• 제목/요약/키워드: Equilibrium stage

검색결과 198건 처리시간 0.026초

금속수소화물 수소저장 용기 내부의 열 및 물질전달 현상에 대한 수치적 연구(I) - $LaNi_5$ 베드를 이용한 수소 흡장반응 해석 모델 개발 (Numerical analysis of the coupled heat and mass transfer phenomena in a metal hydride hydrogen storage reactor(I) - Model development of analyzation for hydrogen absorption reaction using the $LaNi_5$ bed)

  • 남진무;주현철
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.225.1-225.1
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    • 2010
  • Within recent years attention has been focused on the method of hydrogen storage using metal hydride reactor due to its high energy density, durability, safety and low operating pressure. In this paper, a numerical study is carried out to investigate the coupled heat and mass transfer process for absorption in a cylindrical metal hydride hydrogen storage reactor using a newly developed model. The simulation results demonstrate the evolution of temperature, equilibrium pressure, H/M atomic ratio and velocity distribution as time goes by. Initially, hydrogen is absorbed earlier from near the wall which sets the cooling boundary condition owing to that absorption process is exothermic reaction. Temperature increases rapidly in entire region at the beginning stage due to the initial low temperature and enough metal surface for hydrogen absorption. As time goes by, temperature decreases slowly from the wall region due to the better heat removal. Equilibrium pressure distribution appears similarly with temperature distribution for reasons of the function of temperature. This work provides a detailed insight into the mechanism and corresponding physicochemical phenomena in the reactor during the hydrogen absorption process.

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Equilibrium Removal of Pb (II) Ions from Aqueous Solution onto Oxidized-KOH-Activated Carbons

  • Fathy, Nady A.;El-Sherif, Iman Y.
    • Carbon letters
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    • 제12권1호
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    • pp.1-7
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    • 2011
  • In the present study, the removal of Pb (II) ions on oxidized activated carbons (ACs) was investigated. ACs were derived from activation of indigenous cotton stalks waste with potassium hydroxide (KOH) in two-stage process. The KOH-ACs were subjected to liquid-phase oxidation with hot $HNO_3$ and one untreated sample was included for comparison. The obtained carbons were characterized by Fourier transform infrared (FTIR), slurry pH and $N_2$-adsorption at 77 K, respectively. Adsorption capacity of Pb (II) ions on the resultant carbons was determined by batch equilibrium experiments. The experimental results indicated that the oxidation with nitric acid was associated with a significant increase in mass of yield as well as a remarkable reduction in internal porosity as compared to the untreated carbon. The AC-800N revealed higher adsorption capacity than that of AC-800, although the former sample exhibited low surface area and micropore volume. It was observed that the adsorption capacity enhancement attributed to pore widening, the generation of oxygen functional groups and potassium containing compounds leading to cation-exchange on the carbon surface. These results show that the oxidized carbons represented prospective adsorbents for enhancing the removal of heavy metals from wastewater.

Dynamic Analysis of Topside Module in Lifting Installation Phase

  • Lee, Jong-Hyun
    • 한국해양공학회지
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    • 제25권4호
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    • pp.7-11
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    • 2011
  • The installation phase for a topside module suggested can be divided into 9 stages, which include start, pre-lifting, lifting, lifted, rotating, positioning, lowering, mating, and end of installation. The transfer of the topside module from a transport barge to a crane vessel takes place in the first three stages, from start to lifting, while the transfer of the module onto a floating spar hull occurs in the last three stages, from lowering to the end. The coupled multi-body motions are calculated in both calm water and in irregular waves with significant wave height (1.52m), with suggested force equilibrium diagrams. The effects of the hydrodynamic interactions between the crane vessel and barge during the lifting stage have been considered. The internal forces caused by the load transfer and ballasting are derived for the lifting phases. The results of these internal forces for the calm water condition are compared with those in the irregular sea condition. Although the effect of pitch motion on the relative vertical motion between the deck of the floating structure and the topside module is significant in the lifting phases, the internal force induced pitch motion is too small to show its influence. However, the effect of the internal force on the wave-induced heave responses in the lifting phases is noticeable in the irregular sea condition because the transfer mass-induced draught changes in the floating structure are observed to have higher amplitudes than the external force induced responses.

Analysis of Revenue-Sharing Contracts for Service Facilities

  • Yeh, Ruey Huei;Lin, Yi-Fang
    • Industrial Engineering and Management Systems
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    • 제8권4호
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    • pp.221-227
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    • 2009
  • There are customer services jointly provided by two facilities so that each customer will complete the course made up of both facilities' sub-services. The two facilities are assumed invested respectively by an infrastructure owner and one subordinate facility owner, whose partnership is built on their capital investments. This paper presents a mathematical model of Stackelberg competition between the two facility owners to derive their optimal Nash equilibrium. In this study, each facility owner's profit is consisted of fixed revenue fractions of sold services, operating costs (including depreciation cost) and maintenance costs of her facility. The maintenance costs of one facility are incurred both by failures and deterioration due to usage. Moreover, for both facilities, failures are rectified immediately by minimal repairs and preventive maintenance is carried out at a fixed time epoch. Additional assumptions are also employed to develop the model such as customer arrivals are manipulated to follow a Poisson process, and each facility's lifetime is independently Weibull-distributed. The Stackelberg game proceeds as follows. At the first stage of decision making process, the infrastructure owner (acting as a leader) decides the allocation of revenue shares based on her self-interest. After observing the allocation of revenue shares, the subordinate facility owner determines her own optimal price of services. This paper investigates actions and reactions of the two partners in the system. Then analytical conditions are proposed to achieve a unique optimal Nash equilibrium. Finally, some suggestions for further research are discussed.

재 점화가 있는 가압식 추진기관의 액체산소 탱크 가압 헬륨량 산정 (Helium Quantity Estimation for LOx Tank Pressurization of a Restartable Pressure-fed Propulsion System)

  • 조규식;정영석;오승협
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2011년도 제37회 추계학술대회논문집
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    • pp.201-205
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    • 2011
  • 극저온 추진제 탱크 속에서 가압 가스는 열손실에 의해 수축하고 추진제는 기화한다. 재 점화가 있는 추진기관의 경우 무추력 비행구간에서 극저온 추진제가 가압가스와 넓은 표면적으로 접촉하기 때문에 이러한 현상이 증대된다. 가압 가스량을 산정함에 있어 이러한 탱크 내부 열 물질 전달 현상을 고려하여야 한다. 무추력 비행구간에서 열 물질 전달 준 평형상태에 도달한다는 가정 하에 평형압력 계산절차를 제시하였다. 이를 적용하여 Falcon-1 발사체 2단에 탑재된 헬륨량을 산정하였다.

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자유낙하수맥 하류부에서의 세굴에 관한 실험적 연구 (Experimental Study on Downstream Local Scour of Free-Falling Jet)

  • 윤세의;이종태
    • 물과 미래
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    • 제28권4호
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    • pp.147-154
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    • 1995
  • 본 연구에서는 특별한 에너지 감세를 위한 수공구조물이 설치되지 않은 중 소규모 단락부 하류부에서 자유낙하하는 수맥으로 인하여 발생되는 비점착성 하상재료의 세굴특성을 수리모형실험을 통하여 분석하였다. 단락수맥 하류부에서의 세굴특성을 분석하기 위하여 먼저 직사각형 단락수맥의 흐름특성을 조사하였으며, 하상재료, 유량, 하류수심을 변화시키면서 세굴공의 직하류부에 생성되는 둔덕(mound)의 유무로 인한 세굴특성을 비교 분석하였다. 평형세굴심 뿐만 아니라 둔덕의 높이도 밀도 후르드수의 함수로 표시되며, 밀도 후르드수는 다른 무차원량 보다 평형세굴심과 비교적 깊은 관계가 있는 것을 확인하였다. 단락부 하류부 하상 보호공의 설계시 둔덕의 영향을 고려해야 한다는 결론을 얻었다.

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유기물(有機物)의 시용(施用)이 토양(土壤)의 화학적(化學的) 성질(性質)에 미치는 영향(影響) (Effects of Organic Materials on Soil Chemical Properties)

  • 오왕근
    • 한국토양비료학회지
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    • 제11권3호
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    • pp.161-174
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    • 1979
  • A review was made on the effect of organic matter application on the chemical characteristics of soils such as pH, solubilities of minerals, and cation exchange capacity mainly at flooded rice soils. The review can be summarized as follows: 1. Application of organic material such as rice straw and compost in flooded rice soil leads to a temporary lowering of soil pH at the earlier stage of soil reduction, due to the production of various organic acids and carbonic acid. This temporary lowered pH is replaced with the production of alkaline substances such as ammonia as the reduction of soil proceeds. 2. Incorporation of organic materials intensifies the ferrous iron, dissolving various minerals, virtually to the increase in electrical conductivity of soils. 3. Organic materials also play an important role in dissolving soil minerals through the production of various chelating agents. 4. Application of soil organic matter significantly increases cation exchange capacity of soils. 5. Continuous application of rice straw or compost leads to the increase in soil organic matter content to some extent, up to the level of equilibrium. In soils low in organic matter the equilibrium level is attained with five years continuous application of compost. 6. The manner of chemical fertilizer application influences the accumulation of organic matter applied in soils. Low levels of fertilization lowers the accumulation while high levels of fertilization accerelates the accumulation.

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버섯의 건조특성(乾燥特性)에 관한 연구 (Drying Characteristics of Mushroom)

  • 송성규;고학균;이정호
    • Journal of Biosystems Engineering
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    • 제19권2호
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    • pp.112-123
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    • 1994
  • At present, no appropriate drying conditions can be found for the heated-air drying of mushroom in Korea. Usually, mushroom is being dried at the temperature range of 40 to $50^{\circ}C$ until the moisture content reaches 10~13% (wb). However, drying characteristics of the mushroom should be investigated for quality improvement and efficient drying operation of the mushroom. The results of this study may be summarized as follows ; 1. The effect of air temperature on the rate of drying was greater than that of relative humidity for drying of mushroom, and the rate of drying was increased with increase in the air temperature. 2. Drying rate for Shiitake mushroom showed falling-rate period of drying without constant-rate period of drying. Drying rate for Oyster mushroom showed a short constant-rate period at the initial stage of drying process, and followed by falling-rate period of drying. 3. Exponential and App.-Diffusion models were found to describe well the drying process of Shiitake mushroom. Exponential and Thompson models for Oyster mushroom in which Thompson model was the most suitable for Oyster mushroom. 4. The equilibrium moisture content of the mushroom decreased with decrease in the air temperature and increase in the relative humidity. In room condition($20^{\circ}C$, 54% RH), the calculated values of the equilibrium moisture content showed 11.17% for Shiitake mushroom and 13.19% for Oyster mushroom, respectively.

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陽이온 交換한 天然 제올라이트에 依한 有機黃化合物의 液相吸着 特性 (Liquid Phase Adsorption Properties of Organo Surfur Compounds on Cation Exchanged Natural Zeolites)

  • 김종택;허남호
    • 대한화학회지
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    • 제28권3호
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    • pp.194-202
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    • 1984
  • 陽이온 交換한 天然제올라이트에 依한 有機黃化合物의 液相吸着特性을 考察하였다. 平衡吸着量은 天然제올라이트의 交換한 陽이온과 吸着質인 有機黃化合物의 構造에 影響을 받고 있음을 알 수 있었다. 또한 平衡吸着量은 메르캅탄(mercaptane), 설파이드(sulfide), 디설파이드(disulfide), 치오펜(thiopen) 順으로 減小하였으며, 치오펜 誘導體의 경우는 ${\pi}$ 電子가 많아짐에 따라 吸着能은 교환 이온의 polarizing power에 比例하였다. 吸着速度로부터 有機黃化合物의 吸着은 pore 내의 擴散이 律速段階임을 알수 있었고, 水分과 같은 작은 吸着質은 micro pore에 吸着이 일어나는 反面, 有機黃化合物은 transitional-pore에 吸着이 일어났다.

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Modelling of strains in reinforced concrete flexural members using alpha-stable distribution

  • Rao, K. Balaji;Anoop, M.B.;Kesavan, K.;Balasubramanian, S.R.;Ravisankar, K.;Iyer, Nagesh R.
    • Computers and Concrete
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    • 제11권5호
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    • pp.411-440
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    • 2013
  • Large fluctuations in surface strain at the level of steel are expected in reinforced concrete flexural members at a given stage of loading due to the emergent structure (emergence of new crack patterns). This has been identified in developing deterministic constitutive models for finite element applications in Ibrahimbegovic et al. (2010). The aim of this paper is to identify a suitable probability distribution for describing the large deviations at far from equilibrium points due to emergent structures, based on phenomenological, thermodynamic and statistical considerations. Motivated by the investigations reported by Prigogine (1978) and Rubi (2008), distributions with heavy tails (namely, alpha-stable distributions) are proposed for modeling the variations in strain in reinforced concrete flexural members to account for the large fluctuations. The applicability of alpha-stable distributions at or in the neighborhood of far from equilibrium points is examined based on the results obtained from carefully planned experimental investigations, on seven reinforced concrete flexural members. It is found that alpha-stable distribution performs better than normal distribution for modeling the observed surface strains in reinforced concrete flexural members at these points.