• Title/Summary/Keyword: Ethylene-Air

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SiO2/styrene butadiene rubber-coated poly(ethylene terephthalate) nonwoven composite separators for safer lithium-ion batteries

  • Lee, Jung-Ran;Won, Ji-Hye;Lee, Sang-Young
    • Journal of Electrochemical Science and Technology
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    • v.2 no.1
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    • pp.51-56
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    • 2011
  • We develop a new nonwoven composite separator for a safer lithium-ion battery, which is based on coating of silica ($SiO_2$) colloidal particles/styrene-butadiene rubber (SBR) binder to a poly(ethylene terephthalate) (PET) nonwoven support. The $SiO_2$ particles are interconnected by the SBR binder and closely packed in the nonwoven composite separator, which thus allows for the development of unusual porous structure, i.e. highly-connected interstitial voids formed between the $SiO_2$ particles. The PET nonwoven serves as a mechanical support that contributes to suppressing thermal shrinkage of the nonwoven composite separator. The $SiO_2$/SBR content in the nonwoven composite separators plays an important role in determining their separator properties. Porous structure, air permeability, and electrolyte wettability of the nonwoven composite separators, in comparison to a commercialized polyethylene (PE) separator, are elucidated as a function of the $SiO_2$/SBR content. Based on this understanding of the nonwoven composite separators, the effect of $SiO_2$/SBR content on the electrochemical performances such as self-discharge, discharge capacity, and discharge C-rate capability of cells assembled with the nonwoven composite separators is investigated.

Treatment of Ethylene Glycol in Polyester Weight Loss Wastewater(I) - Reaction Characteristics - (Polyester감량폐수 중에 존재하는 Ethylene Glycol의 처리(I) - 반응 특성 -)

  • Kim, Jeong-Mog;Huh, Man-Woo;Han, Myung-Ho
    • Textile Coloration and Finishing
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    • v.8 no.5
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    • pp.84-89
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    • 1996
  • This study carried out batch and continuous experiments using calcium hydroxide as neutralization agent and immobilization media for removing the ethylene glycol in the pretreated polyester weight loss wastewater. The $TCOD_{Mn}$ concentration in the treated wastewater using culture of iramobilization and suspension for the synthetic wastewater were found as 650mg/l and 1,250mg/l after 48hours, respectively. SVI(Sludge Volume Index) and $TCOD_{Mn}$ concentration were 74 and 73mg/l at optimum F/M ratio, 1.32kg-TCO $D_{Mn}$ /day. kg-MLVSS. The $TCOD_{Mn}$ concentration and removal efficiency were 213mg/l and 93.5% by continuous experiments in the air-lift bioreactor, respectively. The $TCOD_{Mn}$ concentration was 82mg/l, and also the MLVSS concentration was 2,550mg/l, when the volumetric loading rate was 3.04kg-$TCOD_{Mn}/m^{2}$ day for real polyester weight loss wastewater.

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Influence of Storage Atmosphere on Quality Preservation of 'Tsugaru' Apples (저장기체조성이 Tsugaru 사과의 품질유지에 미치는 영향)

  • Chung, Hun-Sik;Lee, Hyun-Dong;Kim, Sung-Youl;Lee, Hun-Chul;Jeong, Hye-Seung;Choi, Jong-Uck
    • Korean Journal of Food Science and Technology
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    • v.32 no.3
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    • pp.668-673
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    • 2000
  • The influence of storage atmosphere on ethylene production, quality attributes and storage injury of 'Tsugaru' apples was investigated. Apples were stored in 1% $O_2+1%\;CO_2,\;1%\;O_2+3%\;CO_2,\;3%\;O_2+1%\;CO_2,\;3%\;O_2+3%\;CO_2$ and air at $0^{\circ}C$ for 5 months. Ethylene production was more suppressed by 1% $O_2$ than 3% $O_2$ atmospheres regardless $CO_2$ levels. The loss of flesh firmness and the decrease of titratable acidity were not significantly different among the storage atmospheres until 3 months of storage but more retarded by 1% $O_2$ than 3% $O_2$ atmospheres thereafter. Soluble solid content was unaffected by the storage atmosphere, but the content tended to be increased until 2 months of storage and then not varied. Ethanol content increased up to a peak level followed by a gradual loss during storage in CA but increased continuously in air. In the sensory evaluation after storage for 5 months, hardness, tartness and overall acceptability of apples stored in 1% $O_2$ atmospheres were significantly higher than those stored in the others. There was no fruit injury or off-flavor production resulting from the 1% $O_2$ atmospheres. The incidence of bitter pit was reduced as storage $O_2$ level decreased. The results show that the optimum conditions of CA storage for 'Tsugaru' apples are $0^{\circ}C$ and 1% $O_2+1{\sim}3%\;CO_2$.

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Control of Softening of Long-Term Stored 'Fuji' Apples at Low Temperature and Subsequent Shelf-life by Combination Treatment of 1-MCP and Ethylene (1-MCP와 에틸렌 혼용처리가 장기간 저온저장 후 상온에 보관된 '후지' 사과의 연화 억제에 미치는 영향)

  • Choi, Hyun-Sug;Jung, Seok-Kyu
    • Journal of Bio-Environment Control
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    • v.26 no.2
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    • pp.108-114
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    • 2017
  • The effect of 1-methylcyclopropene (1-MCP) at $1.0{\mu}L{\cdot}L^{-1}$ was compared with control and $10{\mu}L{\cdot}L^{-1}$ ethylene treatment to evaluate softening control of apple (Malus ${\times}$ domestica Borkh.) fruit for 180 days at $0.5^{\circ}C$ in the air, followed for 28 days at a room temperature. 1-MCP or 1-MCP+ethylene treatment maintained high fruit titratable acidity and firmness after 120 days during the cold storage, which was similarly observed for 28 days at a room temperature. 1-MCP treatment maintained fruit firmness more than 14 N during the cold storage and shelf-life at room temperature. Fruit surface red color was not consistently affected by the treatments during the cold storage but enhanced more than 4.0 by 1-MCP at 21- and 28-days of room temperature. Control or ethylene treatment advanced overall preceeding of fruit softening as rapid ethylene production and respiration rates at 90 days during the cold storage increased to a climacteric maximum. Therefore, pre 1-MCP-treated fruit maintained high fresh condition at a long-term low storage + approximately one month room temperature-storage under $10{\mu}L{\cdot}L^{-1}$ ethylene treatment.

Analysis of the Surface Degradation in UV-irradiated Poly(ethylene terephthalate) films (자외선 조사된 Poly(ethylene terephthalate) 필름의 표면 열화 분석)

  • Lim, Kyung-Bum;Kim, Jong-Yoon;Choi, Hoon-Young
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.12
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    • pp.2230-2234
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    • 2010
  • This paper deals with the change of surface potential decay, surface resistivity, contact angle and XPS of ultraviolet-treated PET films. From the experimental results on the surface potential decay of UV degraded-samples, it was found that the accumulation of charge is decreased and the surface potential decay time is shortened. Also, from the result of XPS, it was found that the changes affected by the surface degradation of PET film were caused by the generation of carboxyl groups through the chain decomposition and recombination with oxygen molecules in the air.

Analysis of the Surface Degradation in UV-irradiated Poly(ethylene terephthalate) films (자외선 조사된 Poly(ethylene terephthalate) 필름의 표면 열화 분석)

  • Lim, K.B.;Lee, B.S.;Hwang, M.H.;Kim, Y.Y.;Lim, H.C.;Chi, C.S.;Nam, K.W.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1457-1459
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    • 2001
  • This paper deals with the change of surface Potential decay, surface resistivity, contact an91e and XPS of ultraviolet-treated PET films. From the experimental results on the surface Potential decay of UV degraded-samples, it was found that the accumulation of charge is decreased and the surface potential decay time is shortened. Also, from the result of XPS, it was found that the changes affected by the surface degradation of PET film were caused by the generation of carboxyl groups through the chain decomposition and recombination with oxygen molecules in the air.

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Soot Formation and Oxidation of an Ethylene Laminar Diffusion Flame with Different Radiation Boundary Conditions (에틸렌 층류 확산화염의 복사경계조건에 따른 매연생성 및 산화특성)

  • Lee, Chun-Beom;Nam, Youn-Woo;Lee, Won-Nam;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.11-18
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    • 2003
  • The soot formation and oxidation characteristics with different radiation boundary conditions have been studied experimentally in a co-flow ethylene/air laminar diffusion flame. The boundary conditions are two cases, one is a fully refractive radiation boundary condition by a polished aluminum cylinder(AL) and the other is a fully absorbing radiation boundary condition by a black body cylinder(BB). The AL case compared with BB condition show the lower inception point, denser soot volume fraction, wider and longer annular soot area owing to the reabsorption of radiating energy.

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The Characteristics of Performance and Exhaust Emission on Simultaneous Application with Biodiesel Fuel and Oxygen Component in a C.I. Engine (압축착화기관에서 바이오디젤유 및 함산소성분 동시적용시 성능과 배기배출물 특성)

  • Choi, S.H.;Oh, Y.T.;Lee, D.H.
    • Journal of Power System Engineering
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    • v.14 no.1
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    • pp.11-15
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    • 2010
  • Our environment is faced with serious problems related to the air pollution from automobiles in these days. In particular, the exhaust emissions from the diesel engines are recognized as main cause which has a great influence on environment. In this study, the potential of biodiesel fuel and oxygenated fuel(ethylene glycol mono-n-butyl ether; EGBE) was investigated as an effective method of decreasing the smoke emission. The smoke emission of blending fuel(EGBE 0~20 vol-%) was reduced in comparison with diesel fuel and it was reduced approximately 64% at 2000 rpm, full load in the 20% of blending rate. On the contrary NOx emissions from biodiesel fuel and EGBE blended fuel were increased compared with diesel fuel. Torque and brake specific energy consumption(BSEC) didn't have large differences.

Helium/Oxygen Atmospheric Pressure Plasma Treatment on Poly(ethylene terephthalate) and Poly(trimethylene terephthalate) Knitted Fabrics: Comparison of Low-stress Mechanical/Surface Chemical Properties

  • Hwang Yoon Joong;McCord Marian G.;Kang Bok Choon
    • Fibers and Polymers
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    • v.6 no.2
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    • pp.113-120
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    • 2005
  • Helium-oxygen plasma treatments were conducted to modify poly(trimethylene terephthalate) (PIT) and poly(ethylene terephthalate) (PET) warp knitted fabrics under atmospheric pressure. Lubricant and contamination removals by plasma etching effect were examined by weight loss $(\%)$ measurements and scanning electron microscopy (SEM) analysis. Surface oxidation by plasma treatments was revealed by x-ray photoelectron spectroscopy (XPS) analyses, resulting in formation of hydrophilic groups and moisture regain $(\%)$ enhancement. Low-stress mechanical properties (evaluated by Kawabata evaluation system) and bulk properties (air permeability and bust strength) were enhanced by plasma treatment. Increasing interfiber and interyarn frictions might play important roles in enhancing surface property changes by plasma etching effect, and then changing low-stress mechanical properties and bulk properties for both fabrics.

The Radiation Resistance Evaluation of Electrically Insulating Polymers

  • Lee, Dong-Hoon;Jung, Chan-Hee;Hwang, In-Tae;Choi, Jae-Hak;Im, Don-Sun;Kim, Ki-Yup;Nho, Young-Chang
    • Journal of Radiation Industry
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    • v.5 no.3
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    • pp.237-242
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    • 2011
  • In this research, the radiation resistance of ethylene propylene rubber (EPR) and chlorosulfonated polyethylene (CSPE) which can be used as a insulating materials of for electrical cable in the nuclear power plant were investigated. EPR and CSPE were irradiated by ${\gamma}$-ray at various doses ranging from 50 to 500 kGy at room temperature in air. The irradiated EPR and CSPE was investigated in terms of activation energy, mechanical properties, and oxidation stability. The experimental results revealed that CSPE exhibited the higher radiation resistance in comparison to that of EPR.