• Title/Summary/Keyword: Ethylene Recovery

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Fixation of Sericin of Silk Fabric by Epoxy Resin (Epoxy수지에 의한 견직물의 Sericin정착)

  • 문영배;남중희
    • Journal of Sericultural and Entomological Science
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    • v.26 no.2
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    • pp.16-25
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    • 1984
  • The sericin fixation of silk fabrics by epoxy resins was studied in the presence of aqueous salt solution in different solvents at the indicated temperature for the desired time. Heavy weight gains were obtained in the reaction with glycerol diglycidyl ether (EX-313) and ethylene glycol diglycidyl ether (EX-810) catalyzed by potassium thiocyanate in such solvents as carbon tetrachloride and p-chloroethylene. The obtained results were summarized as follows; 1) The tested resins were found similar in reaction behavior to silk fabric. The effect of fixation and weight gains was higher in EX-810 than EX-313. 2) The weight gains were increased with reaction time and temperature, and degumming ratio reached a constant value in 90 min at 70$^{\circ}C$. 3) The weight gains and the degumming ratio reached an equilibrium at 3-5% of epoxy concentration. 4) The weight gains were remarkably influenced and increased by the concentration of salt solution. The degumming ratio reached an equilibrium over 0.5N concentration of salt. 5) The weight gains were increased with the dipping time in gently-sloping. The degumming ratio reached an equilibrium over 15 min dipping. 6) The effect of sericin fixation of hydrophobic solvents, such as Carbon Tetrachloride, p-Chloroeth-ylene, Cyclohexane, Xylene and Toluene, was found suitable. 7) The effect of drying temperature was not remarkable on the weight gains and the degumming ratio. 8) There was a slight decrease in the moisture regain of sericin-fixed silk and it may be possible to maintain the moisture regain in the sericin-fixed silk by the epoxy resins. 9) The results on testing physical properties of sericin-fixed silk fabric were as follows; The crease recovery was almost not different from undegummed fabric, but inferior to degummed fabric. The tensile strength was improving in accordance with the effect of sericin fixation, either the elongation did.

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The Simulation and Control of the Reactive Distillation Process for Dimethylcarbonate(DMC) Production

  • Jang, Yong-Hee;Yang, Dae-Ryook
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.1215-1220
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    • 2004
  • Reactive distillation (RD) is a combination process where both separation and reaction are considered simultaneously in a single vessel. This kind of combination to enhance the overall performance is not a new attempt in the chemical engineering areas. The recovery of ammonia in the classic Solvay process for soda ash of the 1860s may be cited as probably the first commercial application of RD. The RD system has been used for a long time as a useful process and recently the importance of the RD is enlarged more and more. In addition to that, the application fields of RD are diversely diverged. To make the most of the characteristic of RD system, we must decide the best operating condition under which the process shows the most effective productivity and should decide the best control algorithm which satisfies an optimal operating condition. Phosgene which is a highly reactive chemical is used for the production of isocyanates and polycarbonates. Because it has high reactivity and toxicity, its utilization is increasingly burdened by growing safety measures to be adopted during its production. Dimethyl Carbonate (DMC) was proposed as a substitute of phosgene because it is non-toxic and environmentally benign chemical. In this study, RD is used for DMC production process and the transesterification is performed inside of column to produce DMC. In transesterification, the methanol and ethylene carbonate (EC) are used as the reactants. This process use homogeneous catalyst and the azeotrope exists between the reactant and product. Owing to azeotrope, we should use two distillation columns. For this DMC production process, we can suggest two configurations. One is EC excess process and the other is methanol excess process. From the comparison of steady state simulation results where the Naphtali-Sandholm algorithm is used, it showed the better performance to use the methanol excess process configuration than EC excess process. Then, the dynamic simulation was performed to be based on the steady state simulation results and the optimal control system was designed. In addition to that, the optimal operating condition was suggested from previous results.

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Sow Transfer of Cultured Embryos : Embryo Recovery, Oocyte Collection, IVM-IVF-IVC Treatment, Vitrification/Thaw, and Surgical and Nonsurgical Transfer

  • Kim, In-Doc;Ahn, Mi-Hyun;Hur, Tae-Young;Son, Dong-Soo;Hong, Moon-Pyo;Seok, Ho-Bong
    • Proceedings of the Korean Society of Developmental Biology Conference
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    • 2003.10a
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    • pp.128-128
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    • 2003
  • The aims of this study are 1) to test oocytes and embryos collected from in-vivo and in-vitro to achieving the valuable protocol by culturing, vitrifying and thawing of oocytes/embryos, and 2) to transfer them to recipient, and finally have resulted in pregnancies from recipient females after surgical or nonsurgical transfer. In vitro maturation and fertilization were performed according to the procedures of Funahashi et al. Fertilized oocytes were cultured in glucose-free NCSU 23 supplemented with 5 mM sodium pyruvate, 0.5 mM sodium lactate and 4 mg/ml bovine serum albumin for 2 days at 39$^{\circ}C$, and 10% fetal bovine serum was added to the culture medium thereafter. Embryos were treated with 7.5$\square$g/ml cytochalasin-B for 30 min, centrifuged at 13,000 ${\times}$ g for 13 min and then exposed sequentially to an ethylene glycol (EG) vitrification solution, aspirated into OPSs, and plunged/thawed into/from liquid nitrogen. In vivo embryos were surgically collected from three donors after Al. Forty-six embryos (18, 9 and 19 embryos, respectively) were washed 3 times in mPBS+10%FBS, followed treatments : cultured, centrifuged, vitrified, recovered and transferred to recipients as in vitro prepared embryos. Three recipients received surgically 34(control), 188 and 184 embryos (derived from abattoir), respectively. Another three recipients were received nonsurgically 150, 100 and 150 embryos, respectively. All recipient sows exhibited delayed returns to estrus. To our knowledge, these results suggest that required an improved techniques, more vigorous embryos preparation and cleaner uterous condition(use gilt).

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Mechanical Properties of Monodisperse Polymer Particles and Electroless Ni Plated Monodisperse Polymer Particles (단분산 가교고분자 미립자 및 그의 무전해 니켈도금체의 기계적 물성 연구)

  • Kim Dong-Ok;Jin Jeong-Hee;Shon Won-IL;Oh Seok-Heon
    • Polymer(Korea)
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    • v.30 no.4
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    • pp.332-337
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    • 2006
  • Monodisperse polymer particles were prepared via one-step seeded polymerization using PMMA seed particles and HDDA (or EGDMA) as crosslinking monomer. For the study, the effects of 1) the ratio of the absorbed monomer or monomer mixture to the seed polymer particles (swelling ratio), 2) the ratio of EGDMA in absorbed monomer mixture, 3) the dosage of initiator, and 4) electro less Ni plating on the variation of mechanical properties of monodisperse polymer particles, such as recovery rate, K-values, breaking strength and breaking displacement, were investigated by using MCT (micro compression test). It was observed that monomer swelling ratio influenced only breaking strength, but EGDMA ratio in monomer mixture, dosage of initiator and electroless Ni plating affected both K-values and breaking strength.

Preparation of a Novel PU-LMO Adsorbent by Immobilization of LMO on Polyurethane Foam for Recovery of Lithium Ions (폴리우레탄 폼에 LMO를 고정화하여 리튬이온 회수를 위한 새로운 PU-LMO 흡착제의 제조)

  • You, Hae-Na;Lee, Min-Gyu
    • Clean Technology
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    • v.20 no.3
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    • pp.277-282
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    • 2014
  • In this study, PU-LMO was made by immobilization of LMO on urethane foam (PU) with using an EVA as a binder. PU-LMO was characterized by using X-Ray Diffractometer (XRD) and Scanning Electron Microscopy (SEM). The optimal ratio of EVA/LMO for preparation of PU-LMO was 0.26 gEVA/gLMO. The adsorption of lithium ions by PU-LMO was found to follow the pseudo-second-order kinetic model. The equilibrium data fitted well with Langmuir isotherm model and the maximum removal capacity of lithium ions was 17.09 mg/g. The PU-LMO was found to have a remarkably high selectivity of lithium ions and high adsorption capacity because the distribution coefficient ($K_d$) of lithium ion was higher than those of other metal ions.

Surface Performance of Housing Materials and Profiles in AC Tracking Wheel Tests (AC 트래킹 휠 시험에서 하우징 재료 및 형상의 표면 성능)

  • Kim, Seung-Hyun;Noh, Yo-Han;Cheong, Jong-Hun;Cho, Han-Goo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.2
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    • pp.135-140
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    • 2020
  • An experimental study was conducted using the tracking wheel test (IEC 62217) method for evaluating the performance of insulator materials, in particular ethylene propylene diene monomer (EPDM) and silicone rubber. In addition, we studied the tracking characteristics resulting from applying the same method for the shape of the insulator housing, that is, the performance of regular and alternating sheds. The evaluation parameters were leakage current, surface characteristics, SEM, EDX, hydrophobicity, and temperature distribution; likewise, we applied the commercial frequency dry (and wet) flashover voltage test. We found that the regular shed had a greater leakage current than the alternating shed and that the recovery of the hydrophobicity in terms of rest time was greater than that of the EPDM in terms of leakage current. All of the regular-shed insulators of silicone rubber had tracking traces and choking on the sheath parting line, while the alternating shed showed only choking at the interface but no tracking traces. Therefore, it can be concluded that the commercial frequency wet flashover voltage of the silicone rubber with regular shed before and after the tracking wheel test is higher than that of the alternating shed.

Effects of Flooding Treatment on Physiological Characteristics of Rice Cultivars (수도 관수처리에 의한 생리적 특성의 품종간 차이)

  • 강양순;양의석;정연태;정근식
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.33 no.2
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    • pp.189-194
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    • 1988
  • To clarify the varietal differences of resistance to complete flooding, physiological characteristics in relation to flooding resistance in each growth stage of rice plants, the present study was carried out. The rate of survival after flooding at seeding stage of rice plants of the cultivar 'FR 13A' and Ind. X Jap. cultivars were 91.8% and 33.8% to 40%, respectively, while the Japonica varieties were completely dead. The tolerant varieties which has higher rate of survival showed the higher $O_2$ release, the higher catalase activity and lower peroxidase activity according to flooding treatment. Japonica type varieties showed the higher elongation of plant during flooding, lower recovery of flooding damage and the abrupt decrease of yield according to the increase of flooding periods in comparision to Ind. X Jap. crossed varieties when they were flooded at the active tillering stage. When rice plants were flooded at the booting stage, Ind. X Jap. crossed varieties had the higher photosynthesis, respiratory rate, root oxidizing power, ethylene evolution and lower yield reduction in comparision to japonica varieties.varieties.

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Development of Triboelectrostatic Separation Technique for Material Separation of EVA & PET Mixture Plastic Wastes (EVA와 PET 혼합(混合) 폐플라스틱의 재질분리(材質分離)를 위한 마찰하전형(摩擦荷電形) 정전선별(靜電選別) 기술개발(技術開發))

  • Jeon, Ho-Seok;Park, Chul-Hyun;Baek, Sang-Ho;Kim, Byoung-Gon;Kim, Hyung-Seok
    • Resources Recycling
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    • v.18 no.1
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    • pp.13-21
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    • 2009
  • A research on material separation of EVA and PET mixture plastic waste using a triboelectrostatic separator has been carried out. It was found that PP was the best charging material to give the highest charge on the surface of EVA and PET mixture plastics with an opposite polarity. Therefore, a charger of pipe line type using PP material was manufactured for separation of EVA and PET mixture plastic waste. At optimum test conditions that used PP cyclone charger developed in this study, we could separate out PET with a glade of 98.7% and a recovery of 89.7%.

Recycling of End-of-Life Photovoltaic Silicon Modules (사용 후 태양광 실리콘 모듈의 리싸이클링)

  • Kim, Joon Soo;Cho, Jae Young;Lee, Jae Kyung;Park, Areum;Park, Jin Hyuk;Yun, Hyun Mok;Jun, Yun-Su
    • Resources Recycling
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    • v.28 no.5
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    • pp.19-29
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    • 2019
  • Recently, it is increasing a amount of installized solar-cell rapidly, and waste Solar cell module are generated in according to the reduction of efficiency largely. Therefore, it is concerned at the environmental problems and recycling of valuable materials, greatly. The treatment processes of end-of-life photovoltaic modules are composed the disassembly of Aluminum frames, separation of Tempered glass, removal of Ethylene Vinyl Acetate and recovery of valuable Metals. For the efficient recycling, we are considered to the treatment technology seriously. And we are proposed on the general opinions according to the developing technology, EPR (Extended Producer Responsibility) problems and promotion plans for the activation of recycling industry.

A Study on Changes of Physico-Chemical Properties of Plow Layer Soil and its Response of Tobacco Growth under Poly Ethylene Film Mulching Condition. -2. Effect of Poly Ethylene Film Mulch on the Mineralization of Compound Fertilizer and Mobility of Mineralized Nutrients in the Plow Layer (연초피복재배(煙草被覆栽培)에서 작토층(作土層)의 이화학성(理化學性) 변화(變化)와 연초생장반응(煙草生長反應)에 관(關)한 연구(硏究) -2. 피복조건(被覆條件)이 시비(施肥)된 비료(肥料)의 무기화작용(無機化作用)과 무기화(無機化)된 양분(養分)의 작토층위별(作土層位別) 이동(移動)에 미치는 영향(影響))

  • Hong, Soon-Dal;Lee, Yun-Hwan;Kim, Jai-Joung;Cho, Seong-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.2
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    • pp.140-147
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    • 1985
  • This experiment was conducted in the field to investigate the effects of mulched condition on nutrient's mineralization and its mobility as affected by environmental changes (soil moisture and soil temperature) in the plow layer. 1. Nitrogen mineralization was faster owing to the prevention of evaporation and the increase of soil temperature in the poly ethylene mulched plot. As a result, nitrate form of nitrogen was much earlier available for plant in mulched plot than in non mulched plot. 2. Available $P_2O_5$ content in the plow layer was kept highest in the fertilized zone (10-20 cm depth) regardless of difference between mulched and non mulched condition, and was nearly constant without showing difference between planting and non planting of tobacco due to the lower availability of phosphorus by tobacco. 3. Potassium applied in the plow layer was remained a large quantity until the latter growth stage resulting in the lower recovery of potassium by tobacco. 4. Mineralized nutrients such as $NH_4-N$, $NO_3-N$, and K in the plow layer of mulched plot were transported from the fertilized layer (10-20 cm depth) and accumulated to the surface layer (0-10 cm depth) as the growing time goes by, but those in non mulched plot were distributed to the deeper layer. 5. Mobility of available nutrients in the plow layer was If order as $NO_3-N$ $$\geq_-$$ $NH_4-N$ > K > available $P_2O_5$. 6. Leaching degree of mineralized nutrients in the mulched plot was much lower than in the non mulched plot.

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