• Journal of the Korean Society of Safety
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• v.28 no.1
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• pp.29-34
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• 2013

When flammable gases are mixed with air or oxygen in the explosion concentration range and are ignited by sufficiently large electrostatic discharge energy, they may explode causing severe disaster in workplace. The minimum ignition energy(MIE) of single gas-air mixtures has been already investigated by many research, but the MIE of mixtures of more than ternary gas mixture is not examined yet. The purpose of this study is to investigate the MIE of a ternary gas(methane, ethylene, hydrogen, propane) mixtures experimentally. The results of our experiment show that the ignition of a methane-ethylene-air, methane-hydrogen-air, methane-propane-air, ethylene-hydrogen-air, ethylene-propane-air and hydrogen-propane-air mixture due to electrostatic discharge energy primarily depends on that the mixture: the MIE decreases gradually with the increase of having the lower MIE than other mixture ratio in the normal atmospheric pressure.

• Textile Coloration and Finishing
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• v.13 no.4
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• pp.264-271
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• 2001

Catalytic wet oxidation of ethylene glycol as refractory compound was studied in a batch slurry reactor using lwt% $Pt/A1_2O_3$, lwt% $Pt/TiO_2,\;Mn/CeO_2$(1:1) and 5wt% $Mn/Al_2O_3$. Experiments were conducted to investigate theeffects of temperature, initial ethylene glycol concentration, catalyst dosage and PH on the ethylene glycol decomposition. When compared with the uncatalyzed reaction, the use of catalysts could increase the rate of ethylene glycol decomposition. The lwt% $Pt/A1_2O_3$ catalyst was preferable to the other catalysts for the destructive oxidation of ethylene glycol. The reaction rate was first order with respect to initial concentration of ethylene glycol. In acidic condition the removal efficiency of ethylene glycol was good, but there was a significant leaching of platinum. Small amount of acetic acid, oxalic acid, masonic acid and formic acid as intermediates were detected during catalytic wet air oxidation of ethylene glycol.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.686-690
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• 2017

In this study, we numerically investigate the detonation characteristics (detonation velocity and pressure) of a hybrid ethylene-air and RDX mixture using two-phase model. Compared with detonation of pure ethylene-air mixture, the detonation of the hybrid ethylene-air and RDX mixture has higher pressure and stronger impulse because the hybrid mixture has additional chemical heat release of RDX particles. To validate the numerical results using two-phase model, we compare the experimental data which show changes of detonation pressure and velocity according to concentration of RDX particles.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.569-572
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• 2009

The numerical simulations of hydrocarbon fueled scramjet engine have been studied less than them of hydrogen fueled scramjet engine. Ethylene is selected in hydrocarbon because of its good thermochemical properties and a direct-connect scramjet combustor at the American Air Force Research laboratory is taken to a two-dimensional simulation model. Ignition time delay of ethylene was monitored and air throttling was imposed to generate ignition inside the model scramjet.

• 한국연소학회:학술대회논문집
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• 1999.10a
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• pp.241-249
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• 1999

Soot particle temperatures in co-flow diffusion flames have been measured using a two-color pyrometry at the pressure of 0.2 MPa(2 atm). The measured soot particle temperatures along with the integrated soot volume fractions are analyzed to understand soot formation characteristics. At 0.2 MPa, the addition of small amount of air into ethylene do not change the soot particle temperature in soot formation regions. This result showed that the increase of soot formation with addition of air is mostly due to the chemical effect of the added air, such as the increased role of C3 chemistry during the early stage of soot inception process. The addition of sufficient air into ethylene, however, changes soot particle temperatures and the understanding of soot formation characteristics becomes complicated. Measured soot particle temperatures also showed that there is no significant temperature effect for the synergistic effect of ethylene/propane mixture on soot formation.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.19 no.11
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• pp.743-750
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• 2007

In this study, ice slurry generator using air cylinder was designed and manufactured to investigate the heat transfer characteristic of the ice slurry generator. The ice slurry generator has the same shape as the shell-and-tube type heat exchanger. Refrigerant is flowing in the shell side and ethylene glycol solution in the tube side. The experiment was conducted on performance of ice slurry generator using air cylinder with standard condition and the results are plotted on the time scale. The experimental tests on the various concentration of ethylene glycol solution, the various solution velocity in the tube side and the various tube size have been carried. For the above experimental conditions, ice making characteristics of the ice slurry generator are evaluated in terms of the overall heat transfer coefficient. And the experimental results show that the overall heat transfer coefficient of the system is increased as the tube size and the concentration of ethylene glycol decreases.

• Journal of the Korea Safety Management & Science
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• v.25 no.1
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• pp.51-58
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• 2023

Determination of explosion reference pressure is important in designing and testing flameproof enclosures (Ex d). Although relative humidity affects to explosion pressure, its effect is not well investigated for the gas group IIB, IIA, and I. This study tested explosion pressure for Ethylene (8 vol.%), Propane (4.6 vol.%), and Methane (9.8 vol.%), which are the representative gas of the gas group IIB, IIA, and I, at ambient temperature and atmospheric pressure (1 atm) under different relative humidity (0% ~ 80%). Ethylene- and Propane-air mixed gases generally tended to decrease as the relative humidity increased; however, explosion pressure was largely dropped at 20% of relative humidity compared to 0% and 10% of relative humidity. On the other hand, Methane-air mixture gas showed similar pressures at 0% and 10% of relative humidity; but no explosion occurred at more than 20%. The results of this study can be used in setting a testing protocol of explosion reference pressure for designing and testing a flameproof enclosure.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.9 no.1
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• pp.112-124
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• 1999

The purposes of this study were to provide the data for composition of ethylene glycol ethers and 2-ethoxyethyl acetate(EEA) exposure assessment of workers in various industrial operations. In this study, 80 thinners were analyzed to identify their composition and the air concentration of 2-ethoxyethyl acetate(EEA) and urinary 2-ethoxyacetic acid(EAA) were measured. In this study the subjects were the total of 183 drawn from 98 workers who were occupationally exposed to EEA and 85 workers who were not. The results were as follows: 1. There were found average 4.2 components in each thinner. 2. There were 90 components(26.9%) in ethylene glycol ethers of total of 334 detected organic solvents 3. Ethoxyethyl acetate, ethoxyethanol, buthoxyethanol, methoxy-ethanol were found in 30(37.5%), 27(33.8%), 19(23.8%), 2thinners(2.5%), respectively and their contents were average 18.5%. 4. Benzene was found 8 thinners(10.0%) of the total 80 surveyed. 5. In the electronic painting workers EEA exposure concentration was the highest, as showed 2.88ppm(0.01~15.1ppm), cases of exceeded threshold limit value(TLV=5ppm) were 7(10.6%) workers among the total of 98 exposed workers. 6. The geometric mean of urinary EEA in exposed workers was 1.61 mg/gcreatinine, and was higher than that of workers who were not exposed. In the electronic painting workers and offset printers, the geometric mean of urinary EAA was the highest showing 2.8 mg/gcreatinine. 7. The correlation coefficient between urinary concentration of EAA and air concentration of EEA was 0.90(P<0.05). The present results suggest that composition of ethylene glycol ethers in thinners must be evaluated when industrial hygiene surveys and biological monitoring are performed.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.28 no.8
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• pp.331-336
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• 2016

This study presents a coolant density calculation device and its corresponding method by using a mass flowmeter and the LabVIEW program. The method can be easily measured with a mixture of coolant and by calculating the percentage of ethylene-glycol without additional investment. The cooling water is very important in a vehicle to protect the engine, and the cooling performance is affected by the mixture concentration and coolant density. The coolant density calculation device measures the mixed concentration in the anti-freeze cooling mixture made from distilled water and ethylene-glycol in real time with the mass flowmeter that is commonly attached to the radiator or heater core. The calculation program for the mixture concentration percentage was developed using the LabVIEW software. The correlation between experimental results and the calculation was conducted for a range of temperature from 40 to $90^{\circ}C$ and by varying the mixture ratio of distilled water and ethylene-glycol. As a result, the anti-freeze coolant concentration in the volume percentage is able to monitor the coolant density in a timely basis by implementing a mixture concentration calculation program without the need for additional equipment investment. The results of the calculation for the mixture concentration level show a maximum 2.7% deviation compared to the experimental results.

• Journal of the Korean Institute of Gas
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• v.1 no.1
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• pp.106-112
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• 1997

This study measured the ignition limits of methane-air, propane-air, ethylene-air, and hydrogen-air mixture gases by discharge spark of D.C. power resistive circuit. The used experimental device is the IEC type spark ignition test apparatus, it consists of explosion chamber and supply -exhaust system of mixture gas. Mixture gases (methane-air, propane-air, ethylene-air, and hydrogen-air) were put into explosion chamber of IEC type spark ignition test apparatus, then it was confirmed whether ignition was made by 3,200 times of discharge spark between tungsten electrode and cadmium electrode. The ignition limits were found by increasing or decreasing the value of current. For the exact experiment, the ignition sensitivity was calibrated before and after the experiment in each condition. The ignition limits were found by changing the value of concentration of each gas-air mixture in D.C. 24 [V] resistive circuit. As the result of experiment, it was found that the minimum ignition limit currents exist at the value of methane-air 8.3 [$Vol\%$], propane-air 5.25[$Vol\%$], ethylene-air 7.8 [$Vol\%$], and hydrogen-air 21[$Vol\%$] mixture gases. For each the minimum ignition concentration of gases, the relationships between voltage and minimum ignition current were found. The results are as follows. - The minimum ignition limits are decreasing in the order of methane, propane, ethylene, and hydrogen. - The value of ignition current is inversely proportional to the value of source voltage. - The minimum ignition limit currents increase sharply at more than 2 [A]. The reason is caused by overheating the electrode.