the outstanding wear resistance of Al-15wt.%Si alloy in engine oil environment. In the $4kg_f$ condition, the wear rate of gray cast iron was $6.0{\times}10^{-5}$ and that of Al-Si measured $0.8{\times}10^{-5}$. The microstructures after wear of the two materials were analyzed using scanning electron microscope (SEM) and electron backscatter diffraction (EBSD). The primary Si and eutectic Si of Al-Si alloy effectively mitigated the abrasive wear, and the Al matrix effectively endured to accept a significant amount of plastic deformation caused by wear.

Effect of Sc, Sr Elements on Eutectic Mg2Si Modification and Castability of Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe Casting Alloy (주조용 Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe 합금의 공정 Mg2Si 개량과 주조특성에 미치는 Sc, Sr 첨가원소의 영향)

  • Kim, Heon-Joo
    • Journal of Korea Foundry Society
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    • v.35 no.6
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    • pp.147-154
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    • 2015
  • The effects of Sc and Sr elements on the modification of the eutectic $Mg_2Si$ phase and the castability were investigated in the Al-4wt%Mg-0.9wt%Si-0.3wt%Mn-0.15wt%Fe alloy. Measurements of the cooling curve and microstructure observations were performed to analyze the additional effects of Sc and Sr minor elements during the solidification process. A prominent effect found on the modification of the eutectic $Mg_2Si$ phase with additions of the Sr and Sc elements. Here, a fine eutectic $Mg_2Si$ phase and a decrease in the growth temperature of the eutectic $Mg_2Si$ phase were evident with an addition of Sc element up to 0.2 wt%. The growth temperature of the eutectic $Mg_2Si$ phase decreased and the effect on the modification of the eutectic $Mg_2Si$ phase increased with the addition of Sr element up to 0.02 wt%. The addition of 0.02wt%Sr had the strongest effect on the modification of the eutectic $Mg_2Si$ phase, and the resulting microstructure of the eutectic $Mg_2Si$ phase was found to have a fibrous morphology with a decreased aspect ratio and an increased modification ratio. Fluidity and shrinkage tests were conducted to evaluate the castability of the alloy. The addition of 0.02wt%Sr effectively increased the fluidity of the alloy, while an addition of Sc did not show any effect compared to when nothing was added. The maximum filling length was recorded for 0.01wt%TiB-0.02wt%Sr owing to the effect of the fine ${\alpha}$-Al grains. The macro-shrinkage ratio decreased, while the micro-shrinkage ratio increased with the addition of various eutectic modifiers. The highest ratio of micro-shrinkage was recorded for the 0.02wt%Sr condition. However, the total shrinkage ratio was nearly identical regardless of the amounts added in this study.

Microstructural Control of Al-Sn Metal Bearing Alloy with Heat Treatment (열처리에 따른 메탈베어링용 Al-Sn 합금의 미세조직 제어)

  • Kim, Jin-Soo;Park, Tae-Eun;Hahn, Chun-Feng;Sohn, Kwang-Suk;Kim, Dong-Gyu
    • Journal of Korea Foundry Society
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    • v.29 no.1
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    • pp.45-51
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    • 2009
  • Conventionally, Al-Sn bearing manufacturing involves casting the Al-Sn alloy and roll-bonding to a steel backing strip. This article will describe the microstructural control of Al-Sn metal bearing alloy following heat treatment. When the pure aluminum rod dipped in the melt of tin maintained below the melting point of aluminum, the melting of aluminum was accelerated with penetration of tin along the grain boundary of aluminum. The length of plate-shaped eutectic tin was decreased with heat treatment time. With even longer heat treatment time over 1 hour the length of eutectic tin didn't decrease any more, while resulting in coarsening of aluminum matrix. Exuded liquid of eutectic tin was formed at the surface of Al-Sn alloy after heat treatment even at below eutectic temperature.

Influence of Sr and TiB on the Microstructure and Eutectic Temperature of Al-12Si Die-Cast Alloys (Sr과 TiB 첨가에 따른 다이캐스팅용 Al-Si 합금의 미세조직과 공정온도의 변화)

  • Choi, Yong-Lak;Kim, Seon-Hwa;Kim, Dong-Hyun;Yoon, Sang-Il;Kim, Ki-Sun
    • Korean Journal of Materials Research
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    • v.27 no.10
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    • pp.544-551
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    • 2017
  • In order to develop a new commercial Al-12%Si casting alloy with improved physical properties, we investigated the effect of adding Sr and TiB to the alloy. Al-12%Si alloys were prepared by die casting at $660^{\circ}C$. The eutectic temperature of the Sr-modified Al-12%Si alloy decreased to $9^{\circ}C$ and the mushy zone region increased. The shape of the Si phase changed from coarse acicula to fine fiber with the addition of Sr. The addition of TiB in the Al-12%Si alloy reduced the size of the primary ${\alpha}$-Al and eutectic Si phases. When Sr and TiB were added together, it worked more effectively in refinement and modification. The density of twins in the Si phase-doped Sr increased and the width of the twins was refined to 5 nm. These results are related to the impurity induced twinning(IIT) growth.

Mechanical Properties of Hyper-Eutectic Aluminum Alloys for Automobile Parts (자동차 부품용 과공정 알루미늄 합금의 기계적 특성)

  • Bae, Chul-Hong;Kim, Jong-Myung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.1
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    • pp.120-126
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    • 2010
  • It was known that the excellent wear resistance of hyper eutectic aluminum alloy is based on the primary Si particles which are distributed in the base metal. When the primary Si volume fraction increases, the smaller size have excellent wear resistance characteristics. However, this trend always does not match. There is no investigation result based on the materials and methods for real using parts. In this study, using the automotive parts manufacturer currently in use hyper eutectic Al alloy tensile test specimen type sample was fabricated by 350Ton high pressure die-casting machine. Then, fluidity, tensile, impact and wear resistance properties were evaluated. If the casting quality, primary Si size, fraction and distribution are similar, mechanical properties and wear resistance are equivalent.

A Study on Deformation Behavior of the Grain-Size Controlled Rheology Material by Using Nanoindenter and AFM (나노인덴터와 원자력간 현미경을 이용한 결정립 제어 레오로지 소재의 변형거동에 관한 연구)

  • 윤성원;김정원;강충길
    • Transactions of Materials Processing
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    • v.13 no.4
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    • pp.374-381
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    • 2004
  • In this study, the deformation behavior of semi-solid Al-Si alloy was investigated by nanoindenter as a part of the research on the surface crack behavior in thixoformed automobile component. The microstructure of semi-solid Al-Si alloy consists of primary and eutectic regions. In eutectic regions the crack initiation begins with initial fracture of the eutectic silicon particles and inside other intermetallic phases. Nano-deformation characteristics in the eutectic and primary phase of semi-solid aluminium alloy were investigated through the nano-indentation experiments and the AFM observation. In addition, mechanical properties of each region were investigated and compared with each other.