• Title/Summary/Keyword: Eu doped silicate phosphors

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BGR mixture phosphor for white-light-emitting diode of liquid crystal display backlight

  • Lee, Sung-Hoon;Park, Je-Hong;Seo, Kwang-Il;Kim, Jong-Su
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1559-1560
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    • 2007
  • BGR mixture phosphor pumped by 400 nm is developed for white-light-emitting diode of liquid crystal display backlight. White-emitting phosphor is prepared by mixing $Ba_2SiO_4:Eu^{2+}$ and $(Ba,Sr)_3MgSi_2O_8:Eu^{2+},Mn^{2+}$ phosphors.

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Synthesis and Optical Properties of BaSiO3:RE3+ (RE = Sm, Eu) Phosphors (BaSiO3:RE3+ (RE = Sm, Eu) 형광체의 합성과 광학 특성)

  • Cho, Shinho
    • Korean Journal of Materials Research
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    • v.29 no.6
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    • pp.356-362
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    • 2019
  • $BaSiO_3:RE^{3+}$ (RE = Sm or Eu) phosphor powders with different concentrations of activator ions are synthesized using the solid-state reaction method. The effects of the concentration of activator ions on the structural, photoluminescent, and morphological properties of the barium silicate phosphors are investigated. X-ray diffraction data reveals that the crystal structure of all the phosphors, regardless of the type and the concentration of the activator ions, is an orthorhombic system with a main (111) diffraction peak. The grain particles agglomerate together to form larger clusters with increasing concentrations of activator ions. The emission spectra of the $Sm^{3+}$-doped $BaSiO_3$ phosphors under excitation at 406 nm consist of an intense orange band at 604 nm and three weak bands centered at 567, 651, and 711 nm, respectively. As the concentration of $Sm^{3+}$ increases from 1 to 5 mol%, the intensities of all the emission bands gradually increase, reach maxima at 5 mol% of $Sm^{3+}$ ions, and then decrease significantly with further increases in the $Sm^{3+}$ concentration due to the concentration quenching phenomenon. For the $Eu^{3+}$-doped $BaSiO_3$ phosphors, a strong red emission band at 621 nm and several weak bands are observed. The optimal orange and red light emissions of the $BaSiO_3$ phosphors are obtained when the concentrations of $Sm^{3+}$ and $Eu^{3+}$ ions are 5 mol% and 15 mol%, respectively.

Synthesis and luminescent properties of $Sr_2SiO_4:Eu^{2+}$ phosphors ($Sr_2SiO_4:Eu^{2+}$ 형광체의 합성 및 발광특성)

  • Kim, Jong-Min;Park, Yong-Seo;Choi, Hyung-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.430-431
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    • 2009
  • In this study, europium doped strontium silicate ($Sr_2SiO_4:Eu^{2+}$) phosphor has been synthesized by conventional solid-state method and investigated luminescent characteristic. $SrCO_3$ and $SiO_2$ were mixed together by 2:1 mole ratio. Also $NH_4Cl$ was added as a flux. The mixture were sintered at $800^{\circ}C$, $1000^{\circ}C$ for 3h under the atmosphere (5% $H_2$/95% $N_2$). This phosphor can be applicated to the yellow phosphor for white LED because it has yellow emission band (540nm), which emits efficiently under the 370nm excitaion energy.

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