• Title/Summary/Keyword: Equilibrium point

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Application of Pseud-superplastic PM Process to Ti-Al Intermetallic Compound for MEMS Parts

  • Miyano, Naoki;Kumagai, Yusuke;Yoshimoto, Masayoshi;Nishimura, Yuta;Tanaka, Shigeo;Ameyama, Kei
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1292-1293
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    • 2006
  • A non-equilibrium powder metallurgy processing such as an MA/SPS (Mechanical Alloying / Spark Plasma Sintering) process is examined in a Ti-48moll%Al. TiAl intermetallic compound is a potential light-weight/high-temperature structural material. One of the major problems, however, limiting the practical use of the material is its poor workability. From this point, the powder metallurgy (PM) processing route has been attractive alternative of the conventional processing for such material The MA/SPS process is able to apply to a LIGA process. Optimization of the pseudo-superplasticity enables to fabricate micro-parts made of fine grained ceramics composites of TiAl by the LIGA process.

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Thermodynamic Elucidation of Binding Isotherms for Hemoglobin & Globin of Human and Bovine upon Interaction with Dodecyl Trimethyl Ammonium Bromide

  • Bordbar, A.K.;Nasehzadeh, A.;Ajloo, D.;Omidiyan, K.;Naghibi, H.;Mehrabi, M.;Khajehpour, H.;Rezaei-Tavirani, M.;Moosavi-Movahedi, A.A.
    • Bulletin of the Korean Chemical Society
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    • v.23 no.8
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    • pp.1073-1077
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    • 2002
  • Binding of dodecyl trimethylammonium bromide (DTAB) to human and bovine hemoglobin and globin samples has been investigated in 50 mM glycine buffer pH = 10, I = 0.0318 and 300 K by equilibrium dialysis and temperature scanning spectrophotometry techniques and method for calculation of average hydrophobicity. The binding data has been analyzed, in terms of binding capacity concept $({\theta})$, Hill coefficient (nH) and intrinsic Gibbs free energy of binding $({\Delta}Gbv).$ The results of binding data, melting point (Tm) and average hydrophobicity show that human hemoglobin has more structural stability than bovine hemoglobin sample. Moreover the results of binding data analysis represent the systems with two and one sets of binding sites for hemoglobin and globin, respectively. It seems that the destabilization of hemoglobin structure due to removal of heme group, is responsible of such behavior. The results indicating the removal of heme group from hemoglobin caused the depletion of first binding set as an electrostatic site upon interaction with DTAB and exposing the hydrophobic patches for protein.

Nonlinear Analysis of RC Beams under Cyclic Loading Based on Moment-Curvature Relationship. (모멘트-곡률 관계에 기초한 반복하중을 받는 철근콘크리트 보의 비선형 해석)

  • 곽효경;김선필
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2000.10a
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    • pp.190-197
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    • 2000
  • A moment-curvature relationship to simulate the behavior of reinforced concrete beam under cyclic loading is introduced. Unlike previous moment-curvature models and the layered section approach, the proposed model takes into consideration the bond-slip effect by using monotonic moment-curvature relationship constructed on the basis of the bond-slip relation and corresponding equilibrium equation at each nodal point. In addition, the use of curved unloading and reloading branches inferred from the stress-strain relation of steel gives more exact numerical result. The advantages of the proposed model, comparing to layered section approach, may be on the reduction in calculation time and memory space in case of its application to large structures. The modification of the moment-curvature relation to reflect the fixed-end rotation and pinching effect is also introduced. Finally, correlation studies between analytical results and experimental studies are conducted to establish the validity of the proposed model.

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Non-Linear Behavior of Tapered Beams with Clamped-Roller Ends, subjected to a Concentrated Load (집중하중을 받는 변단면 고정-이동지점 보의 비선형 거동)

  • 이병구;이종국;최규문;김무영
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2000.10a
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    • pp.201-208
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    • 2000
  • This paper explores the non-linear behavior of tapered beam subjected to a floating concentrated load. For applying the Bernoulli-Euler beam theory to this beam, the bending moment at any point of elastica is obtained from the final equilibrium state. By using the bending moment equation and the Bernoulli-Euler beam theory, the differential equations governing the elastica of clamped-roller beam are derived, and solved numerically. Three kinds of tapered beam types are considered. The numerical results of the non-linear behavior obtained in this study are agreed quite well to the results obtained from the laboratory-scale experiments.

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Nonlinear Analysis of RC Columns under Cyclic Loading Based on Moment-Curvature Relationship (반복하중을 받는 RC기둥의 비선형 해석을 위한 모멘트-곡률 관계의 개발)

  • 곽효경;김선필
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2002.04a
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    • pp.3-11
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    • 2002
  • A moment-curvature relationship to simulate the behavior of reinforced concrete (RC) columns under cyclic loading is introduced. Unlike previous moment-curvature models and the layered section approach, the unposed model takes into account the bond-slip effect by using a monotonic moment-curvature relationship constructed on the basis of the bond-slip relation and corresponding equilibrium equation at each nodal point. In addition, the use of curved unloading and reloading branches inferred from the stress-strain relation of steel gives more exact numerical result. The pinching enact caused by axial force is considered with an assumption that the absorbing energy corresponding to any deformation level maintains constant regardless of the magnitude of applied axial force. The advantages of the proposed model, comparing tn layered section approach, may be on the reduction in calculation time and memory space in case of its application to large structures.. Finally, correlation studies between analytical results and experimental studies are conducted to establish the validity of the proposed mood.

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A Study of Germanium Substrate Vacancy Clustering Formation using Monte Carlo Method (Monte Carlo방법을 이용한 Germanium 기판의 결공형 클러스터링 형성에 대한 연구)

  • Lee, Jun-Ha
    • Journal of the Semiconductor & Display Technology
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    • v.10 no.2
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    • pp.45-48
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    • 2011
  • In this paper, vacancy clustering formation and diffusion of germanium substrate was studied. The analysis method was adopted Monte Carlo method. At temperatures higher than melting point, fewer clusters formed, but there was less variation in the number of clusters than at lower temperatures, as the time increased. Equilibrium diffusivities in the clustering region were $10^2$ lower than those of free vacancies in the initial stage of kinetic lattice Monte Carlo simulations. They were expressed according to three temperature regimes: at temperatures above 1,100 K, at temperatures of 1,100-900 K, and at temperatures below 900 K. The effective mean migration energy, 1.1 eV, closely coincided with that of the 1.0-1.2 eV in experiments.

Phase Equilibria Measurement of Binary Mixture for the Propoxylated Neopentyl Glycol Diacrylate in Supercritical Carbon Dioxide

  • Byun, Hun-Soo
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.206-212
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    • 2016
  • Experimental data are reported on the phase equilibrium of propoxylated neopentyl glycol diacrylate in supercritical carbon dioxide. Phase equilibria data were measured in static method at a temperature of (313.2, 333.2, 353.2, 373.2 and 393.2) K and at pressures up to 27.82 MPa. At a constant pressure, the solubility of propoxylated neopentyl glycol diacrylate for the (carbon dioxide + propoxylated neopentyl glycol diacrylate) system increases as temperature increases. The (carbon dioxide + propoxylated neopentyl glycol diacrylate) system exhibits type-I phase behavior. The experimental result for the (carbon dioxide + propoxylated neopentyl glycol diacrylate) system is correlated with Peng-Robinson equation of state using mixing rule. The critical property of propoxylated neopentyl glycol diacrylate is predicted with Joback and Lyderson method.

Non-Linear Behavior of Tapered Simple Beam with a Floating Concentrated Load (변화위치 집중하중을 받는 변단면 단순보의 비선형 거동)

  • 이병구
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.42 no.2
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    • pp.108-114
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    • 2000
  • This paper explores the non-linear behavior of tapered beam subjected to a floating concentration load. For applying the Bernoulli-Euler beam theory to this beam, the bending moment at any point of elastical is obtained from the final equilibrium stage. By using the bending moment equation and the Bernoulli-Euler beam theory, the differential equations governing the elastica of simple beam are derived , and solved numberically . Three kinds of tapered beam types are considered . The numerical results of the non-linear behavior obtained in this study are agreed quite well to the results obtained from the laboratory-scale experiments.

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Purification and Structural Studies on Human Pro-ghrelin

  • Yun, Ji-Hye;Lee, Jee-Won;Lee, Weon-Tae
    • Journal of the Korean Magnetic Resonance Society
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    • v.12 no.1
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    • pp.40-50
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    • 2008
  • Ghrelin is a unique peptide hormone that releases growth factor and it stimulates appetite. It comes from pre pro-ghrelin by the post translational modification process and its innate functions are known as food up-take and the growth hormone regulation. Therefore, the structural information of ghrelin precursor is of importance in understanding it function. From our results, we found that the solution structure of ghrelin is mostly random coil conformation at neutral pH value and the structural population changes with pH environments. Data from circular dichroism in different TFE concentrations revealed that the secondary structure changes from random coil to a-helix and the isodichroic point is observed at 202nm, implying that two equilibrium states exist between random coil and helical structure.

Control-to-output Transfer Function of the Open-loop Step-up Converter in CCM Operation

  • Wang, Faqiang;Ma, Xikui
    • Journal of Electrical Engineering and Technology
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    • v.9 no.5
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    • pp.1562-1568
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    • 2014
  • Based on the average method and the geometrical technique to calculate the average value, the average model of the open-loop step-up converter in CCM operation is established. The DC equilibrium point and corresponding small signal model is derived. The control-to-output transfer function is presented and analyzed. The theoretical analysis and PSIM simulations shows that the control-to-output transfer function includes not only the DC input voltage and the DC duty cycle, but also the two inductors, the two energy-transferring capacitors, the switching frequency and the load. Finally, the hardware circuit is designed, and the circuit experimental results are given to confirm the effectiveness of theoretical derivations and analysis.