• Title/Summary/Keyword: Ether ether sulfone unit

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Synthesis of Aminated Poly(ether sulfone) as Anion Exchanger and its NO Gas Adsorption (Aminated Poly(ether sulfone)의 합성과 NO 가스의 흡착특성)

  • Son, W.K.;Park, S.G.
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.857-862
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    • 1999
  • Aminated poly(ether sulfone)(APES) was prepared by amination of nitrated poly(ether sulfone)(NPES) after poly(ether sulfone)(PES) was nitrated with mixed acid of nitric acid and sulfuric acid(sulfuric acid is a catalyst). As a results of the FT-IR spectrum analysis, the nitration of PES was confirmed by the bands of asymmetric stretching and symmetric stretching of $NO_2$ group at 1537 and $1351cm^{-1}$, respectively. Also when the NPES was aminated, it was disappeared to absorbance peaks of $NO_2$ group. And It was confirmed by the bands of asymmetric stretching and symmetric stretching of $NH_2$ group at 3470 and $3374cm^{-1}$, respectively. The optimum condition of the nitration on PES(5 g; 21.55 mmol.) was 12 hr of reaction time, $120^{\circ}C$ of reaction temperature, nitric acid of 28.00 mmol. and sulfuric acid of 52.00 mmol. As a result of the elemental analysis of APES, reapeating unit per amine groups were induced to 0.89. The adsorption rate of NO gas was lower than that of silica gel and active carbon. But the adsorption capacity of NO gas was higher than that of these. When the APES was absorbed to NO gas, the chemical adsorption rate was lower than the physical adsorption rate. But the chemical adsorption capacity of it was higher than physical adsorption capacity.

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Synthesis and Characterization of Mono-sulfonated Poly(ether sulfone) for a Fuel Cell Application (고분자 전해질 연료전지용 Sulfonated Poly(ether sulfone)의 합성 및 특성 평가)

  • Krishnan N.N.;Kim H.-J.;Prasanna M.;Cho E.-A.;Oh I.-H.;Hong S.-A.;Lim T.-H.
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.235-238
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    • 2005
  • Sulfonated poly(ether sulfone) copolymers (PESs) were synthesized using hydroquinone 2-potassium sulfonate (HPS) with other monomers (bisphenol A and 4-fluorophenyl sulfone). PESs with different $mole\%$ of hydrophilic group were prepared by changing the mole ratio of HPS in the polymerization reaction. The chemical structure and the thermal stability of these polymers were characterized by using $^1H-NMR$, FT-IR and TGA techniques. The PES 60 membrane, which has $60 mole\%$ of HPS unit in the polymer backbone, has a proton conductivity of 0.091 S/cm and good insolubility in boiling water. The TGA showed that PES 60 was stable up to $272^{\circ}C$ with a char yield of about $29\%\;at\;900^{\circ}C\;under\;N_2$ atmosphere. To investigate the single cell performance, the catalyst coated PES 60 membrane was used and a single cell test was carried out using $H_2/O_2$ gases as fuel and oxidant at various temperatures. We observed that the cell performance was enhanced by increasing the cell temperature. A current density of $1400 mA/cm^2$ at 0.60 V was obtained at $70^{\circ}C$.

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Synthesis and Characterization of Sulfonated Poly (Arylene ether Sulfone) Multi-Block Copolymer for PEMFC Application (고분자연료전지용 설폰산화 폴리아릴렌에테르설폰 멀티블록공중합체의 합성 및 특성 분석)

  • Ahn, Jinju;Choi, Young-Woo;Yang, Tae-Hyun;Kim, Chang-Soo;Bae, Byungchan
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.461-467
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    • 2012
  • Multi-block sulfonated poly (arylene ether sulfone) (SPES) membranes were synthesized by post-sulfonation and its properties characterized. Two types of oligomers, F-terminated and OH-terminated telechelic oligomers, were synthesized by controlling the feed ratio of dihydroxyl- and difluoro-monomers. Their number of repeating unit (X and Y) was analyzed by GPC and $^1H$ NMR. Copolymerization with F-terminated and OH-terminated telechelic oligomers via nucleophilic aromatic substitution, gave high-molecular-weight multi-block PESs. Each block length was controlled to have different values with X5Y10, X10Y10, X20Y10 and X20Y20. Successful polymerization and its successful sulfonation was confirmed by GPC and $^1H$ NMR. RH dependence of proton conductivity of multi-block SPES membranes was comparable to that of Nafion 212 at high RH conditions.

Effect of Linkage Groups on the Properties of Semi-flexible Liquid Crystalline Polymers (연결기가 반 유연성 액정중합체의 물성에 미치는 영향)

  • Park, Jong-Ryul;Yoon, Doo-Soo;Bang, Moon-Soo
    • Applied Chemistry for Engineering
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    • v.26 no.4
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    • pp.445-451
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    • 2015
  • Semi-flexible liquid crystalline polymers containing a mesogenic group and an octamethylene flexible spacer in the main chain were synthesized by solution polycondensation. The mesogenic group in the polymer consists of four aromatic rings connected by ester and ketone, ether, sulfide, methylene, sulfone, or isopropylidene linkage groups. This paper discusses effects of the central linker of the mesogenic group on polymer properties. The structures and properties of synthesized polymers were investigated by $^1H$-NMR, FT-IR, differential scanning calorimeter (DSC), thermogravimetric analyzer (TGA), X-ray diffractometer (XRD), and polarizing optical microscope (POM). Polymers having bent linkage groups exhibited low thermal transition temperatures, narrow mesophase temperature ranges, low liquid crystallinity, and good solubilities in organic solvents, while those having bulky linkage groups were amorphous and exhibited high glass transition temperatures.